Grain Size Analysis and Permeametry for Estimating Hydraulic Conductivity in Engineered Porous Media     

Allison Cormican  J.F. Devlin  Craig Divine 《Ground Water Monitoring & Remediation》2020,40(2):65-72

Grain size analysis and permeametry are common methods for estimating the hydraulic conductivity (K) of porous media. It is well known that these methods have limited accuracy when they are used to characterize natural sediments. However, hydrogeological research has increasingly introduced technologies dependent on engineered porous media that may be less problematic because complex geologic structures are eliminated in the lab and field-scale packings. The recently introduced Horizontal Reactive Media Treatment Wells (HRX® Wells), for in situ, passive remediation of groundwater is one such example. The HRX Well passively collects groundwater and directs it through a horizontal pipe packed with an engineered porous medium. In this project, grain size analysis was conducted for sand and sand-iron mixtures to estimate K using the 16 algorithms provided in the HydrogeoSieveXL2.3.2 software. The results were compared to K determined by permeametry and a field-scale column, 30 cm long and 25 cm in diameter, representing an HRX Well. The best comparability of K estimates from grain size analysis and permeametry were obtained using the USBR, Slichter, and Shepherd K estimation methods. These also showed good agreement between lab-scale and field-scale K estimations, with reproducibility within the range ±20%. This study shows that laboratory K estimations can be representative across various relevant scales, including the field-scale, for engineered porous media. This finding extends to filter packs, and other engineered porous media design methods by emphasizing and demonstrating one case of accuracy in lab-scale permeability estimation for field-scale implementations.  相似文献   

Hydraulic Performance of the Horizontal Reactive Media Treatment Well: Pilot and Numerical Study     

Blossom N. Nzeribe  Wen Li  Michelle Crimi  Guangming Yao  Craig E. Divine  Jeff McDonough  Jack Wang 《Ground Water Monitoring & Remediation》2020,40(3):30-41

This study is focused on a passive treatment system known as the horizontal reactive treatment well (HRX Well®) installed parallel to groundwater flow, which operates on the principle of flow focusing that results from the hydraulic conductivity (K) ratio of the well and aquifer media. Passive flow and capture in the HRX Well are described by simplified equations adapted from Darcy's Law. A field pilot-scale study (PSS) and numerical simulations using a finite element method (FEM) were conducted to verify the HRX Well concept and test the validity of the HRX Well-simplified equations. The hydraulic performance results from both studies were observed to be within a close agreement to the simplified equations and their hydraulic capture width approximately five times greater than the well diameter (0.20 m). Key parameters affecting capture included the aquifer thickness, well diameter, and permeability ratio of the HRX Well treatment media and aquifer material. During pilot testing, the HRX Well captured 39% of flow while representing 0.5% of the test pit cross-sectional volume, indicating that the well captures a substantial amount of surrounding groundwater. While uncertainty in the aquifer and well properties (porosity, K, well losses), including the effects of boundary conditions, may have caused minor differences in the results, data from this study indicate that the simplified equations are valid for the conceptual design of a field study. A full-scale HRX Well was installed at Site SS003 at Vanderberg Air Force Base, California, in July/August 2018 based on outcomes from this study.  相似文献   

Field Demonstration of the Horizontal Treatment Well (HRX Well®) for Passive In Situ Remediation     

Craig E. Divine  Jesse Wright  Michelle Crimi  J.F. Devlin  Michael Lubrecht  Jack Wang  Jeff McDonough  Michael Kladias  Jesse Hinkle  Allison Cormican  Trevor Osorno  Blossom N. Nzeribe  Fiona Laramay  Daniel Ombalski  Kathleen Gerber  Hunter Anderson 《Ground Water Monitoring & Remediation》2020,40(3):42-54

