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61.
Keegan E. Alagna Maurizio Petrelli Diego Perugini Giampiero Poli 《Geostandards and Geoanalytical Research》2008,32(1):103-120
In this study we evaluated the capability of a 213 nm laser ablation system coupled to a quadrupole-based ICP-MS in delivering accurate and precise U-Pb ages on zircons and monazites. Four zircon samples ( ca. 50 Ma to ca. 600 Ma) and four monazite samples ( ca. 30 Ma to ca. 1390 Ma) of known ages were analysed utilising laser ablation pits with diameters of 20 μm and 60 μm. Instrument mass bias and laser induced time-dependent elemental fractionation were corrected for by calibration against a matrix-matched reference material. Tera-Wasserburg plots of the calculated U-Pb data were employed to assess, and correct for, common Pb contributions. The results indicated that the LA-ICP-MS technique employed in this study allowed precise and accurate U-Pb isotope dating of zircon and monazite on sample areas 20 μm in diameter. At this spot size, the precisions achieved for single spot 206 Pb/238 U ages, were better than 5% (2s) for monazites and zircons with ages down to 30 Ma and 50 Ma, respectively. The precisions reported are comparable to those generally reported in SIMS and LA-MC-ICP-MS U-Pb isotope determinations. 相似文献
62.
The Aptian-Albian 'Scisti a Fucoidi' varicoloured pelagic sediments in central Italy, show a 'couplet' alternation of carbonate-rich/carbonate-poor layers, which are interpreted as the sedimentary expression of precession (frequency 19–23 kyr). Carbonate content, chromatic variation, and planktonic foraminiferal abundance were analysed at a 1-cm spacing for a 10-m interval of the Piobbico core, specifically drilled through this formation. Spectral analysis of these parameters shows a prominent signal equated to the c . 100 kyr cycle of orbital eccentricity at a sedimentation rate of 5 mm kyr−1 . The coherency of the spectral response of each parameter suggests that a single mechanism controlled the whole sedimentary record. Detailed study of planktonic foraminiferal distribution of the same section at 1-mm scale resolves the Milankovitch frequencies of 41 kyr and 18 to 23 kyr, equated with the obliquity and precessional cycles. But foraminiferal abundance is not in phase with carbonate content, which was largely controlled by calcareous nannofossils, but peaked at intermediate carbonate values. The proposed model for explaining the discrepancy at the precessional level is that foraminifera thrived at intermediate values of the precession index, when the environment was only moderately fertile but stable, while during highs of the precession index, mixing of the water column increased fertility and caused calcareous nannofossil blooms and restriction of planktonic foraminifera to few and tolerant species. The resulting bimodality of foraminiferal abundance per precessional cycle appears to be recorded in the spectrum by peaks at the 11 and 14 kyr levels. Cross correlation of foraminiferal abundances with the calcium carbonate curve over 1–2 Myr intervals produces discrepant results (apparent phase lags) which we attribute to differences in the response to the fundamental eccentricity cycles. 相似文献
63.
64.
Maurizio Petrelli Luca Caricchi Peter Ulmer 《Geostandards and Geoanalytical Research》2007,31(1):13-25
In this contribution we evaluate the capabilities of laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) using a 12 μm spot size. Precision, accuracy and detection limits were assessed on the USGS BCR-2G reference material. We demonstrate that the 12 μm LA-ICP-MS analyses of experimentally-grown amphibole and garnet are in excellent agreement with secondary ion mass spectrometry (SIMS) trace element determinations on the same crystals. The 12 μm spot size configuration was subsequently used to determine trace element crystal-melt partition coefficients (Dc/m ) for a wide range of trace elements in amphibole in equilibrium with a basanitic melt. The following strategy to determine accurately and evaluate Dc/m is proposed. One or more major elements determined previously by electron probe microanalysis (EPMA) was used to ensure consistency between EPMA and the composition of the aerosol produced by the laser ablation. Measured Dc/m values were successively evaluated using the lattice strain model. The use of this strategy significantly improved the precision and accuracy of Dc/m determination when a LA-ICP-MS configuration with a high spatial resolution was employed. 相似文献
65.
Federico Cella Maurizio Fedi Giovanni Florio Marino Grimaldi Antonio Rapolla 《Journal of Volcanology and Geothermal Research》2007
A gravity investigation was carried out in the Somma–Vesuvius complex area (Campania, Italy) based on a dataset recently enlarged with new measurements. These cover the volcanic top and fill some other important spatial gaps in previous surveys. Besides the new gravity map of the Vesuvius, we also present the results of a 3D inverse modelling, carried out by using constraints from deep well exploration and seismic reflection surveys. The resulting density model provides a complete reconstruction of the top of the carbonate basement. This is relevant mostly on the western side of the survey area, where no significant information was previously available. Other new information regards the Somma–Vesuvius structure. It consists of an annular volume of rocks around the volcanic vent and that extends down to the carbonate basement. It results to be denser with respect to the surrounding sedimentary cover of the Campanian Plain and to the material located just along the central axis of the volcanic structure. The coherence between these features and other geophysical evidences from previous studies, will be discussed together with the other results of this research. 相似文献
66.
