Sr-Nd-Pb isotopes from the Radicofani Volcano, Central Italy: constraints on heterogeneities in a veined mantle responsible for the shift from ultrapotassic shoshonite to basaltic andesite magmas in a post-collisional setting     

Sandro Conticelli  Riccardo Avanzinelli  Sara Marchionni  Simone Tommasini  Leone Melluso 《Mineralogy and Petrology》2011,103(1-4):123-148

The Radicofani Volcano is characterised by few lava flows, a cinder cone and a denudated neck, and is part of the Tuscan Magmatic Province, the northernmost volcanic region of the Italian peninsula. In spite of the short time span of activity, a large time-dependant chemical and isotopic variability is observed. Most of the rocks of the Radicofani volcano are ultrapotassic shoshonites associated to younger basaltic andesites, found at the bottom of the neck. K₂O contents are positively correlated with trace element and isotopic variations. Shoshonitic and high-K calc-alkaline rocks of the Radicofani volcano are significantly different from shoshonites occurring in association with leucite-bearing ultrapotassic rocks in the southernmost portion of the Roman Magmatic Province. The studied rocks are characterised by high, but variable, levels of incompatible trace elements with a subduction-related signature, with troughs at Ba, Ta, Nb, and Ti, and peaks at Cs, K, Th, U, and Pb. Initial values of ⁸⁷Sr/⁸⁶Sr range from 0.71333 to 0.71588, ¹⁴³Nd/¹⁴⁴Nd ranges from 0.512050 to 0.512183, while the lead isotope ratios vary between 18.672 and 18.716 for ²⁰⁶Pb/²⁰⁴Pb, 15.665 to 15.696 for ²⁰⁷Pb/²⁰⁴Pb, and 39.981 to 39.081 for ²⁰⁸Pb/²⁰⁴Pb. Ultrapotassic shoshonites show the highest incompatible trace element contents coupled with the highest ⁸⁷Sr/⁸⁶Sr and the lowest ¹⁴³Nd/¹⁴⁴Nd. On the basis of geochemical and isotopic signatures it is argued that magmas were generated in a modified lithospheric peridotitic source containing metasomatic veins generated by K-rich melts from recycled sediments within the mantle via subduction. A further metasomatic event generated by slab-derived fluids pervasively enriched the peridotitic source. Partial melting of the veins produced leucite-free ultrapotassic magmas (i.e. lamproite), and was triggered by rising of the isotherms after the orogenic front migrated eastward in the Italian Peninsula. Further rise of the isotherms induced larger degrees of partial melting inducing melting of the surrounding wall peridotite. The variation of the degree of partial melting of such a heterogeneous peridotitic source produced a wide spectrum of magma compositions, which mimic a mixing line between two components: ultrapotassic magma from partial melting of the metasomatic vein and a basaltic andesitic magma from partial melting of the surrounding peridotite.  相似文献   

Background simulations for the Large Area Detector onboard LOFT     

Riccardo Campana  Marco Feroci  Ettore Del Monte  Teresa Mineo  Niels Lund  George W. Fraser 《Experimental Astronomy》2013,36(3):451-477

The Large Observatory For X-ray Timing (LOFT), currently in an assessment phase in the framework the ESA M3 Cosmic Vision programme, is an innovative medium-class mission specifically designed to answer fundamental questions about the behaviour of matter, in the very strong gravitational and magnetic fields around compact objects and in supranuclear density conditions. Having an effective area of ～10 m² at 8 keV, LOFT will be able to measure with high sensitivity very fast variability in the X-ray fluxes and spectra. A good knowledge of the in-orbit background environment is essential to assess the scientific performance of the mission and optimize the design of its main instrument, the Large Area Detector (LAD). In this paper the results of an extensive Geant-4 simulation of the instrumentwillbe discussed, showing the main contributions to the background and the design solutions for its reduction and control. Our results show that the current LOFT/LAD design is expected to meet its scientific requirement of a background rate equivalent to 10 mCrab in 2?30 keV, achieving about 5 mCrab in the most important 2–10 keV energy band. Moreover, simulations show an anticipated modulation of the background rate as small as 10 % over the orbital timescale. The intrinsic photonic origin of the largest background component also allows for an efficient modelling, supported by an in-flight active monitoring, allowing to predict systematic residuals significantly better than the requirement of 1 %, and actually meeting the 0.25 % science goal.  相似文献   

Spectroscopic Characterization of Compost at Different Maturity Stages   总被引：1，自引：0，他引：1  

Riccardo Spaccini  Alessandro Piccolo 《洁净——土壤、空气、水》2008,36(2):152-157

We studied the physicochemical and molecular changes of compost during its maturation within 60, 90, and 150 days after the composting process. Moreover, the changes were also studied in compost residues after sequential removal of lipidic compounds. Infrared DRIFT spectrometry and ¹³C‐CPMAS‐NMR spectroscopy indicate that the molecular composition of compost changes dramatically during the stabilization period. The most decomposable components, mainly represented by bioavailable lipidic and peptidic structures, were progressively mineralized passing from 60 days to longer periods of compost stabilization. At increasing maturity stages, the composition of organic matter underwent a progressive enrichment in stable hydrophobic and ligno‐cellulosic material. The sequential extraction of lipidic compounds allowed an improved characterization of substrates and confirmed the outlined progressive transformation of compost. Compost may well be chosen on the basis of selected characteristics for environmental applications.  相似文献   

Exploring determinants of the extent of long distance commuting in Australia: accounting for space     

Christopher Nicholas  Riccardo Welters 《The Australian geographer》2016,47(1):103-120

Previous research exploring the impacts of long distance commuting (LDC) or, more generally, mining on host regions, struggles to explain the variability of these impacts over time and across space. This article argues that spatial effects should be accounted for explicitly in order to improve the predictive power of contemporary research. We study the extent of LDC in a region in a spatial model disaggregating Australia into 325 subregions. We find evidence that space is an important factor in explaining the extent of LDC in a region, which challenges the validity of studying LDC impacts on host regions in isolation. With regards to the determinants of the extent of LDC, we find that residential attractiveness of a region influences the extent of LDC in a region; the size of the pool of unemployed in a region does not.  相似文献   

FAOSTAT estimates of greenhouse gas emissions from biomass and peat fires     

Simone Rossi  Francesco N. Tubiello  Paolo Prosperi  Mirella Salvatore  Heather Jacobs  Riccardo Biancalani  Joanna I. House  Luigi Boschetti 《Climatic change》2016,135(3-4):699-711

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Erratum to: FAOSTAT estimates of greenhouse gas emissions from biomass and peat fires     

Simone Rossi  Francesco N. Tubiello  Paolo Prosperi  Mirella Salvatore  Heather Jacobs  Riccardo Biancalani  Joanna I. House  Luigi Boschetti 《Climatic change》2016,135(3-4):713-713

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Studying travertines for neotectonics investigations: Middle–Late Pleistocene syn-tectonic travertine deposition at Serre di Rapolano (Northern Apennines, Italy)     

Andrea Brogi  Enrico Capezzuoli  Riccardo Aqué  Marilì Branca  Mario Voltaggio 《International Journal of Earth Sciences》2010,99(6):1383-1398

Middle–Late Pleistocene tectonic activity has been inferred through studies on travertine deposits exposed in a tract of the hinterland Northern Apennines. A detailed study on the relationships between tectonics and travertine deposition coupled with ²³⁰Th/²³⁴U age determination of travertines at Cava Oliviera quarry, located close to Serre di Rapolano village (southern Tuscany, Northern Apennines), allowed us to recognise Pleistocene faults, whose activity has been referred to 157–24 ka, at least. Travertine deposition was tectonically controlled by WSW-ENE striking, oblique and normal faults, associated to a main fault (named as the Violante Fault). This structure dissected a regional normal fault (known as the Rapolano Fault) Early–Middle Pliocene in age, which bounded the eastern side of the Pliocene Siena Basin, and gave rise to space accommodation for clayey and sandy marine sediments. Hydrothermal circulation (and related travertine deposition) was favoured by the damaging enhancement due to the fault–fault intersection. Tectonic activity has been also documented by deformation recorded by travertines, which suggest a main tectonic event between 64 ± 5 and 40 ± 5 ka. The tectonic activity described for the study area agrees with the Quaternary tectonic evolution documented in the surrounding areas (e.g. Mt. Amiata and Mt. Vulsini), as well as the Tyrrhenian margin of the Central Apennines, indicating that a widespread tectonic activity affected the inner part of the Apennines until the latest Quaternary.  相似文献   

Transpressional tectonics and nappe stacking along the Southern Variscan Front of Morocco   总被引：1，自引：0，他引：1  

Andrea Cerrina Feroni  Alessandro Ellero  Marco G. Malusà  Giovanni Musumeci  Giuseppe Ottria  Riccardo Polino  Leonardo Leoni 《International Journal of Earth Sciences》2010,99(5):1111-1122

The Southern Variscan Front in the Tinerhir area involves Palaeozoic allochthonous units (Ouaklim and Tilouine units) thrust onto the northern edge of the West African Craton during late Carboniferous time. Illite crystallinity data highlight an anchizonal grade for the Ouaklim Unit, and a diagenesis-anchizone transition for the Tilouine Unit during deformation phase D1. The tectonic stack is crosscut by major dextral reverse faults bounding E–W trending domains of dominant shortening deformation (central domain) and strike-slip deformation (northern and southern domains), later segmented by a network of post-Variscan faults. This complex deformation pattern is the result of kinematic partitioning of dextral transpression along the Southern Variscan Front, coeval with the Neovariscan (300–290 Ma) oblique convergence observed at the scale of the whole Moroccan Variscides. Partitioning of dextral transpression described in the Tinerhir area is consistent with dextral wrench faulting along the Tizi n’ Test Fault, and with Appalachian-style south-directed thrusting in the Tinerhir and Bechar-Bou Arfa areas.  相似文献   

New data for the kinematic interpretation of the Alps–Apennines junction (Northwestern Italy)     

Pietro Mosca  Riccardo Polino  Sergio Rogledi  Massimo Rossi 《International Journal of Earth Sciences》2010,99(4):833-849

Alps and Apennines are juxtaposed within an approximately 100 km-wide area covered by the Upper Eocene to Miocene successions of the Tertiary Piedmont Basin. The Upper Eocene–Oligocene evolution of this area was characterized to the north and west by the propagation of the SE-verging Southalpine thrust-fold belt that can be traced from the Po Plain subsurface until the Torino Hill-Saluzzese area, and to the south by a high-angle, broadly E–W oriented megashear zone that led to the juxtaposition of different crustal levels and controlled the development of a mosaic of partly independent sub-basins. Since the latest Oligocene the N-verging Apenninic tectonics prevailed in the collisional system and the Tertiary Piedmont Basin evolved as a wide thrust-top basin, bounded to the north by the N-verging Monferrato arc and characterized by a tectono-sedimentary evolution recording changes of subsidence and shift of depocentres in relation to crustal structures.  相似文献   

Evaluating asbestos fibre concentration in metaophiolites: a case study from the Voltri Massif and Sestri–Voltaggio Zone (Liguria, NW Italy)     

Folco Giacomini  Vittorio Boerio  Simona Polattini  Massimo Tiepolo  Riccardo Tribuzio  Alberto Zanetti 《Environmental Earth Sciences》2010,61(8):1621-1639

This work is part of the project study for a road tunnel bypassing the town of Genova and was aimed at evaluating the amount of asbestos fibres in the metaophiolites belonging to the Voltri Group and the Sestri–Voltaggio Zone (Liguria, Northern Italy). The 85 studied rock samples (mainly mafic and ultramafic rocks) derive from exposed outcrops and prospecting boreholes. The study of field relations and petrographic/microtextural investigations under the optical microscope allowed for the identification and characterisation of asbestos-bearing settings and lithotypes. Mineralogy and concentration of asbestos fibres in powdered specimens were determined by means of a scanning electron microscope equipped with an energy-dispersive X-ray spectroscopy device. These investigations were combined with petrography on thin-section, X-ray diffraction analysis and phase contrast optical microscopy on rock powders. Mafic and ultramafic rocks commonly contain asbestos in concentrations below 1,000 mg/kg (considered as the contamination threshold under Italian law). However, the fibre concentration rises abruptly within localised zones, where the metaophiolite sequences were involved into late ductile to brittle tectono-metamorphic events. Two groups of asbestos-bearing settings have been so far identified in the area: (a) fracture networks within serpentinites (dominated by fibrous chrysotile), and (b) boudins of chlorite-tremolite schists, likely deriving from dynamic recrystallisation of mafic rocks under greenschist facies conditions (dominated by fibrous amphibole). Even considering the low volumetric incidence of these settings (metres to few tens of metres), their high asbestos content locally controls the total fibre amount in the excavation products, thus requiring special prevention measures during excavation, management and final storage of the contaminated debris.  相似文献