Chemistry of Fe-Ti oxide minerals in the Hobenzan granitic complex,SW Japan: Subsolidus reduction in relation to base metal mineralization     

K. Nakashima 《Mineralogy and Petrology》1996,58(1-2):51-69

Summary The mineralized stock of the Hobenzan granitic complex is composed of tonalite and a continuous differentiation series of biotite-hornblende granodiorite, hornblende biotite granite and biotite granite. Texture and mineral chemistry of the Fe-Ti oxide minerals in the Hobenzan granitic complex exhibit two different processes of magma evolution: one is an oxyexsolution process related to the magmatic and high temperature subsolidus stage, and the other is a reduction process of consecutive subsolidus stage. Rocks distributed in the northern part of the granitic complex preserve well the oxyexsolution process and show higher magnetic susceptibility, whereas those in the southern part of the complex, record the reduction process and show lower magnetic susceptibility.The magnetite-ilmenite geothermometer indicates temperatures of ca. 730°C for the oxide pairs of the early stage. Oxygen fugacity of one to three orders of magnitude higher than the annite-sanidine-magnetite (ASM) univariant curve, and an aqueous sulfur composition,fSO₂/fH₂S, of around 1.0 is indicated. This first stage corresponds to the crystallization of phenocrystic hornblende and plagioclase at depth. At about 700°C crystallization changed to biotite, K-feldspar and quartz, and continued to about 600°C. ThefO₂ during this second stage is buffered by the ASM assemblage. This second stage defines the oxyexsolution process. Below about 600°C, a reduction process, caused by assimilation of carbonaceous matter of country rocks, overprinted the southern part of the complex. Oxide pairs show that thefO₂ is about four orders of magnitude lower than the ASM univariant curve, andfSO₂/fH₂S is 10^–8.0 or less at 550°C for this reduced assemblage. The drastic change in composition of sulfur-bearing aqueous species may be one of the principal factors allowing base metal mineralization.

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Chemismus von Fe-Ti Oxiden des Hobenzan Granitkomplexes, SW Japan: Subsolidus Reduktion und ihre Beziehung zu metallischen Vererzungen

Zusammenfassung Der mineralisierte Hobenzan Granitkomplex setzt sich aus Tonaliten und einer kontinuierlichen Differentiationsserie, bestehend aus Biotit-Hornblende-Granodioriten, Hornblende-Biotit-Graniten und Biotit-Graniten, zusammen. Die Texturen und die Mineralchemie der Fe-Ti Oxide belegen zwei unterschiedliche Prozesse bei der Entwicklung des Hobenzan Granitkomplexes: einerseits einen Oxyexsolution-Prozeß, während des magmatischen und hochtemperierten Subsolidus-Stadiums, andererseits einen Reduktionsprozeß während des tiefertemperierten Subsolidus-Stadiums. Gesteine im nördlichen Hobenzan Komplex belegen vor allem den Oxyexsolution Prozeß und zeigen höhere magnetische Suszeptibilität, während jene im südlichen Teil den Reduktionsprozeß widerspiegeln und niedrigere magnetische Suszeptibilität zeigen.Das Magnetit-Ilmenit Geothermometer ergab Temperaturen von ca. 730°C für Oxidpaare des Frühstadiums. Die Sauerstoff Fugazität liegt um eine bis drei Größenordnungen über der univarianten Reaktionskurve Annit-Sanidin-Magnetit (ASM), und dasfSO₂/fH₂S Verhältnis der wässrigen Schwefelkomplexe bei ca. 1.0. Dieses Frühstadium korrespondiert mit der Kristallisation von Horblende und Plagioklas im Magma in größerer Tiefe. Ab ca. 700°C erfolgt die Kristallisation von Biotit, Alkalifeldspat und Quarz bis etwa 600°C, wobeifO₂ durch die ASM Mineralassoziation gepuffert wird. Dieses zweite Stadium wird als Oxyexsolution Prozeß beschrieben. Unter 600°C erfolgte eine Reduktion durch Assimilation von kohlenstoffreichem Material vor allem im südlichen Teil des Komplexes. Oxidpaare dieses Stadiums belegen, daßfO₂ um etwa vier Größenordnungen unterhalb des ASM Puffers liegt, undfSO₂/fH₂S ist 10^–8 bei 550°C. Die dramatische Änderung in der Zusammensetzung der Schwefelkomplexe in den Lösungen wird als der Hauptfaktor für die Bildung der Erzmineralisationen angesehen.

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Oxygen isotope evolution of the Lake Owyhee volcanic field,Oregon, and implications for the low-δ18O magmatism of the Snake River Plain–Yellowstone hotspot and other low-δ18O large igneous provinces     

Tyler B. Blum  Kouki Kitajima  Daisuke Nakashima  Ariel Strickland  Michael J. Spicuzza  John W. Valley 《Contributions to Mineralogy and Petrology》2016,171(11):92

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Effect of oxidation state on Bi mineral speciation in oxidized and reduced granitoids from the Uetsu region,NE Japan     

Yuya Izumino  Teruyuki Maruoka  Kazuo Nakashima 《Mineralium Deposita》2016,51(5):603-618

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The Cretaceous Ofuku Pluton and Its Relation to Mineralization in the Western Akiyoshi Plateau,Yamaguchi Prefecture,Japan          下载免费PDF全文

Yuka Sasaki  Teruyoshi Imaoka  Mariko Nagashima  Kazuo Nakashima  Takafumi Sonehara  Koshi Yagi  Tetsumaru Itaya 《Resource Geology》2016,66(2):85-113

The relationship between the magmatism of the Cretaceous Ofuku pluton and mineralization in and around the Akiyoshi Plateau, Yamaguchi Prefecture, Japan was investigated using a combination of field observation, petrographic and geochemical analyses, K–Ar geochronology, and fluid inclusion data. The Ofuku pluton has a surface area of 1.5 × 1.0 km, and was intruded into the Paleozoic accretionary complexes of the Akiyoshi Limestone, Ota Group and Tsunemori Formation in the western part of the Akiyoshi Plateau. The pluton belongs to the ilmenite‐series and is zoned, consisting mainly of early tonalite and granodiorite that share a gradational contact, and later granite and aplite that intruded the tonalite and granodiorite. Harker diagrams show that the Ofuku pluton has intermediate to silicic compositions ranging from 60.4 to 77.9 wt.% SiO₂, but a compositional gap exists between 70.5 to 73.4 wt.% SiO₂ (anhydrous basis). Modal and chemical variations indicate that the assumed parental magma is tonalitic. Quantitative models of fractional crystallization based on mass balance calculations and the Rayleigh fractionation model using major and trace element data for all crystalline phases indicate that magmatic fractionation was controlled mainly by crystal fractionation of plagioclase, hornblende, clinopyroxene and orthopyroxene at the early stage, and quartz, plagioclase, biotite, hornblende, apatite, ilmenite and zircon at the later stage. The residual melt extracted from the granodiorite mush was subsequently intruded into the northern and western parts of the Ofuku pluton as melt lens to form the granite and aplite. The age of the pluton was estimated at 99–97 Ma and 101–98 Ma based on K–Ar dating of hornblende and biotite, respectively. Both ages are consistent within analytical error, indicating that the Ofuku pluton and the associated Yamato mine belong to the Tungsten Province of the San‐yo Belt, which is genetically related to the ilmenite‐series granitoids of the Kanmon to Shunan stages. The aplite contains Cl‐rich apatite and REE‐rich monazite‐(Ce), allanite‐(Ce), xenotime and bastnäsite‐(Ce), indicating that the residual melt was rich in halogens and REEs. The tonalite–granodiorite of the Ofuku pluton contains many three‐phase fluid inclusions, along with daughter minerals such as NaCl and KCl, and vapor/liquid (V/L) volume ratios range from 0.2 to 0.9, suggesting that the fluid was boiling. In contrast, the granite and aplite contain low salinity two‐phase inclusions with low V/L ratios. The granodiorite occupies a large part of the pluton, and the inclusions with various V/L ratios with chloride daughter minerals suggest the boiling fluids might be related to the mineralization. This fluid could have carried base metals such as Cu and Zn, forming Cu ore deposits in and around the Ofuku pluton. The occurrence and composition of fluid inclusions in the igneous rocks from the Akiyoshi Plateau are directly linked to Cu mineralization in the area, demonstrating that fluid inclusions are useful indicators of mineralization.  相似文献   

Impact Of The PROCEEDINGS ON THE ANNUAL MEETING OF THE ASSOCIATION OF AMERICAN GEOGRAPHERS: A COMPARISON OF SCIENTIFIC INFORMATION EXCHANGE AT THE 1967 AND 1969 ANNUAL MEETINGS*     

Carnot E. Nelson  Kazuo Tomica 《The Professional geographer》1970,22(4):221-226

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Is beach-spawning success for capelin, Mallotus villosus (Muller), a function of the beach?     

Nakashima  Brian S.; Taggart  Christopher T. 《ICES Journal of Marine Science》2002,59(5):897-908

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Generation of high resolution sea surface temperature using multi-satellite data for operational oceanography     

YANG Chan-Su  KIM Sun-Hw  OUCHI Kazuo  BACK Ji-Hun 《海洋学报(英文版)》2015,34(7):74-88

In the present article, we introduce a high resolution sea surface temperature(SST) product generated daily by Korea Institute of Ocean Science and Technology(KIOST). The SST product is comprised of four sets of data including eight-hour and daily average SST data of 1 km resolution, and is based on the four infrared(IR) satellite SST data acquired by advanced very high resolution radiometer(AVHRR), Moderate Resolution Imaging Spectroradiometer(MODIS), Multifunctional Transport Satellites-2(MTSAT-2) Imager and Meteorological Imager(MI), two microwave radiometer SSTs acquired by Advanced Microwave Scanning Radiometer 2(AMSR2), and Wind SAT with in-situ temperature data. These input satellite and in-situ SST data are merged by using the optimal interpolation(OI) algorithm. The root-mean-square-errors(RMSEs) of satellite and in-situ data are used as a weighting value in the OI algorithm. As a pilot product, four SST data sets were generated daily from January to December 2013. In the comparison between the SSTs measured by moored buoys and the daily mean KIOST SSTs, the estimated RMSE was 0.71°C and the bias value was –0.08°C. The largest RMSE and bias were 0.86 and –0.26°C respectively, observed at a buoy site in the boundary region of warm and cold waters with increased physical variability in the Sea of Japan/East Sea. Other site near the coasts shows a lower RMSE value of 0.60°C than those at the open waters. To investigate the spatial distributions of SST, the Group for High Resolution Sea Surface Temperature(GHRSST) product was used in the comparison of temperature gradients, and it was shown that the KIOST SST product represents well the water mass structures around the Korean Peninsula. The KIOST SST product generated from both satellite and buoy data is expected to make substantial contribution to the Korea Operational Oceanographic System(KOOS) as an input parameter for data assimilation.  相似文献   

Characteristic of Si:P:N ratio in bottom water in central Suo-Nada,western Seto Inland Sea   总被引：1，自引：0，他引：1  

Kazuo Abe  Mutsumi Tsujino  Norihisa Nakagawa  Katsuyuki Abo 《Journal of Oceanography》2015,71(1):53-63

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Underestimation of nutrient fluxes due to possible bacterial activity during a core incubation experiment   总被引：1，自引：0，他引：1  

Kazuo Abe  Mutsumi Tsujino  Takehiro Kazama  Norihisa Nakagawa  Katsuyuki Abo 《Journal of Oceanography》2015,71(3):263-270

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Ag-Cu-Pb-Bi-S Minerals Newly Discovered from the Ohori Base Metal Deposit, Yamagata Prefecture, NE Japan: Implications for Bi-metallogenesis in the Green-Tuff Region     

Yu Yokoro    Kazuo Nakashima 《Resource Geology》2010,60(1):1-17

The Ohori deposit, one of the base metal deposits in the Green-Tuff region, NE Japan, is composed of two types of mineralization; a skarn-type (Kaninomata orebody) made by the replacement of the Miocene calcareous layer, and a vein-type (Nakanomata orebody). While the ore mineral assemblage of the deposit (chalcopyrite, pyrite, sphalerite and galena) has been known for being rather simple, some Pb-Bi-S minerals have been discovered for the first time in the present study. The minerals mainly occur in the chalcopyrite-rich ores of both orebodies. They essentially belong to the Pb-Bi-S system and contain Cu and Ag in minor amounts, which correspond to the lillianite–gustavite solid solution series (phases Z and X), cosalite, neyite, felbertalite, krupkaite and Bi-bearing galena. The chalcopyrite-rich (Bi-bearing) ores from both orebodies are richer in chalcopyrite, pyrite and chlorite, and have higher homogenization temperatures (>300°C) of fluid inclusions, and higher FeS contents in sphalerite compared to the Bi-free ores. In the Green-Tuff region, Bi-minerals have been reported from many base metal deposits. Most of these Bi-bearing ore deposits are referred to as xenothermal-type deposits, and are characterized by the following common features; composite mineralization of high- and low-temperatures in the shallower environments, and close relationships with the Tertiary granitic rocks. The whole mineralization at the Ohori deposit also has a similar xenothermal character because of the coexistence of high-temperature chalcopyrite-rich ores with Pb-Bi-S minerals, which were formed by the influence of the Tertiary granitic rocks at a shallow depth.  相似文献