Equations of state of CaSiO3 Perovskite: a molecular dynamics study     

Yigang Zhang  Dapeng Zhao  Masanori Matsui  Guangjun Guo 《Physics and Chemistry of Minerals》2006,33(2):126-137

The molar volumes and bulk moduli of CaSiO₃ perovskite are calculated in the temperature range from 300 to 2,800 K and the pressure range from 0 to 143 GPa using molecular dynamics simulations that employ the breathing shell model for oxygen and the quantum correction in addition to the conventional pairwise interatomic potential models. The performance of five equations of state, i.e., the Keane, the generalized-Rydberg, the Holzapfel, the Stacey–Rydberg, and the third-order Birch–Murnaghan equations of state are examined using these data. The third-order Birch–Murnaghan equation of state is found to have a clear tendency to overestimate the bulk modulus at very high pressures. The Stacey–Rydberg equation of state degrades slightly at very high pressures along the low-temperature isotherms. In comparison, the Keane and the Holzapfel equations of state remain accurate in the whole temperature and pressure range considered in the present study. K ₀′ derived from the Holzapfel equation of state also agrees best with that calculated independently from molecular dynamics simulations. The adiabatic bulk moduli of CaSiO₃ perovskite along lower mantle geotherms are further calculated using the Keane and the Mie-Grüneisen–Debye equations of state. They are found to be constantly higher than those of the PREM by ~5%, and also very similar to those of the MgSiO₃ perovskite. Our results support the view that CaSiO₃ perovskite remains invisible in the Earth’s lower mantle.  相似文献   

Carbon and hydrogen isotope variation of plant biomarkers in a plant-soil system   总被引：2，自引：0，他引：2  

Yoshito Chikaraishi  Hiroshi Naraoka 《Chemical Geology》2006,231(3):190-202

Stable carbon (δ¹³C) and hydrogen (δD) isotopic compositions of n-alkanes, anteiso-alkanes, n-alkanoic acids, n-alkanols, phytol and sterols in raw leaves of Acer argutum and Acer carpinifolium, their fallen leaves, mold and soils from a natural Acer forest were measured in order to: (1) understand isotopic variation of the plant biomarkers in a plant-soil system and (2) evaluate which biomarker is the most effective recorder of soil vegetation. Long-chain (> C₂₄) n-alkanes, n-alkanoic acids and n-alkanols are gradually enriched in ¹³C up to 12.9‰ (average of 4.3‰) and depleted in D up to 94‰ (average of 55‰) from raw leaves to soils. However, anteiso-alkanes, phytol and sterols show little variation in both δ¹³C (< ± 1‰) and δD (< ± 2‰) from raw leaves to soils. These isotope signatures in a plant-soil system indicate that isoprenoid plant biomarkers such as sterols in soils faithfully preserve the isotopic compositions of dominant higher plants growing on the soils without a diagenetic effect upon the isotopic compositions. In contrast, long-chain n-alkyl molecules in soils undergo specific isotopic modification during biodegradation associated with early diagenesis and/or a significant contribution from heterotrophic reworking.  相似文献   

Cyclic tests on steel and concrete‐filled tube frames with Slit Walls     

Toko Hitaka  Chiaki Matsui  Jun'ichi Sakai 《地震工程与结构动力学》2007,36(6):707-727

Cyclic loading tests were performed on three one‐storey steel frames and four three‐storey concrete‐filled tube (CFT) moment frames reinforced with a new type of earthquake‐resisting element consisting of a steel plate shear wall with vertical slits. In this shear wall system, the steel plate segments between the slits behave as a series of flexural links, which provide fairly ductile response without the need for heavy stiffening of the wall. The steel shear walls and the moment frames behaved in a ductile manner up to more than 4% drift without abrupt strength degradation or loss of axial resistance. Results of these tests and complementary analysis provide a basis for an equivalent brace model to be employed in commercially available frame analysis programs. Test and analytical results suggest that the horizontal force is carried by the bolts in the middle portion of the wall–frame connection, while the vertical forces coupled with the moment in the connection are resisted by the bolts in the edge portion of the connection, for which the friction bolts in the connection should be designed. When sufficient transverse stiffening is provided, full plastic strength and non‐degrading hysteretic behaviour can be achieved for this new type of shear wall. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Estimation of the apertures of water-saturated fractures by nuclear magnetic resonance well logging   总被引：1，自引：0，他引：1  

