Spectrophotometric determination of pH in seawater off Taiaroa Head,Otago, New Zealand: Full-spectrum modelling and prediction of pCO₂ levels     

Shane M. Ohline  Malcolm R. Reid  Shamus L.G. Husheer  Kim I. Currie  Keith A. Hunter 《Marine Chemistry》2007

Accurate measurement of seawater pH has long been sought by marine chemists (for example: [Dickson, A.G. 1993a. The measurement of sea water pH. Marine Chemistry, 44, 131–142, Dickson, A.G. 1993b. pH buffers for sea water media based on the total hydrogen ion concentration scale. Deep-Sea Research, 40, 107–118; Zhang, 1996; Tapp, M., Hunter, K.A., Currie, K. and Macaskill, B. 2000. Apparatus of continuous-flow underway spectrophotometric measurement of surface water pH. Marine Chemistry 72(2–4), 193–202; Friis, K., Koetzinger, A., Wallace, D.W.R. 2004. Spectrophotometric pH measurement in the ocean: Requirements, design and testing of an autonomous charge-coupled device detector system. Limnology and Oceanography: Methods 2, 126–136]. Recently, such attempts have taken on greater significance as anthropogenic carbon dioxide emissions may create rapidly changing oceanic pH. Spectrophotometric techniques have been accepted generally as the best for determination of seawater pH. Here we report a new technique using thymol blue as the indicator dye and fitting the entire spectrum from 400 to 900 nm rather than measuring the absorbance values at only two or three points in the spectrum. This full-spectrum modelling enables a reduction in signal to noise over other techniques. In the laboratory, we find with seawater samples a pH precision increase of five-fold “within” a sample and seven-fold “between” samples when comparing the full spectrum to the three-point method of analysis [Zhang, H., Byrne, R.H. 1996. Spectrophotometric pH measurements of surface seawater at in-situ conditions: absorbance and protonation behaviour of thymol blue. Marine Chemistry 52, 17–25].  相似文献   

Porites corals as recorders of mining and environmental impacts: Misima Island, Papua New Guinea   总被引：1，自引：0，他引：1  

Stewart J. Fallon  Jamie C. White†Malcolm T. McCulloch 《Geochimica et cosmochimica acta》2002,66(1):45-62

In 1989 open-cut gold mining commenced on Misima Island in Papua New Guinea (PNG). Open-cut mining by its nature causes a significant increase in sedimentation via the exposure of soils to the erosive forces of rain and runoff. This increased sedimentation affected the nearby fringing coral reef to varying degrees, ranging from coral mortality (smothering) to relatively minor short-term impacts. The sediment associated with the mining operation consists of weathered quartz feldspar, greenstone, and schist. These rocks have distinct chemical characteristics (rare earth element patterns and high abundances of manganese, zinc, and lead) and are entering the near-shore environment in considerably higher than normal concentrations. Using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), we analyzed eight colonies (two from high sedimentation, two transitional, two minor, and two unaffected control sites) for Y, La, Ce, Mn, Zn, and Pb. All sites show low steady background levels prior to the commencement of mining in 1988. Subsequently, all sites apart from the control show dramatic increases of Y, La, and Ce associated with the increased sedimentation as well as rapid decreases following the cessation of mining. The elements Zn and Pb exhibit a different behavior, increasing in concentration after 1989 when ore processing began and one year after initial mining operations. Elevated levels of Zn and Pb in corals has continued well after the cessation of mining, indicating ongoing transport into the reef of these metals via sulfate-rich waters. Rare earth element (REE) abundance patterns measured in two corals show significant differences compared to Coral Sea seawater. The corals display enrichments in the light and middle REEs while the heavy REEs are depleted relative to the seawater pattern. This suggests that the nearshore seawater REE pattern is dominated by island sedimentation. Trace element abundances of Misima Island corals clearly record the dramatic changes in the environmental conditions at this site and provide a basis for identifying anthropogenic influences on corals reefs.  相似文献   

Classification of artificial (man-made) ground   总被引：1，自引：0，他引：1  

M. S. Rosenbaum  A. A. McMillan  J. H. Powell  A. H. Cooper  M. G. Culshaw  K. J. Northmore 《Engineering Geology》2003,69(3-4):399-409

The legacy inherited from anthropogenic processes needs to be addressed in order to provide reliable and up-to-date ground information relevant to development and regeneration in the urban environment. The legacy includes voids as well as anthropogenic deposits (artificial ground). Their characteristics derive from former quarrying and mining activities industrial processes creating derelict ground, variably consolidated made ground, and contaminated groundwater and soils. All need to be systematically assessed to inform the planning process and provide the basis for engineering solutions. Site-specific investigation needs to be conducted on the back of good quality geoscientific data. This comes from ‘field’ survey, remotely sensed data interpretation, historical maps, soil geochemical sampling, and geotechnical investigation. Three-dimensional and, in the future, four dimensional, characterization of superficial deposits is required to reach an understanding of the potential spatial lithological variability of artificial ground and the geometry of important surfaces, i.e. the boundary conditions. The classification scheme for artificial ground outlined in this paper and adopted by the British Geological Survey, will help in achieving this understanding.  相似文献   

A review of some tracer-test design equations for tracer-mass estimation and sample-collection frequency     

Malcolm S. Field 《Environmental Geology》2003,44(2):240-241

  相似文献   

Source of trace element variability in Great Barrier Reef corals affected by the Burdekin flood plumes     

Chantal Alibert  Les Kinsley  Malcolm T. McCulloch  Felicity McAllister 《Geochimica et cosmochimica acta》2003,67(2):231-246

Massive corals in the Great Barrier Reef, analyzed at high-resolution for Sr/Ca (thermal ionization mass spectrometry) and trace elements such as Ba and Mn (laser ablation inductively coupled plasma mass spectrometry), can provide continuous proxy records of dissolved seawater concentrations, as well as sea surface temperature (SST). A 10-yr record (1989 to 1998) from Pandora Reef, an inshore reef regularly impacted by the freshwater plumes of the Burdekin River, is compared with an overlapping record from a midshelf reef, away from runoff influences. Surface seawater samples, taken away from river plumes, show little variability for Sr/Ca (8484 ± 10 μmol/mol) and Ba (33.7 ± 0.7 nmol/kg). Discrete Ba/Ca peaks in the inshore coral coincide with flood events. The magnitude of this Ba/Ca enrichment is most likely controlled by the amount of suspended sediments delivered to the estuary, which remains difficult to monitor. The maximum flow rate at peak river discharge is used here as a proxy for the sediment load and is shown to be strongly correlated with coral Ba/Ca (r = 0.97). After the wet summer of 1991, the coral Ba/Ca flood peak is followed by a plateau that lingers for several months after dissipation of plume waters, signifying an additional flux of Ba that may originate from submarine groundwater seeps and/or mangrove reservoirs. Both Mn and Y are enriched by a factor of ∼5 in inshore relative to midshelf corals. Mn/Ca ratios show a seasonal cycle that follows SST (r = 0.7), not river discharge, with an additional high variability in summer suggesting a link with biological activity. P and Cd show no significant seasonal variation and are at a low level at both inshore and midreef locations. However, leaching experiments suggest that part of the coral P is not lattice bound.  相似文献   

Correction to Roberts and Clemens (1995) “Feasibility of AFC models for the petrogenesis of calc-alkaline magma series”     

Malcolm P. Roberts  John D. Clemens 《Contributions to Mineralogy and Petrology》1997,128(1):97-99

  相似文献   

Resolution Sensitivity and Scaling of Large-Eddy Simulations of the Stable Boundary Layer   总被引：1，自引：5，他引：1  

Robert J. Beare  Malcolm K. Macvean 《Boundary-Layer Meteorology》2004,112(2):257-281

Large-eddy simulations (LES) of the continuously turbulent quasi-equilibrium stable boundary layer (SBL) are conducted with grid lengths in the range of 12.5 m to 2 m, in order to explore resolution sensitivity, and determine at what point grid convergence occurs. The structure of the mean potential temperature, winds, and turbulent fluxes varies significantly over this resolution range. The highest resolution simulations show a significant degree of convergence. The dimensionless momentum diffusivity asymptotes to a value of 0.06, corresponding to a limiting flux Richardson number of 0.15.Using the converged simulations, some scaling hypotheses underpinning first-order and second-order closure models are revisited. The effective Richardson number stability functions of the LES are compared with the forms often used in numerical weather prediction (NWP). The mixing implied by the LES is less than that used in NWP. The commonly used similarity profiles for heat and momentum fluxes, and the scalings for dissipation and pressure covariances are compared with the LES. This information could provide guidance for the next generation of SBL parametrization schemes.  相似文献   

Pliocene and Quaternary regional uplift in western Turkey: the Gediz River terrace staircase and the volcanism at Kula     

Rob Westaway  Malcolm Pringle  Sema Yurtmen  Tuncer Demir  David Bridgland  George Rowbotham  Darrel Maddy 《Tectonophysics》2004,391(1-4):121

Along the upper reaches of the Gediz River in western Turkey, in the eastern part of the Aegean extensional province, the land surface has uplifted by 400 m since the Middle Pliocene. This uplift is revealed by progressive gorge incision, and its rate can be established because river terraces are capped by basalt flows that have been K–Ar and Ar–Ar dated. At present, the local uplift rate is 0.2 mm a⁻¹. Uplift at this rate began around the start of the Middle Pleistocene, following a span of time when the uplift was much slower. This was itself preceded by an earlier uplift phase, apparently in the late Late Pliocene and early Early Pleistocene, when the uplift rate was comparable to the present. The resulting regional uplift history resembles what is observed in other regions and is analogously interpreted as the isostatic response to changing rates of surface processes linked to global environmental change. We suggest that this present phase of surface uplift, amounting so far to 150 m, is being caused by the nonsteady-state thermal and isostatic response of the crust to erosion, following an increase in erosion rates in the late Early Pleistocene, most likely as a result of the first large northern-hemisphere glaciation during oxygen isotope stage 22 at 870 ka. We suggest that the earlier uplift phase, responsible for the initial 250 m of uplift, resulted from a similar increase in erosion rates caused by the deterioration in local climate at 3.1 Ma. This uplift thus has no direct relationship to the crustal extension occurring in western Turkey, the rate and sense of which are thought not to have changed significantly on this time scale. Our results thus suggest that the present, often deeply incised, landscape of western Turkey has largely developed from the Middle Pleistocene onwards, for reasons not directly related to the active normal faulting that is also occurring. The local isostatic consequences of this active faulting are instead superimposed onto this “background” of regional surface uplift. Modelling of this surface uplift indicates that the effective viscosity of the lower continental crust beneath this part of Turkey is of the order of 10¹⁹ Pa s, similar to a recent estimate for beneath central Greece. The lower uplift rates observed in western Turkey, compared with central Greece, result from the longer typical distances of fluvial sediment transport, which cause weaker coupling by lower-crustal flow between offshore depocentres and eroding onshore regions that provide the sediment source.  相似文献   

Metrics to assess how longitudinal channel network connectivity and in‐stream Atlantic salmon habitats are impacted by hydropower regulation          下载免费PDF全文

Willem B. Buddendorf  Iain A. Malcolm  Josie Geris  Mark E. Wilkinson  Chris Soulsby 《水文研究》2017,31(12):2132-2142

Habitat fragmentation in channel networks and riverine ecosystems is increasing globally due to the construction of barriers and river regulation. The resulting divergence from the natural state poses a threat to ecosystem integrity. Consequently, a trade‐off is required between the conservation of biodiversity in channel networks and socio‐economic factors including power generation, potable water supplies, fisheries, and tourism. Many of Scotland's rivers are regulated for hydropower generation but also support populations of Atlantic salmon (Salmo salar L.) that have high economic and conservation value. This paper investigates the use of connectivity metrics and weightings to assess the impact of river barriers (impoundments) associated with hydropower regulation on natural longitudinal channel connectivity for Atlantic salmon. We applied 2 different weighting approaches in the connectivity models that accounted for spatial variability in habitat quality for spawning and fry production and contrasted these models with a more traditional approach using wetted area. Assessments of habitat loss using the habitat quality weighted models contrasted with those using the less biologically relevant wetted area. This highlights the importance of including relevant ecological and hydrogeomorphic information in assessing regulation impacts on natural channel connectivity. Specifically, we highlight scenarios where losing a smaller area of productive habitat can have a larger impact on Atlantic salmon than losing a greater area of less suitable habitat. It is recommended that future channel connectivity assessments should attempt to include biologically relevant weightings, rather than relying on simpler metrics like wetted area which can produce misleading assessments of barrier impacts.  相似文献   

Spatial variability of hydrological processes and model structure diagnostics in a 50 km2 catchment          下载免费PDF全文

Hilary McMillan  Myriam Gueguen  Elisabeth Grimon  Ross Woods  Martyn Clark  David E. Rupp 《水文研究》2014,28(18):4896-4913

  相似文献