The horizontal reactive media treatment well (HRX Well®) uses directionally drilled horizontal wells filled with a treatment media to induce flow-focusing behavior created by the well-to-aquifer permeability contrast to passively capture proportionally large volumes of groundwater. Groundwater is treated in situ as it flows through the HRX Well and downgradient portions of the aquifer are cleaned via elution as these zones are flushed with clean water discharging from the HRX Well. The HRX Well concept is particularly well suited for sites where long-term mass discharge control is a primary performance objective. This concept is appropriate for recalcitrant and difficult-to-treat constituents, including chlorinated solvents, per- and polyfluoroalkyl substances (PFAS), 1,4-dioxane, and metals. A full-scale HRX Well was installed and operated to treat trichloroethene (TCE) with zero valent iron (ZVI). The model-predicted enhanced flow through the HRX Well (compared to the flow in and equivalent cross-sectional area orthogonal to flow in the natural formation before HRX Well installation) and treatment zone width was consistent with flows and widths estimated independently by point velocity probe (PVP) testing, HRX Well tracer testing, and observed treatment in downgradient monitoring wells. The actual average capture zone width was estimated to be between 45 and 69 feet. Total TCE mass discharge reduction was maintained through the duration of the performance monitoring period and exceeded 99.99% (%). Decreases in TCE concentrations were observed at all four downgradient monitoring wells within the treatment zone (ranging from 50 to 74% at day 436), and the first arrival of treated water was consistent with model predictions. The field demonstration confirmed the HRX Well technology is best suited for long-term mass discharge control, can be installed under active infrastructure, requires limited ongoing operation and maintenance, and has low life cycle energy and water requirements.  相似文献   

Towards Quantifying the Likelihood of Water Resource Impacts from Unconventional Gas Development     

Margaret Shanafield  Peter G. Cook  Craig T. Simmons 《Ground water》2019,57(4):547-561

Gas production from unconventional reservoirs has led to widespread environmental concerns. Despite several excellent reviews of various potential impacts to water resources from unconventional gas production, no study has systematically and quantitatively assessed the potential for these impacts to occur. We use empirical evidence and numerical and analytical models to quantify the likelihood of surface water and groundwater contamination, and shallow aquifer depletion from unconventional gas developments. These likelihoods are not intended to be exact. They provide a starting point for comparing the probabilities of adverse impacts between types of water resources and pathways. This analysis provides much needed insight into what are “probable” rather than simply “possible” impacts. The results suggest that the most likely water resource impacts are surface water and groundwater contamination from spills at the well pad, which can be as high as 1 in 10 and 1 in 100 for each gas well, respectively. For wells that are hydraulically fractured, the likelihood of contamination due to inter-aquifer leakage is 1 in 10⁶ or lower (dependent on the separation distance between the production formation and the aquifer). For gas-bearing formations that were initially over-pressurized, the potential for contamination from inter-aquifer leakage after production ceases could be as high as 1 in 400 where the separation between gas formation and shallow aquifer is 500 m, but will be much lower for greater separation distances (more characteristic of shale gas).  相似文献   

Source partitioning of anthropogenic groundwater nitrogen in a mixed-use landscape,Tutuila, American Samoa     

Christopher K. Shuler  Aly I. El-Kadi  Henrietta Dulai  Craig R. Glenn  Joseph Fackrell 《Hydrogeology Journal》2017,25(8):2419-2434

This study presents a modeling framework for quantifying human impacts and for partitioning the sources of contamination related to water quality in the mixed-use landscape of a small tropical volcanic island. On Tutuila, the main island of American Samoa, production wells in the most populated region (the Tafuna-Leone Plain) produce most of the island’s drinking water. However, much of this water has been deemed unsafe to drink since 2009. Tutuila has three predominant anthropogenic non-point-groundwater-pollution sources of concern: on-site disposal systems (OSDS), agricultural chemicals, and pig manure. These sources are broadly distributed throughout the landscape and are located near many drinking-water wells. Water quality analyses show a link between elevated levels of total dissolved groundwater nitrogen (TN) and areas with high non-point-source pollution density, suggesting that TN can be used as a tracer of groundwater contamination from these sources. The modeling framework used in this study integrates land-use information, hydrological data, and water quality analyses with nitrogen loading and transport models. The approach utilizes a numerical groundwater flow model, a nitrogen-loading model, and a multi-species contaminant transport model. Nitrogen from each source is modeled as an independent component in order to trace the impact from individual land-use activities. Model results are calibrated and validated with dissolved groundwater TN concentrations and inorganic δ¹⁵N values, respectively. Results indicate that OSDS contribute significantly more TN to Tutuila’s aquifers than other sources, and thus should be prioritized in future water-quality management efforts.  相似文献   

