A hydrocode calculation coupled with reaction kinetics of carbon compounds within an impact vapor plume and its implications for cometary impacts on Galilean satellites     

Ryo Ishimaru  Hiroki Senshu  Takafumi Matsui 《Icarus》2010,210(1):411-423

The synthesis of organic molecules via chemical reactions within impact vapor plumes has been proposed as a mechanism to supply organics on a planet. However, the kinetics of chemical reactions within a rapidly expanding vapor plume or quenching process of the reactions has not been studied extensively. In this study, we constructed a new numerical model that calculates kinetics of the entire chemical reactions within an impact vapor plume. Numerical results revealed that the semi-analytical models proposed so far, in which the final amount of a chemical species was given by the equilibrium abundance at the quenching temperature of the fastest reaction path involving the species, underestimates the yield of organic molecules, such as HCN, by up to a factor of 10. This is because the previously used assumption that a species can achieve equilibrium with the rest of the reaction system via the fastest reaction path involving the species is not necessarily valid. Our analysis of the high-temperature H/C/N/O reaction system suggests that the quenching of slow reactions divides the reaction network into smaller reaction sub-systems isolated from the rest of the reaction system. Then, the fastest reaction path cannot equilibrate an isolated reaction sub-system with the rest of the reaction system. Simulation of this actual disequilibrium mechanism requires a simultaneous numerical calculation of the entire reaction network, which is equivalent to conducting a full kinetic model calculation, such as our model. Our numerical code makes it possible to discuss quantitatively the impact chemistry for various situations, such as the Galilean satellites. In this study, our numerical model is applied to the delivery of organic molecules via cometary impact on the Galilean satellites. Our numerical results indicate that small-particle impacts would produce HCN efficiently. Resulting HCN may freeze out immediately and be deposited on satellite surfaces, where it may be eventually converted into complex organics via irradiation of charged particle. On the other hand, large-size impacts may form transient CH₄-N₂ atmospheres, in which complex organics (tholin) may be formed via energy deposition of UV and/or charged particle. Resulting complex organics may subsequently precipitate on the satellite surfaces without clear correlation with the locations of impact craters. Such distribution of complex organics created by chemical reactions within vapor plumes due to cometary impacts may explain an absorption (4.57 μm) on Galilean satellites nonassociated with observable (moderate- and large-size) impact craters.  相似文献   

The role of organic haze in Titan's atmospheric chemistry: II. Effect of heterogeneous reaction to the hydrogen budget and chemical composition of the atmosphere     

Yasuhito Sekine  Sébastien Lebonnois  Takafumi Matsui  Christopher P. McKay  Seiji Sugita 《Icarus》2008,194(1):201-211

One of the key components controlling the chemical composition and climatology of Titan's atmosphere is the removal of reactive atomic hydrogen from the atmosphere. A proposed process of the removal of atomic hydrogen is the heterogeneous reaction with organic aerosol. In this study, we investigate the effect of heterogeneous reactions in Titan's atmospheric chemistry using new measurements of the heterogeneous reaction rate [Sekine, Y., Imanaka, H., Matsui, T., Khare, B.N., Bakes, E.L.O., McKay, C.P., Sugita, S., 2008. Icarus 194, 186-200] in a one-dimensional photochemical model. Our results indicate that 60-75% of the atomic hydrogen in the stratosphere and mesosphere are consumed by the heterogeneous reactions. This result implies that the heterogeneous reactions on the aerosol surface may predominantly remove atomic hydrogen in Titan's stratosphere and mesosphere. The results of our calculation also indicate that a low concentration of atomic hydrogen enhances the concentrations of unsaturated complex organics, such as C₄H₂ and phenyl radical, by more than two orders in magnitude around 400 km in altitude. Such an increase in unsaturated species may induce efficient haze production in Titan's mesosphere and upper stratosphere. These results imply a positive feedback mechanism in haze production in Titan's atmosphere. The increase in haze production would affect the chemical composition of the atmosphere, which might induce further haze production. Such a positive feedback could tend to dampen the loss and supply cycles of CH₄ due to an episodic CH₄ release into Titan's atmosphere.  相似文献   

Computer simulation of the MgSiO3 polymorphs     

Masanori Matsui  Geoffrey D. Price 《Physics and Chemistry of Minerals》1992,18(6):365-372

