Role of coal type and rank on methane sorption characteristics of Bowen Basin, Australia coals   总被引：5，自引：0，他引：5  

Chikatamarla Laxminarayana  Peter J. Crosdale 《International Journal of Coal Geology》1999,40(4):157

The effect of coal composition, particularly the organic fraction, upon gas sorption has been investigated for Bowen Basin and Sydney Basin, Australia coals. Maceral composition influences on gas retention and release were investigated using isorank pairs of hand-picked bright and dull coal in the rank range of high volatile bituminous (0.78% R_{o max}) to anthracite (3.01% R_{o max}). Adsorption isotherm results of dry coals indicated that Langmuir volume (V_L) for bright and dull coal types followed discrete, second-order polynomial trends with increasing rank. Bright coals had a minimum V_L at 1.72% R_{o max} and dull coals had a minimum V_L at 1.17% R_{o max}. At low rank, V_L was greater in bright coal by about 10 cm³/g, but as rank increased, the bright and dull trends converged and crossed at 1.65% R_{o max}. At ranks higher than 1.65% R_{o max}, both bright and dull coals followed similar trends. These competing trends mean that the importance of maceral composition on V_L varies according to rank. In high volatile bituminous coals, increases in vitrinite content are associated with increases in adsorption capacity. At ranks higher than medium to low volatile bituminous, changes in maceral composition may exert relatively little influence on adsorption capacity. The Langmuir pressure (P_L) showed a strong relationship of decreasing P_L with increasing rank, which was not related to coal type. It is suggested that the observed trend is related to a decrease in the heterogeneity of the pore surfaces, and subsequent increased coverage by the adsorbate, as coal rank increases. Desorption rate studies on crushed samples show that dull coals desorb more rapidly than bright coals and that desorption rate is also a function of rank. Coals of lower rank have higher effective diffusivities. Mineral matter was found to have no influence on desorption rate of these finely crushed samples. The evolution of the coal pore structure with changing rank is implicated in diffusion rate differences.  相似文献   

Development of an operational low-flow index for hydrological drought monitoring over Europe   总被引：1，自引：1，他引：0  

Carmelo Cammalleri  Jürgen Vogt  Peter Salamon 《水文科学杂志》2017,62(3):346-358

Near real-time monitoring of hydrological drought requires the implementation of an index capable of capturing the dynamic nature of the phenomenon. Starting from a dataset of modelled daily streamflow data, a low-flow index was developed based on the total water deficit of the discharge values below a certain threshold. In order to account for a range of hydrological regimes, a daily 95th percentile threshold was adopted, which was computed by means of a 31-day moving window. The observed historical total water deficits were statistically fitted by means of the exponential distribution and the corresponding probability values were used as a measure of hydrological drought severity. This approach has the advantage that it directly exploits daily streamflow values, as well as allowing a near real-time update of the index at regular time steps (i.e. 10 days, or dekad). The proposed approach was implemented on discharge data simulated by the LISFLOOD model over Europe during the period 1995–2015; its reliability was tested on four case studies found within the European drought reference database, as well as against the most recent summer drought observed in Central Europe in 2015. These validations, even if only qualitative, highlighted the ability of the index to capture the timing (starting date and duration) of the main historical hydrological drought events, and its good performance in comparison with the commonly used standardized runoff index (SRI). Additionally, the spatial evolution of the most recent event was captured well in a simulated near real-time test case, suggesting the suitability of the index for operational implementation within the European Drought Observatory.  相似文献   

Extreme floods and their relationship with tropical cyclones in Puerto Rico     

José J. Hernández Ayala  David Keellings  Peter R. Waylen  Corene J. Matyas 《水文科学杂志》2017,62(13):2103-2119

An extreme value analysis (EVA) point process approach has been implemented to examine the flood characteristics of Puerto Rico when tropical cyclones (TCs) are present in the discharge series and when they are removed from it. Mean daily discharge values that exceeded the 99th percentile thresholds were used in both the TC and non-TC data series. In nine of the 12 stations the maximum discharge was associated with a TC, with hurricanes Hortense (1996), Georges (1998) and Eloise (1975) responsible for most of the maximum peaks at each site. Percentage changes in the generalized extreme value parameters, which include location (central tendency), scale (variance) and shape (skewness), between the TC and non-TC data exhibited a decrease in the majority of stations. Stations in the eastern interior and central region of the island showed the largest decrease in all parameters, in flood occurrences and in return periods when TCs were removed from the series.  相似文献   

Emerging Technologies and Synergies for Airborne and Space-Based Measurements of Water Vapor Profiles     

Amin R. Nehrir  Christoph Kiemle  Mathew D. Lebsock  Gottfried Kirchengast  Stefan A. Buehler  Ulrich Löhnert  Cong-Liang Liu  Peter C. Hargrave  Maria Barrera-Verdejo  David M. Winker 《Surveys in Geophysics》2017,38(6):1445-1482

A deeper understanding of how clouds will respond to a warming climate is one of the outstanding challenges in climate science. Uncertainties in the response of clouds, and particularly shallow clouds, have been identified as the dominant source of the discrepancy in model estimates of equilibrium climate sensitivity. As the community gains a deeper understanding of the many processes involved, there is a growing appreciation of the critical role played by fluctuations in water vapor and the coupling of water vapor and atmospheric circulations. Reduction of uncertainties in cloud-climate feedbacks and convection initiation as well as improved understanding of processes governing these effects will result from profiling of water vapor in the lower troposphere with improved accuracy and vertical resolution compared to existing airborne and space-based measurements. This paper highlights new technologies and improved measurement approaches for measuring lower tropospheric water vapor and their expected added value to current observations. Those include differential absorption lidar and radar, microwave occultation between low-Earth orbiters, and hyperspectral microwave remote sensing. Each methodology is briefly explained, and measurement capabilities as well as the current technological readiness for aircraft and satellite implementation are specified. Potential synergies between the technologies are discussed, actual examples hereof are given, and future perspectives are explored. Based on technical maturity and the foreseen near-mid-term development path of the various discussed measurement approaches, we find that improved measurements of water vapor throughout the troposphere would greatly benefit from the combination of differential absorption lidar focusing on the lower troposphere with passive remote sensors constraining the upper-tropospheric humidity.  相似文献   

Conditional effects of tides and waves on short‐term marsh sedimentation dynamics          下载免费PDF全文

Zhigang Ma  Tom Ysebaert  Daphne van der Wal  Peter M.J. Herman 《地球表面变化过程与地形》2018,43(10):2243-2255

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A method for uncertainty constraint of catchment discharge and phosphorus load estimates          下载免费PDF全文

Michael J. Hollaway  Keith J. Beven  Clare Mc W. H. Benskin  Adrian L. Collins  Robert Evans  Peter D. Falloon  Kirsty J. Forber  Kevin M. Hiscock  Ron Kahana  Christopher J. A. Macleod  Mary C. Ockenden  Martha L. Villamizar  Catherine Wearing  Paul J. A. Withers  Jian G. Zhou  Nicholas J. Barber  Philip M. Haygarth 《水文研究》2018,32(17):2779-2787

River discharge and nutrient measurements are subject to aleatory and epistemic uncertainties. In this study, we present a novel method for estimating these uncertainties in colocated discharge and phosphorus (P) measurements. The “voting point”‐based method constrains the derived stage‐discharge rating curve both on the fit to available gaugings and to the catchment water balance. This helps reduce the uncertainty beyond the range of available gaugings and during out of bank situations. In the example presented here, for the top 5% of flows, uncertainties are shown to be 139% using a traditional power law fit, compared with 40% when using our updated “voting point” method. Furthermore, the method is extended to in situ and lab analysed nutrient concentration data pairings, with lower uncertainties (81%) shown for high concentrations (top 5%) than when a traditional regression is applied (102%). Overall, for both discharge and nutrient data, the method presented goes some way to accounting for epistemic uncertainties associated with nonstationary physical characteristics of the monitoring site.  相似文献   

Statistical evidence for long-range space-time relationships between large earthquakes     

Peter A. Rogerson 《Journal of Seismology》2018,22(6):1423-1435

Whether large earthquakes are triggered by other large earthquakes at very large distances, and at time scales where the triggered event is delayed by more than several days or weeks, is an open question. Here I provide statistical evidence to show that large earthquakes near the subduction zones of the Pacific plate boundary lessen significantly the average time until the next large earthquake that occurs near the boundaries of the smaller and adjacent Nazca and Cocos plates in the eastern Pacific Ocean. In addition, the existence and importance of this relationship is enriched by the finding that the larger the magnitude of the Pacific plate earthquake, the more likely it becomes that the time until the next earthquake in the distant triggered zone is less than the time since the last earthquake in the triggered zone. There are also specific regions along the western and northern Pacific plates where these relationships appear to be particularly prominent. The findings call into question the notion that the hazard of large earthquakes in distant regions is not raised following other large earthquakes, and they provide statistical evidence for relationships between earthquakes occurring months apart on different plates.  相似文献   