Yoshito Nakashima  Tsuneo Kikuchi 《Geophysical Prospecting》2007,55(2):235-254

Fracture aperture is an important transport property in subsurface hydrology because it influences well productivity and the volume of the water resource. Nuclear magnetic resonance (NMR) well logging measures the hydrogen‐bearing fluid molecules in porous or fractured strata, and the NMR signal intensity increases with the amount of fluid in the sensed region of the NMR sonde. Fluid confined in a large fracture of >>0.2 mm in aperture has T2 (i.e. spin‐spin relaxation time) values as long as those of the bulk fluid. The bulk‐fluid porosity (i.e. porosity calculated using this long T2 component in a T2 histogram data) increases linearly with aperture. Therefore, NMR logging enables quantitative estimation of fracture apertures of >>0.2 mm using the bulk‐fluid porosity data if the calibration of the NMR sonde is performed adequately. We applied NMR logging to a borehole in a Holocene andesite lava at Sumikawa, Japan, to estimate the aperture of open fractures within the lava. A test well of 100 m depth and 20 cm diameter, filled with bentonite drilling mud, was scanned with an NMR sonde to obtain a profile of the porosity and the T2 histogram of the andesite. The bulk‐fluid porosity was calculated from the T2 histogram data, as the porosity at which the T2 value is larger than or equal to a threshold T2 of bulk bentonite mud. The bulk‐fluid porosity of a specific inclined fracture responsible for the total loss of circulation at 61.2 m depth during drilling was calculated assuming a threshold or T2 cut‐off of 33 ms, and again for a cut‐off of 100 ms. Calibration of the NMR sensor in a laboratory and measurement of the fracture dip angle by electrical microimaging logging enabled us to estimate the fracture aperture as 1.7 cm, assuming a T2 cut‐off of 33 ms, or 1.6 cm for a T2 cut‐off of 100 ms. The method of aperture determination described in this study is independent of fluid species and lithology, and is applicable to various hydrogen‐bearing borehole fluids (clean water, mud and oil) and geological settings.  相似文献   

Nonlinear sloshing in a floating‐roofed oil storage tank under long‐period seismic ground motion     

Tetsuya Matsui  Takashi Nagaya 《地震工程与结构动力学》2013,42(7):973-991

A hybrid analytical and FEM is proposed to investigate the nonlinear sloshing in a floating‐roofed oil storage tank under long‐period seismic ground motion. The tank is composed of a rigid cylindrical wall and a flat bottom, whereas the floating roof is treated as an elastic plate undergoing large deflection. The contained liquid is assumed to be inviscid and incompressible, and the flow is assumed to be irrotational. The method of analysis is based on representation of the liquid motion by superposing the analytical modes that satisfy the Laplace equation and the rigid wall and bottom boundary conditions. The FEM is then applied to solve the remaining kinematic and dynamic boundary conditions at the moving liquid surface coupled with the nonlinear equation of motion of the floating roof. This requires only the discretization of the liquid surface and the floating roof into finite elements, thus leading to a computationally efficient and accurate method compared with full numerical analysis. As numerical examples to illustrate the applicability of the proposed method, two oil storage tanks with single‐deck type floating roofs damaged during the 2003 Tokachioki earthquake are studied. It is shown that the nonlinear oscillation modes with the circumferential wave numbers 0, 2 and 3 caused by the finite liquid surface elevation as well as the membrane action due to large deflection of the deck produce excessively large stresses in the pontoon, which may cause the catastrophic failure of pontoon followed by the submergence of the roof. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Evidence for ocean water invasion into the Chicxulub crater at the Cretaceous/Tertiary boundary     

Kazuhisa Goto  Ryuji Tada  Eiichi Tajika  Timothy J. Bralower  Takashi Hasegawa  Takafumi Matsui 《Meteoritics & planetary science》2004,39(8):1233-1247

Abstract— The possibility of ocean water invasion into the Chicxulub crater following the impact at the Cretaceous/Tertiary boundary was investigated based on examination of an impactite between approximately 794.63 and 894.94 m in the Yaxcopoil‐1 (Yax‐1) core. The presence of cross lamination in the uppermost part of the impactite suggests the influence of an ocean current at least during the sedimentation of this interval. Abundant occurrence of nannofossils of late Campanian to early Maastrichtian age in the matrices of samples from the upper part of the impactite suggests that the carbonate sediments deposited on the inner rim margin and outside the crater were eroded and transported into the crater most likely by ocean water that invaded the crater after its formation. The maximum grain size of limestone lithics and vesicular melt fragments, and grain and bulk chemical compositions show a cyclic variation in the upper part of the impactite. The upward fining grain size and the absence of erosional contact at the base of each cycle suggest that the sediments were derived from resuspension of units elsewhere in the crater, most likely by high energy currents association with ocean water invasion.  相似文献