Greenhouse gases abatement by catalytic dry reforming of methane to syngas over samarium oxide-supported cobalt catalyst     

B. V. Ayodele  M. R. Khan  C. K. Cheng 《International Journal of Environmental Science and Technology》2017,14(12):2769-2782

Anthropogenic activities often result in the emissions of methane (CH₄) and carbon dioxide (CO₂) which are the principal components of greenhouse gases. The mitigation of these gases to avert further occurrence of global warming has attracted a lot of research interest. In this study, the potential of greenhouse gases abatement via catalytic CO₂ (dry) reforming of methane to syngas over samarium oxide-supported cobalt (20 wt% Co/80 wt% Sm₂O₃) catalyst was investigated. The 20 wt% Co/80 wt% Sm₂O₃ material was synthesized via wet impregnation method and characterized using different instrument techniques. The methane dry reforming reaction, as well as its kinetics over the catalyst, was studied in a stainless steel fixed-bed continuous flow reactor at feed (CH₄:CO₂) ratios range of 0.1–1.0, temperature range of 923–1023 K and gas hourly space velocity (GHSV) of 30,000 h^?1. The 20 wt% Co/80 wt% Sm₂O₃ catalyst showed promising catalytic activity evident from the highest CH₄ and CO₂ conversion of ~71 and ~74% as well as the highest hydrogen (H₂) and carbon monoxide (CO) yield of ~62 and ~73%, respectively. Moreover, the methane dry reforming over the 20 wt% Co/80 wt% Sm₂O₃ catalyst produces H₂/CO ratio close to unity hence suitable for use as a chemical intermediate for synthesis of oxygenated fuels. The kinetic data obtained from the methane dry reforming were fitted to power law model. Apparent activation energies of 88.62, 80.12, 108.12 and 100.91 kJ mol^?1 were obtained for CH₄, CO₂, H₂ and CO, respectively. The characterization of the spent 20 wt% Co/80 wt% Sm₂O₃ catalyst after 4 h of time-on-stream has confirmed the presence of amorphous carbon which can easily be gasified.  相似文献   

Feasibility,emission and fuel requirement analysis of hybrid car versus solar electric car: a comparative study     

I. Safdar  A. Raza  A. Z. Khan  E. Ali 《International Journal of Environmental Science and Technology》2017,14(8):1807-1818

The problem regarding environment has been considered as contemporary issue, and to cater this, various technologies have been revolutionized in vehicle transport field. Efforts have been made to make vehicle engine efficient and introducing hybridized vehicles with the aim of reducing emissions and less fuel dependency. In essence of this, trends of solar electric cars in different countries have been reviewed. Feasibility analysis is done by doing fuel cost analysis of two cases, i.e., simple hybrid vehicle and hybrid vehicle equipped with solar module and increased battery energy storage capacity for a specific round trip distance between two cities, i.e., Rawalpindi and Islamabad in comparison with feasibility of third case, i.e., proposed solar electric car model. The solar module selection along with desired number of batteries with charging and discharging time and motor power required to carry five persons weight (70 kg each) is calculated for third case. Moreover, total carbon dioxide emission analysis has been carried out from car material production to its assembly, manufacturing solar module and nickel metal hydride battery for each case. The annual carbon dioxide emitted from fuel in first two cases relative to electric outlet in third case for specific distance has been analyzed. On large scale, emission analyses for hundred cars of each case have been done at 100 km distance. From calculations, it is revealed that overall emissions in third case on large scale and from its material production, assembly, solar module and batteries manufacturing perspective are comparatively less than other cases.  相似文献   

Potential of fungus <Emphasis Type="Italic">Trichoderma harzianum</Emphasis> for toxicity reduction in municipal solid waste leachate     

A. K. Awasthi  A. K. Pandey  J. Khan 《International Journal of Environmental Science and Technology》2017,14(9):2015-2022

The purpose of this research was to test the ability of selected fungus Trichoderma harzianum for municipal solid waste leachate treatment. The research carried out by inoculating the enzyme produced by T. harzianum with different ratio (10% up to 80% v/v) of solid waste leachate. The findings clearly indicated that the enzymatic addition was effectively acted (86.09% of chemical oxygen demand removed), and the rate of chemical degradation amended treatment enhanced as compared to control. Also, the enzymatic addition excellently reduced the inhibition of germination (35.8 ± 0.7) of seed (Zea mays L.) and improved the environmental quality of treated leachate. Therefore, these results can be use to articulate the preliminary feedstock for pilot to field-scale application.  相似文献   

Combining AHP and genetic algorithms approaches to modify DRASTIC model to assess groundwater vulnerability: a case study from Jianghan Plain,China     

Jing Yang  Zhonghua Tang  Tian Jiao  Akhtar Malik Muhammad 《Environmental Earth Sciences》2017,76(12):426

