Partition of arsenic in soils sediments and the origin of naturally elevated concentrations in groundwater of the southern pampa region (Argentina)     

María del Carmen Blanco  Juan Darío Paoloni  Hector Morrás  Carmen Fiorentino  Mario Eduardo Sequeira  Nilda N. Amiotti  Oscar Bravo  Silvana Diaz  Martín Espósito 《Environmental Earth Sciences》2012,66(7):2075-2084

Excessive arsenic concentrations above the Argentinean and WHO guidelines for drinking water (10 μg L⁻¹) affects shallow aquifers of the southern Pampean Plain (Argentina) hosted in the Pampean and the Post Pampean formations (loess and reworked loess; Plio-Pleistocene–Holocene). Health problems related to high As concentrations in drinking waters are known as Endemic Regional Chronic Hydroarsenicism. Hydrochemistry of shallow groundwaters and soil geochemistry were investigated aiming to (1) understand the partition of As in the solid phase and its relationship with unacceptable As concentrations in waters, (2) identify the provision source of As to groundwaters. Only 5% of the samples had As concentrations <10 μg L⁻¹; in 27% As concentrations ranged from 10 to 50 μg L⁻¹ and in 58% it reached 60–500 μg L⁻¹. The coarse fraction (50–2,000 μm) hosts about 27% of the total As in the solid phase, being positively correlated to Ba (p < 0.01; r ² = 0.93). About 70% is included in the <2 μm fraction and had positive correlations of As–Fe (p < 0.05; r ² = 0.85) and As–Cr (p < 0.05; r ² = 0.68). Soils and sediment sand fractions of vadose zones are the primary sources of As in shallow groundwater while adsorption–desorption processes, codisolution–coprecipitation, and evaporation during the dry seasons raise As concentrations in waters exceeding the guideline value for drinking water.  相似文献   

Climate variability and change in the drylands of Western North America     

M.K. Hughes  H.F. Diaz   《Global and Planetary Change》2008,64(3-4):111

We argue that it is important to expand the consideration of climate in the context of provision of ecosystem services in drylands. In addition to climate change, it is necessary to include climate variability on timescales relevant to human and ecological considerations, namely interannual to decadal and multidecadal. The period of global instrumental record (about a century and a half long at the very most) is neither an adequate nor an unbiased sample of the range and character of natural climate variability that might be expected with the climate system configured as it is now. We base this on evidence from W. N. America, where there has recently been a major multi-year drought, of a scale and intensity that has occurred several times in the last 2000 years, and on attempts to provide explanations of these phenomena based on physical climatology. Ensembles of runs of forced climate system models suggest the next 50 years will bring much more extensive and intense drought in the continental interior of North America. The trajectory followed by the supply of ecosystem services will be contingent not only on the genotypes available and the antecedent soil, economic and social conditions but also on climate variability and change. The critical features of climate on which patterns of plant growth and water supply depend may vary sharply during and between human generations, resulting in very different experiences and hence, expectations.  相似文献   

Size and elemental distributions of nano- to micro-particulates in the geochemically-stratified Great Salt Lake     

Ximena Diaz  William P. Johnson  Diego Fernandez  David L. Naftz   《Applied Geochemistry》2009,24(9):1653-1665

The characterization of trace elements in terms of their apportionment among dissolved, macromolecular, nano- and micro-particulate phases in the water column of the Great Salt Lake carries implications for the potential entry of toxins into the food web of the lake. Samples from the anoxic deep and oxic shallow brine layers of the lake were fractionated using asymmetric flow field-flow fractionation (AF4). The associated trace elements were measured via online collision cell inductively-coupled plasma mass spectrometry (CC-ICP-MS). Results showed that of the total (dissolved + particulate) trace element mass, the percent associated with particulates varied from negligible (e.g. Sb), to greater than 50% (e.g. Al, Fe, Pb). Elements such as Cu, Zn, Mn, Co, Au, Hg, and U were associated with nanoparticles, as well as being present as dissolved species. Particulate-associated trace elements were predominantly associated with particulates larger than 450 nm in size. Among the smaller nanoparticulates (<450 nm), some trace elements (Ni, Zn, Au and Pb) showed higher percent mass (associated with nanoparticles) in the 0.9–7.5 nm size range relative to the 10–250 nm size range. The apparent nanoparticle size distributions were similar between the two brine layers; whereas, important differences in elemental associations to nanoparticles were discerned between the two layers. Elements such as Zn, Cu, Pb and Mo showed increasing signal intensities from oxic shallow to anoxic deep brine, suggesting the formation of sulfide nanoparticles, although this may also reflect association with dissolved organic matter. Aluminum and Fe showed greatly increased concentration with depth and equivalent size distributions that differed from those of Zn, Cu, Pb and Mo. Other elements (e.g. Mn, Ni, and Co) showed no significant change in signal intensity with depth. Arsenic was associated with <2 nm nanoparticles, and showed no increase in concentration with depth, possibly indicating dissolved arsenite. Mercury was associated with <2 nm nanoparticles, and showed greatly increased concentration with depth, possibly indicating association with dissolved organic matter.  相似文献