Geochemical fingerprints of dolomitization in Bahamian carbonates: Evidence from sulphur,calcium, magnesium and clumped isotopes     

Sean T. Murray  John A. Higgins  Chris Holmden  Chaojin Lu  Peter K. Swart 《Sedimentology》2021,68(1):1-29

In an effort to constrain the mechanism of dolomitization in Neogene dolomites in the Bahamas and improve understanding of the use of chemostratigraphic tracers in shallow‐water carbonate sediments the δ³⁴S, Δ₄₇, δ¹³C, δ¹⁸O, δ^44/40Ca and δ²⁶Mg values and Sr concentrations have been measured in dolomitized intervals from the Clino core, drilled on the margin of Great Bahama Bank and two other cores (Unda and San Salvador) in the Bahamas. The Unda and San Salvador cores have massively dolomitized intervals that have carbonate associated sulphate δ³⁴S values similar to those found in contemporaneous seawater and δ^44/40Ca, δ²⁶Mg values, Sr contents and Δ₄₇ temperatures (25 to 30°C) indicating relatively shallow dolomitization in a fluid‐buffered system. In contrast, dolomitized intervals in the Clino core have elevated values of carbonate associated sulphate δ³⁴S values indicating dolomitization in a more sediment‐buffered diagenetic system where bacterial sulphate reduction enriches the residual in ³⁴S, consistent with high sediment Sr concentrations and low δ^44/40Ca and high δ²⁶Mg values. Only dolomites associated with hardgrounds in the Clino core have carbonate associated δ³⁴S values similar to seawater, indicating continuous flushing of the upper layers of the sediment by seawater during sedimentary hiatuses. This interpretation is supported by changes to more positive δ^44/40Ca values at hardground surfaces. All dolomites, whether they formed in an open fluid‐buffered or closed sediment‐buffered diagenetic system have similar δ²⁶Mg values suggesting that the HMC transformed to dolomite. The clumped isotope derived temperatures in the dolomitized intervals in Clino yield temperatures that are higher than normal, possibly indicating a kinetic isotope effect on dolomite Δ₄₇ values associated with carbonate formation through bacterial sulphate reduction. The findings of this study highlight the utility of applying multiple geochemical proxies to disentangle the diagenetic history of shallow‐water carbonate sediments and caution against simple interpretations of stratigraphic variability in these geochemical proxies as indicating changes in the global geochemical cycling of these elements in seawater.  相似文献   

Modeling the formation of undulations of the coastline: The role of tides     

M. van der Vegt  H.M. Schuttelaars  H.E. de Swart 《Continental Shelf Research》2007

An idealized model is developed and analyzed to investigate the relevance of tidal motion for the emergence of undulations of a sandy coastline. The model describes feedbacks between tidal and steady flow on the inner shelf, sand transport in the nearshore zone and an irregular coastline. It is demonstrated that an initially straight coastline can become unstable with respect to perturbations with a rhythmic structure in the alongshore direction. The mechanism causing the growth of these perturbations is explained in terms of vorticity concepts. The relative importance of tide-related and wave-driven sediment fluxes in generating undulations of the coastline is investigated for the Dutch coast. Using parameter values that are appropriate for the Dutch coast it is found that tides can render a straight coastline unstable. The model predicts a fastest growing mode (FGM) with a wavelength that is in the order of the observed length of barrier islands. The mode grows on a time scale of 50 yr and it migrates 200 m per year. The wavelength of the FGM decreases with increasing amplitude of the tidal currents. This result is consistent with data of tides, waves and the lengths of barrier islands that are located along the Dutch and German Wadden coast.  相似文献   

Ocean robotics in support of fisheries research and management     

S Swart  JJ Zietsman  JC Coetzee  DG Goslett  A Hoek  D Needham 《African Journal of Marine Science》2016,38(4):525-538

South Africa’s small-pelagic fishery is a socio-economically important component of the country’s commercial fisheries sector, second in value only to the demersal trawl fishery. Management of this sector relies on infrequent hydro-acoustic surveys, which provide measures of anchovy Engraulis encrasicolus and sardine Sardinops sagax biomass used in the assessments of stock status and in the development of management plans for the sustainable utilisation of these resources. We demonstrate how technological capabilities in ocean robotics at the Council for Scientific and Industrial Research (CSIR) could augment the current resource-intensive hydro-acoustic ship-based survey programme and create opportunities for expanding its spatial and temporal resolution. We successfully implement and demonstrate an autonomous wave glider, fitted with a hydro-acoustic sensor and compare the data to a collocated ‘traditional’ ship-based acoustics survey. In the future these autonomous systems approaches could be seen as a means to lessen the cost burden of the ship-based survey, while at the same time with the added advantage of continuous collection over much wider spatial and temporal domains. This could enable a more reflexive stock management approach taking into account the seasonal characteristics of the fishery and its ecosystem. Gliders thus have potential to increase dramatically the quantity of information available to fisheries managers, thereby reducing uncertainty and contributing to improved management of valuable fish resources. They are likely to contribute to improved knowledge of the ecology of small pelagic fish species off the coast of South Africa in a changing climate and should potentially also permit the collection of biomass data for other marine resources currently not routinely monitored.  相似文献   

