The effect of pumice as aggregate on the mechanical and thermal properties of foam concrete     

Şemsettin Kilincarslan  Metin Davraz  Mehmet Akça 《Arabian Journal of Geosciences》2018,11(11):289

Pumice is a porous rock, which is formed as a result of volcanic activity and does not include any crystal water. Its porous structure makes it lightweight and provides advantage for heat and sound isolation. Foam concrete is a type of lightweight concrete. Foam concrete is obtained by adding the foam obtained from the agent to the mixture of cement, water, and aggregate. Foam concrete is an environmentally friendly structure and insulation material which provides light, heat, and impact sound insulation that can be used in place of the building elements used in the interior-exterior walls and floors of all buildings. Because of the lack of coarse aggregate in the foam concrete mix, it has some structural problems and this limits its usage area. In this study, four different types of pumice aggregates and stone powder were used to overcome the structural problems of foam. The cement dosages (250 kg/m³), aggregate amounts (250 kg/m³), fresh concrete densities and w/c ratio (0.45) were kept constant in all foamed concrete mixtures. Then, physical, mechanical, and thermal conductivity properties of the resulting foam concretes were investigated. When the findings were evaluated, the most suitable type of lightweight aggregates for use in foam concrete have been determined in terms of compressive strength and thermal conductivity properties. In all aggregate groups, Nevsehir Pumice has the highest compressive strength while Karaman Pumice has the lowest thermal conductivity. However, when both properties were evaluated together, it was determined that the most favorable lightweight aggregate was Nevsehir Pumice.  相似文献   

Novel applications of fluid inclusions and isotope geochemistry in unravelling the genesis of fossil travertine systems   总被引：1，自引：0，他引：1       下载免费PDF全文

Hamdy El Desouky  Jeroen Soete  Hannes Claes  Mehmet Özkul  Frank Vanhaecke  Rudy Swennen 《Sedimentology》2015,62(1):27-56

The Denizli Basin is a fault‐bounded Neogene–Quaternary depression located in the Western Anatolian Extensional Province, Western Turkey. The basin is a unique geological site with abundant active and fossil (Quaternary) travertine and tufa deposits. Fluid inclusion microthermometry and isotopic analysis were applied to study the genesis of the Ball?k fossil travertine deposits, located in the south‐eastern part of the basin. Microthermometry on fluid inclusions indicates that the main travertine precipitating and cementing fluids are characterized by low salinity (<0·7 wt% NaCl equivalent) and variable temperatures that cluster at <50°C and ca 100°C. Fluids of meteoric origin have been heated by migration to the deeper subsurface, possibly in a local high geothermal gradient setting. A later uncommon cementation phase is related to a fluid with a significantly higher salinity (25·5 to 26·0 wt% bulk). The fluid obtained its salinity by interaction with Late Triassic evaporite layers. Strontium isotopes indicate that the parent carbonate source rock of the different travertine precipitates is very likely to be the Triassic limestone of the Lycian Nappes. Carbon isotopes suggest that the parent CO₂ gas originated from thermal decarbonation of the Lycian limestones with minor contributions of magmatic degassing and organic soil CO₂. Oxygen isotopes confirm the meteoric origin of the fluids and indicate disequilibrium precipitation because of evaporation and degassing. Results were integrated within the available geological data of the Denizli Basin in a generalized travertine precipitation model, which enhanced the understanding of fossil travertine systems. The study highlights the novel application of fluid inclusion research in unravelling the genesis of continental carbonates and provides several recommendations for hydrocarbon exploration in travertine‐bearing sedimentary basins. The findings suggest that travertine bodies and their parent carbonate source rocks have the potential to constitute interesting subsurface hydrocarbon reservoirs.  相似文献   

Geochemistry,provenance and tectonic setting of the Late Cambrian–Early Ordovician Seydişehir Formation in the Çaltepe and Fele areas,SE Turkey     

