Halogen diffusion in a basaltic melt   总被引：2，自引：0，他引：2  

Marina Alletti  Don R. Baker  Carmela Freda 《Geochimica et cosmochimica acta》2007,71(14):3570-3580

The diffusion of the halogens fluorine, chlorine and bromine was measured in a hawaiitic melt from Mt. Etna at 500 MPa and 1.0 GPa, 1250 to 1450 °C at anhydrous conditions; the diffusion of F and Cl in the melt was also studied with about 3 wt% of dissolved water. Experiments were performed using the diffusion-couple technique in a piston cylinder. Most experiments were performed with only one halogen diffusing between the halogen-enriched and halogen-poor halves of the diffusion couple, but a few experiments with a mixture of halogens (F, Cl and Br) were also performed in order to investigate the possibility of interactions between the halogens during diffusion. Fluorine and chlorine diffusivity show a very similar behavior, slightly diverging at low temperature. Bromine diffusion is a factor of about 2-5 lower than the other halogens in this study. Diffusion coefficients for fluorine range between 2.3 × 10⁻¹¹ and 1.4 × 10⁻¹⁰ m² s⁻¹, for chlorine between 1.1 × 10⁻¹¹ and 1.3 × 10⁻¹⁰ and for bromine between 9.4 × 10⁻¹² and 6.8 × 10⁻¹¹ m² s⁻¹. No pressure effect was detected at the conditions investigated. In experiments involving mixed halogens, the diffusivities appear to decrease slightly (by a factor of ∼3), and are more uniform among the three elements. However, activation energies for diffusion do not appear to differ between experiments with individual halogens or when they are all mixed together. The effect of water increases the diffusion coefficients of F and Cl by no more than a factor of 3 compared to the anhydrous melt (D_F = 4.0 × 10⁻¹¹ to 1.6 × 10⁻¹⁰ m² s⁻¹; D_Cl = 3.0 × 10⁻¹¹ to 1.9 × 10⁻¹⁰ m² s⁻¹). Comparing our results to the diffusion coefficients of other volatiles in nominally dry basaltic melts, halogen diffusivities are about one order of magnitude lower than H₂O, similar to CO₂, and a factor of ∼5 higher than S. The contrasting volatile diffusivities may affect the variable extent of volatile degassing upon melt depressurization and vesiculation, and can help our understanding of the compositions of rapidly grown magmatic bubbles.  相似文献   

Directed blasts and blast-generated pyroclastic density currents: a comparison of the Bezymianny 1956, Mount St Helens 1980, and Soufrière Hills,Montserrat 1997 eruptions and deposits     

Alexander Belousov  Barry Voight  Marina Belousova 《Bulletin of Volcanology》2007,69(7):701-740

We compare eruptive dynamics, effects and deposits of the Bezymianny 1956 (BZ), Mount St Helens 1980 (MSH), and Soufrière Hills volcano, Montserrat 1997 (SHV) eruptions, the key events of which included powerful directed blasts. Each blast subsequently generated a high-energy stratified pyroclastic density current (PDC) with a high speed at onset. The blasts were triggered by rapid unloading of an extruding or intruding shallow magma body (lava dome and/or cryptodome) of andesitic or dacitic composition. The unloading was caused by sector failures of the volcanic edifices, with respective volumes for BZ, MSH, and SHV c. 0.5, 2.5, and 0.05 km³. The blasts devastated approximately elliptical areas, axial directions of which coincided with the directions of sector failures. We separate the transient directed blast phenomenon into three main parts, the burst phase, the collapse phase, and the PDC phase. In the burst phase the pressurized mixture is driven by initial kinetic energy and expands rapidly into the atmosphere, with much of the expansion having an initially lateral component. The erupted material fails to mix with sufficient air to form a buoyant column, but in the collapse phase, falls beyond the source as an inclined fountain, and thereafter generates a PDC moving parallel to the ground surface. It is possible for the burst phase to comprise an overpressured jet, which requires injection of momentum from an orifice; however some exploding sources may have different geometry and a jet is not necessarily formed. A major unresolved question is whether the preponderance of strong damage observed in the volcanic blasts should be attributed to shock waves within an overpressured jet, or alternatively to dynamic pressures and shocks within the energetic collapse and PDC phases. Internal shock structures related to unsteady flow and compressibility effects can occur in each phase. We withhold judgment about published shock models as a primary explanation for the damage sustained at MSH until modern 3D numerical modeling is accomplished, but argue that much of the damage observed in directed blasts can be reasonably interpreted to have been caused by high dynamic pressures and clast impact loading by an inclined collapsing fountain and stratified PDC. This view is reinforced by recent modeling cited for SHV. In distal and peripheral regions, solids concentration, maximum particle size, current speed, and dynamic pressure are diminished, resulting in lesser damage and enhanced influence by local topography on the PDC. Despite the different scales of the blasts (devastated areas were respectively 500, 600, and >10 km² for BZ, MSH, and SHV), and some complexity involving retrogressive slide blocks and clusters of explosions, their pyroclastic deposits demonstrate strong similarity. Juvenile material composes >50% of the deposits, implying for the blasts a dominantly magmatic mechanism although hydrothermal explosions also occurred. The character of the magma fragmented by explosions (highly viscous, phenocryst-rich, variable microlite content) determined the bimodal distributions of juvenile clast density and vesicularity. Thickness of the deposits fluctuates in proximal areas but in general decreases with distance from the crater, and laterally from the axial region. The proximal stratigraphy of the blast deposits comprises four layers named A, B, C, D from bottom to top. Layer A is represented by very poorly sorted debris with admixtures of vegetation and soil, with a strongly erosive ground contact; its appearance varies at different sites due to different ground conditions at the time of the blasts. The layer reflects intense turbulent boundary shear between the basal part of the energetic head of the PDC and the substrate. Layer B exhibits relatively well-sorted fines-depleted debris with some charred plant fragments; its deposition occurred by rapid suspension sedimentation in rapidly waning, high-concentration conditions. Layer C is mainly a poorly sorted massive layer enriched by fines with its uppermost part laminated, created by rapid sedimentation under moderate-concentration, weakly tractive conditions, with the uppermost laminated part reflecting a dilute depositional regime with grain-by-grain traction deposition. By analogy to laboratory experiments, mixing at the flow head of the PDC created a turbulent dilute wake above the body of a gravity current, with layer B deposited by the flow body and layer C by the wake. The uppermost layer D of fines and accretionary lapilli is an ash fallout deposit of the finest particles from the high-rising buoyant thermal plume derived from the sediment-depleted pyroclastic density current. The strong similarity among these eruptions and their deposits suggests that these cases represent similar source, transport and depositional phenomena.  相似文献   

