A combined paleolimnological/genetic analysis of diatoms reveals divergent evolutionary lineages of Staurosira and Staurosirella (Bacillariophyta) in Siberian lake sediments along a latitudinal transect     

Kathleen R. Stoof-Leichsenring  Nadine Bernhardt  Luidmila A. Pestryakova  Laura S. Epp  Ulrike Herzschuh  Ralph Tiedemann 《Journal of Paleolimnology》2014,52(1-2):77-93

Diatom diversity in lakes of northwest Yakutia (Siberia) was investigated by microscopic and genetic analysis of surface and cored lake sediments, to evaluate the use of sedimentary DNA for paleolimnological diatom studies and to identify obscure genetic diversity that cannot be detected by microscopic methods. Two short (76 and 73 bp) and one longer (577 bp) fragments of the ribulose 1,5-bisphosphate carboxylase/oxygenase (rbcL) gene, encoding the large subunit of the rbcL, were used as genetic markers. Diverse morphological assemblages of diatoms, dominated by small benthic fragilarioid taxa, were retrieved from the sediments of each lake. These minute fragilarioid taxa were examined by scanning electron microscopy, revealing diverse morphotypes in Staurosira and Staurosirella from the different lakes. Genetic analyses indicated a dominance of haplotypes that were assigned to fragilarioid taxa and less genetic diversity in other diatom taxa. The long rbcL_577 amplicon identified considerable diversification among haplotypes clustering within the Staurosira/Staurosirella genera, revealing 19 different haplotypes whose spatial distribution appears to be primarily related to the latitude of the lakes, which corresponds to a vegetation and climate gradient. Our rbcL markers are valuable tools for tracking differences between diatom lineages that are not visible in their morphologies. These markers revealed putatively high genetic diversity within the Staurosira/Staurosirella species complex, at a finer scale than is possible to resolve by microscopic determination. The rbcL markers may provide additional reliable information on the diversity of barely distinguishable minute benthic fragilarioids. Environmental sequencing may thus allow the tracking of spatial and temporal diversification in Siberian lakes, especially in the context of diatom responses to recent environmental changes, which remains a matter of controversy.  相似文献   

Transport and Variability of Fecal Bacteria in Carbonate Conglomerate Aquifers     

Nadine Goeppert  Nico Goldscheider 《Ground water》2011,49(1):77-84

Clastic sedimentary rocks are generally considered non‐karstifiable and thus less vulnerable to pathogen contamination than karst aquifers. However, dissolution phenomena have been observed in clastic carbonate conglomerates of the Subalpine Molasse zone of the northern Alps and other regions of Europe, indicating karstification and high vulnerability, which is currently not considered for source protection zoning. Therefore, a research program was established at the Hochgrat site (Austria/Germany), as a demonstration that karst‐like characteristics, flow behavior, and high vulnerability to microbial contamination are possible in this type of aquifer. The study included geomorphologic mapping, comparative multi‐tracer tests with fluorescent dyes and bacteria‐sized fluorescent microspheres, and analyses of fecal indicator bacteria (FIB) in spring waters during different seasons. Results demonstrate that (1) flow velocities in carbonate conglomerates are similar as in typical karst aquifers, often exceeding 100 m/h; (2) microbial contaminants are rapidly transported toward springs; and (3) the magnitude and seasonal pattern of FIB variability depends on the land use in the spring catchment and its altitude. Different groundwater protection strategies that currently applied are consequently required in regions formed by karstified carbonatic clastic rocks, taking into account their high degree of heterogeneity and vulnerability.  相似文献   

Accounting for carbon dioxide emissions from international shipping: Burden sharing under different UNFCCC allocation options and regime scenarios     

Nadine Heitmann  Setareh Khalilian 《Marine Policy》2011

CO₂ emissions from international shipping, which are currently unregulated, are predicted to rise dramatically if no regulations are implemented. International bunker fuel emissions have been excluded from the Kyoto Protocol; the UNFCCC conference in Copenhagen also failed to bring about clear directions on how to proceed with these emissions.  相似文献   

Density functional theory modeling of chromate adsorption onto ferrihydrite nanoparticles     

James D. Kubicki  Nadine Kabengi  Maria Chrysochoou  Nefeli Bompoti 《Geochemical transactions》2018,19(1):8

