Evaluating asbestos fibre concentration in metaophiolites: a case study from the Voltri Massif and Sestri–Voltaggio Zone (Liguria, NW Italy)     

Folco Giacomini  Vittorio Boerio  Simona Polattini  Massimo Tiepolo  Riccardo Tribuzio  Alberto Zanetti 《Environmental Earth Sciences》2010,61(8):1621-1639

This work is part of the project study for a road tunnel bypassing the town of Genova and was aimed at evaluating the amount of asbestos fibres in the metaophiolites belonging to the Voltri Group and the Sestri–Voltaggio Zone (Liguria, Northern Italy). The 85 studied rock samples (mainly mafic and ultramafic rocks) derive from exposed outcrops and prospecting boreholes. The study of field relations and petrographic/microtextural investigations under the optical microscope allowed for the identification and characterisation of asbestos-bearing settings and lithotypes. Mineralogy and concentration of asbestos fibres in powdered specimens were determined by means of a scanning electron microscope equipped with an energy-dispersive X-ray spectroscopy device. These investigations were combined with petrography on thin-section, X-ray diffraction analysis and phase contrast optical microscopy on rock powders. Mafic and ultramafic rocks commonly contain asbestos in concentrations below 1,000 mg/kg (considered as the contamination threshold under Italian law). However, the fibre concentration rises abruptly within localised zones, where the metaophiolite sequences were involved into late ductile to brittle tectono-metamorphic events. Two groups of asbestos-bearing settings have been so far identified in the area: (a) fracture networks within serpentinites (dominated by fibrous chrysotile), and (b) boudins of chlorite-tremolite schists, likely deriving from dynamic recrystallisation of mafic rocks under greenschist facies conditions (dominated by fibrous amphibole). Even considering the low volumetric incidence of these settings (metres to few tens of metres), their high asbestos content locally controls the total fibre amount in the excavation products, thus requiring special prevention measures during excavation, management and final storage of the contaminated debris.  相似文献   

The relationship between websterite and peridotite in the Balmuccia peridotite massif (NW Italy) as revealed by trace element variations in clinopyroxene   总被引：7，自引：0，他引：7  

Rivalenti  Giorgio  Mazzucchelli  Maurizio  Vannucci  Riccardo  Hofmann  Albrecht W.  Ottolini  Luisa  Bottazzi  Piero  Obermiller  Walter 《Contributions to Mineralogy and Petrology》1995,122(3):275-288

 Field, mineralogical and petrological data are presented on a newly found carbonatite occurrence associated with “kamafugite” lava at Cupaello, central Italy. This carbonatite occurrence is part of the Late Pleistocene Umbria-Latium ultra-alkaline district (ULUD) which extends southwards within the Apennines to Mount Vulture, delineating an important magmatic province along the most peripheral belt of the Tyrrhenian extensional tectonic system. This province is distinct, but probably related genetically with the more abundant and common leucite-bearing assemblages of the Roman Comagmatic Region and represents the first reported occurrence of carbonatite assemblages in the Mediterranean Basin. The Cupaello suite indicates that primary or near-primary mantle silicate melts of “kamafugitic” composition are transitional with Ca-carbonatite liquid and provides direct evidence of immiscibility of carbonatite from “kamafugite” magma. It is inferred that a primary mantle origin of Ca-carbonatites is conditional upon a potential silicate magma that may be coupled with the carbonatite, but may not have reached the surface. The data indicate a strong genetic link between ULUD Ca-carbonatites and some African analogues, supporting the view that their genesis depends on similar source and associated tectonic conditions. Received: 17 January 1995 / Accepted: 14 June 1995  相似文献   

Fast collocation     

Gian Paolo Bottoni  Riccardo Barzaghi 《Journal of Geodesy》1993,67(2):119-126

In this paper a new method to compute in a fast and reliable way the collocation solution is presented. In order to speed up the numerical procedures, some restrictions on input data are needed.The basic assumption is that data are gridded and homogeneous; this implies that the autocovariance matrix entering in the collocation formula is of Toeplitz type. In particular, if observations are placed on a two dimensional planar grid, the autocovariance matrix is a symmetric block Toeplitz matrix and each block is itself a symmetric Toeplitz matrix (Toeplitz/Toeplitz structure). The analysis can be extended to a regular geographical grid, considered as a generalization of the planar one, taking into account the distortions on the Toeplitz/Toeplitz structure induced by the convergence of the meridians. The devised method is based on a combined application of the Preconditioned Conjugate Gradient Method and of the Fast Fourier Transform. This allows a proper exploitation of the Toeplitz/Toeplitz structure of the autocovariance matrix in computing the collocation solution.The numerical tests proved that the application of this algorithm leads to a relevant decrease in CPU time if compared with standard methods used to solve a collocation problem (Cholesky, Levinson).  相似文献   

Subsolidus reactions monitored by trace element partitioning: the spinel- to plagioclase-facies transition in mantle peridotites     

