Sorption behavior of the Pt(II) complex anion on manganese dioxide (δ-MnO2): a model reaction to elucidate the mechanism by which Pt is concentrated into a marine ferromanganese crust     

Mamiko Yamashita Maeno  Hironori Ohashi  Kotaro Yonezu  Akane Miyazaki  Yoshihiro Okaue  Koichiro Watanabe  Tamao Ishida  Makoto Tokunaga  Takushi Yokoyama 《Mineralium Deposita》2016,51(2):211-218

  相似文献   

Molecular and isotopic characteristics of gas hydrate-bound hydrocarbons in southern and central Lake Baikal   总被引：4，自引：4，他引：0  

Akihiro Hachikubo  Oleg Khlystov  Alexey Krylov  Hirotoshi Sakagami  Hirotsugu Minami  Yutaka Nunokawa  Satoshi Yamashita  Nobuo Takahashi  Hitoshi Shoji  Shin’ya Nishio  Masato Kida  Takao Ebinuma  Gennadiy Kalmychkov  Jeffrey Poort 《Geo-Marine Letters》2010,30(3-4):321-329

We investigated the molecular composition (methane, ethane, and propane) and stable isotope composition (methane and ethane) of hydrate-bound gas in sediments of Lake Baikal. Hydrate-bearing sediment cores were retrieved from eight gas seep sites, located in the southern and central Baikal basins. Empirical classification of the methane stable isotopes (δ¹³C and δD) for all the seep sites indicated the dominant microbial origin of methane via methyl-type fermentation; however, a mixture of thermogenic and microbial gases resulted in relatively high methane δ¹³C signatures at two sites where ethane δ¹³C indicated a typical thermogenic origin. At one of the sites in the southern Baikal basin, we found gas hydrates of enclathrated microbial ethane in which ¹³C and deuterium were both highly depleted (mean δ¹³C and δD of –61.6‰ V-PDB and –285.4‰ V-SMOW, respectively). To the best of our knowledge, this is the first report of C₂ δ¹³C–δD classification for hydrate-bound gas in either freshwater or marine environments.  相似文献   

SAINF: A toolbox for analyzing the effect of point-like,line-like and polygon-like infrastructural features on the distribution of point-like non-infrastructural features     

Atsuyuki?OkabeEmail author  Tohru?Yoshikawa 《Journal of Geographical Systems》2003,5(4):407-413

This paper introduces a GIS-based toolbox, called SAINF, for analyzing the effects of infrastructural features on the distribution of non-infrastructural features. One of the distinct characteristics of SAINF is that it can deal not only with point-like infrastructural features but also line-like (e.g. railways) and polygon-like (e.g. big parks) features. SAINF analyzes these effects with the conditional nearest neighbor distance method and the cross K-function method. First, the paper briefly refers to these methods. Second, the paper illustrates how to use SAINF with an actual example. SAINF can be downloaded via the Internet without charge for non-profit uses.We express our thanks to Exceed Co. Ltd. for helping us program SAINF, and to Miki Arimoto for making the data of high-class apartment buildings and parks in Kiba. This development was partly supported by Grant-in-aid for Scientific Research No. 10202201 (Spatial information science for human and social sciences) and No. 14350327 (Regional supporting network planning for the elderly) by the Ministry of Education, Culture, Sports, Science and Technology of Japan.  相似文献   

Statistical empirical index of chemical weathering in igneous rocks: A new tool for evaluating the degree of weathering   总被引：6，自引：0，他引：6  

Tohru Ohta  Hiroyoshi Arai 《Chemical Geology》2007,240(3-4):280-297

Chemical weathering indices are useful tools in characterizing weathering profiles and determining the extent of weathering. However, the predictive performance of the conventional indices is critically dependent on the composition of the unweathered parent rock. To overcome this limitation, the present paper introduces an alternative statistical empirical index of chemical weathering that is extracted by the principal component analysis (PCA) of a large dataset derived from unweathered igneous rocks and their weathering profiles. The PCA analysis yields two principal components (PC1 and PC2), which capture 39.23% and 35.17% of total variability, respectively. The extent of weathering is reflected by variation along PC1, primarily due to the loss of Na₂O and CaO during weathering. In contrast, PC2 is the direction along which the projections of unweathered felsic, intermediate and mafic igneous rocks appear to be best discriminated; therefore, PC1 and PC2 represent independent latent variables that correspond to the extent of weathering and the chemistry of the unweathered parent rock. Subsequently, PC1 and PC2 were then mapped onto a ternary diagram (MFW diagram). The M and F vertices characterize mafic and felsic rock source, respectively, while the W vertex identifies the degree of weathering of these sources, independent of the chemistry of the unweathered parent rock.