Six polymorphs of MgSiO₃ have been studied using molecular dynamic (MD) simulation techniques, based on the empirical potential (MAMOK), which is composed of terms to describe pairwise additive Coulomb, van der Waals attraction, and repulsive interactions. Crystal structures, bulk moduli, volume thermal expansivities, and enthalpies were simulated for the known MgSiO₃ polymorphs; orthoenstatite, clinoenstatite, protoenstatite, garnet, ilmenite, and perovskite. The simulated values compare very well with the available experimental data, and the results are quite satisfactory in view of the diversity of the crystal structures of the six polymorphs, the wide range of simulated properties, and the simplicity of the MAMOK potential. MD simulation was further successfully used to study the possibile existence of a post-protoenstatite phase at high temperature, and a C2/c phase at high pressure, both phases being suggested or inferred previously from experimental works.  相似文献   

Infrared device for simultaneous measurement of fluctuations of atmospheric carbon dioxide and water vapor   总被引：3，自引：0，他引：3  

Eiji Ohtaki  Tetsuji Matsui 《Boundary-Layer Meteorology》1982,24(1):109-119

An infrared device designed to measure simultaneous fluctuations of atmospheric CO₂ and water vapor concentrations is described. The measuring frequency is 30 Hz. The sensing path length is 20 cm. It is compatible with the path length of the standard type of a sonic anemometer. The noise level of the device is equivalent to fluctuations of about 0.8 ppm peak-to-peak for CO₂ and 0.02 g kg^-1 peak-to-peak for water vapor. Field tests have showed that the device is suitable for simultaneous measurement of turbulent fluxes of CO₂ and water vapor in conjunction with a sonic anemometer.  相似文献   

Thermodynamic analyses of equilibria involving olivine,orthopyroxene and garnet     

Toshisuke Kawasaki  Yoshito Matsui 《Geochimica et cosmochimica acta》1983,47(10):1661-1679

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The Tsenkher structure in the Gobi-Altai, Mongolia: Geomorphological hints of an impact origin     

Goro Komatsu  John W. Olsen  Jens Orm  Gaetano Di Achille  David A. Kring  Takafumi Matsui 《Geomorphology》2006,74(1-4):164-180

The Tsenkher structure, in the Gobi-Altai region of Mongolia, was studied using a wide array of remote sensing data and field observations. The structure has a shallow, 3.6 km wide, central depression bordered by a near-circular ridge (putative crater rim) with breaches to the northwest. The central depression is obliterated partially by fluvial infill through these breaches. Outside the ridge, the western side is a rugged terrain, but the eastern half is characterized by a concentric outer ridge that occurs at about one radius distance from the inner ridge. Although intrusion, salt tectonics and maar crater hypotheses cannot be completely ruled out, its morphology strongly implies an impact origin for the Tsenkher structure. If of impact origin, it has a well-preserved morphology and its position in the basin fills indicates that the formation may have occurred relatively recently, sometime during the late Tertiary or Quaternary. The outer ridge morphology is similar to rampart craters on Mars, whose formation has been attributed to fluidization of a water-rich target layer and ejecta materials, or to atmospheric entrainment and deposition of ejected materials. However, other hypotheses including erosional remnant of ejecta blanket, erosional scarp of structural rim uplift, multi-ring or deeply eroded crater rim of a peak-ring crater are also possible at this stage. A complex fluvial and probable lacustrine history is envisaged within the Tsenkher structure. The structure is also associated with archaeology, including Paleolithic and Bronze Age remains.  相似文献   

Spatiotemporal characteristics of interannual temperature variations in the Tsushima Strait     

Tomoharu Senjyu  Sigeaki Matsui  In-Seong Han 《Journal of Oceanography》2010,66(6):789-799

Spatiotemporal characteristics of interannual temperature variations in the Tsushima Strait are investigated on the basis of historical hydrographic data applying the same procedures as Senjyu et al. (2006). Empirical orthogonal function (EOF) analysis revealed that the most energetic mode of variation (the EOF first mode), which accounts for about 31.5% of the total variance, is the in-phase temperature change for the entire strait. The wintertime temperature variation described by the first mode is associated with the wintertime heat flux in the northern East China Sea, while they are poorly correlated in other seasons. The large standard deviation in the time coefficient of the first mode in August suggests a relationship with the horizontal heat advection in summer in the northern East China Sea. On the other hand, the EOF second mode, which explains about 12.6% of the total variance, is associated with the stratification and baroclinicity in the strait. The time coefficient of the EOF second mode negatively correlates with the baroclinic volume transport through the strait in summer. Comparison of temporal variations among the leading EOF modes for temperature and salinity shows no significant correlations. This indicates that the principal modes of variation in temperature and salinity vary independently within an interannual timescale.  相似文献   

