ERORUN-STAFOR: A collaborative observatory for the multidisciplinary study of the critical zone processes in a tropical volcanic watershed including a Tropical Montane Cloud Forest     

Alix Toulier  Jean-Lambert Join  Pierre Staménoff  Yoan Benoit  Geneviève Lebeau  Maxime Gautier  Caroline Gorge  Eric Gayer  Emmanuel Cordier  Victor Kbidi  Guillaume Payen  Magali David  Sophie Ferreira  François Bonnardot  Julien Bonnier  Stéphane Martel  Jimmy Gonthier  Emilie Roulleau  Jean-Pierre Cammas  Dominique Strasberg  Olivier Flores  Fabrice R. Fontaine  Thomas Giambelluca  Claudine Ah-Peng 《水文研究》2024,38(2):e15061

Tropical volcanic islands are biodiversity hotspots where the Critical Zone (CZ) still remains poorly studied. In such steep topographic environments associated with extreme climatic events (cyclones), deployment and maintenance of monitoring equipment is highly challenging. While a few Critical Zone Observatories (CZOS) are located in tropical volcanic regions, none of them includes a Tropical Montane Cloud Forest (TMCF) at the watershed scale. We present here the dataset of the first observatory from the French network of critical zone observatories (OZCAR) located in an insular tropical and volcanic context, integrating a ‘Tropical Montane Cloud Forest’: The ERORUN-STAFOR observatory. This collaborative observatory is located in the northern part of La Réunion island (Indian Ocean) within the 45.0 km² watershed of Rivière des Pluies (i.e., Rainfall river) which hosts the TMCF of Plaines des Fougères, one of the best preserved natural habitats in La Réunion Island. Since 2014, the ERORUN-STAFOR monitoring in collaboration with local partners collected a multidisciplinary dataset with a constant improvement of the instrumentation over time. At the watershed scale and in its vicinity, the ERORUN-STAFOR observatory includes 10 measurement stations covering the upstream, midstream and downstream part of the watershed. The stations record a total of 48 different variables through continuous (sensors) or periodic (sampling) monitoring. The dataset consists of continuous time series variables related to (i) meteorology, including precipitation, air temperature, relative humidity, wind speed and direction, net radiation, atmospheric pressure, cloud water flux, irradiance, leaf wetness and soil temperature, (ii) hydrology, including water level and temperature, discharge and electrical conductivity (EC) of stream, (iii) hydrogeology, including (ground)water level, water temperature and EC in two piezometers and one horizontally drilled groundwater gallery completed by soil moisture measurements under the canopy. The dataset is completed by periodic time series variables related to (iv) hydrogeochemistry, including field parameters and water analysis results. The periodic sampling survey provides chemical and isotopic compositions of rainfall, groundwater, and stream water at different locations of this watershed. The ERORUN-STAFOR monitoring dataset extends from 2014 to 2022 with an acquisition frequency from 10 min to hourly for the sensor variables and from weekly to monthly frequency for the sampling. Despite the frequent maintenance of the monitoring sites, several data gaps exist due to the remote location of some sites and instrument destruction by cyclones. Preliminary results show that the Rivière des Pluies watershed is characterized by high annual precipitation (>3000 mm y⁻¹) and a fast hydrologic response to precipitation (≈2 h basin lag time). The long-term evolution of the deep groundwater recharge is mainly driven by the occurrence of cyclone events with a seasonal groundwater response. The water chemical results support existing hydrogeological conceptual models suggesting a deep infiltration of the upstream infiltrated rainfall. The TMCF of Plaine des Fougères shows a high water storage capacity (>2000% for the Bryophytes) that makes this one a significant input of water to groundwater recharge which still needs to be quantified. This observatory is a unique research site in an insular volcanic tropical environment offering three windows of observation for the study of critical zone processes through upstream-midstream-downstream measurements sites. This high-resolution dataset is valuable to assess the response of volcanic tropical watersheds and aquifers at both event and long-term scales (i.e., global change). It will also provide insights in the hydrogeological conceptual model of volcanic islands, including the significant role of the TMCFs in the recharge processes as well as the watershed hydrosedimentary responses to extreme climatic events and their respective evolution under changing climatic conditions. All data sets are available at https://doi.org/10.5281/zenodo.7983138 .  相似文献   

F,Cl and S input via serpentinite in subduction zones: implications for the nature of the fluid released at depth     

Baptiste Debret  Kenneth T. Koga  Christian Nicollet  Muriel Andreani  Stéphane Schwartz 《地学学报》2014,26(2):96-101

The abundances of F, Cl and S in arc magmas are systematically higher than in other mantle‐derived magmas, suggesting that these elements are added from the slab along with H₂O. We present ion probe microanalyses of F, Cl and S in serpentine minerals that represent the P–T evolution of the oceanic lithosphere, from its serpentinization at the ridge, to its dehydration at around 100 km depth during subduction. F, Cl and S are incorporated early into serpentine during its formation at mid‐ocean ridges, and serpentinized lithosphere then carries these elements to subduction zones. More than 50% of the F, Cl and S are removed from serpentine during the prograde metamorphic lizardite/antigorite transition. Due to the low solubility of F in water, and to the low amount of water released during this phase transition, the fluids mobilizing these elements must be dominated by SO_X rather than H₂O.  相似文献   

Magnetite‐out and pyrrhotite‐in temperatures in shales and slates     

Charles Aubourg  Mike Jackson  Maxime Ducoux  Mohannad Mansour 《地学学报》2019,31(6):534-539

Clay‐rich basins have undergone varying degrees of magnetic transformation during burial, affecting their ability to retain accurate records of Earth's dynamic magnetic field. We propose to bracket the magnetite‐out and pyrrhotite‐in temperatures in shales and slates from Taiwan and the Pyrenees by using a combination of low‐temperature magnetic transitions and geothermometers. For T_burial < 340°C, the magnetic assemblage is dominated by magnetite. Gradually with increasing burial temperature, the concentration of magnetite decreases to a few ppmv. We observe the magnetite‐out isograd at T_burial ~350°C. At T_burial >60°C and T_burial >340°C respectively, fine‐grained and coarse‐grained pyrrhotite develop. In the course of burial, a clay‐rich basin gradually loses its capability to retain a record of Earth's magnetic field. It is only during basin uplift, that coarse pyrrhotite might acquire a thermo remanent magnetization. Our results point out therefore highly contrasted magnetic properties and palaeomagnetic records between deeply buried basins and exhumed ones.  相似文献   

Adoption of flood-related preventive behaviours by people having different risks and histories of flooding     

Valois  Pierre  Bouchard  David  Talbot  Denis  Caron  Maxime  Renaud  Jean-Sébastien  Gosselin  Pierre  Jacob  Johann 《Natural Hazards》2020,102(3):1155-1173

Natural Hazards - The increase in the frequency of floods, which is a projected consequence of climate change, can have wide-ranging health and economic impacts. To cope with these floods and to...  相似文献   

Estimation of large wood budgets in a watershed and river corridor at interdecadal to interannual scales in a cold‐temperate fluvial system          下载免费PDF全文

Maxime Boivin  Thomas Buffin‐Bélanger  Hervé Piégay 《地球表面变化过程与地形》2017,42(13):2199-2213

Large wood (LW) is a ubiquitous feature in rivers of forested watersheds worldwide, and its importance for river diversity has been recognized for several decades. Although the role of LW in fluvial dynamics has been extensively documented, there is a need to better quantify the most significant components of LW budgets at the river scale. The purpose of our study was to quantify each component (input, accumulation, and output) of a LW budget at the reach and watershed scales for different time periods (i.e. a 50‐year period, decadal cycle, and interannual cycle). The LW budget was quantified by measuring the volumes of LW inputs, accumulations, and outputs within river sections that were finally evacuated from the watershed. The study site included three unusually large but natural wood rafts in the delta of the Saint‐Jean River (SJR; Québec, Canada) that have accumulated all LW exported from the watershed for the last 50 years. We observed an increase in fluvial dynamics since 2004, which led to larger LW recruitment and a greater LW volume trapped in the river corridor, suggesting that the system is not in equilibrium in terms of the wood budget but is rather recovering from previous human pressures as well as adjusting to hydroclimatic changes. The results reveal the large variability in the LW budget dynamics during the 50‐year period and allow us to examine the eco‐hydromorphological trajectory that highlights key variables (discharge, erosion rates, bar surface area, sinuosity, wood mobility, and wood retention). Knowledge on the dynamics of these variables improves our understanding of the historical and future trajectories of LW dynamics and fluvial dynamics in gravel‐bed rivers. Extreme events (flood and ice‐melt) significantly contribute to LW dynamics in the SJR river system. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