A New Appraisal of Sri Lankan BB Zircon as a Reference Material for LA‐ICP‐MS U‐Pb Geochronology and Lu‐Hf Isotope Tracing          下载免费PDF全文

Maristella M. Santos  Cristiano Lana  Ricardo Scholz  Ian Buick  Mark D. Schmitz  Sandra L. Kamo  Axel Gerdes  Fernando Corfu  Simon Tapster  Penelope Lancaster  Craig D. Storey  Miguel A.S. Basei  Eric Tohver  Ana Alkmim  Herminio Nalini  Klaus Krambrock  Cristiano Fantini  Michael Wiedenbeck 《Geostandards and Geoanalytical Research》2017,41(3):335-358

A potential zircon reference material (BB zircon) for laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) U‐Pb geochronology and Hf isotope geochemistry is described. A batch of twenty zircon megacrysts (0.5–1.5 cm³) from Sri Lanka was studied. Within‐grain rare earth element (REE) compositions are largely homogeneous, albeit with some variation seen between fractured and homogeneous domains. Excluding fractured cathodoluminescence bright domains, the variation in U content for all analysed crystals ranged from 227 to 368 μg g^?1 and the average Th/U ratios were between 0.20 and 0.47. The Hf isotope composition (0.56–0.84 g/100 g Hf) is homogeneous within and between the grains – mean ¹⁷⁶Hf/¹⁷⁷Hf of 0.281674 ± 0.000018 (2s). The calculated alpha dose of 0.59 × 10¹⁸ g^?1 for a number of BB grains falls within the trend of previously studied, untreated zircon samples from Sri Lanka. Aliquots of the same crystal (analysed by ID‐TIMS in four different laboratories) gave consistent U‐Pb ages with excellent measurement reproducibility (0.1–0.4% RSD). Interlaboratory assessment (by LA‐ICP‐MS) from individual crystals returned results that are within uncertainty equivalent to the TIMS ages. Finally, we report on within‐ and between‐grain homogeneity of the oxygen isotope systematic of four BB crystals (13.16‰ VSMOW).  相似文献   

A Correction on Coastal Heads for Groundwater Flow Models          下载免费PDF全文

Chunhui Lu  Adrian D. Werner  Craig T. Simmons  Jian Luo 《Ground water》2015,53(1):164-170

We introduce a simple correction to coastal heads for constant‐density groundwater flow models that contain a coastal boundary, based on previous analytical solutions for interface flow. The results demonstrate that accurate discharge to the sea in confined aquifers can be obtained by direct application of Darcy's law (for constant‐density flow) if the coastal heads are corrected to ((α + 1)/α)h_s ? B/2α, in which h_s is the mean sea level above the aquifer base, B is the aquifer thickness, and α is the density factor. For unconfined aquifers, the coastal head should be assigned the value . The accuracy of using these corrections is demonstrated by consistency between constant‐density Darcy's solution and variable‐density flow numerical simulations. The errors introduced by adopting two previous approaches (i.e., no correction and using the equivalent fresh water head at the middle position of the aquifer to represent the hydraulic head at the coastal boundary) are evaluated. Sensitivity analysis shows that errors in discharge to the sea could be larger than 100% for typical coastal aquifer parameter ranges. The location of observation wells relative to the toe is a key factor controlling the estimation error, as it determines the relative aquifer length of constant‐density flow relative to variable‐density flow. The coastal head correction method introduced in this study facilitates the rapid and accurate estimation of the fresh water flux from a given hydraulic head measurement and allows for an improved representation of the coastal boundary condition in regional constant‐density groundwater flow models.  相似文献   

Very slow erosion rates and landscape preservation across the southwestern slope of the Ladakh Range,India          下载免费PDF全文

Craig Dietsch  Jason M. Dortch  Scott A. Reynhout  Lewis A. Owen  Marc W. Caffee 《地球表面变化过程与地形》2015,40(3):389-402

Erosion rates are key to quantifying the timescales over which different topographic and geomorphic domains develop in mountain landscapes. Geomorphic and terrestrial cosmogenic nuclide (TCN) methods were used to determine erosion rates of the arid, tectonically quiescent Ladakh Range, northern India. Five different geomorphic domains are identified and erosion rates are determined for three of the domains using TCN ¹⁰Be concentrations. