High-Frequency Hydroacoustic Monitoring in an Underground Iron Mine     

Séverine Bernardie  Jean-Pascal Gilbert  François Lebert  Hubert Fabriol 《Pure and Applied Geophysics》2007,164(1):177-197

The monitoring of the stability of old mines constitutes an important research objective for our institution, BRGM. The study reported here shows the contribution of high-frequency (>30 kHz) acoustic emissions to the detection of the damage within a rock mass, during an experiment within a pilot site of an old flooded iron mine. The experiment consisted of recording all the hydroacoustic events in a broad frequency band (between 30 Hz and 180 kHz), during 18 months. The monitoring network has been calibrated by a triggered block fall that made it possible to highlight a relationship between the occurrence of high-frequency/low-frequency hydroacoustic emissions and rock falls. The events recorded have been associated with the micro-failure of the rock mass near the roof, prior to the detachment of the blocks. This monitoring showed important high-frequency hydroacoustic activity, which may be associated with mechanical instabilities generated by the evolution of water pressure during the experiment. In conclusion, the high-frequency hydroacoustic activity appears to be a good indicator of instability and, therefore, this new technique constitutes a promising tool for monitoring abandoned underground cavities.  相似文献   

Ophiolite emplacement by strike-slip tectonics between the Pontide Zone and the Sakarya Zone in northwestern Anatolia, Turkey     

Ali Elmas  Erdinç Yiğitbaş 《International Journal of Earth Sciences》2001,90(2):257-269

Northwestern Anatolia contains three main tectonic units: (a) the Pontide Zone in the north which consists mainly of the Gstanbul-Zonguldak Unit in the west and the BallLda<-Küre Unit in the east; (b) the Sakarya Zone (or Continent) in the south, which is juxtaposed against the Pontide Zone due to the closure of Paleo-Tethys prior to Late Jurassic time; and (c) the Armutlu-OvacLk Zone which appears to represent a tectonic mixture of both zones. These three major tectonic zones are presently bounded by the two branches of the North Anatolian Transform Fault. The two tectonic contacts follow older tectonic lineaments (the Western Pontide Fault) which formed during the development of the Armutlu-OvacLk Zone. Since the earliest Cretaceous, an overall extensional regime dominated the region. A transpressional tectonic regime of Coniacian/Santonian to Campanian age caused the welding of the Gstanbul-Zonguldak Unit to the Sakarya Zone by an oblique collision. In the Late Campanian, a transtensional tectonic regime developed, forming a new basin within the amalgamated tectonic mosaic. The different tectonic regimes in the region were caused by activity of the Western Pontide Fault. Most of the ophiolites within the Armutlu-OvacLk Zone belong to the Paleo-Tethyan and/or pre-Ordovician ophiolitic core of the Gstanbul-Zonguldak Unit. The Late Cretaceous ophiolites in the eastern parts of the Armutlu-OvacLk Zone were transported from Neo-Tethyan ophiolites farther east by left-lateral strike-slip faults along the Western Pontide Fault. There is insufficient evidence to indicate the presence of an ocean (Intra-Pontide Ocean) between the Gstanbul-Zonguldak Unit and the Sakarya Zone during Late Cretaceous time.  相似文献   

Spatiotemporal changes in cadmium contamination in the Seine estuary (France)     

Jean-François Chiffoleau  Dominique Auger  Emmanuelle Chartier  Pierre Michel  Isabelle Truquet  André Ficht  Jean-Louis Gonzalez  Louis-Alexandre Romana 《Estuaries and Coasts》2001,24(6):1029-1040

