Spatial character of the gaseous and particulate state compound correlation of urban atmospheric pollution in winter and summer   总被引：1，自引：0，他引：1  

XU Xiangde  SHI Xiaohui  XIE Lian  DING Guoan  MIAO Qiuju  MA Jianzhong  ZHENG Xiangdong 《中国科学D辑(英文版)》2005,48(Z2)

The spatial/temporal variation information of atmospheric dynamic-chemical processes at observation site points of the "canopy" boundary of Beijing urban building ensemble and over urban area "surface", as well as the seasonal correlation structure of the gaseous and particulate states of urban atmospheric pollution (UAP) and its seasonal conversion feature at observation points are investigated, using the comprehensive observation data of the Beijing City Air Pollution Observation Experiment (BECAPEX) in winter and summer 2003 with a "point-surface" combined research approach. By using "one dimension spatial empirical orthogonal function (EOF)" principal component analysis (PCA) mode, the seasonal change of gaseous and particulate states of atmospheric aerosols and the association feature of pollutant species under the background of the complicated structure of urban boundary layer (UBL) are analyzed. The comprehensive analyses of the principal components of particle concentrations,gaseous pollutant species, and meteorological conditions reveal the seasonal changes of the complex constituent and structure features of the gaseous and particulate states of UAP to further trace the impact feature of urban aerosol pollution surface sources and the seasonal difference of the component structure of UAP. Research results suggest that in the temporal evolution of the gaseous and particulate states of winter/summer UAP, NOx, CO, and SO2 showed an "in-phase" evolution feature, however, O3 showed an "inverse-phase" relation with other species,all possessing distinctive dependent feature. On the whole, summer concentrations of gaseous pollutants CO, SO2, and NOx were obviously lower than winter ones, especially, the reduction in CO concentration was most distinctive, and ones in SO2 and NOx were next. However, the summer O3 concentration was more than twice winter one. Winter/summer differences in PM10and PM2.5 particle concentrations were relatively not obvious, which indicates that responses of PM10 and PM2.5 particle concentrations to the difference of winter/summer heating period emission sources are far less distinctive than those of NOx, SO2, and CO. The correlation feature of winter/summer gaseous and particulate states depicts that both PM10 and PM2.5 particles were significantly correlated with NOx, and their correlations with NOx are more significant than those with other pollutants. Through PCA, it is found that there was a distinctive difference in the principal component combination structure of winter/summer PM10 and PM2.5 particles: SO2 and NOx dominated in the principal component of winter PM10 and PM2.5 particles; while CO and NOx played the major role in the principal component of summer PM10 and PM2.5 particles. For winter/summer PM10 and PM2.5 particles, there might exist the gaseous and particulate states correlation structures of different "combinations" of such dependent pollutant species. Research results also uncover that the interaction processes of gaseous and particulate states were also related with the vertical structure of UBL, that is to say, the low value layer of UBL O3 concentration was associated with the collocation of atmospheric vertical structures of the low level inversion,inverse humidity, and small wind, which depicts summer boundary layer atmospheric character, i.e.the compound impact of the dependent factor "combination" of wind, temperature, and humidity elements and their collocation structure on the variations of different gaseous pollutant concentrations. Such a depth structure of the extremely low value of O3 concentration in the UBL accords with its "inverse-phase" relation with other gaseous pollutant species. The PCA of meteorological factors associated with PM10 and PM2.5 concentrations also reveals the sensitivity of PM10 and PM2.5 concentration to the combinatory feature of local meteorological conditions.  相似文献   

Correlation between magnetic susceptibility and heavy metals in urban topsoil: a case study from the city of Xuzhou, China   总被引：7，自引：0，他引：7  

Xue Song WANG  Yong QIN 《Environmental Geology》2005,49(1):10-18

Anthropogenic influence, mainly due to urban and industrial activities and traffic exhaust, may affect urban topsoil via atmospheric contamination and solid waste. Magnetic susceptibility measurements were conducted on 21 urban topsoil samples from the city of Xuzhou, China. High intensities of magnetic susceptibility were detected in the majority of the samples. SEM analysis shows that magnetic minerals are in the form of spherules and mainly due to anthropogenic inputs. The heavy metals Pb, Cu, Zn, Se, Sc, Mo, Fe, and Bi show strong correlations with magnetic susceptibility, and Ag, Ba, Cd, Ni, Cr, Sb, and Sn, on the other hand, show a weak correlation with magnetic susceptibility. Whereas, of these metals studied, only Hg has no significant correlation with the susceptibility. The Tomlinson pollution load index (PLI) also shows significant correlation with the susceptibility (χ). The present study shows that magnetic susceptibility is a fast, inexpensive, and non-destructive method for the detection and mapping of contaminated soils.  相似文献   

天津地区表土PAHs含量的多尺度空间相关性   总被引：1，自引：1，他引：1  

刘瑞民  王学军  陶澍  沈伟然  秦宝平  孙韧  张文具 《地理研究》2005,24(4):565-571

本文应用因子克立格分析方法,分析了天津表土16种PAHs之间多尺度空间结构特征。分析结果显示,天津表土PAHs在空间上可以划分三种尺度:块金尺度(0～5km),小空间尺度(5～10km)和大空间尺度(10～50km)。在不同的空间尺度上,16种PAHs之间表现出不同的空间相关性,具有空间尺度相关性。这种空间尺度相关性,是由于不同的空间污染过程造成的,有助于下一步的多尺度空间污染源的判断和污染物迁移转化规律的识别。  相似文献   

喀斯特土地利用变化及其区域生态环境效应--以广西都安瑶族自治县为例   总被引：9，自引：1，他引：9  

许俐俐  胡宝清  严志强  廖赤眉  覃开贤 《地域研究与开发》2005,24(6):66-71

从土地利用转移类型、空间格局变化定量分析、动态变化预测模型等方面分析近20年都安土地利用变化,进而对其生态环境质量变化进行定量分析,得出结论:都安各乡(镇)生态环境质量改善与恶化在很大程度取决于裸岩地扩展与收缩,土地利用时空变化与区域生态环境质量的区域差异有很大相关性。  相似文献   

表面多次波衰减技术在渤海海峡应用效果     

孙运宝  赵铁虎  潘军  梅赛  冯京  秦轲 《海洋地质与第四纪地质》2015,(2):179-184

浅水地震勘探对于了解近海底地质构造具有重要意义,目前已被广泛用于油气开发、近岸工程等领域。表面多次波的存在干扰了有效波信息,影响了资料品质,造成解释假象,如何有效地压制多次波,已成为浅水地震勘探中的关键问题。表面多次波衰减方法(SRME)是一种去除海面相关多次波效果较好的技术方法,但是,一般认为SRME技术并不适合于浅水区域。分析了SRME去除多次波的基本原理,并将其应用于海洋高分辨率浅水区域多次波的去除。实际处理效果表明,使用SRME技术处理后的叠加剖面多次波去除效果明显,剖面基底清楚,断面清晰。通过对SRME技术应用于浅水区域的探讨,证实了SRME技术在海洋高分辨率地震勘探浅水区域应用效果较好。  相似文献   

Efficient estimation of flood forecast prediction intervals via single‐ and multi‐objective versions of the LUBE method          下载免费PDF全文

Lei Ye  Jianzhong Zhou  Hoshin V. Gupta  Hairong Zhang  Xiaofan Zeng  Lu Chen 《水文研究》2016,30(15):2703-2716

Prediction intervals (PIs) are commonly used to quantify the accuracy and precision of a forecast. However, traditional ways to construct PIs typically require strong assumptions about data distribution and involve a large computational burden. Here, we improve upon the recent proposed Lower Upper Bound Estimation method and extend it to a multi‐objective framework. The proposed methods are demonstrated using a real‐world flood forecasting case study for the upper Yangtze River Watershed. Results indicate that the proposed methods are able to efficiently construct appropriate PIs, while outperforming other methods including the widely used Generalized Likelihood Uncertainty Estimation approach. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Response of Plant Community Carbon and Nitrogen Stoichiometry to Experimental Warming on the Qinghai-Tibet Plateau     

ZHANG Haorui  QIN Jiwei  FU Gang 《资源与生态学报(英文版)》2020,11(3):315-321

Low temperature is an important limiting factor for alpine ecosystems on the Tibetan Plateau. This study is based on data from on-site experimental warming platforms (open top chambers, OTC) at three elevations (4300 m, 4500 m, 4700 m) on the Qinghai-Tibet Plateau. The carbon and nitrogen stoichiometry characteristics of plant communities, both above-ground and below-ground, were observed in three alpine meadow ecosystems in August and September of 2011 and August of 2012. Experimental warming significantly increased above-ground nitrogen content by 21.4% in September 2011 at 4500 m, and reduced above-ground carbon content by 3.9% in August 2012 at 4300 m. Experimental warming significantly increased below-ground carbon content by 5.5% in August 2011 at 4500 m, and the below-ground ratio of carbon to nitrogen by 28.0% in September 2011 at 4300 m, but reduced below-ground nitrogen content by 15.7% in September 2011 at 4700 m, below-ground carbon content by 34.3% in August 2012 at 4700 m, and the below-ground ratio of carbon to nitrogen by 37.9% in August 2012 at 4700 m. Experimental warming had no significant effect on the characteristics of community carbon and nitrogen stoichiometry under other conditions. Therefore, experimental warming had inconsistent effects on the carbon and nitrogen stoichiometry of plant communities at different elevations and during different months. Soil ammonium nitrogen and nitrate nitrogen content were the main factors affecting plant community carbon and nitrogen stoichiometry.  相似文献   