E. Rampone  G. B. Piccardo  R. Vannucci  P. Bottazzi  L. Ottolini 《Contributions to Mineralogy and Petrology》1993,115(1):1-17

Mantle peridotites of the External Liguride (EL) Units (Northern Apennines) mainly consist of fertile spinel-lherzolites partially recrystallized to plagioclase-facies assemblages, and are consequently appropriate to investigate the interphase element partitioning related to the transition from spinel- to plagioclase-facies stability field. Evidence for the development of the plagioclase-facies assemblage is mainly given by: (1) large exsolution lamellae of orthopyroxene and plagioclase within spinel-facies clinopyroxene; (2) plagioclase rims around spinel; (3) granoblastic domains made up of olivine+plagioclase±clino-and orthopyroxene. In situ major and trace [REE (rare-earth elements), Ti, Sc, V, Cr, Sr, Y, Zr and Ba] element mineral analyses have been performed, by electron and ion probe, on selected samples which show the progressive development of the plagioclase-bearing assemblage. The main compositional variations observed during the change from spinel- to plagioclase-facies minerals are as follows: (1) clinopyroxenes decrease in Al, Na, Sr, Eu/Eu^* and increase in Y, V, Sc, Cr, Zr and Ti; (2) amphiboles decrease in Eu/Eu^*, Sr, Ba and increase in Zr and V; (3) spinels decrease in Al and increase in Cr and Ti. The most striking feature is the decoupling in the behaviour of similarly incompatible elements (D about 0.1) in clinopyroxene, e.g. Sr decrease is mirrored by Zr increase. Massbalance calculations indicate that the trace element interphase redistribution documented in the EL peridotites occurred in a closed system and in response to the metamorphic reaction governing the transition from the spinel- to the plagioclase-facies stability field. The observed element partitioning reveals, moreover, that subsolidus re-equilibration processes in the upper mantle produce HFSE (high-field-strength element)/REE fractionation in minerals, which must be evaluated for a reliable determination of mineral-melt distribution coefficients. The results of this study furnish evidence for subsolidus metamorphic evolution during decompression, without concomitant partial melting processes. This is consistent with the interpretation that the EL peridotites represent subcontinental lithospheric mantle emplaced at the surface in response to lithospheric thinning and tectonic denudation mechanisms related to the Triassic-Jurassic rifting of the Ligure-Piedmontese basin.  相似文献   

Post‐Variscan tectonics in eastern Anti‐Atlas (Morocco)     

Marco G. Malus  Riccardo Polino  Andrea Cerrina Feroni  Alessandro Ellero  Giuseppe Ottria  Lahssen Baidder  Giovanni Musumeci 《地学学报》2007,19(6):481-489

New field data integrated by fission‐track (FT) analysis unravel an innovative scenario for the post‐Variscan evolution of the eastern Anti‐Atlas. This area, unaffected by Meso‐Cenozoic tectonics according to most workers, is crosscut by crustal faults bearing evidence of a polyphase deformation history. Apatite FT ages, ranging between 284 and 88 Ma, point to fast Neogene exhumation and unravel contrasting cooling paths across major faults. Results show that the study area was buried beneath 2 km of allochthonous Variscan units, now eroded. The eastern Anti‐Atlas acted as the southern shoulder of the Atlasic rift in the Mesozoic, and underwent a dextral transpressional structuring of Neogene age followed by sub‐meridian shortening. The southern front of Atlasic deformation is therefore located inside the Anti‐Atlas region, and it is still active.  相似文献   

New constraints on the origin and age of Variscan eclogitic rocks (Ligurian Alps,Italy)     

Folco Giacomini  Roberto Braga  Massimo Tiepolo  Riccardo Tribuzio 《Contributions to Mineralogy and Petrology》2007,153(1):29-53

Gabbro and eclogite boudins are preserved within the amphibolites of the composite para- and ortho-gneiss Variscan basement of the Savona Crystalline Massif (Ligurian Briançonnais, Italy). Whole rock trace element patterns, low initial εNd (+5.4 to +8.8) data and trace element analyses on relict igneous clinopyroxene revealed that the mafic rocks were derived from depleted mantle melts, which most likely underwent crustal contamination during emplacement. Gabbros have a cumulus origin controlled by clinopyroxene and plagioclase segregation, whereas the eclogites represent evolved melts. U-Pb and trace element micro-analyses on zircons separated from one amphibolitised gabbro and one eclogite help to constrain coeval ages at ~468 Ma for their igneous protoliths. The occurrence of a few inherited zircons confirms the involvement of a crustal component in the petrogenesis of the mafic rocks. In the eclogite, concordant zircon ages younger than the protolith age testify to metamorphic re-crystallisation (or new growth) from about 420 to 305 Ma. Zircon textures and trace element compositions indicate that eclogite facies metamorphism occurred 392–376 Ma ago. The younger zircon portions yielding a mean Concordia age of 333 ± 7 Ma are related to equilibration or new growth during the post-eclogite, amphibolite-facies equilibration.  相似文献   

N-MORB crust beneath Fuerteventura in the easternmost part of the Canary Islands: evidence from gabbroic xenoliths     

Else-Ragnhild?NeumannEmail author  Riccardo?Vannucci  Massimo?Tiepolo 《Contributions to Mineralogy and Petrology》2005,150(2):156-173

Gabbro xenoliths reported in this paper were collected in northern Fuerteventura, the Canary Island located closest to the coast of Africa. The xenoliths are very fresh and consist of Ti–Al-poor clinopyroxene + plagioclase (An_87–67) + olivine (Fo_72–86) ± orthopyroxene. Clinopyroxene and orthopyroxene are constantly and markedly depleted in light rare earth elements (LREE) relative to heavy REE (HREE), as expected for cumulus minerals formed from highly refractory N-MORB-type melts. In contrast, whole-rock Primordial Mantle-normalized trace element patterns range from mildly S-shaped (mildly depleted in Pr–Sm relative to both the strongly incompatible elements Rb–La and the HREE) to enriched. Estimates show that the trace element compositions of the rocks and their minerals are compatible with formation as N-MORB gabbro cumulates, which have been infiltrated at various extents (≤1% to >5%) by enriched alkali basaltic melts. The enriched material is mainly concentrated along grain boundaries and cracks through mineral grains, suggesting that the infiltration is relatively recent, and is thus associated with the Canary Islands magmatism. Our data contradict the hypothesis that a mantle plume was present in this area during the opening of the Atlantic Ocean. No evidence of continental material that might reflect attenuated continental crust in the area has been found. Gabbro xenoliths with REE and trace element compositions similar to those exhibited by the Fuerteventura gabbros are also found among gabbro xenoliths from the islands of La Palma (western Canary Islands) and Lanzarote. The compositions of the most depleted samples from these islands are closely similar, implying that there was no significant change in chemistry during the early stages of formation of the Atlantic oceanic crust in this area. Strongly depleted gabbros similar to those collected in Fuerteventura have also been retrieved in the MARK area along the central Mid-Atlantic Ridge. The presence of N-MORB oceanic crust beneath Fuerteventura implies that the continent–ocean transition in the Canary Islands area must be relatively sharp, in contrast to the situation both further north along the coast of Morocco, and along the Iberian peninsula.  相似文献   

The structure of coronal magnetic loops     

Riccardo Giachetti  Gerard Van Hoven  Claudio Chiuderi 《Solar physics》1977,55(2):371-386

We present the second part of a complete theory for the plasma and field structure of a cool coronal arch, corresponding to those observed in the EUV from Skylab. The global magneto-hydrodynamic (MHD) stability of a previously described equilibrium-loop model is evaluated, and compared with that of an unmodified ambient force-free field. The influence of the photospheric boundary condition is also evaluated, producing a specification of stability limits which depend on the relative field and plasma pressures and scale widths. The resulting restrictions on the allowable field configuration of a coronal loop are then compared with observed values. The implications of this general method for deducing small-scale coronal magnetic-field structure from the measured plasma profile of an emissive feature are also described.  相似文献   

Carbonate pseudotachylytes: evidence for seismic faulting along carbonate faults     

Alfio Viganò  Simone Tumiati  Sandro Recchia  Silvana Martin  Marcello Marelli  Riccardo Rigon 《地学学报》2011,23(3):187-194

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Limestone Provenance in Roman Lime‐Volcanic Ash Mortars from the Villa dei Quintili,Rome     

Giusj Valentina Fichera  Cristina Maria Belfiore  Mauro Francesco La Russa  Silvestro Antonio Ruffolo  Donatella Barca  Riccardo Frontoni  Giuliana Galli  Antonino Pezzino 《Geoarchaeology》2015,30(2):79-99

Roman mortars were collected from the Villa dei Quintili in Rome, an archaeological site consisting of numerous edifices from nine construction phases dating from the 2nd century A.D. to modern times. A multianalytical approach was used on 34 mortar samples to infer the evolution of production techniques over time and to identify the source area of calcareous raw materials used in the preparation of the lime. Optical microscopy, scanning electron microscopy coupled with an energy‐dispersive system, and laser ablation inductively coupled plasma mass spectrometry were used to study the samples. The major and trace element data were compared with the compositions of two types of limestone samples (Calcare Massiccio and Calcare Maiolica) collected from the Cornicolani Mountains. The results suggest that the technological practices and the calcareous raw materials used for lime production remained unchanged over the time period considered (2nd century A.D. to 3rd century A.D.). The compositions of lime‐related particles in the mortars match those of Calcare Maiolica, which suggests its use as raw material for lime production. On the whole, the results are in agreement with data from existing literature regarding both the use by Roman builders of specific raw materials for the mortars’ production and the relative supply area.  相似文献