Density functional theory (DFT) calculations were performed on a model of a ferrihydrite nanoparticle interacting with chromate (\( {\text{CrO}}_{4}^{2 - } \)) in water. Two configurations each of monodentate and bidentate adsorbed chromate as well as an outer-sphere and a dissolved bichromate (\( {\text{HCrO}}_{4}^{ - } \)) were simulated. In addition to the 3-D periodic planewave DFT models, molecular clusters were extracted from the energy-minimized structures. Calculated interatomic distances from the periodic and cluster models compare favorably with Extended X-ray Absorption Fine Structure spectroscopy values, with larger discrepancies seen for the clusters due to over-relaxation of the model substrate. Relative potential energies were derived from the periodic models and Gibbs free energies from the cluster models. A key result is that the bidentate binuclear configuration is the lowest in potential energy in the periodic models followed by the outer-sphere complex. This result is consistent with observations of the predominance of bidentate chromate adsorption on ferrihydrite under conditions of high surface coverage (Johnston Environ Sci Technol 46:5851–5858, 2012). Cluster models were also used to perform frequency analyses for comparison with observed ATR FTIR spectra. Calculated frequencies on monodentate, bidentate binuclear, and outer-sphere complexes each have infrared (IR)-active modes consistent with experiment. Inconsistencies between the thermodynamic predictions and the IR-frequency analysis suggest that the 3-D periodic models are not capturing key components of the system that influence the adsorption equilibria under varying conditions of pH, ionic strength and electrolyte composition. Model equilibration via molecular dynamics (MD) simulations is necessary to escape metastable states created during DFT energy minimizations based on the initial classical force field MD-derived starting configurations.  相似文献   

Geochemical evidence for melting of carbonated peridotite on Santa Maria Island, Azores     

Christoph Beier  João Mata  Ferdinand Stöckhert  Nadine Mattielli  Philipp A. Brandl  Pedro Madureira  Felix S. Genske  Sofia Martins  José Madeira  Karsten M. Haase 《Contributions to Mineralogy and Petrology》2013,165(5):823-841

The islands of the Azores archipelago emerge from an oceanic plateau built on lithosphere increasing in age with distance from the Mid-Atlantic Ridge from 10 to 45 Ma. Here, we present the first comprehensive major and trace element and Sr–Nd–Pb isotope data from Santa Maria, the easternmost island of the archipelago, along with published data from the other Azores islands situated much closer to the Mid-Atlantic Ridge axis. We can show that the distinctively more variable and more enriched trace element ratios at Santa Maria combined with a relatively small range in Sr–Nd–Pb isotope ratios are the result of low degrees of partial melting of a common Azores mantle plume source underneath thicker lithosphere. This implies that melt extraction processes and melting dynamics may be able to better preserve the trace element mantle source variability underneath thicker lithosphere. These conclusions may apply widely for oceanic melts erupted on relatively thick lithosphere. In addition, lower Ti/Sm and K/La ratios and SiO₂ contents of Santa Maria lavas imply melting of a carbonated peridotite source. Mixing of variable portions of deep small-degree carbonated peridotite melts and shallow volatile-free garnet peridotite could explain the geochemical variability underneath Santa Maria in agreement with the volatile-rich nature of the Azores mantle source. However, Santa Maria is the Azores island where the CO₂-rich nature of the mantle source is more evident, reflecting a combination of a smaller extent of partial melting and the positioning at the edge of the tilted Azores mantle plume.  相似文献   

Evaluating the effect of snow and ice melt in an Alpine headwater catchment and further downstream in the River Rhine     

Nadine Junghans  Johannes Cullmann  Matthias Huss 《水文科学杂志》2013,58(6):981-993

Abstract

The runoff regime of glacierized headwater catchments in the Alps is essentially characterized by snow and ice melt. High Alpine drainage basins influence distant downstream catchments of the Rhine River basin. In particular, during the summer months, low-flow conditions are probable with strongly reduced snow and ice melt under climate change conditions. This study attempts to quantify present and future contributions from snow and ice melt to summer runoff at different spatial scales. For the small Silvretta catchment (103 km²) in the Swiss Alps, with a glacierization of 7%, the HBV model and the glacio-hydrological model GERM are applied for calculating future runoff based on different regional climate scenarios. We evaluate the importance of snow and ice melt in the runoff regime. Comparison of the models indicates that the HBV model strongly overestimates the future contribution of glacier melt to runoff, as glaciers are considered as static components. Furthermore, we provide estimates of the current meltwater contribution of glaciers for several catchments downstream on the River Rhine during the month of August. Snow and ice melt processes have a significant direct impact on summer runoff, not only for high mountain catchments, but also for large transboundary basins. A future shift in the hydrological regime and the disappearance of glaciers might favour low-flow conditions during summer along the Rhine.

Citation Junghans, N., Cullmann, J. & Huss, M. (2011) Evaluating the effect of snow and ice melt in an Alpine headwater catchment and further downstream in the River Rhine. Hydrol. Sci. J. 56(6), 981–993.  相似文献   

Groundwater flow and its effect on salt dissolution in Gypsum Canyon watershed,Paradox Basin,southeast Utah,USA     

Nadine G. Reitman  Shemin Ge  Karl Mueller 《Hydrogeology Journal》2014,22(6):1403-1419