Origin of blocky aragonite cement in Cenozoic glaciomarine sediments,McMurdo Sound,Antarctica     

Mingyu Yang  Tracy D. Frank  Christopher R. Fielding  Megan E. Smith  Peter K. Swart 《Sedimentology》2020,67(2):721-741

Inorganic aragonite occurs in a wide spectrum of depositional environments and its precipitation is controlled by complex physio-chemical factors. This study investigates diagenetic conditions that led to aragonite cement precipitation in Cenozoic glaciomarine deposits of McMurdo Sound, Antarctica. A total of 42 sandstones that host intergranular cement were collected from the CIROS-1 core, located proximal to the terminus of Ferrar Glacier. Standard petrography, Raman spectroscopy and electron microprobe analysis reveal a prominent aragonite cement phase that occurs as a pore-filling blocky fabric throughout the core. Oxygen isotope compositions (δ¹⁸O = −30·0 to −8·6‰ Vienna Pee-Dee Belemnite) and clumped isotope temperatures (TΔ₄₇ = 13·1 to 31·5°C) determined from the aragonite cements provide precise constraints on isotopic compositions (δ¹⁸O_w) of the parent fluid, which mostly range from −10·8 to −7·2‰ Vienna Standard Mean Ocean Water. The fluid δ¹⁸O_w values are consistent with those of pore water, previously identified as cryogenic brine in the nearby AND-2A core. Petrographic and geochemical data suggest that aragonite cement in the CIROS-1 core precipitated from a similar brine. The brine likely formed and infiltrated sediments in flooded glacial valleys along the western margin of McMurdo Sound during the middle Miocene Climatic Transition, and subsequently flowed basinward in the subsurface. Consequently, the brine forms as a longstanding subsurface fluid that has saturated Cenozoic sediments below southern McMurdo Sound since at least the middle Miocene. Aragonite cementation in the CIROS-1 core is interpreted to reflect its proximal position to sites of brine formation and greater likelihood of experiencing brines with sustained high carbonate saturation states and Mg/Ca ratios. This unusual occurrence expands the range of known natural occurrences of aragonite cement. Given the potential for cryogenic brine formation in glaciomarine settings, blocky aragonite, as the end member of the spectrum of aragonite cement morphology, may be more widespread in glaciomarine sediments than currently thought.  相似文献   

Feedback between residual circulations and sediment distribution in highly turbid estuaries: An analytical model     

S.A. Talke  H.E. de Swart  H.M. Schuttelaars 《Continental Shelf Research》2009

Motivated by field studies of the Ems estuary which show longitudinal gradients in bottom sediment concentration as high as O(0.01 kg/m⁴), we develop an analytical model for estuarine residual circulation based on currents from salinity gradients, turbidity gradients, and freshwater discharge. Salinity is assumed to be vertically well mixed, while the vertical concentration profile is assumed to result from a balance between a constant settling velocity and turbulent diffusive flux. Width and depth of the model estuary are held constant. Model results show that turbidity gradients enhance tidally averaged circulation upstream of the estuarine turbidity maximum (ETM), but significantly reduce residual circulation downstream, where salinity and turbidity gradients oppose each other. We apply the condition of morphodynamic equilibrium (vanishing sediment transport) and develop an analytical solution for the position of the turbidity maximum and the distribution of suspended sediment concentration (SSC) along a longitudinal axis. A sensitivity study shows great variability in the longitudinal distribution of suspended sediment with the applied salinity gradient and six model parameters: settling velocity, vertical mixing, horizontal dispersion, total sediment supply, fresh water flow, and water depth. Increasing depth and settling velocity move the ETM upstream, while increasing freshwater discharge and vertical mixing move the ETM downstream. Moreover, the longitudinal distribution of SSC is inherently asymmetric around the ETM, and depends on spatial variations in the residual current structure and the vertical profile of SSC.  相似文献   

Citation of John Hudson for Honorary Membership of the International Association of Sedimentologists     

Peter K. Swart 《Sedimentology》2011,58(3):827-828

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Rectification of the wind-driven ocean circulation on the beta plane     

H. E. De Swart  J. T. F. Zimmerman 《地球物理与天体物理流体动力学》2013,107(1-4):17-41

Abstract

A nonlinear Stommel model of the ocean circulation on the beta plane, driven by a time periodic wind stress, is investigated in order to study symmetry properties of the observed time-mean ocean gyres. Due to the presence of vorticity advection terms the model will have a steady or rectified response to fluctuating wind fields. In this paper a small inverse Ekman number, “the small beta regime”, is considered. It is demonstrated that for this case all qualitative features of the residual circulation, obtained numerically by Veronis (1970). are reproduced in an analytical way. They include the dipole character of the gyre, its maximum symmetry breaking around the north-south axis for intermediate Reynolds numbers, measuring the ratio of vorticity forcing and dissipation, and the maximum residual response for intermediate forcing frequencies.  相似文献   

Determining Spatial and Temporal Inputs of Freshwater,Including Submarine Groundwater Discharge,to a Subtropical Estuary Using Geochemical Tracers,Biscayne Bay,South Florida     

Jeremy C. Stalker  René M. Price  Peter K. Swart 《Estuaries and Coasts》2009,32(4):694-708

Geochemical mixing models were used to decipher the dominant source of freshwater (rainfall, canal discharge, or groundwater discharge) to Biscayne Bay, an estuary in south Florida. Discrete samples of precipitation, canal water, groundwater, and bay surface water were collected monthly for 2 years and analyzed for salinity, stable isotopes of oxygen and hydrogen, and Sr²⁺/Ca²⁺ concentrations. These geochemical tracers were used in three separate mixing models and then combined to trace the magnitude and timing of the freshwater inputs to the estuary. Fresh groundwater had an isotopic signature (δ ¹⁸O = −2.66‰, δD −7.60‰) similar to rainfall (δ ¹⁸O = −2.86‰, δD = −4.78‰). Canal water had a heavy isotopic signature (δ ¹⁸O = −0.46‰, δD = −2.48‰) due to evaporation. This made it possible to use stable isotopes of oxygen and hydrogen to separate canal water from precipitation and groundwater as a source of freshwater into the bay. A second model using Sr²⁺/Ca²⁺ ratios was developed to discern fresh groundwater inputs from precipitation inputs. Groundwater had a Sr²⁺/Ca²⁺ ratio of 0.07, while precipitation had a dissimilar ratio of 0.89. When combined, these models showed a freshwater input ratio of canal/precipitation/groundwater of 37%:53%:10% in the wet season and 40%:55%:5% in the dry season with an error of ±25%. For a bay-wide water budget that includes saltwater and freshwater mixing, fresh groundwater accounts for 1–2% of the total fresh and saline water input.  相似文献   

豫西崤山早元古代中酸性侵入岩锆石/斜锆石U-Pb测年及其对熊耳火山岩系时限的约束   总被引：5，自引：4，他引：1  

崔敏利  张宝林  彭澎  张连昌  沈晓丽  郭志华  黄雪飞 《岩石学报》2010,26(5):1541-1549

熊耳火山岩系是华北克拉通早元古代晚期重要的岩浆记录,其火山作用时限的厘定对于揭示华北该时期的构造格局与演化历史有重要意义。对侵入到熊耳火山岩系顶层马家河组的石英闪长岩体中的斜锆石与锆石和花岗斑岩体中的锆石进行了高精度SIMSU-Pb定年。三个样品共58个测点,石英闪长岩体中的斜锆石207Pb/206Pb平均年龄为1789±4Ma,锆石207Pb/206Pb平均年龄1778±12Ma,花岗斑岩体中的锆石207Pb/206Pb平均年龄为1786±8Ma。这些年龄数据表明石英闪长岩体从生成到侵位是一个短暂而连续的过程,这一岩体与花岗斑岩岩体基本同期。同时,由于这两个岩体侵入到了熊耳火山岩系最顶部的马家河组,因此可以限定熊耳火山岩系的上限。结合前人的年代学数据,我们提出熊耳火山岩系的岩浆作用时限在1770～1800Ma之间,峰期为1780Ma。这一研究结果从年代学上支持熊耳火山岩系形成于快速拉张的裂谷环境。  相似文献   

The effect of velocity veering on sand transport in a shallow sea     

G. I. Shapiro  J. van der Molen  H. E. de Swart 《Ocean Dynamics》2004,54(3-4):415-423

This study aims at comparing and contrasting two different models for sand transport by currents in a shallow sea to illustrate the effect of velocity veering. The first model uses the Bailard-type formulation, which allows calculation of erosion/deposition rates at a fixed location on the sea floor via the divergence of horizontal sediment fluxes. The second model is a semi-analytical 2.5-dimensional model, which takes into account the time lag between erosion and deposition events and the velocity veering within the sediment-laden (nepheloid) layer caused by the Coriolis force. The velocity veering implies that the direction of the sediment flux is generally different from the direction of the surface flow. The latter model was designed for rapid, semi-analytical computations of sediment transport, using flow fields from 2-DH numerical models. The two models use a matching set of parameters to provide identical values for the bottom stress and suspended sediment load for a uniform steady current at any given surface velocity. The two models were compared in a range of sand grain sizes 50–500 m and current speeds up to 1 m s^–1 for an idealised square region (100 × 100 km) of a shelf sea of constant depth. The erosion/deposition patterns and suspension load were examined in three settings: (1) uniform steady flow, (2) straight jet, (3) meandering jet. It was found that both the rates and, in particular, the spatial distribution of the areas of erosion/deposition differ significantly between the models in cases (2) and (3). This difference can be attributed to additional flux divergence due to velocity veering. A comparison of model results with field data, collected at Long Island Shelf, supports the relevance of Coriolis-induced veering of currents on the direction of the sediment flux.Responsible Editor: Jens Kappenberg  相似文献