阿尔泰小土尔根铜矿区岩体LA-ICP-MS锆石U-Pb定年及地质意义     

秦纪华  耿新霞  温超权  郭建新  任宇晨 《矿床地质》2016,35(1):18-32

小土尔根是近年来阿尔泰诺尔特盆地发现的首例斑岩铜矿床,其成岩成矿年代学的研究可以对矿床模型构建、区域成矿规律的总结提供制约。矿区侵入岩发育,矿化受花岗闪长斑岩控制,少部分赋存在地层中。文章利用LA-ICP-MS锆石U-Pb测年法对矿区岩体进行了成岩年代学研究。含矿花岗闪长斑岩、黑云二长花岗岩和花岗斑岩中锆石的206Pb/238U年龄的加权平均值分别为(401.0±2.9)Ma、(398.1±2.2)Ma和(400.5±2.0)Ma,为早泥盆世同一岩浆侵入活动形成的不同侵入岩。侵入岩年龄结合凝灰岩年龄,将矿区地层划归早泥盆世诺尔特组。含矿花岗闪长斑岩锆石U-Pb年龄限定小土尔根斑岩铜矿床成矿时代略晚于401 Ma,即矿床形成于早泥盆世。  相似文献   

天气尺度波列对长江中下游6月梅雨的影响   总被引：2，自引：2，他引：0       下载免费PDF全文

黄海燕  王亚非  何金海  陈圣劼  秦坚肇 《大气科学学报》2016,39(1):28-36

采用1979—2007年6月NCEP/NCAR2.5°×2.5°逐日再分析资料和中国743站逐日降水资料,利用相关分析、合成分析等方法,分析了天气尺度波列的特征及其对长江中下游6月梅雨的影响。结果表明:当长江中下游6月梅雨较少时,东亚及西太平洋区域存在一个天气尺度波列;该波列的延伸距离较短(从黄河河套地区经过长江中下游至南海、菲律宾海一带),维持时间也很短,且仅仅在500 h Pa以下较强。诊断及个例分析表明,当该波列异常显著时,长江中下游梅雨降水明显减少,而其南部区域降水则增多,说明该波列对预报长江中下游降水具有重要的指示意义。  相似文献   

川西义敦岛弧稻城花岗岩体和海子山花岗岩体锆石U-Pb年代学、Hf同位素特征及地质意义   总被引：2，自引：0，他引：2  

王楠  吴才来  秦海鹏  雷敏  郭文峰  张昕  陈红杰 《地质学报》2016,90(11):3227-3245

义敦岛弧形成于晚三叠世大规模俯冲造山作用过程中,位于松潘-甘孜褶皱带和羌塘地体之间。稻城岩体和海子山岩体分别为义敦岛弧上出露的晚三叠世和白垩纪花岗质岩体。结合野外考察,本文对上述岩体进行岩相学、锆石U-Pb年代学和Hf同位素的研究,结果表明,1稻城岩体和海子山岩体主要矿物为斜长石、钾长石、石英和黑云母,副矿物为锆石、榍石、磁铁矿和磷灰石等;钠质斜长石颗粒,以及钾长石和石英不连续出现,表明二者均属于低熔线花岗岩,是含水条件下,在与造山事件有关的环境中形成。2稻城岩体的侵位年龄为217.4Ma,属晚三叠世花岗岩侵入体,εHf(t)为-7.1~-0.1,二阶段模式年龄(tDM2)为1.26~1.7Ga,表明在中元古代与扬子克拉通经历了共同的地壳演化历史;海子山岩体的形成时代为98.3 Ma,为白垩纪时期产物,εHf(t)变化于-12.1~+2.5,二阶段模式年龄(tDM2)变化于1.0~1.93Ga。3结合前人研究成果,本文认为稻城岩体源岩可能是与扬子克拉通有关的中元古代的下地壳物质,在甘孜-理塘洋俯冲闭合后的同碰撞造山阶段,因地幔岩浆底侵作用而发生了部分熔融,同时伴有少量的亏损地幔成分加入,之后上升侵位于中—上地壳,并且侵位后经历了快速的冷却过程。海子山岩体是与俯冲有关的造山后伸展环境下形成的A2型花岗岩,源岩主要为中元古代地壳物质,同样有少量地幔物质加入,在白垩纪时侵位于地壳较浅部位,之后亦同样经历了快速的冷却过程。  相似文献