The role of organic haze in Titan's atmospheric chemistry: I. Laboratory investigation on heterogeneous reaction of atomic hydrogen with Titan tholin     

Yasuhito Sekine  Hiroshi Imanaka  Takafumi Matsui  Emma L.O. Bakes  Christopher P. McKay 《Icarus》2008,194(1):186-200

In Titan's atmosphere consisting of N₂ and CH₄, large amounts of atomic hydrogen are produced by photochemical reactions during the formation of complex organics. This atomic hydrogen may undergo heterogeneous reactions with organic aerosol in the stratosphere and mesosphere of Titan. In order to investigate both the mechanisms and kinetics of the heterogeneous reactions, atomic deuterium is irradiated onto Titan tholin formed from N₂ and CH₄ gas mixtures at various surface-temperatures of the tholin ranging from 160 to 310 K. The combined analyses of the gas species and the exposed tholin indicate that the interaction mechanisms of atomic deuterium with the tholin are composed of three reactions; (a) abstraction of hydrogen from tholin resulting in gaseous HD formation (HD recombination), (b) addition of D atom into tholin (hydrogenation), and (c) removal of carbon and/or nitrogen (chemical erosion). The reaction probabilities of HD recombination and hydrogenation are obtained as ηabst=1.9(±0.6)×¹⁰⁻³×exp(−300/T) and ηhydro=2.08(±0.64)×exp(−1000/T), respectively. The chemical erosion process is very inefficient under the conditions of temperature range of Titan's stratosphere and mesosphere. Under Titan conditions, the rates of hydrogenation > HD recombination ? chemical erosion. Our measured HD recombination rate is about 10 times (with an uncertainty of a factor of 3-5) the prediction of previous theoretical model. These results imply that organic aerosol can remove atomic hydrogen efficiently from Titan's atmosphere through the heterogeneous reactions and that the presence of aerosol may affect the subsequent organic chemistry.  相似文献   

Study on the physical disintegration characteristics of Subang claystone subjected to a modified slaking index test   总被引：2，自引：0，他引：2  

I. A.?SadisunEmail author  H.?Shimada  M.?Ichinose  K.?Matsui 《Geotechnical and Geological Engineering》2005,23(3):199-218

Some instability problems were found on natural or engineered slopes mostly lying on Subang claystones. The instability problems included excessive erosion, slumps and rock falls. The field performance surveys of the problems suggested that the claystones physically weather rapidly so that the rock properties they exhibit during excavation often change to properties with a more characteristic of soil. Such a phenomenon is generally known as a slaking process. In order to gain better understanding about the slaking of Subang claystones, a series of experimental laboratory studies were carried out involving a modified slaking index test. Claystone samples used in this study were obtained from their exposures along the Northern West Java area of Indonesia. Petrographic analysis was correspondingly performed to identify mineral and texture/fabric, and in turn, to determine the inherent factors of the rocks which might affect the slaking process. The stssudy results indicated that the claystones were characterized by high to very high slaking properties having a maximum slaking index (I_s) of 57.4% and a mean I_s of 43.8%. Major dispersion slaking on sample surfaces and high cracking in response to excessive swelling were recognized as main slaking modes within the claystones. All samples lose progressively less material through the five wet–dry cycles of a slaking index test, indicating a decelerated slaking rate. It was evident that the main inherent factors controlling the slaking process were expandable clay mineral smectite, non-clay mineral pyrite and soluble mineral calcite. Moreover, a quite important of inherent bonding material and stress release energy in the slaking characteristics of the claystones was revealed by a closure phase of an initial hairline crack during unloading.  相似文献   

Crustal structure of south-western Honshu, Japan, derived from explosion seismic waves     

Michio Hashizume  Yoshito Matsui 《Geophysical Journal International》1979,58(1):181-199

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