Microbial activity and chemical weathering in the Middendorf aquifer,South Carolina     

Jungho Park  Robert A. Sanford  Craig M. Bethke 《Chemical Geology》2009,258(3-4):232-241

We use reactive transport modeling to better understand the kinetics of chemical weathering in the Cretaceous Middendorf aquifer of South Carolina, USA, and the relationship of this process to subsurface microbial activity. We constructed a model accounting for the kinetics of mineral dissolution and precipitation, ion exchange, and the CO₂ and bicarbonate produced by iron reducing and sulfate reducing bacteria in the aquifer. We then fit the model to observed trends in the chemical composition of groundwater along the aquifer by adjusting the rate constants for the kinetic reactions considered. The modeling portrays weathering in the Middendorf as a slow process by which groundwater gradually reacts toward equilibrium with minerals in the aquifer. The rate constants predicted are 6 to 7 orders of magnitude smaller than measured in laboratory experiments and 3 to 4 orders of magnitude less than those inferred from weathering rates in soils. The rate constants are smaller even than expected by projecting observed trends with the duration of weathering to the geologic age of the Middendorf. Weathering is driven largely by biological activity: about half the acid consumed is CO₂ derived from the recharge area, and about half is supplied by iron reducing bacteria in the aquifer; only about 1% of the acid is of atmospheric origin, from CO₂ dissolved in rainwater.  相似文献   

Diana Rosemary Howlett, 1934–2018     

R. Gerard Ward 《The Australian geographer》2020,51(1):131-132

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Correction to: Projection of Iron Ore Production     

Mohr  Steve  Giurco  Damien  Yellishetty  Mohan  Ward  James  Mudd  Gavin 《Natural Resources Research》2020,29(1):561-561

Natural Resources Research - The original version of this article unfortunately contained an error in Equation 3.  相似文献   

Financialization and urban politics: expanding the optic   总被引：1，自引：1，他引：0  

Kevin Ward 《Urban geography》2017,38(1):1-4

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Late Pleistocene talus flatiron formation below the Coal Cliffs cuesta,Utah, USA          下载免费PDF全文

Christopher E. Sheehan  Dylan J. Ward 《地球表面变化过程与地形》2018,43(9):1973-1992

Cuesta escarpment retreat is a principal mode of exhumation in regions of layered sedimentary rock. On the Colorado Plateau, this process acts as a mechanism for maintaining high‐relief topography and facilitating drainage divide migration. Quantitative estimates of cuesta evolution are difficult to evaluate over glacial‐interglacial timescales, and thus rates of geomorphic change along individual escarpments have mostly been constrained over millions of years. Several studies have addressed this problem by dating colluvium‐mantled talus flatirons. However, this technique has not been applied systematically on the Colorado Plateau. This study quantifies geomorphic change along a single Colorado Plateau cuesta using ³⁶Cl surface exposure dating. We present 33 ages from a single generation of talus flatirons below the Coal Cliffs of central Utah. Landscape evolution is further constrained using 14 ages from in‐situ bedrock, 3 ages from boulders on gully interfluves, and two ages from terrace alluvium. Results suggest a colluvial apron was deposited below the cuesta beginning as early as Marine Isotope Stage 3, and the latest depositional phase occurred near the Last Glacial Maximum. A switch from apron deposition to incision initiated flatiron formation sometime between 19.7 ± 2.5 and 11.8 ± 1.6 ka, broadly coincident with the transition from glacial to interglacial conditions. Our results have several important implications. Climatic changes during the end of the last glacial period appear to have shifted the balance between deposition and erosion below the Coal Cliffs, emptying the sediment reservoir at their base and increasing their height via bedrock incision. The climatic forcing could be imparted by several mechanisms, including local controls on debris generation / mobilization and base level changes exerted by transverse streams. Similar processes may have occurred during previous glacial‐interglacial transitions, implying that the escarpment retreat processes may be partially modulated by orbitally‐controlled variations in Earth's climate over larger timescales. Copyright © 2018 John Wiley & Sons, Ltd.  相似文献   

The impact of submersed aquatic vegetation on the development of river mouth bars     

Sara Lera  William Nardin  Lawrence Sanford  Cindy Palinkas  Roberto Guercio 《地球表面变化过程与地形》2019,44(7):1494-1506

This work is inspired by the sudden resurgence of the submersed aquatic vegetation (SAV) bed in the Chesapeake Bay (USA). Because the SAV bed occurs at the mouth of the Bay's main tributary (Susquehanna River), it plays a significant role in modulating sediment and nutrient inputs from the Susquehanna to the Bay. Previous model studies on the impact of submersed aquatic vegetation on the development of river mouth bars lacked a complete mechanistic understanding. This study takes advantage of new advances in 3D computational models that include explicit physical-sedimentological feedbacks to obtain this understanding. Specifically, we used Delft3D, a state-of-the-art hydrodynamic model that provides fine-scale computations of three-dimensional flow velocity and bed shear stress, which can be linked to sediment deposition and erosion. Vegetation is modeled using a parameterization of hydraulic roughness that depends on vegetation height, stem density, diameter, and drag coefficient. We evaluate the hydrodynamics, bed shear stresses, and sediment dynamics for different vegetation scenarios under conditions of low and high river discharge. Model runs vary the vegetation height, density, river discharge, and suspended-sediment concentration. Numerical results from the idealized model show that dense SAV on river mouth bars substantially diverts river discharge into adjacent channels and promotes sediment deposition at ridge margins, as well as upstream bar migration. Increasing vegetation height and density forms sandier bars closer to the river mouth and alteration of the bar shape. Thus, this study highlights the important role of SAV in shaping estuarine geomorphology, which is especially relevant for coastal management. © 2019 John Wiley & Sons, Ltd.  相似文献   