First record of the Australian ascidian Eudistoma elongatum in northern New Zealand     

Peter J. Smith  Mike Page  Sean J. Handley  S. Margaret McVeagh  Merrick Ekins 《新西兰海洋与淡水研究杂志》2013,47(4):347-355

A colonial ascidian was first reported by marine farmers in Houhora Harbour, Northland, New Zealand in early 2005 and subsequently found on oyster racks in Parengarenga Harbour and the Bay of Islands. The Northland ascidian was identified with a combination of morphological characters and DNA cytochrome c oxidase I (COI) sequence data, as Eudistoma elongatum, a species native to Australia, where it is found from northern New South Wales to Northern Queensland, and distinguished from Eudistoma circumvallatum, the only reported species in this genus from New Zealand. Ascidian larvae are weak dispersers and long distance dispersal of E. elongatum is likely to be enhanced by vectors such as oyster barges and/or movement of cultured oysters. In its native range, E. elongatum is restricted to areas with a minimum winter sea temperature of 16°C. Assuming similar biological limitations apply in New Zealand, the spread of E. elongatum might be restricted to northern New Zealand (north of latitude 37°S).  相似文献   

The origins of agriculture in Europe     

Peter Bogucki 《Geoarchaeology》2000,15(4):377-379

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Enstatite meteorite clasts in Almahata Sitta and other polymict ureilites: Implications for the formation of asteroid 2008 TC3 and the history of enstatite meteorite parent asteroids     

Cyrena Anne Goodrich  Hilary Downes  Richard Greenwood  Aidan J. Ross  Anna Maria Fioretti  Louise Alexander  Noriko T. Kita  Jon Butler  Michael J. Jercinovic  Peter Jenniskens  Muawia H. Shaddad 《Meteoritics & planetary science》2024,59(4):719-753

The anomalous polymict ureilite Almahata Sitta (AhS) fell in 2008 when asteroid 2008 TC₃ disintegrated over Sudan and formed a strewn field of disaggregated clasts of various ureilitic and chondritic types. We studied the petrology and oxygen isotope compositions of enstatite meteorite samples from the University of Khartoum (UoK) collection of AhS. In addition, we describe the first bona fide (3.5 mm-sized) clast of an enstatite chondrite (EC) in a typical polymict ureilite, Northwest Africa (NWA) 10657. We evaluate whether 2008 TC₃ and typical polymict ureilites have a common origin, and examine implications for the history of enstatite meteorite asteroids in the solar system. Based on mineralogy, mineral compositions, and textures, the seven AhS EC clasts studied comprise one EH_a3 (S151), one EL_b3 (AhS 1002), two EH_b4-5 (AhS 2012, AhS 26), two EH_b5-6 or possibly impact melt rocks (AhS 609, AhS 41), and one EL_b6-7 (AhS 17), while the EC clast in NWA 10657 is EH_a3. Oxygen isotope compositions analyzed for five of these are similar to those of EC from non-UoK collections of AhS, and within the range of individual EC meteorites. There are no correlations of oxygen isotope composition with chemical group or subgroup. The EC clasts from the UoK collection show the same large range of types as those from non-UoK collections of AhS. The enstatite achondrite, AhS 60, is a unique type (not known as an individual meteorite) that has also been found among non-UoK AhS samples. EC are the most abundant non-ureilitic clasts in AhS but previously were thought to be absent in typical polymict ureilites, necessitating a distinct origin for AhS. The discovery of an EC in NWA 10657 changes this. We argue that the types of materials in AhS and typical polymict ureilites are essentially similar, indicating a common origin. We elaborate on a model in which AhS and typical polymict ureilites formed in the same regolith on a ureilitic daughter body. Most non-ureilitic clasts are remnants of impactors implanted at ~50–60 Myr after CAI. Differences in abundances can be explained by the stochastic nature of impactor addition. There is no significant difference between the chemical/petrologic types of EC in polymict ureilites and individual EC meteorites. This implies that fragments of the same populations of EC parent bodies were available as impactors at ~50–60 Myr after CAI and recently. This can be explained if materials excavated from various depths on EC bodies at ~50–60 Myr after CAI were reassembled into mixed layers, leaving relatively large bodies intact to survive 4 billion years. Polymict ureilites record a critical timestep in the collisional and dynamical evolution of the solar system, showing that asteroids that may have accreted at distant locations had migrated to within proximity of one another by 50–60 Myr after CAI, and providing constraints on the dynamical processes that could have caused such migrations.  相似文献