The W index has a number of significant properties that are not found in conventional weathering indices. First, the W index is sensitive to chemical changes that occur during weathering because it is based on eight major oxides, whereas most conventional indices are defined by between two and four oxides. Second, the W index provides robust results even for highly weathered sesquioxide-rich samples. Third, the W index is applicable to a wide range of felsic, intermediate and mafic igneous rock types. Finally, the MFW diagram is expected to facilitate provenance analysis of sedimentary rocks by identifying their weathering trends and thereby enabling a backward estimate of the composition of the unweathered source rock.  相似文献   

Simulation of seismicity due to fluid migration in a fault zone   总被引：5，自引：0，他引：5  

Teruo Yamashita 《Geophysical Journal International》1998,132(3):674-686

Spatio-temporal variation of rupture activity is modelled assuming fluid migration in a narrow, porous fault zone formed along a vertical strike-slip fault in a semi-infinite elastic medium. The principle of the effective stress coupled to the Coulomb failure criterion introduces mechanical coupling between fault slip and the pore fluid. The fluid is assumed to flow out of a localized high-pressure fluid compartment in the fault at the onset of earthquake rupture. The duration of the earthquake sequence is assumed to be much shorter than the recurrence period of characteristic events on the fault. Both an earthquake swarm and a foreshock–main-shock sequence can be simulated by changing the relative magnitudes of the initial tectonic stress, pore fluid pressure, fracture strength and so on. When an inhomogeneity is introduced into the spatial distribution of fracture strength, high complexity is observed in the spatio-temporal variation of rupture activity. For example, the time interval between two successive events is highly irregular, and a relatively long quiescence of activity is sometimes observed in a foreshock–main-shock sequence. The quiescence is caused by the temporary arresting of rupture extension, due to an encounter with fault segments having locally high strengths. The frequency–magnitude statistics of intermediate-size events obey the Gutenberg–Richter relation. The calculations show the temporal variation of the b value during some foreshock sequences, and the degree of the change seems to depend on the statistical distribution of the fracture strength.  相似文献   

Fast Oxidation Reaction of Nitrite by Dissolved Oxygen in the Freezing Process in the Tropospheric Aqueous Phase     

Norimichi Takenaka  Tohru Daimon  Akihiro Ueda  Keiichi Sato  Masaru Kitano  Hiroshi Bandow  Yasuaki Maeda 《Journal of Atmospheric Chemistry》1998,29(2):135-150

Nitrite oxidation in the tropospheric aqueous phase by freezing was evaluated by freezing a field sample. Nitrite oxidation by dissolved oxygen in the freezing process is much faster than by other oxidation processes, such as reactions with ozone, hydrogen peroxide or dissolved oxygen in an aqueous solution at pHs 3 to –6. At pH 4.5 and 25°C, the lifetime of nitrite in the aqueous phase is ca. 1 hr in oxidation by ozone (6×10^-10 mol dm^-3), ca. 10 hr in oxidation by H₂O₂ (2×10^-4 mol dm^-3), and 7.5 hr (Fischer and Warneck, 1996) in photodissociation at midday in summer. Under the same conditions at a temperature below 0°C, the lifetime of nitrite in the freezing process is estimated as ca. 2 sec when the droplets are frozen within a second. The reaction by freezing is affected by the presence of salts, such as NaCl or KCl, or orgnaic compounds, such as methanol or acetone. The results of freezing a field rain or fog sample showed that nitrite oxidation proceeds below pH 6, and the conversion ratio of nitrate from nitrite increases with decreasing pH. The oxidation of nitrite by freezing was also observed in freezing fog particles generated by an ultrasonic humidifier. The ratios of the concentrations of ions in the winter sample to those in the summer sample (or those in the fog sample) were almost the same values. However, the concentration of nitrite in the winter sample was lower than that estimated by the ratios of other ions. From the present study, it seems that the freezing process plays an important role in the nitrite sink process in the tropospheric aqueous phase.  相似文献   

Seismological significance of the 1977–1978 eruptions and the magma intrusion process of usu volcano, Hokkaido     

Hm. Okada  H. Watanabe  H. Yamashita  I. Yokoyama 《Journal of Volcanology and Geothermal Research》1981,9(4):311-334

An earthquake swarm, and the major pumice eruptions in August 1977 which followed, marked the start of the dacitic doming activity of Usu volcano in southwestern Hokkaido, Japan. The sequence of magma intrusion processes was investigated in detail by means of seismological and other geophysical data. The distribution of the abundant hypocenters shows clearly an earthquake-free zone beneath the summit crater. The hypocenters migrated in a manner consistent with the development of the observed asymmetrical surface deformations, considered due to magma intrusion into this earthquake-free zone. The earthquake mechanism solutions are mostly of dip-slip type and are interpreted in terms of the doming deformations. The existence of earthquake families (earthquakes with similar waveforms) is the main cause of the peculiar occurrence of earthquakes in space, time and magnitude. The concept of scattered barriers of different sizes and strengths can explain well the distinct characteristics of the occurrence of the swarm, and the observed episodic deformations.  相似文献   

Extension of a polar ionospheric current to the nightside equator     

Tohru Araki  Joe H. Allen  Yuriko Araki 《Planetary and Space Science》1985,33(1):11-16

A detailed analysis of rapid-run magnetograms from Guam (geomagnetic latitude = 4.2°) revealed that there are two kinds of geomagnetic sudden commencement (SC) observed in nighttime. One is the ordinary SC consisting of a main impulse only which has a smooth rise of the H-component. The other is a superposition by a small positive impulse on the very beginning part of the smooth rise of the main impulse and consequently the SC starts with a small stepwise increase of the H-component. The latter type of SC occurs between 20 and 08 h L.T. and its occurrence rate takes the maximum value of about 50% around 03 h L.T. Corresponding magnetograms from a dayside equatorial station (Huancayo, geomagnetic latitude = ?0.7°) were examined and a good correlation was found between the stepwise SC at the nightside (Guam) and SC¹ with a preliminary reverse impulse (PRI) at the dayside (Huancayo). Since PRI observed at the dayside equator may be interpreted as an extension of an ionospheric current due to an dusk-to-dawn electric field impressed on the polar ionosphere, our results show that a polar originating ionospheric current can extend to the nightside equator and produce a small but observable magnetic effect in spite of much reduced nighttime ionospheric conductivity.  相似文献   

Floating plastic in the Kuroshio Current area, western North Pacific Ocean   总被引：1，自引：0，他引：1  

Yamashita R  Tanimura A 《Marine pollution bulletin》2007,54(4):485-488

  相似文献   

Speciation of reduced C-O-H volatiles in coexisting fluids and silicate melts determined in-situ to ∼1.4 GPa and 800 °C     

Bjorn O. Mysen  Shigeru Yamashita 《Geochimica et cosmochimica acta》2010,74(15):4577-155

The structure of silicate melts in the system Na₂O·4SiO₂ saturated with reduced C-O-H volatile components and of coexisting silicate-saturated C-O-H solutions has been determined in a hydrothermal diamond anvil cell (HDAC) by using confocal microRaman and FTIR spectroscopy as structural probes. The experiments were conducted in-situ with the melt and fluid at high temperature (up to 800 °C) and pressure (up to 1435 MPa). Redox conditions in the HDAC were controlled with the reaction, Mo + H₂O = MoO₂ + H₂, which is slightly more reducing than the Fe + H₂O = FeO + H₂ buffer at 800 °C and less.The dominant species in the fluid are CH₄ + H₂O together with minor amounts of molecular H₂ and an undersaturated hydrocarbon species. In coexisting melt, CH₃ - groups linked to the silicate melt structure via Si-O-CH₃ bonding may dominate and possibly coexists with molecular CH₄. The abundance ratio of CH₃ - groups in melts relative to CH₄ in fluids increases from 0.01 to 0.07 between 500 and 800 °C. Carbon-bearing species in melts were not detected at temperatures and pressures below 400 °C and 730 MPa, respectively. A schematic solution mechanism is, Si-O-Si + CH₄?Si-O-CH₃+H-O-Si. This mechanism causes depolymerization of silicate melts. Solution of reduced (C-O-H) components will, therefore, affect melt properties in a manner resembling dissolved H₂O.  相似文献