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11.
The analytical capabilities of laser ablation (LA)-ICP-MS in determining Li, Be and B at trace levels in geological samples have been tested on a series of glass reference materials and natural samples. The LA-ICP-MS instrument used consisted of a sector-field ICP-MS coupled with a laser ablation microprobe operating at either 266 or 213 nm wavelength. Reference glasses from NIST (SRM 612, 614 and 616) and MPI-DING (KL2-G, ML3B-G, StHs6/80-G, GOR128-G, GOR132-G, T1-G and ATHO-G) were selected to develop the analytical method and to assess the best instrumental configuration. A series of calcic amphiboles with different Li, Be and B concentrations were also analysed using both LA-ICP-MS and SIMS to test the applicability of the method to natural minerals. Results indicated that with a spot size of 40 μm the agreement between measured and reference values of Li, Be and B is generally better than 10% for NIST SRM 612 and 20% for NIST SRM 614. Average reproducibility at the 2s level was 10% for Li, 20% for Be and 15% for B. Limits of detection were approximately 100 ng g-1 for Be and B and 200 ng g-1 for Li. These results were confirmed by analyses carried out on natural amphiboles and compared well in terms of precision and accuracy with those commonly achieved by SIMS.  相似文献   
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The fine-scale heterogeneity of porous media affects the large-scale transport of solutes and contaminants in groundwater and it can be reproduced by means of several geostatistical simulation tools. However, including the available geological information in these tools is often cumbersome. A hierarchical simulation procedure based on a binary tree is proposed and tested on two real-world blocks of alluvial sediments, of a few cubic meters volume, that represent small-scale aquifer analogs. The procedure is implemented using the sequential indicator simulation, but it is so general that it can be adapted to various geostatistical simulation tools, improving their capability to incorporate geological information, i.e., the sedimentological and architectural characterization of heterogeneity. When compared with a standard sequential indicator approach on bi-dimensional simulations, in terms of proportions and connectivity indicators, the proposed procedure yields reliable results, closer to the reference observations. Different ensembles of three-dimensional simulations based on different hierarchical sequences are used to perform numerical experiments of conservative solute transport and to obtain ensembles of equivalent pore velocity and dispersion coefficient at the scale length of the blocks (meter). Their statistics are used to estimate the impact of the variability of the transport properties of the simulated blocks on contaminant transport modeled on bigger domains (hectometer). This is investigated with a one-dimensional transport modeling based on the Kolmogorov-Dmitriev theory of branching stochastic processes. Applying the proposed approach with diverse binary trees and different simulation settings provides a great flexibility, which is revealed by the differences in the breakthrough curves.  相似文献   
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In order to explain a fine structure of parallel ridges in stationary type IV continua, the emission due to the coupling of electrostatic upper hybrid waves and Bernstein waves at the sum frequency of the upper hybrid and harmonics of the gyro frequency has been calculated. If the energy density of these electrostatic waves is of the order of 10-3 times the thermal energy density, then the observed zebra pattern can be emitted by a region with a diameter of 103 km.  相似文献   
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We present a comparison between the peculiar velocity fields measured from a recently completed l -band Tully–Fisher survey of field spirals (SFI) and that derived from the IRAS 1.2-Jy redshift survey galaxy distribution. The analysis is based on the expansion of these data in redshift space using smooth orthonormal functions, and is performed using low- and high-resolution expansions, with an effective smoothing scale which increases almost linearly with redshift. The effective smoothing scales at 3000 km s−1 are 1500 and 1000 km s−1 for the low- and high-resolution filters. The agreement between the high- and low-resolution SFI velocity maps is excellent. The general features in the filtered SFI and IRAS velocity fields agree remarkably well within 6000 km s−1. This good agreement between the fields allows us to determine the parameter β = Ω0.6 / b , where Ω is the cosmological density parameter, and b is the linear biasing factor. From a likelihood analysis on the SFI and IRAS modes we find that β = 0.6 ± 0.1, independently of the resolution of the modal expansion. For this value of β, the residual fields for the two filters show no systematic variations within 6000 km s−1. Most remarkable is the lack of any coherent, redshift-dependent dipole flow in the residual field.  相似文献   
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MAGIA is a mission approved by the Italian Space Agency (ASI) for Phase A study. Using a single large-diameter laser retroreflector, a large laser retroreflector array and an atomic clock onboard MAGIA we propose to perform several fundamental physics and absolute positioning metrology experiments: VESPUCCI, an improved test of the gravitational redshift in the Earth?CMoon system predicted by General Relativity; MoonLIGHT-P, a precursor test of a second generation Lunar Laser Ranging (LLR) payload for precision gravity and lunar science measurements under development for NASA, ASI and robotic missions of the proposed International Lunar Network (ILN); Selenocenter (the center of mass of the Moon), the determination of the position of the Moon center of mass with respect to the International Terrestrial Reference Frame/System (ITRF/ITRS); this will be compared to the one from Apollo and Lunokhod retroreflectors on the surface; MapRef, the absolute referencing of MAGIA??s lunar altimetry, gravity and geochemical maps with respect to the ITRF/ITRS. The absolute positioning of MAGIA will be achieved thanks to: (1) the laboratory characterization of the retroreflector performance at INFN-LNF; (2) the precision tracking by the International Laser Ranging Service (ILRS), which gives two fundamental contributions to the ITRF/ITRS, i.e. the metrological definition of the geocenter (the Earth center of mass) and of the scale of length; (3) the radio science and accelerometer payloads; (4) support by the ASI Space Geodesy Center in Matera, Italy. Future ILN geodetic nodes equipped with MoonLIGHT and the Apollo/Lunokhod retroreflectors will become the first realization of the International Moon Reference Frame (IMRF), the lunar analog of the ITRF.  相似文献   
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The satellite PLATO represents a new challenge for future investigations of exoplanets and oscillations of stars. It is one of the proposed missions of ESA COSMIC VISION 2015–2025 and it is scheduled for launch in 2017. The goal of the mission is a full characterization of the planet star systems with an asteroseismic analysis of the host stars. The PLATO Payload Consortium (PPLC) includes several European countries which are employed in the assessment study of the mission. Thanks to the high precision photometry, PLATO is thought to be able to detect planets and oscillations within a large sample of targets.  相似文献   
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Accidental release of crude oil into the sea due to human activity causes water pollution and heavy damages to natural ecosystems killing birds, fish, mammals and other organisms. A number of monitoring systems are used for tracking the spills and their effects on the marine environment, as well as for collecting data for feeding models. Among them, Earth observation technologies play a crucial role and moderate spatial resolution satellite systems are able to collect images with a very short revisit time or even daily. This paper describes the use of Moderate-Resolution Imaging Spectroradiometer data for monitoring large oil slicks with the fluorescence/emissivity index and object-based image analysis. Two case studies are presented: the Deepwater Horizon (2010) and the Campos Basin (2011) oil spill accidents. Results show that it is possible to track the dynamics of the slick both for massive and long-lasting accidents and for smaller and very quick accidents. The main advantages of the method proposed are a straightforward implementation, a fast and semi-automated data processing and the capability of integration of daytime and nighttime acquisitions, as well as its adaptability to different sensors.  相似文献   
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