Accurate identification of vulnerability areas is critical for groundwater resources protection and management. The present study employed the modified DRASTIC model to assess the groundwater vulnerability of Jianghan Plain, a major farming area in central China. DRASTICL model was developed by incorporating the land use factor to the original model. The ratings and weightings of the selected parameters were optimized by analytic hierarchy process (AHP) method and genetic algorithms (GAs) method, respectively. A combined AHP–GAs method was proposed to further develop this methodology. The unity-based normalization process was employed to categorize the vulnerability maps into four types, such as very high (>0.75), high (0.5–0.75), low (0.25–0.5), and very low (<0.25). The accuracy of vulnerability mapping was validated by Pearson’s correlation coefficient between vulnerability index and the nitrate concentration in groundwater and analysis of variance F statistic. The results revealed that the modified DRASTIC model had a large improvement over the conventional model. The correlation coefficient increased significantly from 41.07 to 75.31% after modification. Sensitivity analysis indicated that the depth to groundwater with 39.28% of mean effective weight was the most critical factor affecting the groundwater vulnerability. The developed vulnerability model proposed in this study could provide important objective information for groundwater and environmental management at local level and innovation for international researchers.  相似文献   

Temporal change of glaciers area and geomorphometric parameters in Parbati valley,Himachal Pradesh,India     

Sarfaraz Ahmad  Khatib Khan  Nepal Singh  Zabiullah Ansari  Md. Mulhim 《Environmental Earth Sciences》2017,76(11):407

Temporal change in the glacier coverage is analyzed for the period between 1962 and 2003 in Parbati valley, Himachal Pradesh. It is observed that the total glacier cover has been decreased by 17% ranging between 8 and 100% for individual glacier. The pattern of de-glaciation shows a high degree of shrinkage in outer zone of Parbati valley, while least shrinkage is observed in the inner valley. The present study is conducted to establish relationship between glacio-geomorphic parameters and glaciers shrinkage pattern to predict the future glacier cover in warming scenario. A systematic change is observed for glacio-geomorphic parameters associated with temporal change in glacier cover. It is observed that mean and minimum elevation, slope, relief and duration of insolation have changed substantially. Maximum elevation, plan/profile curvatures and aspect have shown less change from 1962 to 2003. A correlation matrix between glacio-geomorphic parameters for glaciers between 1962 and 2003 shows that the recent glaciers are much more controlled by terrain characteristics than that in the recent past.  相似文献   

Quasi MT Inversion of Short-Offset Transient Electromagnetic Data   总被引：1，自引：0，他引：1  

Wei-ying Chen  Guo-qiang Xue  Muhammad Younis Khan 《Pure and Applied Geophysics》2016,173(7):2413-2422

  相似文献   

Recent developments of the Middle East catalog   总被引：8，自引：2，他引：6  

Mehdi Zare  Hamideh Amini  Pouye Yazdi  Karin Sesetyan  Mine Betul Demircioglu  Dogan Kalafat  Mustafa Erdik  Domenico Giardini  M. Asif Khan  Nino Tsereteli 《Journal of Seismology》2014,18(4):749-772

This article summarizes a recent study in the framework of the Global Earth model (GEM) and the Earthquake Model of the Middle East (EMME) project to establish the new catalog of seismicity for the Middle East, using all historical (pre-1900), early and modern instrumental events up to 2006. According to different seismicity, which depends on geophysical, geological, tectonic, and seismicity data, this region is subdivided to nine subregions, consisting of Alborz–Azerbaijan, Afghanistan–Pakistan, Saudi Arabia, Caucasus, Central Iran, Kopeh–Dagh, Makran, Zagros, and Turkey (Eastern Anatolia; after 30° E). After omitting the duplicate events, aftershocks, and foreshocks by using the Gruenthal method, and uniform all magnitude to Mw scale, 28,244 main events remain for the new catalog of Middle East from 1250 B.C. through 2006. The magnitude of completeness (Mc) was determined as 4.9 for five out of nine subregions, where the least values of Mc were found to be 4.2. The threshold of Mc is around 5.5, 5.0, 4.5, and 4.0, for the time after 1950, 1963, 1975, and 2000, respectively. The average of teleseismic depths in all regions is less than 15 km. Totally, majority of depth for Kopeh–Dagh and Central Iran, Zagros, and Alborz–Azerbaijan, approximately, is 15, 13, and 11 km and for Afghanistan–Pakistan, Caucasus, Makran, Turkey (after 30° E), and Saudi Arabia is about 9 km.  相似文献   

Potential Heavy Metals Accumulation of Indigenous Plant Species along the Mafic and Ultramafic Terrain in the Mohmand Agency,Pakistan          下载免费PDF全文

Mohammad T. Shah  Jamila Ara  Said Muhammad  Sardar Khan  Saeed A. Asad  Liaqat Ali 《洁净——土壤、空气、水》2014,42(3):339-346

  相似文献   

Cometabolic Degradation Kinetics of Trichloroethylene Based on Toluene Enhancement by Encapsulated Burkholderia cepacia G4          下载免费PDF全文

Shanawar Hamid  Muhammad T. Amin  Abdulrahman A. Alazba  Umair Manzoor  Muhammad N. Amin 《洁净——土壤、空气、水》2014,42(11):1642-1649

  相似文献   

Organoclays as Sorbent Material for Phenolic Compounds: A Review          下载免费PDF全文

Muhammad Nafees  Amir Waseem 《洁净——土壤、空气、水》2014,42(11):1500-1508

  相似文献