Non‐Destructive or Noninvasive? The Potential Effect of X‐Ray Fluorescence Spectrometers on Luminescence Age Estimates of Archaeological Samples     

Jillian Huntley  Kira E. Westaway  Damian B. Gore  Maxime Aubert  June Ross  Michael J. Morwood 《Geoarchaeology》2016,31(6):592-602

The non‐destructive nature of X‐ray fluorescence (XRF) spectrometers is a principal reason for an increase in their use in archaeological science over the last 15 years, especially for analyzing museum‐curated artifacts and in situ site fabrics. Here, we show that low‐power XRF spectrometry can be detrimental for luminescence dating (surface applications such as mud‐wasp nest dating in particular). We investigated the effects of irradiation by X‐rays emitted from handheld and benchtop spectrometers on optically stimulated luminescence (OSL) signals. Measurements were taken using a portable OSL (pOSL) unit on the following unprepared archaeological materials: sedimentary quartz grains, pottery, a mud‐wasp nest, stone tools, and a rock flake with anthropogenically applied pigment and natural pigmentation (iron oxides). We observed an increase in luminescence compared to initial background counts for all materials tested, which could lead to overestimation of age determinations in some situations. Our experiment provides a reminder of the potential effects of X‐ray radiation, and the need for thorough documentation of all recording and analytical techniques applied to archaeological materials.  相似文献   

On the limits of using combined U-series/ESR method to date fossil teeth from two Early Pleistocene archaeological sites of the Orce area (Guadix-Baza basin,Spain)     

Mathieu Duval  Christophe Falguères  Jean-Jacques Bahain  Rainer Grün  Qingfeng Shao  Maxime Aubert  Jean-Michel Dolo  Jordi Agustí  Bienvenido Martínez-Navarro  Paul Palmqvist  Isidro Toro-Moyano 《Quaternary Research》2012,77(3):482-491

The combined U-series/electron spin resonance (ESR) dating method was applied to nine teeth from two Early Pleistocene archaeological sites located in the Orce area (Guadix-Baza Basin, Southern Spain): Fuente Nueva-3 (FN-3) and Barranco León (BL). The combination of biostratigraphy and magnetostratigraphy places both sites between the Olduvai and Jaramillo subchrons (1.78–1.07 Ma).Our results highlight the difficulty of dating such old sites and point out the limits of the combined U-series/ESR dating method based on the US model. We identified several sources of uncertainties that may lead to inaccurate age estimates. Seven samples could not be dated because the dental tissues had (²³⁰Th/²³⁴U) activity ratios higher than equilibrium, indicating that uranium had probably leached from these tissues. It was however possible to calculate numerical estimates for two of the teeth, both from FN-3. One yielded a Middle Pleistocene age that seems to be strongly underestimated; the other provided an age of 1.19 ± 0.21 Ma, in agreement with data obtained from independent methods. The latter result gives encouragement that there are samples that can be used for routine dating of old sites.  相似文献   

Ensemble-Based Seismic and Production Data Assimilation Using Selection Kalman Model     

Conjard  Maxime  Grana  Dario 《Mathematical Geosciences》2021,53(7):1445-1468

Data assimilation in reservoir modeling often involves model variables that are multimodal, such as porosity and permeability. Well established data assimilation methods such as ensemble Kalman filter and ensemble smoother approaches, are based on Gaussian assumptions that are not applicable to multimodal random variables. The selection ensemble smoother is introduced as an alternative to traditional ensemble methods. In the proposed method, the prior distribution of the model variables, for example the porosity field, is a selection-Gaussian distribution, which allows modeling of the multimodal behavior of the posterior ensemble. The proposed approach is applied for validation on a two-dimensional synthetic channelized reservoir. In the application, an unknown reservoir model of porosity and permeability is estimated from the measured data. Seismic and production data are assumed to be repeatedly measured in time and the reservoir model is updated every time new data are assimilated. The example shows that the selection ensemble Kalman model improves the characterisation of the bimodality of the model parameters compared to the results of the ensemble smoother.