The first known natural occurrence of calcium monoaluminate,in a calcium‐aluminum‐rich inclusion from the CH chondrite Northwest Africa 470     

Marina A. Ivanova  Michail I. Petaev  Glenn J. Macpherson  Michail A. Nazarov  Lawrence A. Taylor  John A. Wood 《Meteoritics & planetary science》2002,37(10):1337-1344

Abstract— Natural calcium monoaluminate, CaAl₂O₄, has been found in a grossite‐rich calcium‐aluminum‐rich inclusion (CAI) from the CH chondrite Northwest Africa 470. The calcium monoaluminate occurs as colorless ～10 μm subhedral grains intergrown with grossite, perovskite, and melilite. Nebular condensation is the most likely origin for the precursor materials of this CAI, but calculations suggest that dust/gas ratios substantially enhanced over solar are required to stabilize CaAl₂O₄.  相似文献   

The decline of Daphnia hyalina galeata in Lago Maggiore: a comparison of the population dynamics before and after oligotrophication     

Marina Manca  Claudio Ramoni  Patrizia Comoli 《Aquatic Sciences - Research Across Boundaries》2000,62(2):142-153

We reconstruct the impact of different environmental cues on Daphnia seasonal dynamics by means of an analysis of demographic and reproductive parameters, as well as of the size structure of the population. Data from 1996, indicative of the most recent productivity of the lake, with those from 1973, when the lake was meso-eutrophic, allow a discussion of the relevance of the observed changes for the structure of the pelagic food web of Lago Maggiore. Daphnia summer dynamics is mainly controlled by Bythotrephes longimanus. This is quite a different situation from that of the past, when Leptodora kindtii was the prevalent predatory cladocera. The size structure of Daphnia population revealed a depletion of small ovigerous females with increases in the predator. Our data allow a discussion of the idea, recently proposed, of Bythotrephes longimanus as a visual sit- and -wait predator.  相似文献   

Implementation of the European Marine Strategy Framework Directive: a methodological approach for the assessment of environmental status, from the Basque Country (Bay of Biscay)     

Borja A  Galparsoro I  Irigoien X  Iriondo A  Menchaca I  Muxika I  Pascual M  Quincoces I  Revilla M  Germán Rodríguez J  Santurtún M  Solaun O  Uriarte A  Valencia V  Zorita I 《Marine pollution bulletin》2011,62(5):889-904

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Distribution of trace metals in anchialine caves of Adriatic Sea,Croatia     

Vlado Cuculić  Neven CukrovŽeljko Kwokal  Marina Mlakar 《Estuarine, Coastal and Shelf Science》2011

This study presents results of the first comprehensive research on ecotoxic trace metals (Cd, Pb, Cu and Zn) in aquatic anchialine ecosystems. Data show the influence of hydrological and geological characteristics on trace metals in highly stratified anchialine water columns.  相似文献   

