A diatom‐inferred record of lake variability during the last 900 years in Lützow–Holm Bay,East Antarctica          下载免费PDF全文

Rachel C. Rudd  Jonathan J. Tyler  John Tibby  Yusuke Yokoyama  Ines Tavernier  Elie Verleyen  Manabu Fukui  Yoshinori Takano 《第四纪科学杂志》2016,31(2):114-125

Decadal–centennial‐scale climate variability in coastal Antarctica remains poorly understood due to the limited number of highly resolved, well‐dated records. We present a 900‐year, decadal‐scale reconstruction based on sedimentary diatoms from Lake Abi in Lützow–Holm Bay, East Antarctica. Hydrological change is inferred from diatom ecological preferences in conjunction with an existing regional training set and implies that lake water specific conductivity, depth and nitrogen availability are the key drivers of diatom assemblage change. Lake Abi underwent a series of subtle environmental changes related to these environmental variables, possibly driven by changes in catchment snow melt and the duration of seasonal ice cover. Ordination is used to trace the major patterns of change in the diatom community, with notable shifts identified between 470 and 400 and at ～350 cal a BP (where present = CE 1950). The frequency of environmental variability at Lake Abi is broadly consistent with a record of the Interdecadal Pacific Oscillation during the last millennium, but contrasts with the apparent climate stability elsewhere in eastern Antarctica. Further research is required to constrain the limnological and ecological responses of lakes in coastal Antarctica to obtain more rigorous palaeoclimate reconstructions from these sites of immense potential.  相似文献   

Cations in olivine,Part 1: Calcium partitioning and calcium-magnesium distribution between olivines and coexisting melts,with petrologic applications   总被引：2，自引：0，他引：2  

Amy J. G. Jurewicz  E. Bruce Watson 《Contributions to Mineralogy and Petrology》1988,99(2):176-185

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Pressure and temperature dependence of cation distribution in Mg-Mn olivine     

Tadashi Akamatsu  Kiyoshi Fujino  Mineo Kumazawa  Akio Fujimura  Manabu Kato  Hiroshi Sawamoto  Takamitsu Yamanaka 《Physics and Chemistry of Minerals》1988,16(2):105-113

Synthetic (Mg_0.51, Mn_0.49)₂SiO₄ olivine samples are heat-treated at three different pressures; 0, 8 and 12 GPa, all at the same temperature (～500° C). X-ray structure analyses on these single crystals are made in order to see the pressure effect on cation distribution. The intersite distribution coefficient of Mg and Mn in M1 and M2 sites, K _D = (Mn/Mg) _M1/(Mn/Mg) _M2, of these samples are 0.192 (0 GPa), 0.246 (8 GPa) and 0.281 (12 GPa), indicating cationic disordering with pressure. The small differences of cell dimensions between these samples are determined by powder X-ray diffraction. Cell dimensions b and c decrease, whereas a increases with pressure of equilibration. Cell volume decreases with pressure as a result of a large contraction of the b cell dimension. The effect of pressure on the free energy of the cation exchange reaction is evaluated by the observed relation between the cell volume and the site occupancy numbers. The magnitude of the pressure effect on cation distribution is only a fifth of that predicted from the observed change in volume combined with thermodynamic theory. This phenomenon is attributed to nonideality in this solid solution, and nonideal parameters are required to describe cation distribution determined in the present and previous experiments. We use a five-parameter equation to specify the cationic equilibrium on the basic of thermodynamic theory. It includes one energy parameter of ideal mixing, two parameters for nonideal effects, one volume parameter, and one thermal parameter originated from the lattice vibrational energy. The present data combined with some of the existing data are used to determine the five parameters, and the cation distribution in Mg-Mn olivine is described as a function of temperature, pressure, and composition. The basic framework of describing the cationic behavior in olivine-type mineral is worked out, although the result is preliminary: each of the determined parameters is not accurate enough to enable us to make a reliable prediction.  相似文献   

Fluids in the lithosphere, 2. Experimental constraints on CO₂ transport in dunite and quartzite at elevated P-T conditions with implications for mantle and crustal decarbonation processes     

James M. Brenan  E. Bruce Watson 《Earth and Planetary Science Letters》1988,91(1-2)