Mehmet Muzaffer Karadağ 《Chemie der Erde / Geochemistry》2014

The major, trace and rare earth element (REE) contents of metapelite (MPL), metapsammite (MPS) and metamarl (MM) samples from the Cambro-Ordovician Seydi?ehir Formation were analyzed to investigate their provenance and tectonic setting. The MPS, MPL, and MM samples have variable SiO₂ concentrations, with average values of 72.36, 55.54, and 20.95 wt%, moderate SiO₂/Al₂O₃ ratios (means of 6.88, 3.23, and 3.80), moderate to high Fe₂O₃ + MgO contents (means of 5.14, 9.55, 3.56 wt%), and high K₂O/Na₂O ratios (means of 3.26, 3.64, 2.90), respectively. On average, the chemical index of alteration (CIA) values of the MPS and the MPL are 65.87 and 71.96, respectively, while the chemical index of weathering (CIW) values are 74.54 and 85.09, respectively. These data record an intermediate to high degree of alteration (weathering) of plagioclase to illite/kaolinite in the samples’ provenance. The chondrite-normalized REE patterns of all the sample groups are similar and are characterized by subparallel light rare earth elements (LREE)-enriched, relatively flat heavy rare earth elements (HREE) patterns with pronounced Eu anomalies (mean of 0.69) and moderate fractionation [average (La/Yb)_N = 8.7]. Plots of sediments in ternary diagrams of La, Th, Sc and elemental ratios (La/Sc, Th/Sc, Cr/Th, Eu/Eu*, La/Lu, Co/Th, La/Sc and Sc/Th), which are critical for determining provenance, and REE patterns indicate that the metaclastic units of the Seydi?ehir Formation were derived dominantly from felsic to intermediate magmatic rocks and not from a mafic source. The La–Sc–Th and Th–Sc–Zr/10 ternary diagrams of the Seydi?ehir Formation are typical of continental island arc/active continental margin tectonic settings. The geologic location and geochemistry of the Seydi?ehir Formation suggest that it was deposited in an Andean-type retroarc foreland basin during the Late Cambrian–Early Ordovician period. The Neoproterozoic intermediate to felsic magmatic rocks and metaclastic sediments with felsic origins of the Sand?kl?–Afyon Basement Complex (SBC) and their equivalent units, which are thought to be overlain by the younger units in the study area, may be the dominant source rocks for the Seydi?ehir Formation.  相似文献   

Determining the impact of climate change on land suitability for rice paddy cultivation using GIS and RS on FAO maximum limitation approach     

Ozsahin  Emre  Ozdes  Mehmet 《Theoretical and Applied Climatology》2022,149(1-2):53-68

Theoretical and Applied Climatology - In the present study, we aimed to understand the current condition of land suitability and how climate change will affect its suitability for rice paddy...  相似文献   

Petrogenesis of the late Cretaceous Turnag(o)l intrusion in the eastern Pontides: Implications for magma genesis in the arc setting     

Abdullah Kaygusuz  Ferkan Sipahi  Nurdane lbeyli  Mehmet Arslan  Bin Chen  Emre Aydnakr 《地学前缘(英文版)》2013,4(4)

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Petrogenesis of the late Cretaceous Turnagoel intrusion in the eastern Pontides： Implications for magma genesis in the arc setting     

Abdullah Kaygusuz  Ferkan Sipahi  Nurdane Ilbeyli  Mehmet Arslan  Bin Chen  Emre Aydinakir 《地学前缘(英文版)》2013,4(4):423-438

A series of Cretaceous plutons is present in the eastern Pontides of northeastern Turkey.The Turnagl intrusion is the least studied and,thus,the least understood plutons in the orogen.This intrusion consists of hornblende-biotite granodiorites emplaced at 78 Ma based on LA-ICP-MS U-Pb zircon dating.It is of sub- alkaline affinity,belongs to the medium- to high-K calc-alkaline series,and displays features typical of Itype granites.The rocks of the intrusion are enriched in large-ion lithophile elements and light rare earthelements with negative Eu anomalies（Eu/Eu^*= 0.69-0.82）,but are deficient in high-field-strength elements.They have a small range of (⁸⁷Sr/⁸⁶Sr)_i（0.7060-0.7063）,ε_Ndi（-2.6 to -3.1）,and δ¹⁸O（+8.1 to +9.1） values.Their Pb isotopic ratios are ²⁰⁶Pb/²⁰⁴Pb = 18.63-18.65,²⁰⁷Pb/²⁰⁴Pb = 15.62-15.63,and ²⁰⁸Pb/²⁰⁴Pb = 38.53-38.55.The fractionation of plagioclase,hornblende,and Fe-Ti oxides had key functions in the evolution of the Tumagl intrusion.The crystallization temperatures of the melts ranged from 758 to 885℃ as determined by zircon and apatite saturation thermometry.All these characteristics,combined with the low values of K₂O/Na₂O and（Na₂O + K₂O）/（FeO^t+MgO + TiO₂）,as well as the high values of （CaO + FeO^t + MgO + TiO₂）.suggest an origin by dehydration melting from a metabasaltic lowercrustal source.  相似文献   

Fractionation of Ni,Cr and Cu from Soil by Sequential Extraction Procedure and Determination by Inductively Coupled Plasma Optical Emission Spectrometry     

Sukran Akkus  Tulin Bal  Nagihan M. Karaaslan  Emre Yaman  Ersin Kilinc  Mehmet Yaman 《洁净——土壤、空气、水》2013,41(12):1229-1234