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Tinted windows: The presence of the UV absorbing compounds called mycosporine-like amino acids embedded in the frustules of marine diatoms     

Anitra E. Ingalls  Kenia Whitehead  Maxime C. Bridoux 《Geochimica et cosmochimica acta》2010,74(1):104-115

Diatom frustule-bound organic compounds presumably play an important role in biomineralization and constitute an important pool of organic matter preserved in diatom frustule-rich sediments. In this study, detailed analysis of diatom frustule-bound organic matter in opal-rich Southern Ocean plankton and sediments revealed for the first time the presence of low molecular weight, UV light absorbing compounds called mycosporine-like amino acids (MAAs). Chemically cleaned diatom frustule-derived biosilica was dissolved in HF, releasing bound or entrapped organic compounds that were subsequently characterized using liquid chromatography with UV-Vis and electrospray ionization mass spectrometry (LC/PDA/ESI-MS). Palythine ([M+H]⁺ = 245), porphyra-334 ([M+H]⁺ = 347) and shinorine ([M+H]⁺ = 333) were the most abundant MAAs detected in HF digests of plankton and sediment. Traces of asterina ([M+H]⁺ = 289), palythinol ([M+H]⁺ = 303) and palythinic acid ([M+H]⁺ = 329) were also detected. MAAs in cleaned HF digested frustules were up to two orders of magnitude more abundant than methanol extractable MAAs. MAAs are substituted with acid hydrolysable amino acid residues. Our results suggest that MAAs, and not proteins, could be responsible for the high proportion of the amino acids glycine and threonine found in hydrolysates of HF digested diatom-rich environmental samples. Total MAAs accounted for 3-27% of the carbon and 2-18% of total nitrogen in the frustules undergoing various chemical cleaning treatments. This is the first report of MAAs in close association with a mineral phase and we hypothesize that the mineral matrix could stabilize these compounds, thereby enhancing photoprotection against the harmful effects of UV light. The presence of frustule-bound MAAs in sediment cores further suggests the possibility that they could be used in compound-specific isotope analysis of diatom-bound organic matter and as indicators of past solar irradiance.  相似文献   

Influence of glass polymerisation and oxidation on micro-Raman water analysis in alumino-silicate glasses   总被引：1，自引：0，他引：1  

Maxime Mercier  Andrea Di Muro  Daniele Giordano  Priscille Lesne  Bruno Scaillet  Gilles Montagnac 《Geochimica et cosmochimica acta》2009,73(1):197-217

The development of an accurate analytical procedure for determination of dissolved water in complex alumino-silicate glasses via micro-Raman analysis requires the assessment of the spectra topology dependence on glass composition. We report here a detailed study of the respective influence of bulk composition, iron oxidation state and total water content on the absolute and relative intensities of the main Raman bands related to glass network vibrations (LF: ∼490 cm⁻¹; HF: ∼960 cm⁻¹) and total water stretching (H₂O_T: ∼3550 cm⁻¹) in natural glasses. The evolution of spectra topology was examined in (i) 33 anhydrous glasses produced by the re-melting of natural rock samples, which span a very large range of polymerisation degree (NBO/T from 0.00 to 1.16), (ii) 2 sets of synthetic anhydrous basaltic glasses with variable iron oxidation state (Fe³⁺/Fe_T from 0.05 to 0.87), and (iii) 6 sets of natural hydrous glasses (C_H2OT from 0.4 to 7.0 wt%) with NBO/T varying from 0.01 to 0.76.In the explored domain of water concentration, external calibration procedure based on the H₂O_T band height is matrix-independent but its accuracy relies on precise control of the focusing depth and beam energy on the sample. Matrix-dependence strongly affects the internal calibrations based on H₂O_T height scaled to that of LF or HF bands but its effect decreases from acid (low NBO/T, SM) to basic (high NBO/T, SM) glasses. Structural parameters such as NBO/T (non-bridging oxygen per tetrahedron) and SM (sum of structural modifiers) describe the matrix-dependence better than simple compositional parameters (e.g. SiO₂, Na₂O + K₂O). Iron oxidation state has only a minor influence on band topology in basalts and is thus not expected to significantly affect the Raman determinations of water in mafic (e.g. low SiO₂, iron-rich) glasses. Modelling the evolution of the relative band height with polymerisation degree allows us to propose a general equation to predict the dissolved water content in natural glasses: