Waters of the western springs catchment,Auckland     

W. J. Russell  K. A. Rodgers 《新西兰海洋与淡水研究杂志》2013,47(4):713-728

Abstract

Aquifers occur in basalt deposits infilling valleys in the Western Springs catchment of Auckland City, and they discharge into small streams incised along the edges of major lava flows. Total run‐off from the area is >0.261 m³·s^?1. Analyses by standard methods of twelve subsurface and surface waters show that flowing groundwaters have a low level of pollution (dissolved oxygen x = 7.6 mg·l^?1, abuminoid nitrogen x = 0.038 mg·l^?1, and total solids x = 188 mg·l^?1). Surface waters and stagnant groundwater have high, but varying levels of biological activity. Although much of the dissolved solid content of all the waters (e.g., Ca²⁺, Mg²⁺, Na⁺, K⁺, SiO₂) is consistent with the chemistry of the rocks of the catchment, particularly the glassy volcanic tuffs, for surface waters various sources of pollution also make significant contributions (e.g., leaking sewers, sewage overflows, combustion of fossil fuels, fertilisers, zoo animals). Apart from its iron level, the moderate volume (～.0.13 m³·s^?1) of flowing groundwater is of suitable quality for domestic, industrial and irrigation needs.  相似文献   

Effect of temperature and mass transport on transition metal isotope fractionation during electroplating     

Jay R. Black  Seth John  Abby Kavner 《Geochimica et cosmochimica acta》2010,74(18):5187-715

Transition metal stable isotope signatures can be useful for tracing both natural and anthropogenic signals in the environment, but only if the mechanisms responsible for fractionation are understood. To investigate isotope fractionations due to electrochemistry (or redox processes), we examine the stable isotope behavior of iron and zinc during the reduction reaction  + 2e⁻ = M_metal as a function of electrochemical driving force, temperature, and time. In all cases light isotopes are preferentially electroplated, following a mass-dependent law. Generally, the extent of fractionation is larger for higher temperatures and lower driving forces, and is roughly insensitive to amount of charge delivered. The maximum fractionations are δ^56/54Fe = −4.0‰ and δ^66/64Zn = −5.5‰, larger than observed fractionations in the natural environment and larger than those predicted due to changes in speciation. All the observed fractionation trends are interpreted in terms of three distinct processes that occur during an electrochemical reaction: mass transport to the electrode, chemical speciation changes adjacent to the electrode, and electron transfer at the electrode. We show that a large isotope effect adjacent the electrode surface arises from the charge-transfer kinetics, but this effect is attenuated in cases where diffusion of ions to the electrode surface becomes the rate-limiting step. Thus while a general increase in fractionation is observed with increasing temperature, this appears to be a result of thermally enhanced mass transport to the reacting interface rather than an isotope effect associated with the charge-transfer kinetics. This study demonstrates that laboratory experiments can successfully distinguish isotopic signatures arising from mass transport, chemical speciation, and electron transfer. Understanding how these processes fractionate metal isotopes under laboratory conditions is the first step towards discovering what role these processes play in fractionating metal isotopes in natural systems.  相似文献   

Urban greenspace from the inside out: An argument for the approach and a study with city workers     

Russell Hitchings 《Geoforum》2010,41(6):855-864

How might the fact that western people now spend so much of their time indoors impact upon techniques for studying urban greenspace experience? This paper takes this question as its starting point before substantiating one possible answer. It does so by using qualitative methods to examine the everyday practices of city professionals in London and what they tell us about the likelihood that this group will ever venture out into the various parks and gardens found around their offices. Many studies have considered which physical arrangements of city greenspace seem to deliver the greatest amounts of human benefit. Yet this kind of endeavour gives us only one part of the puzzle and contextual studies with those now generally found indoors have something important to add. It is with this in mind that the paper discusses how one sample of office workers quite easily forgot about these spaces, how certain social injunctions both pushed them outside and sealed them indoors, and why it sometimes made good sense for them to avoid any areas of local outdoor vegetation during the day. In so doing it highlights contextual dynamics that seem set to make significant impacts on the future of urban environmental experience and offers some novel suggestions about how best to promote positive greenspace relations in cities today.  相似文献   

The grain size distribution of matrix in primitive chondrites     

E. Vaccaro  P. Wozniakiewicz  I. A. Franchi  N. Starkey  S. S. Russell 《Meteoritics & planetary science》2023,58(5):688-704

The matrix of primitive chondrites is composed of submicron crystals embedded in amorphous silicates. These grains are thought to be the remains of relatively unprocessed dust from the inner regions of the protoplanetary disk. The matrix of primitive meteorites is often compared to chondritic porous interplanetary dust particles (CP-IDPs) which are believed to be of cometary origin, having accreted in the outermost regions of the solar nebula. Crystalline grains in CP-IDPs show evidence of a size–density relationship between the silicates and sulfides suggesting that these components experienced sorting prior to accretion. Here, we investigate whether such evidence of sorting is also present in the matrix constituents of primitive chondrites. We report findings from our study of grain size distributions of discrete silicate and opaque (sulfide and metal) grains within the matrix of the primitive meteorites Acfer 094 (C2-ung.), ALHA77307 (CO3), MIL 07687 (C3-ung.), and QUE 99177 (CR2). Mean radii of matrix silicate grains range from 103 nm in QUE 99177 to 2018 nm in MIL 07687. The opaque grains show a wider variation, with average radii ranging from 15 nm in QUE 99177 to 219 nm in MIL07687. Our results indicate that, in contrast to CP-IDPs, the size distribution of matrix components of these primitive meteorites cannot be explained by aerodynamic sorting that took place prior to accretion. We conclude that any evidence of sorting is likely to have been lost due to a greater variety and degree of processing experienced on these primitive chondrites than on cometary parent bodies.  相似文献   

Applications of situation-dependent intensity and intensity spread predictions based on a weighted analog technique     

Hsiao-Chung Tsai  Russell L. Elsberry 《Asia-Pacific Journal of Atmospheric Sciences》2014,50(4):507-518

A version of our situation-dependent intensity prediction (SDIP) is proposed for operational application after three modifications: (i) Ten historical track analogs are matched with Joint Typhoon Warning Center (JTWC) official track forecasts rather than besttracks; (ii) Giving two times as much weight to the 72 h — 120 h portion of the track as to the 0–72 h portion to give higher rankings for analog tracks with similar landfall or recurvature positions and timing; and (iii) Weighting both the intensity prediction technique and a new intensity spread guidance product according to new rankings of the track analogs rather than assuming all track analogs are equally likely. These special matchings and weightings of the track analogs in this weighted-analog intensity (WANI) add skill in the 72–120 h forecast intervals in regions where landfalls occur. Viability as an operational technique is demonstrated as the WANI has only 1 kt larger mean absolute errors than the JTWC intensity errors from 12 h through 72 h, and the WANI is 5 kt (20%) better at 120 h. The WANI rank-weighted intensity spreads each 12 h among the 10 best historical track analogs are processed to reduce any intensity bias and calibrated to reduce (increase) the over-determined (under-determined) intensity spreads at early (later) forecast intervals. Thus, the situation-dependent intensity spread guidance is generated that will include about 68% of the verifying intensities at all forecast intervals. Four examples of the WANI intensity predictions and intensity spread guidance are presented to illustrate how the forecaster might use this information in potential landfall and intensity bifurcation situations.  相似文献   

Terrain-influenced local wind forecasting for the Sasebo typhoon haven: Improved empirical techniques     

Joel W. Feldmeier  Wendell A. Nuss  Russell L. Elsberry 《Asia-Pacific Journal of Atmospheric Sciences》2014,50(4):459-468

Although the Sasebo, Japan harbor is usually a “typhoon haven” from tropical cyclone (TC) winds due to terrain-blocking effects, in rare cases damaging winds occur that may be attributed to terrain channeling. An empirical parametric model technique is developed and tested that includes consideration of the TC wind structure, land frictional effects, and terrain influences affecting the maximum wind speeds in the harbor when TCs pass within 200 nautical miles of Sasebo. The terrain influence is represented by two sets of wind direction-dependent acceleration factors. The first set, which is directly from the ratio of the local wind to the adjusted parametric wind for TCs passages during 2003–2010, provides mean values that represent the terrain blocking and channeling effects, but the variability with wind direction may be suspect. The second set derived from a large sample of reanalysis winds not limited to TCs has better variability properties, but is not easily related to just the TC passages. A new nomogram modified to include TC wind structure has higher estimates of Sasebo sustained winds for some TC tracks that may be related to terrain influences, but is limited due to the number of TC structure estimates in the developmental sample. These empirical models have the advantage of ease and low cost for future use in also estimating the combined uncertainty in the local winds in Sasebo harbor due to TCs.  相似文献   

Using distributed temperature sensing (DTS) technology in acid gas injection design     

Liaqat Ali  Russell E. Bentley  Alberto A. Gutierrez  Yosmar Gonzalez 《Acta Geotechnica》2014,9(1):135-144

The use of slickline distributed temperature sensing (SL-DTS) technology is becoming widespread due to its ease of operation and ability to acquire real-time multiple temperature traces inside the wellbore. Injection of treated acid gas (TAG)—a mixture of CO₂ and H₂S—into geologic formations has become an attractive technical and economic option for oil and gas producers and processors who are faced with regulations concerning excess sulfur and greenhouse gas emissions. Acid gas injection (AGI) into geologic formations is more economical and more flexible in dealing with varying TAG compositions than sulfur recovery units (SRUs) using the Claus process. SRUs do not achieve air quality standards and have high operation and maintenance costs. In addition, there is low demand for sulfur and sulfur disposal costs are high. The results of the analysis of SL-DTS data acquired in conjunction with step rate and pressure falloff (PFO) tests are presented in this paper. These tests were conducted to evaluate the injection potential of geologic formations. The injection zone consisted of a carbonate formation characterized by Karst features, vugs, and natural fractures. The SL-DTS data during the initial injection flow rate for the step rate test (SRT) indicated that high permeability zones accepted fluid at lower injection rates. An increasing number of discrete zones began to accept fluid as the injection rate was increased. The results of the SRT provided the fracture pressure of the formation. This information was used to design an AGI program that would avoid fracturing the formation while allowing for the required volume of TAG to be injected. The results of the PFO test provided information on the reservoir pressure and permeability and also indicated the presence of one or more hydraulic fractures. This case study of SL-DTS measurements made during a SRT and a PFO test for the design of an AGI well provides valuable insights into the potential of DTS technology and its use in AGI and carbon capture/sequestration (CCS) operations. Its findings could be applied to analyze injection potential of geological formations not only for AGI projects but also for CCS, and CO₂ enhanced oil recovery opportunities.  相似文献   

The 2dF galaxy redshift survey: clustering properties of radio galaxies     

Manuela Magliocchetti  Steve J. Maddox  Ed Hawkins  John A. Peacock  Joss Bland-Hawthorn  Terry Bridges  Russell Cannon  Shaun Cole  Matthew Colless  Chris Collins  Warrick Couch  Gavin Dalton  Roberto de Propris  Simon P. Driver  George Efstathiou  Richard S. Ellis  Carlos S. Frenk  Karl Glazebrook  Carole A. Jackson  Bryn Jones  Ofer Lahav  Ian Lewis  Stuart Lumsden  Peder Norberg  Bruce A. Peterson  Will Sutherland  Keith Taylor 《Monthly notices of the Royal Astronomical Society》2004,350(4):1485-1494

  相似文献   

New 1982 — 1990 photometry of λ Andromedae and its 11-year cycle     

Douglas S. Hall  Gregory W. Henry  Dietmar Böhme  Peter A. Brooks  Sandy Chang  Ales Dolzan  George L. Fortier  Robert E. Fried  Russell M. Genet  Bruce S. Grim  James Hannon  Darrel B. Hoff  Kevin Krisciunas  Howard J. Landis  Howard P. Louth  Larry P. Lovell  Paul Nielsen  Bobby E. Powell  Harry D. Powell  Don Pray  Thomas R. Renner  Charles W. Rogers  Stephen Shervais  Douglas M. Slauson  Samuel Slote  Harold J. Stelzer  Arthur J. Stokes  Jack C. Troeger  Louis C. Turner  Norman F. Wasson  Kenneth W. Zeigler 《Journal of Astrophysics and Astronomy》1991,12(4):281-287

We present photoelectric photometry of λ And never before published, obtained between February 1982 and December 1990 at 29 different observatories. Then we combine it with all other photometry available to us (previously published, contained in the I.A.U. Commission 27 Archives, and obtained with the Vanderbilt 16-inch automatic telescope but not yet published), to yield a 14.8-year data base. Analysis reveals a long-term cycle in mean brightness, with a full range of 0^m.15 and a period of 11.4 ± 0.4 years. Because most of our new photometry was concentrated in the 1983-84 observing season, we analyze that one well-defined light curve with a two-spot model. Spot A keeps a 0^m.04 amplitude throughout four rotation cycles whereas the amplitude of spot B diminishes from 0^m.09 down almost to 0^m.03. The spot rotation periods were 55^d.9 ± 0^d.6 and 520^d.8 ± 1^d.0, respectively.  相似文献   

Raman spectroscopic analysis of cyanobacterial colonization of hydromagnesite, a putative martian extremophile     

Howell G.M. Edwards  Caroline D. Moody  Susana E. Jorge Villar  Michael J. Russell 《Icarus》2005,175(2):372-381

Raman spectra of an extremophile cyanobacterial colony in hydromagnesite from Lake Salda in Turkey have revealed a biogeological modification which is manifest as aragonite in the stratum associated with the colony. The presence of key spectral biomarkers of organic protectant molecules such as β-carotene and scytonemin indicate that the survival strategy of the cyanobacteria is significantly one of UV-radiation protection. The terrestrial location of this extremophile is worthy of consideration further because of its possible putative link with the “White Rock” formations in Sabaea Terra and Juventae Chasma on Mars.  相似文献