淋洗剂乙二胺四乙酸对重金属污染土工程特性的影响   总被引：1，自引：0，他引：1  

王平  李江山  薛强 《岩土力学》2014,35(4):1033-1040

以重金属铅（Pb2+）污染土和淋洗剂乙二胺四乙酸（EDTA）为研究对象,通过批次试验研究了不同浓度EDTA的淋洗对Pb2+污染土的渗透特性、持水特性、压缩特性、抗剪强度等工程特性的影响,为淋洗修复后土壤的二次利用提供参数支持。基于矿物成分、孔隙结构等微观试验,揭示了土壤工程特性变化的内在机制。研究结果表明,当淋洗剂EDTA浓度从0增加到0.15 mol/L,经淋洗修复后的污染土壤pH值从7.94下降到5.12,渗透系数降低超过一个数量级,黏聚力降低50%以上,而内摩擦角增大,持水性能提高,孔隙比从0.81下降到了0.76。微观试验的结果表明,随着淋洗剂浓度的增大,土壤中的蒙脱石、钠长石和伊利石矿物含量减少,石英矿物含量增加,其中蒙脱石含量从7.87%下降到了0.07%,而石英矿物含量增加了11.09%;淋洗后土壤单位质量进汞量由0.22 ml/g降低到0.15 ml/g,土壤总孔隙体积减少。重金属污染土淋洗修复工程在考虑重金属去除率及经济性指标的同时,还应考虑淋洗剂对土壤工程特性的弱化。  相似文献   

基于数字钻进技术和量子遗传-径向基函数神经网络的围岩类别超前识别技术研究     

邱道宏  李术才  薛翊国  田昊  闫茂旺 《岩土力学》2014,35(7):2013-2018

围岩类别超前分类是隧道施工过程中必须开展的一项工作,其直接关系到后续的开挖及施工支护方案。为有效地进行隧道围岩类别超前分类,提出了基于数字钻进技术和量子遗传（QGA）-径向基函数（RBF）神经网络的围岩类别超前分类方法。以数字钻进技术为基础,从钻进参数中提取有用信息,构建围岩类别超前分类指标体系。采用量子计算原理对遗传算法进行改进,通过量子位编码和量子旋转门更新种群,以此来确定RBF神经网络的参数,建立了基于QGA-RBF神经网络的围岩类别超前识别系统。最后将该方法应用于青岛胶州湾海底隧道的围岩类别超前识别中,结果表明,该方法具有较高的准确性,其结果为围岩类别超前分类提供了一种新思路。  相似文献   

崩积混合体直剪试验与PFC2D数值模拟分析     

薛亚东  刘忠强  吴坚 《岩土力学》2014,35(Z2):587-592

通过野外崩积混合体结构特征分析,考虑原样级配,开展对崩积混合体重塑样的室内大尺度直剪试验研究,结合PFC2D颗粒离散元仿真试验,分析了不同含石量情况下崩积混合体变形与强度变化规律及内在机理。将数值试验的成果与室内试验结果进行对比分析。结果表明,随着含石量的增加,崩积混合体的应变硬化效应显著。低法向应力下崩积混合体表现为剪胀,高法向应力下则表现为剪缩;当含石量低于40%时,崩积混合体的力学性质由土体控制,超过80%以后,其力学性质基本上完全由块石控制。  相似文献   

入射频率对煤系薄互层地震响应特征影响的物理模拟     

薛诗桂  郝守玲 《煤田地质与勘探》2014,42(5):92-95

建立薄互层地震物理模型,分别从低频和高频入射时地震记录的振幅谱形态、振幅、频率特征、AVO特征等方面入手,分析了入射频率对煤系薄互层模型地震响应特征的影响。结果表明:入射频率对薄互层层数变化反映敏感,高频入射时振幅谱形态可分辨的厚度比较小,分辨率较高;振幅谱幅值以及主频值的变化与薄互层的总厚度和波长之比有关,并且随着厚度的增加其变化规律符合薄层的振幅调谐规律与频率调谐规律;入射频率不同时,AVO曲线特征也不相同,在进行薄互层资料的对比解释及AVO分析时,要充分考虑入射频率所引起的差异。   相似文献   

新疆阿吾拉勒西段流纹岩及其对该区岩石圈深部过程的约束     

丁振信  薛春纪  赵晓波  闫永红  亚夏尔·亚力坤  冯博  罗晖  俎波  张祺  代志杰 《地学前缘》2014,21(5):196-210

西天山二叠纪的岩石圈深部过程是备受关注的地球动力学问题,新疆阿吾拉勒西段下二叠统流纹岩提供了理解这个问题的良好机会。阿吾拉勒西段流纹岩发育流纹构造、斑状结构,斑晶主要为条纹长石、斜长石和石英,长英质基质呈雏晶微晶结构。岩石为富硅(66.97%~79.00%)、高钾(2.86%~11.07%)钙碱性、准铝质(A/CNK=0.91~0.99)岩浆系列。流纹岩富集U、Th和K等元素,明显亏损Nb、Ta、Eu、P等元素,显示εNd(t)正值(4.7~5.1)和低的初始锶比值((87Sr/86Sr)i=0.705 1~ 0.705 6),锆石饱和温度为818~909 ℃,幔源物质明显。与高分异I型花岗岩地球化学性质相似,岩浆可能起源于壳幔边界早石炭世新生下地壳的部分熔融。流纹岩锆石U Pb法测年获得(290.9±3.3) Ma和(296.3±3.1) Ma的早二叠世成岩年龄,岩浆的起源可能与北天山洋关闭之后洋壳岩石圈板块尾部断离导致软流圈物质和能量上涌并引起新生下地壳底部重熔等深部过程有关。  相似文献   

珠三角外向型制造业非正规部门的形成发展机制——以广州市狮岭镇皮具产业为例   总被引：2，自引：0，他引：2  

薛德升  林韬  黄耿志 《地理研究》2014,33(4):698-709

作为世界城市化发展中的普遍现象,非正规部门的形成发展一直是研究重点。以广州狮岭皮具产业为例,以非正规工厂和临时工为对象,研究了外向型制造业中非正规部门的形成发展机制。研究认为：正规企业为满足产品生产和降低成本的需求而采取的生产分包模式是非正规部门形成的根本因素;正规企业劳动保障的缺失与工人对自由轻松的工作方式的追求促使工人转入非正规工厂和临时工市场,推动了非正规部门的发展;当地宽松的管制环境为非正规部门的存在提供了可能。全球金融危机在短期内对非正规部门的发展起到了催化作用。研究支持了新马克思主义理论,认为正规部门和非正规部门是相互联系的关系,是产业经济发展中有利的组成要素。非正规部门不是劳动者进入正规部门的“跳板”,而是他们逃避正规经济过度剥削的“避难所”。最后讨论了有关非正规部门和非正规劳动者的政策启示。  相似文献   

历史时期全球化作用下的城市空间转变——以1890s~1930s广州东山地区为例     

薛德升  黄鹤绵  王阳 《地理科学》2014,34(6):687-695

世界城市历史研究作为新兴的研究领域,虽然突破了世界城市经典理论的“现代主义”视角,证明全球化对城市空间转变的作用具有长期性,但仍局限在“经济主义”的分析范畴之内,将经济因素视为决定性动力。20世纪初期,广州东山地区完成由“乡村地区”向“社会精英阶层居住地”的空间转变,促使城市空间格局由“东村西富”变为“东贵西富”。这场具有历史意义的空间转变是教会、华侨、政府、官僚4种动力相互作用、相继推动的结果。东山地区的发展历史表明,除经济联系外,城市的全球文化联系对空间转变同样具有重要推动作用。在一些特定的城市或城市中的特定地区,社会文化动力对城市空间转变具有决定性的作用。  相似文献   

实验室条件下微生物降解原油的地球化学特征研究   总被引：13，自引：2，他引：11  

窦启龙  陈践发  薛燕芬  王杰  段文标  郭建军 《沉积学报》2005,23(3):542-547

通过对胜利油田四个正常原油样品微生物作用前后的族组分及饱和烃色谱质谱分析,发现实验室条件下微生物对原油有明显的降解作用。微生物作用以后的原油族组分其饱和烃相对含量降低,饱/芳比也明显降低,而芳烃、非烃和沥青质的相对含量都不同程度的升高。通过饱和烃色谱-质谱分析,发现微生物作用以后原油正构烷烃被严重降解,姥/植(Pr/Ph)比值和∑C_21-/∑C₂₂₊比值都明显降低。微生物作用原油后能产生表面活性剂,造成了培养基表面张力的降低。  相似文献   

Late Paleozoic Fluid Systems and Their Ore-forming Effects in the Yuebei Basin, Northern Guangdong, China   总被引：1，自引：0，他引：1  

DENG Jun  YANG Liqiang  SUN Zhongshi  WANG Jianping  WANG Qingfei  CHENG Xueming  ZHOU Yinghua State Key Laboratory of Geological Processes  Mineral Resources  China University of Geosciences  Beijing  Key Laboratory of Lithosphere Tectonics  Lithoprobing Technology of the Ministry of Education  China University of Geosciences  Beijing School of Earth Sciences  Jilin University  Chuangchun  Jilin 《《地质学报》英文版》2005,79(5):673-687

Based on detailed and systematic researches of the geology of ore deposits, fluid inclusions and isotope geochemistry etc., and regarding the Late Paleozoic fluid system of the Yuebei Basin as an integrated object in this paper, we have revealed the temporo-spatial evolution law of the basin＇s fluid system and discussed its ore-forming effects by simulating and analyzing the distribution of ore-forming elements, the fluid thermodynamics and dynamics of evolution processes of this basin. The results show that Late Paleozoic ore-forming fluid systems of the Yuebei Basin include four basic types as follows. （1） The sea floor volcanic-exhalation system developed during the rapid basin slip-extension stage in the Mid-Late Devonian, which affected the Dabaoshan region. It thus formed the Dabaoshan-type Cu-Pb-Zn-Fe sea floor volcanic-exhalation sedimentary deposits. （2） The compaction fluid system developed during the stable spreading and thermal subsidence-compression stage of the basin in the Mid-Late Devonian. The range of its effects extended all over the whole basin. It resulted in filling-metasomatic deposits, such as the Hongyan-type pyrite deposits and pyrite sheet within the Fankou-type Cu-Pb-Zn-S deposits. （3） The hot water circulation system of sea floor developed during the stage of basin uplifting and micro-aulacogen from the late Late Carboniferous to Middle Carboniferous. The range of its effects covered the Fankou region. It thus formed MVT deposits, such as the main orebody of the Fankou-type Pb-Zn-S deposits. （4） The gravity fluid system developed during the stage of fold uplifting and the basin closed from Middle Triassic to Jurassic, forming groundwater hydrothermal deposits, e.g. the veinlet Pb-Zn-calcite orebodies of the Fankou-type Pb-Zn- S deposits. Migration and concentration of the ore-forming fluids were constrained by the state of temporo-spatial distribution of its fluid potential. Growth faults not only converged the fluids and drove them to move upwards, but also the fluids often crossed the faults to the edges of the basin at the bottom of these faults and the lithologic interfaces, and even migrated to the basin＇s edges from top to bottom along the faults, which may be one of the basic reasons for the stratabound deposits to cluster mainly along the contemporaneous faults on the inner border of the basin. The superposed mineralization resulting from the multi-stage activity of contemporaneous faults and ore-forming fluid systems in the basin may be one of the key factors for forming superlarge ore deposits.  相似文献   

The Yanshanian Orogeny and Two Kinds of Yanshanides in Eastern-Central China   总被引：11，自引：0，他引：11  

WU Genyao Institute of Geology  Geophysics  Chinese Academy of Sciences  Beijing E-mail: dzkx@mail.igcas.ac.cn 《《地质学报》英文版》2005,79(4):507-518

The Tan-Lu Fault was once a transform fault in the Paleotethys, west of which was the Qinling-Dabie Ocean separating the Yangtze Craton from the North China Craton, and east of which was the Su-Lu Ocean separating the Su-Wan Block from the Jiao-Liao Craton. The Qinling-Dabie Ocean closed in the Indosinian orogeny, which created the China-Southeast Asia Subcontinent, with the Tan-Lu Fault becoming a marginal shear zone along the newly-formed amalgamated subcontinent. The Su-Lu Ocean subducted partly in the Indosinian.orogeny, but not closed. In the Jurassic and Early Cretaceous, the Su-Wan Block drifted northwards with subduction of the Su-Lu Ocean and moved westwards to converge the subcontinent by sinistral sheafing of the ENE-striking fractures. The Su-Lu Ocean finally closed and the Su-Wan Block collided with the Jiao-Liao Craton in the Early Cretaceous, which constituted a part of the magnificent interplate Yanshanides. The interplate orogeny rejuvenated the fossil sutures and deep fractures, as well as the Indosinian orogen, and the intraplate （intracontinental） Yanshanian orogeny occurred in the subcontinent. The East Asia Yanshanides, consisting of the interplate orogens in the outer side and the intraplate orogens in the inner side, collapsed quickly in the latest Early Cretaceous and Late Cretaceous. The eastern China area entered a tensile period from the Eogene, and the tectonic differentiation between the central and eastern China areas since the Jurassic was further strengthened.  相似文献