In a series of experiments at 0.5–1.3 GPa and 1050–1200°C we have monitored the transport, via crack propagation, of CO₂ into well-annealed olivine and quartz aggregates. The objectives were to determine (1) the extent and rate of fluid penetration; (2) the effect of varying both P-T conditions and microstructure; and (3) the fluid penetration pathways. Experiments on CO₂ penetration into dunite annealed in the absence of MgO indicate rapid and pervasive fluid transport on a grain-dimension scale, but a limited penetration distance ( 1 mm). Additional experiments on dunite annealed in the presence of MgO (either dispersed or present at both ends), however, resulted in CO₂ penetration that was both pervasive on the scale of individual grains and almost always completely through the 5 mm long samples. The abundance of fine (10 μm) grains in the MgO-free dunite, in contrast to the much larger grain sizes of the samples annealed with MgO present, suggests the difference in fluid penetration behavior may arise because the strength variation in dunite scales with the grain size. Effects arising from changes in olivine point defect chemistry, however, are an additional possibility. The response of synthetic quartzite to CO₂ overpressure is distinct from that of dunite: Quartzite experiences rapid and complete penetration of CO₂, via a macroscopically visible system of transgranular fractures, over the range of P-T conditions investigated.The small amount of porosity ( 2–3%) present in most rock samples fabricated for this study, lacks three-dimensional connectivity, thus precluding any enhanced fluid penetration via porous flow. Pores could possibly enhance fluid penetration as the result of a small reduction in resistance to fracture, but the probable abundance of strength-controlling flaws in natural rocks is likely to produce similar behavior.The results of our experiments on olivine and olivine + MgO suggest that the transport of pressurized CO₂ in very olivine-rich mantle environments will be pervasive on the scale of individual grains and its extent may be dependent on rock microstructure and/or crystal chemical effects. Such pervasive fluid transport, perhaps associated with magma decarbonation, may have interesting implications for both magma transport and local LREE enrichment of adjacent mantle wall-rock. The ease with which quartzite is penetrated by CO₂ at the conditions of our experiments underscores the possible role of decarbonation reactions in crustal permeability-enhancement processes.  相似文献   

NOAA WP-3D instrumentation and flight operations on AGASP-II     

R. C. Schnell  T. B. Watson  B. A. Bodhaine 《Journal of Atmospheric Chemistry》1989,9(1-3):3-16

The second Arctic Gas and Aerosol Sampling Program (AGASP-II) was conducted across the non-Soviet Arctic in March and April 1986, to study the aerosol, gaseous, chemical, and optical properties of Arctic haze. One component of the program was supported with an instrumented NOAA WP-3D atmospheric research aircraft. Measurements of wind, temperature, ozone, water vapor, condensation nucleus concentration, and aerosol scattering extinction coefficient were used to determine the locations and properties of haze layers. The first three NOAA WP-3D research flights were conducted north of Barrow, Alaska, and over the Beaufort Sea northeast of Barter Island, Alaska. The next three sampled conditions in the high Arctic near Alert, Northwest Territories, Canada. All basic meteorological, gas, and aerosol systems are described. The WP-3D flight tracks and operations are presented.  相似文献   

Evaporation from the understorey in the Jarrah (Eucalyptus marginata Don ex Sm.) forest, southwestern Australia     

E.A.N. Greenwood  L. Klein  J.D. Beresford  G.D. Watson  K.D. Wright 《Journal of Hydrology》1985,80(3-4):337-349

Annual evaporation from groundflora, litter and soil of the jarrah forest was estimated from measurements of daily evaporation by ventilated chambers on several days over two separate 12-month periods. In the first year, when sampling ranged over 0.1 ha of forest, annual evaporation during daylight hours was estimated as 410 mm (0.32 rainfall). In the second year, sampling was more frequent, on a larger scale, and included the night hours. Annual evaporation was estimated at 360 mm (0.36 rainfall).

Similarly, in the second year, annual evaporation from two trees of the dominant middle storey species, Banksia grandis, was estimated at 7500 and 18,9001 respectively. The leaf area of these two trees was 9.6 and 22.4 m², respectively, so that annual evaporation, when expressed as mm³ per mm² leaf area, was similar for both trees (mean = 820 ± 30 mm). Applying that value to all Banksia trees in a hectare of forest, and using a measured estimate of leaf area index of 0.19, the estimated annual evaporation from the Banksia component was 155 mm (0.16 rainfall). For the upland part of the forest sampled, the combined annual evaporation from the lower and middle storeys accounted for about half (0.51) of the annual rainfall.