An experimental facility has been developed to investigate magma-water interaction (MWI). The facility operates in a high-pressure
and high-temperature environment, with temperatures up to 1,200°C and pressures up to 200 MPa. Cylindrical sample-holders
(20 by 180 mm in size) are heated conductively to yield a three phase (melt, crystals and gas) system, and then water (or
other fluid) is injected into the sample through a capillary tube (diameter 0.5 mm, length ca. 1,000 mm) under controlled
conditions. Pressure, volume and temperature changes are continuously recorded during every phase of the experiments. To test
this facility, MWI is studied at subliquidus temperatures (800 and 900°C) and pressure (8 MPa), using a leucite tephrite sample
with two different initial grain sizes. Because of the grain-size dependence of sintering, the two starting materials produce
magmas with different textures at the same temperature: porous magma for large initial grain sizes and dense magma for small
initial grain sizes. In these experiments 1.5 g of water at room temperature is injected into 6.0 g of partially molten sample
at velocities ranging from 1 to 3 m/s. We find that the extent of fragmentation and transport caused by MWI are mainly controlled
by the texture of the interacting sample with explosive interaction occurring only for porous magmas. 相似文献
67.
Tatiana Quarta Maurizio Fedi & Angelo De Santis 《Geophysical Journal International》2000,140(2):311-323
An analysis of the field scaling power spectrum yields useful information about the source distribution, but it is uncertain whether deterministic, random, fractal or mixed approaches have to be used for the interpretation. To this end, the scaling properties of potential field spectra are analysed for a number of different source models of geological interest. Besides the models of Naidu (purely random sources) and Spector and Grant (gross block statistical ensembles) we consider other types of density and magnetization distributions with spectral exponents in the fractal range, such as a single homogeneous body with a random white source distribution. Spectral slopes in the fractal range are obtained.
We also study the effects of important natural sources, such as salt domes and sedimentary basins, representing them with simple Gaussians or combinations of Gaussian signals. The same spectral slopes as for gravity signals generated by 3-D fractal source distributions are found for them. Hence the power law decay of the field is not a characteristic only of fractal source models.
If a 3-D fractal source distribution is assumed a priori , a way of verifying the goodness of the model is to examine the whitened field at source level. The probability that the whitened field derives from a random white population is estimated for synthetic and real anomalies by applying the usual statistical tests. 相似文献
We also study the effects of important natural sources, such as salt domes and sedimentary basins, representing them with simple Gaussians or combinations of Gaussian signals. The same spectral slopes as for gravity signals generated by 3-D fractal source distributions are found for them. Hence the power law decay of the field is not a characteristic only of fractal source models.
If a 3-D fractal source distribution is assumed a priori , a way of verifying the goodness of the model is to examine the whitened field at source level. The probability that the whitened field derives from a random white population is estimated for synthetic and real anomalies by applying the usual statistical tests. 相似文献
68.
The Sponge Community of a Semi-Submerged Mediterranean Cave 总被引:1,自引:0,他引:1
Giuseppe Corriero Lidia Scalera Liaci Daniela Ruggiero & Maurizio Pansini 《Marine Ecology》2000,21(1):85-96
Abstract. The sponge fauna of a semi-submerged cave from the Tremiti Archipelago (Adriatic Sea) was studied, and its distribution was analyzed in relation to abiotic (water-movement and light gradients) and biotic (algae and anthozoan substrate cover) ecological factors. Fifty-five species of sponges were recorded. The number of species and the abundance values of sponges increase in the first part of the cave, then progressively decrease, with a sharp fall at the end of the cave. The quick disappearance of algae along the light gradient allows sponges to thrive in the first portion of the cave. The subsequent, progressive decrement of sponges could be the result of food depletion phenomena due to a long persistence of the water body in this long cavity. A high water-turbulence, due to the peculiar morphology of the cave and indicated by the recorded values of water-movement, occurs at the end of the cavity and probably determines the sharp decrement of sponges in the inner portion of the cave. This turbulence may also explain the absence of typical still-water cave species and probably affects the type of development (shape, overgrowth) of the sponges in the community. 相似文献
69.
70.
Marco Bertolino Barbara Calcinai Riccardo Cattaneo‐Vietti Carlo Cerrano Anna Lafratta Maurizio Pansini Daniela Pica Giorgio Bavestrello 《Marine Ecology》2014,35(2):149-158
The Mediterranean coralligenous substratum is a hard bottom of biogenic origin, mainly composed of calcareous algae, growing in dim light conditions. Sponges are among of the most representative taxa of the coralligenous assemblages, with more than 300 recorded species of different habits: massive, erect, boring and insinuating. When sponges die, their siliceous spicules remain trapped in the biogenic concretion, offering the opportunity to describe the coralligenous spongofauna over a very long span of time, virtually dating back to a large part of the Holocene period. The data reported here were obtained from core samples collected from four coralligenous concretions. Each block was collected in a different locality of the Ligurian Sea: Santo Stefano Shoals, Bogliasco, Punta del Faro (Portofino Promontory) and Punta Manara. Radiocarbon age determinations indicate for these conglomerates a maximal age between 1600 and 3100 years. The spicules trapped in the cores show deep dissolution marks in the form of circular holes on their surface or present an enlargement of the axial canal. However, their original shape, generally intact, suggests the absence of mechanical injuries and allows a tentative identification at the species level. The analysis of these old spicules reveals an ancient sponge assemblage composed of 30 recognisable species. This indicates that almost one half of the sponge community today settled on coralligenous substrata has been present in the conglomerates for their entire existence. 相似文献