Five‐step sequential extractions were employed to fractionation of Ni, Cr and Cu in soil polluted by anthropogenic activities and determine the mobility of the metals. Twelve samples were collected on an agricultural area that was located near an airport and intercity roads in Elazig‐Turkey. Exchangeable, organically bounded, carbonate bounded, adsorbed species on Fe and Mn oxides and residual species (except silicates) of Ni, Cr and Cu were extracted into solution by using CaCl₂, Na₄P₂O₇, Na₂EDTA, NH₂OH–HCl and HNO₃–H₂O₂, respectively. Mobile metal concentrations in fractions and total recoverable in soils were determined by using inductively coupled plasma‐optical emission spectrometry (ICP‐OES). Total recoverable Ni, Cr and Cu concentrations were in the range of 40–119, 45–126 and 23–72 mg kg^?1, respectively. It was observed that total concentrations of metals in some of the samples were higher than the permitted values. The sum of the mobile percentages of metals was found to be lower than 50%. The Ni, Cr and Cu percentages for exchangeable species are in the ranges of 0.18–1.64, 0.03–0.59 and 0.42–2.53%, respectively.  相似文献   

Preconcentration by Coprecipitation of Copper and Nickel with Mo(VI)/Triazole Derivative System and Their Determinations by Flame Atomic Absorption Spectrometry in Food and Water Samples     

Duygu Ozdes  Celal Duran  Hacer Bayrak  Volkan Numan Bulut  Mehmet Tufekcı 《洁净——土壤、空气、水》2012,40(2):211-217

A new separation and preconcentration technique based on coprecipitation of Cu(II) and Ni(II) ions by the aid of Mo(VI)/di‐tert‐butyl{methylenebis[5‐(chlorobenzyl)‐4H‐1,2,4‐triazol‐3,4‐diyl]}biscarbamate (BUMECTAC) precipitate has been established. The Mo(VI)/BUMECTAC precipitate was dissolved by concentrated HNO₃ and the solution was completed to 5.0 mL with distilled/deionized water. The levels of the analyte ions were determined by flame atomic absorption spectrometer. The effects of experimental conditions like HNO₃ concentration, amount of BUMECTAC and Mo(VI), sample volume, etc. and also the influences of some foreign ions were investigated in detail on the quantitative recoveries of analyte ions. The preconcentration factors were found to be 40 for Cu(II) and 100 for Ni(II) ions. The detection limits for Cu(II) and Ni(II) ions based on 3σ (N:10) were 0.43 and 0.70 µg L^?1, respectively. The relative standard deviations were found to be lower than 4.0% for both analyte ions. The accuracy of the method was checked by spiked/recovery tests and the analysis of two certified reference materials (Environment Canada TM‐25.3 and CRM‐SA‐C Sandy Soil C). The procedure was successfully applied to sea water and stream water as liquid samples and baby food as solid sample in order to determine the levels of Cu(II) and Ni(II) ions.  相似文献   

Degradation of Malathion and Parathion by Ozonation,Photolytic Ozonation,and Heterogeneous Catalytic Ozonation Processes     

Fatma Beduk  Mehmet Emin Aydin  Senar Ozcan 《洁净——土壤、空气、水》2012,40(2):179-187

The oxidation of organophosphorus pesticides (OPPs), such as malathion and parathion, in aqueous solution was studied using conventional ozonation (O₃), photolytic ozonation (O₃/UV, O₃/UV/H₂O₂), and heterogeneous catalytic ozonation (O₃/TiO₂/UV) processes. Experiments were performed in batch mode at laboratory scale and processes were compared in terms of disappearance kinetics. The best results of pesticide mineralization were obtained when TiO₂ particles in combination with ozone (O₃) and UV photolysis (λ = 254 nm) were applied. Decomposition of 99% of parent compounds were achieved in 10 min and oxon derivatives were completely removed in 30 min. The initial reaction rate increases linearly with increasing catalyst amount. Toxicity measurements of the treated solutions were carried out in order to evaluate the efficiency of the treatment methods. No detoxification was achieved for O₃ and O₃/UV applications. Heterogeneous photocatalytic ozonation was shown to be feasible for achieving complete decomposition of OPPs and their oxon intermediates.  相似文献   

Adsorption of Pb(II) and Cd(II) Ions Onto Dye‐Attached Sawdust          下载免费PDF全文

Kubilay Tekin  Mehmet K. Akalin  Lokman Uzun  Selhan Karagöz  Sema Bektaş  Adil Denizli 《洁净——土壤、空气、水》2016,44(4):339-344

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