We conclude that reduced evaporation from the upper storey following clearing or thinning may be strongly counteracted by increased evaporation from the understorey due to increased availability of energy and water.  相似文献   

The behavior of apatite during crustal anatexis: Equilibrium and kinetic considerations   总被引：5，自引：0，他引：5  

T.Mark Harrison  E.Bruce Watson 《Geochimica et cosmochimica acta》1984,48(7):1467-1477

The solubility and dissolution kinetics of apatite in felsic melts at 850°–1500°C have been examined experimentally by allowing apatite crystals to partially dissolve into apatite-undersaturated melts containing 0–10 wt% water. Analysis of P and Ca gradients in the crystal/melt interfacial region enables determination of both the diffusivities and the saturation levels of these components in the melt. Phosphorus diffusion was identified as the rate-limiting factor in apatite dissolution. Results of four experiments at 8 kbar run in the virtual absence of water yield an activation energy (E) for P diffusion of 143.6 ± 2.8 kcal-mol^?1 and frequency factor (D₀) of 2.23^+2.88_?1.26 × 10⁹cm²-sec^?1. The addition of water causes dramatic and systematic reduction of both E and D₀ such that at 6 wt% H₂O the values are ~25 kcal-mol^?1 and 10^?5 cm²-sec^?1, respectively. At 1300°C, the diffusivity of P increases by a factor of 50 over the first 2% of water added to the melt, but rises by a factor of only two between 2 and 6%, perhaps reflecting the effect of a concentration-dependent mechanism of H₂O solution. Calcium diffusion gradients do not conform well to simple diffusion theory because the release of calcium at the dissolving crystal surface is linked to the transport rate of phosphorus in the melt, which is typically two orders of magnitude slower than Ca. Calcium chemical diffusion rates calculated from the observed gradients are about 50 times slower than calcium tracer diffusion.Apatite solubilities obtained from these experiments, together with previous results, can be described as a function of absolute temperature (T) and melt composition by the expression: In D^apatite/melt_P = [(8400 + ((SiO₂ ? 0.5)2.64 × 10⁴))/T] ? [3.1 + (12.4(SiO₂ ? 0.5))] where SiO₂ is the weight fraction of silica in the melt. This model appears to be valid between 45% and 75% SiO₂, 0 and 10% water, and for the range of pressures expected in the crust.The diffusivity information extracted from the experiments can be directly applied to several problems of geochemical interest, including I) dissolution times for apatite during crustal anatexis, and 2) pileup of P, and consequent local saturation in apatite, at the surfaces of growing major-mineral phases.  相似文献   

Petrological influence on differential weathering and inselberg development in the Kora area of central Kenya     

K. Pye  A. S. Goudie  A. Watson 《地球表面变化过程与地形》1986,11(1):41-52

In the Kora area of central Kenya domed inselbergs are well developed on outcrops of granitoid migmatite, while positive relief features are rare on the surrounding gneiss. Block-strewn, vegetated hills occur on restricted areas of granoblastite, gabbro, and metagabbro. Schmidt Hammer measurements have shown that the apparent differences in resistance to weathering and erosion are not due to variations in rock hardness, since all the rock types have similar ‘R’ values. The results of geochemical analyses have shown that the migmatites are significantly more potassic than the surrounding gneiss. Samples of migmatite from the inselbergs were also found to be slightly richer in potassium than migmatite samples from the inter-inselberg areas. The variations in potassium content probably reflect differences in protolith composition, chemical fractionation during partial melting, and the effects of metasomatism. These findings support earlier suggestions that, other things being equal, potassium-rich granitoid rocks weather more slowly than less potassic rocks.  相似文献   

Spatial variability in soil moisture as predicted from airborne thematic mapper (ATM) data     

Donald A. Davidson  Alistair I. Watson 《地球表面变化过程与地形》1995,20(3):219-230

In the first part of this project, the extent to which moisture content of alluvial soils could be predicted from imagery derived from an airborne thematic mapper (ATM) was investigated. From sampling done on the same day as the flight, it was found that digital numbers derived from the thermal channel (waveband 11) were strongly correlated with gravimetric moisture content. From sampling three fields of contrasting land cover, the relationship between waveband 11 values and moisture content was found to be independent of land cover type. Spatial variation in waveband 11 values and thus moisture content were related to palaeochannel patterns on the alluvial land. This was investigated by deriving variograms for long transects from each of the three investigated fields. The range and sills of the variograms are shown to express the nature and pattern of palaeochannels. By the application of such geostatistical techniques, high resolution imagery can thus be used to quantify palaeochannel characteristics on alluvial land.  相似文献   

An open letter to G. Matheron     

G. M. Philip  D. F. Watson 《Mathematical Geosciences》1987,19(5):453-454

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