Surface melt-driven seasonal behaviour (englacial and subglacial) from a soft-bedded temperate glacier recorded by in situ wireless probes     

Jane K. Hart  Kirk Martinez  Philip J. Basford  Alexander I. Clayton  Graeme M. Bragg  Tyler Ward  David S. Young 《地球表面变化过程与地形》2019,44(9):1769-1782

We investigate the spatial and temporal englacial and subglacial processes associated with a temperate glacier resting on a deformable bed using the unique Glacsweb wireless in situ probes (embedded in the ice and the till) combined with other techniques [including ground penetrating radar (GPR) and borehole analysis]. During the melt season (spring, summer and autumn), high surface melt leads to high water pressures in the englacial and subglacial environment. Winter is characterized by no surface melting on most days (‘base’) apart from a series of positive degree days. Once winter begins, a diurnal water pressure cycle is established in the ice and at the ice/sediment interface, with direct meltwater inputs from the positive degree days and a secondary slower englacial pathway with a five day lag. This direct surface melt also drives water pressure changes in the till. Till deformation occurred throughout the year, with the winter rate approximately 60% that of the melt season. We were able to show the bed comprised patches of till with different strengths, and were able to estimate their size, relative percentage and temporal stability. We show that the melt season is characterized by a high pressure distributed system, and winter by a low pressure channelized system. We contrast this with studies from Greenland (overlying rigid bedrock), where the opposite was found. We argue our results are typical of soft bedded glaciers with low englacial water content, and suggest this type of glacier can rapidly respond to surface-driven melt. Based on theoretical and field results we suggest that the subglacial hydrology comprises a melt season distributed system dominated by wide anastomosing broad flat channels and thin water sheets, which may become more channelized in winter, and more responsive to changes in meltwater inputs. © 2019 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.  相似文献   

Tides, sea-level rise and tidal power extraction on the European shelf     

Sophie L. Ward  J. A. Mattias Green  Holly E. Pelling 《Ocean Dynamics》2012,62(8):1153-1167

An established numerical tidal model has been used to investigate the impact of various sea-level rise (SLR) scenarios, as well as SLR in combination with large-scale tidal power plants on European shelf tidal dynamics. Even moderate and realistic levels of future SLR are shown to have significant impacts on the tidal dynamics of the area. These changes are further enhanced when SLR and tidal power plants are considered in combination, resulting in changes to tidal amplitudes, currents and associated tidal dissipation and bed shear stresses. Sea-level rise is the dominant influence on any far-field impacts, whereas tidal power plants are shown to have the prevailing influence over any changes close to the point of energy extraction. The spatial extent of the impacts of energy extraction is shown to be affected by the sea level when more than one tidal power plant in the Irish Sea was considered. Different ways to implement SLR in the model are also discussed and shown to be of great significance for the response of the tides.  相似文献   

Evaluating the use of 3'-(p-Aminophenyl) fluorescein for determining the formation of highly reactive oxygen species in particle suspensions     

Corey A Cohn  Christopher E Pedigo  Shavonne N Hylton  Sanford R Simon  Martin AA Schoonen 《Geochemical transactions》2009,10(1):8-9

Background  

Given the importance of highly reactive oxygen species (hROS) as reactants in a wide range of biological, photochemical, and environmental systems there is an interest in detection and quantification of these species. The extreme reactivity of the hROS, which includes hydroxyl radicals, presents an analytical challenge. 3'-(p-Aminophenyl) fluorescein (APF) is a relatively new probe used for measuring hROS. Here, we further evaluate the use of APF as a method for the detection of hydroxyl radicals in particle suspensions.  相似文献   

Fine particulate organic matter transport dynamics in a small Coastal Plain stream: influence of hydrology and channel morphology     

Hwaseong Jin  G. M. Ward 《Aquatic Sciences - Research Across Boundaries》2013,75(4):483-492

Fine particulate organic matter (FPOM) represents a major component of stream organic matter budgets, and its dynamics greatly affect the productivity and metabolism of a stream community. FPOM transport dynamics has been well documented in high-gradient streams with rocky substrates, but information from low-gradient, sandy-bottom streams has been lacking. We estimated FPOM retention patterns in Payne Creek, a 2nd order Coastal Plain stream (USA), under naturally varying hydraulic conditions (discharge and velocity). Corn pollen, as an FPOM analogue, was released along with a conservative solute tracer and the particle retention coefficient (k _p) was calculated by fitting the ratio of total pollen remaining in the water column against the longitudinal transport distance to an exponential decay model. Pollen k _p (n = 4) ranged from 0.034 to 0.214 /m, and particle transport distance (S _p) ranged from 4.7 to 29.7 m. The S _p measured in Payne Creek was in the lowest range of previously reported values, and such rapid particle retention was attributed to the low channel slope and slow current velocity. S _p was significantly correlated to water velocity and the channel friction factor, but not to discharge (Q). Two summer experiments conducted in contiguous stream segments resulted in the shortest (4.7 m) and longest (29.7 m) S _p, despite the similar Q. This was attributed to the segment-scale channel alterations that occurred during the previous winter, which led to very different hydraulic conditions in the two stream segments. In Payne Creek, seasonal changes in hydrology and segment-scale variation in channel morphology were the main factors controlling FPOM transport and retention.  相似文献