Groundwater flow is an important control on subsurface evaporite (salt) dissolution. Salt dissolution can drive faulting and associated subsidence on the land surface and increase salinity in groundwater. This study aims to understand the groundwater flow system of Gypsum Canyon watershed in the Paradox Basin, Utah, USA, and whether or not groundwater-driven dissolution affects surface deformation. The work characterizes the groundwater flow and solute transport systems of the watershed using a three-dimensional (3D) finite element flow and transport model, SUTRA. Spring samples were analyzed for stable isotopes of water and total dissolved solids. Spring water and hydraulic conductivity data provide constraints for model parameters. Model results indicate that regional groundwater flow is to the northwest towards the Colorado River, and shallow flow systems are influenced by topography. The low permeability obtained from laboratory tests is inconsistent with field observed discharges, supporting the notion that fracture permeability plays a significant role in controlling groundwater flow. Model output implies that groundwater-driven dissolution is small on average, and cannot account for volume changes in the evaporite deposits that could cause surface deformation, but it is speculated that dissolution may be highly localized and/or weaken evaporite deposits, and could lead to surface deformation over time.  相似文献   

Predictions on the core mass of Jupiter and of giant planets in general     

Nadine Nettelmann 《Astrophysics and Space Science》2011,336(1):47-51

More than 80 giant planets are known by mass and radius. Their interior structure in terms of core mass, number of layers, and composition however is still poorly known. An overview is presented about the core mass M _core and envelope mass of metals M _Z in Jupiter as predicted by various equations of state. It is argued that the uncertainty about the true H/He EOS in a pressure regime where the gravitational moments J ₂ and J ₄ are most sensitive, i.e. between 0.5 and 4 Mbar, is in part responsible for the broad range \(M_{\mathit{core}}=0{-}18\:M_{\oplus }\), \(M_{Z}=0{-}38\:M_{\oplus }\), and \(M_{\mathit{core}}+M_{Z}=14{-}38\:M_{\oplus }\) currently offered for Jupiter. We then compare the Jupiter models obtained when we only match J ₂ with the range of solutions for the exoplanet \(\mathrm{GJ}\:436\mathrm{b}\), when we match an assumed tidal Love number k ₂ value.  相似文献   

Multi-stage emplacement of the G?temar Pluton, SE Sweden: new evidence inferred from field observations and microfabric analysis, including cathodoluminescence microscopy     

Nadine Friese  Axel Vollbrecht  David C. Tanner  Wiebke Fahlbusch  Miriam Weidemann 《International Journal of Earth Sciences》2012,101(5):1149-1167

The emplacement of the Mesoproterozoic G?temar Pluton into Paleoproterozoic granitoid host rocks of the Transscandinavian Igneous Belt is re-examined by microfabric analysis, including cathodoluminescence microscopy. Field data on the pluton-host rock system are used to strengthen the model. The G?temar Pluton, situated on the Baltic Shield of SE Sweden, is a horizontally zoned tabular structure that was constructed by the intrusion of successive pulses of magma with different crystal/melt ratios, at an estimated crustal depth of 4–8?km. Initial pluton formation involved magma ascent along a vertical dike, which was arrested at a mechanical discontinuity within the granitoid host rocks; this led to the formation of an initial sill. Subsequent sill stacking and their constant inflation resulted in deformation and reheating of existing magma bodies, which also raised the pluton roof. This multi-stage emplacement scenario is indicated by complex dike relationships and the occurrence of several generations of quartz (Si-metasomatism). The sills were charged by different domains of a heterogeneous magma chamber with varying crystal/melt ratios. Ascent or emplacement of magma with a high crystal/melt ratio is indicated by syn-magmatic deformation of phenocrysts. Complex crystallization fabrics (e.g. oscillatory growth zoning caused by high crystal defect density, overgrowth and replacement features, resorbed and corroded crystal cores, rapakivi structure) are mostly related to processes within the main chamber, that is repeated magma mixing or water influx.  相似文献   

Approaches to stress monitoring in deep boreholes for future CCS projects   总被引：1，自引：1，他引：0  

Christof Lempp  Khaled M. Shams  Nadine Jahr 《Environmental Earth Sciences》2012,67(2):435-445

There is no monitoring technology available to observe possible changes of stress in the rock mass of a CO₂ reservoir or its cap rock formations. Any development of a stress-monitoring technique must be related to the natural regional stress conditions and must be adjusted to the possibly changing in situ stress conditions due to CCS activity. As a step towards an in situ stress-monitoring probe, a lab scale device was developed and used for investigations on the practicability of a hard-inclusion tool for stress monitoring. In situ stress conditions, as deduced from the Altmark Gas Field, were applied to evaluate the efficiency and the limits of this stress-monitoring technique. At lab-scale the applied stresses resp. stress differences with moderate amounts of 9?C15?% of the vertical stress component Sv coincide sufficiently with the resulting strain answers of the hard inclusion tool (i.e., a steel tube corresponding to the liner in the borehole). Therefore, it was possible to re-calculate the stresses and to compare them with the applied ones. The resulting coincidence, however, can be disturbed at high pressure levels due to rock failure around the borehole with extended deformations. In addition, the results are influenced by the mechanical behaviour of the surrounding rock mass type. Nevertheless, a further development of a hard inclusion probe for monitoring of stress changes in deep boreholes can be successful and may be the only possible way to detect stress changes without fracturing damages in deep boreholes.  相似文献