A dry ashing method is commonly used to remove organic material from samples prior to geochemical analysis. In the course of this study, the Cd isotope ratios of a series of soil and plant reference materials and samples were studied to evaluate the effect of the dry ashing method on measurement results of Cd isotope ratios. The samples were pre‐treated using the dry ashing method and high‐pressure bomb for comparison. The results show that the digestion using high‐pressure bombs did not lead to Cd loss, but using the dry ashing method would cause different proportions of Cd loss. The whole range of Cd isotope difference between two methods was from ?0.07‰ to 3.01‰. There was also an obvious difference in measured Cd isotope ratios from the same leaf sample pre‐treated independently by the dry ashing method, indicating that the amount of Cd loss and the effect on Cd isotope measurement during dry ashing is related to the properties of the samples. Therefore, dry ashing may not be appropriate for the removal of organic material in Cd isotope ratio measurement, especially for samples with high organic contents. The δ114/110Cd values of reference materials NIST SRM 1573a and GSD‐30 are reported for the first time in this study. 相似文献
Weathered rockfill materials, characterized by a mixture of soil matrix and rock aggregates, are widely distributed in mountainous areas. These soils are frequently used for subgrade or riprap in engineering practice, and the mobilized shear strength is crucial for analyzing the displacement and stability of these geo-structures. A series of direct shear tests are performed on a gap-graded soil with a full range of coarse fraction. The behavior of gap-graded soils is analyzed, and a simple model is proposed for the evolution of mobilized stress ratio during direct shearing process based on mixture theory. The change of inter-aggregate configuration is incorporated by introducing a structure variable which increases with coarse fraction and decreases approximately linearly with the overall horizontal shear strain in double logarithmic plot. It reasonably reflects a gradually transformation from a matrix-sustained structure into an aggregate-sustained one with the increase of coarse fraction. The model has four parameters, and at least two direct shear tests need to be done for the calibration. Validation of the model is done by using the test data in this work and those from the literature.
利用以色列特拉维夫大学二维面对称分档云模式(two-dimensional slab-symmetric detailed spectral bin microphysical model of Tel Aviv University),对2016年9月4日16:00(北京时)前后我国华东地区的一次暖性浅对流云降水过程进行模拟,模式模拟的强回波中心高度和最大回波强度范围与观测基本一致。并在此基础上进行了小于1 μm的吸湿性核的播撒减雨试验,分别考虑了不同播撒时间、不同播撒高度以及不同播撒剂量的敏感性测试。结果表明:在云的发展阶段早期播撒能起到更好的减雨效果,播撒时间越早对大粒子生长过程的抑制作用越强,随着播撒时间向后推移,受抑制作用最显著的粒径段向小粒径端偏移;在云中心过饱和度大的区域下方进行播撒,减雨效果更加明显,当播撒剂量为350 cm-3时,地面累积降水量减少率可达23.3%;另外,随着播撒剂量的增加,减雨效果更加显著,甚至能达到消雨的效果。因此,在暖性浅对流云中合理地播撒小于1 μm的吸湿性核能达到较好的减雨或消雨效果。 相似文献