Polarization of the CMB Photons Crossing the Galaxy Clusters     

Marina Gibilisco 《Astrophysics and Space Science》1997,249(2):189-210

In this paper, I investigate a local effect of polarization of the Cosmic Microwave Background (CMB) in clusters of galaxies, induced by the Thomson scattering of an anisotropic radiation. A local anisotropy of the CMB is produced by some scattering and gravitational effects, as, for instance, the Sunyaev Zel‘dovich effect, the Doppler shift due to the cluster motion and the gravitational lensing. The resulting anisotropy ΔI/I depends on the physical properties of the clusters, in particular on their emissivity in the X band on their size, on their gravitational potential and on the peculiar conditions characterizing the gas they contain. By solving the Boltzmann radiative transfer equation in presence of such anisotropies I calculate the average polarization at the centre of some clusters, namelyA2218, A576 and A2163, whose properties are quite well known. I prove that the gravitational effects due to the contraction or to the expansion have some importance, particularly for high density structures; moreover, the peculiar motion of the cluster, considered as a gravitational lens, influences the propagation of the CMB photons by introducing a particular angular dependence in the gravitational anisotropy and in the scattering integrals. Thus, the gravitational and the scattering effects overally produce an appreciable local average polarization of the CMB, may be observable through a careful polarization measurements towards the centres of the galaxy clusters. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Thermal behavior of ferric selenite hydrates (Fe₂(SeO₃)₃·3H₂O,Fe₂(SeO₃)₃·5H₂O) and the water content in the natural ferric selenite mandarinoite     

Astrid Holzheid  Marina V. Charykova  Vladimir G. Krivovichev  Brendan Ledwig  Elena L. Fokina  Ksenia L. Poroshina  Natalia V. Platonova  Vladislav V. Gurzhiy 《Chemie der Erde / Geochemistry》2018,78(2):228-240

Any progress in our understanding of low-temperature mineral assemblages and of quantitative physico-chemical modeling of stability conditions of mineral phases, especially those containing toxic elements like selenium, strongly depends on the knowledge of structural and thermodynamic properties of coexisting mineral phases. Interrelation of crystal chemistry/structure and thermodynamic properties of selenium-containing minerals is not systematically studied so far and thus any essential generalization might be difficult, inaccurate or even impossible and erroneous. Disagreement even exists regarding the crystal chemistry of some natural and synthetic selenium-containing phases. Hence, a systematic study was performed by synthesizing ferric selenite hydrates and subsequent thermal analysis to examine the thermal stability of synthetic analogues of the natural hydrous ferric selenite mandarinoite and its dehydration and dissociation to unravel controversial issues regarding the crystal chemistry. Dehydration of synthesized analogues of mandarinoite starts at 56–87?°C and ends at 226–237?°C. The dehydration happens in two stages and two possible schemes of dehydration exist: (a) mandarinoite loses three molecules of water in the first stage of the dehydration (up to 180?°C) and the remaining two molecules of water will be lost in the second stage (>180?°C) or (b) four molecules of water will be lost in the first stage up to 180?°C and the last molecule of water will be lost at a temperature above 180?°C. Based on XRD measurements and thermal analyses we were able to deduce Fe₂(SeO₃)₃·(6-x)H₂O (x?=?0.0–1.0) as formula of the hydrous ferric selenite mandarinoite. The total amount of water apparently affects the crystallinity, and possibly the stability of crystals: the less the x value, the higher crystallinity could be expected.  相似文献   

Development of Oil and Gas Resources of Russia’s Arctic zone     

Oleg M. Barbakov  Marina L. Belonozhko  Anatoly N. Silin  Alexander S. Gyurdzhinyan 《Journal of the Geological Society of India》2018,92(6):764-766

The article dwells on the problems associated with the development of oil and gas Arctic region of Russia. It also suggests possibilities of their solution based on sociological studies conducted by the authors of representative samples in 2005, 2010 and 2015. Stressing the role and significance of sociological research in the general problem of the circumpolar regions by scientific study, the authors show the need for a sociological diagnosis in the context of different social groups. By doing so, characteristics of social problems inherent to the arctic region and requirements for scientific support of possible technologies is identified.  相似文献   

Modelling of hydraulic fracturing process by coupled discrete element and fluid dynamic methods     

Sousani Marina  Eshiet Kenneth Imo-Imo  Ingham Derek  Pourkashanian Mohamed  Sheng Yong 《Environmental Earth Sciences》2014,72(9):3383-3399

A three-dimensional model is presented and used to reproduce the laboratory hydraulic fracturing test performed on a thick-walled hollow cylinder limestone sample. This work aims to investigate the implications of the fluid flow on the behaviour of the micro-structure of the rock sample, including the material strength, its elastic constants and the initialisation and propagation of fractures. The replication of the laboratory test conditions has been performed based on the coupled Discrete Element Method (DEM) and Computational Fluid Dynamics scheme. The numerical results are in good agreement with the experimental data, both qualitatively and quantitatively. The developed model closely validates the overall behaviour of the laboratory sample, providing a realistic overview of the cracking propagation towards total collapse as well as complying with Lame’s theory for thick-walled cylinders. This research aims to provide some insight into designing an accurate DEM model of a fracturing rock that can be used to predict its geo-mechanical behaviour during Enhanced Oil Recovery applications.  相似文献