Cadmium (Cd) is among the major contaminants in the Seine estuary. In the biota, the RNO (Réseau National d’Observation, the French Mussel-Watch) has shown that Cd concentrations in mussels living at the mouth of the estuary are related to changes in inputs to this area of phosphogypsum, a calcium sulphate that is a by-product of the phosphoric acid naturally enriched with Cd. In the water column, Cd concentrations at several key estuary sites show a very marked trend toward decreased contamination in the particles as well as in the dissolved phase. The behavior of Cd in the estuary has been studied between 1991 and 1998 in the framework of the scientific program Seine-Aval. This program has highlighted punctual Cd inputs in the estuarine water column. The partition of Cd between the dissolved and the particulate phase, previously described in various estuaries, is characterized by an intense phenomenon of solubilization in the mixing zone freshwater-seawater, but the colloidal Cd fraction remains low along the whole salinity gradient, about 5% to 10% of the apparent dissolved fraction. Although the decrease of inputs induced a fall of Cd concentrations in the water column, laboratory experiments show that the estuarine particles are far from being exhausted in Cd. Despite continuous efforts to reduce the urban and industrial inputs into the estuarine and coastal waters, the Seine estuary still remains very contaminated by Cd.  相似文献   

Book reviews     

Kerry Kelts  Patrick De Deckker  Françoise Gasse  Susan K. Short 《Journal of Paleolimnology》1992,7(2):173-178

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Book review     

W. E. Sharp  M. Dane Picard  Jean-François Gaillard 《Mathematical Geosciences》1992,24(4):437-447

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The volcano of Capelinhos (Azores), the solar activity and the earth-tide     

De Mendoça Dias  A. A. 《Bulletin of Volcanology》1962,24(1):211-221

Bulletin of Volcanology - Correlations on the eruptive behaviour of the volcano of Capelinhos (Fayal island) in 1957–58, with (a) solar activity, and (b) earth-tide amplitudes, by way of a...  相似文献   

The submarine volcano of Capelinhos and the tectonics of the Azores     

De Mendoça Dias  A. A. 《Bulletin of Volcanology》1962,24(1):223-231

Bulletin of Volcanology - In another paper of the author, a picture of the tectonics of the Azores was presented. The morphological analysis showed evidence of a folded and faulted structure and...  相似文献   

The LMDZ4 general circulation model: climate performance and sensitivity to parametrized physics with emphasis on tropical convection   总被引：3，自引：11，他引：3  

Frédéric Hourdin  Ionela Musat  Sandrine Bony  Pascale Braconnot  Francis Codron  Jean-Louis Dufresne  Laurent Fairhead  Marie-Angèle Filiberti  Pierre Friedlingstein  Jean-Yves Grandpeix  Gerhard Krinner  Phu LeVan  Zhao-Xin Li  François Lott 《Climate Dynamics》2006,27(7-8):787-813

The LMDZ4 general circulation model is the atmospheric component of the IPSL–CM4 coupled model which has been used to perform climate change simulations for the 4th IPCC assessment report. The main aspects of the model climatology (forced by observed sea surface temperature) are documented here, as well as the major improvements with respect to the previous versions, which mainly come form the parametrization of tropical convection. A methodology is proposed to help analyse the sensitivity of the tropical Hadley–Walker circulation to the parametrization of cumulus convection and clouds. The tropical circulation is characterized using scalar potentials associated with the horizontal wind and horizontal transport of geopotential (the Laplacian of which is proportional to the total vertical momentum in the atmospheric column). The effect of parametrized physics is analysed in a regime sorted framework using the vertical velocity at 500 hPa as a proxy for large scale vertical motion. Compared to Tiedtke’s convection scheme, used in previous versions, the Emanuel’s scheme improves the representation of the Hadley–Walker circulation, with a relatively stronger and deeper large scale vertical ascent over tropical continents, and suppresses the marked patterns of concentrated rainfall over oceans. Thanks to the regime sorted analyses, these differences are attributed to intrinsic differences in the vertical distribution of convective heating, and to the lack of self-inhibition by precipitating downdraughts in Tiedtke’s parametrization. Both the convection and cloud schemes are shown to control the relative importance of large scale convection over land and ocean, an important point for the behaviour of the coupled model.  相似文献   

Trace Metal Solid State Speciation in Aerosols of the Northern Levantine Basin,East Mediterranean   总被引：3，自引：0，他引：3  

Mustafa Koçak  Nilgun Kubilay  Barak Herut  Malcolm Nimmo 《Journal of Atmospheric Chemistry》2007,56(3):239-257

An established three stage sequential leach scheme was applied to a series of selected high volume aerosol samples (n = 35) collected from the Turkish Eastern Mediterranean coastline (Erdemli). Samples were selected according to their air mass back trajectory history to reflect the contrasting mixtures of aerosol material present in the Eastern Mediterranean marine aerosol. Two populations were adopted, those samples which were classed as “anthropogenic” and those which were “Saharan” dominated aerosol populations. Applying the three stage leach it was possible to define the proportion for each of the considered metals (Al, Fe, Cu, Pb, Cd, Zn and Mn) present in the (a) “exchangeable” (b) “carbonate / oxide” and (c) “refractory” phases, representing novel solid state aerosol speciation data for this marine system. Clear trends were established, conforming with data from previous studies with mainly crustal derived metals (Al and Fe) being present in the refractory phases (Al > 88%; Fe > 84%) and those influenced by anthropogenic sources being dominating in the exchangeable phase, although for these metals the variability was comparatively high (12–64%; 19–85%; 40–100% for Zn, Pb and Cd, respectively). For the majority, greater exchangeable fractions were present the lower the crustal source contribution to the aerosol population, whereas the “refractory” fraction exhibited contrasting behaviour. This was illustrated by the novel application of the mixing diagram, presenting each of the three speciation stages against the corresponding percent anthropogenic contribution to each collected sample. Zn, Pb and Cd all illustrated progressive decrease in the percent exchangeable with increasing crustal contribution to the aerosol population. The percent exchangeable was discussed in terms of its use to represent the upper limit of the bioavailable fraction of metal associated with the aerosol, post deposition. The mixing diagram approach enabled the prediction of the residual fractions for Cd, Pb and Zn (41 ± 4%; 62 ± 4% and 82 ± 5%, respectively,) in Saharan end-member material.  相似文献   

Decoupling of arsenic and iron release from ferrihydrite suspension under reducing conditions: a biogeochemical model     

André Burnol  Francis Garrido  Philippe Baranger  Catherine Joulian  Marie-Christine Dictor  Françoise Bodénan  Guillaume Morin  Laurent Charlet 《Geochemical transactions》2007,8(1):12

High levels of arsenic in groundwater and drinking water are a major health problem. Although the processes controlling the release of As are still not well known, the reductive dissolution of As-rich Fe oxyhydroxides has so far been a favorite hypothesis. Decoupling between arsenic and iron redox transformations has been experimentally demonstrated, but not quantitatively interpreted. Here, we report on incubation batch experiments run with As(V) sorbed on, or co-precipitated with, 2-line ferrihydrite. The biotic and abiotic processes of As release were investigated by using wet chemistry, X-ray diffraction, X-ray absorption and genomic techniques. The incubation experiments were carried out with a phosphate-rich growth medium and a community of Fe(III)-reducing bacteria under strict anoxic conditions for two months. During the first month, the release of Fe(II) in the aqueous phase amounted to only 3% to 10% of the total initial solid Fe concentration, whilst the total aqueous As remained almost constant after an initial exchange with phosphate ions. During the second month, the aqueous Fe(II) concentration remained constant, or even decreased, whereas the total quantity of As released to the solution accounted for 14% to 45% of the total initial solid As concentration. At the end of the incubation, the aqueous-phase arsenic was present predominately as As(III) whilst X-ray absorption spectroscopy indicated that more than 70% of the solid-phase arsenic was present as As(V). X-ray diffraction revealed vivianite Fe(II)₃(PO₄)₂.8H₂O in some of the experiments. A biogeochemical model was then developed to simulate these aqueous- and solid-phase results. The two main conclusions drawn from the model are that (1) As(V) is not reduced during the first incubation month with high Eh values, but rather re-adsorbed onto the ferrihydrite surface, and this state remains until arsenic reduction is energetically more favorable than iron reduction, and (2) the release of As during the second month is due to its reduction to the more weakly adsorbed As(III) which cannot compete against carbonate ions for sorption onto ferrihydrite. The model was also successfully applied to recent experimental results on the release of arsenic from Bengal delta sediments.  相似文献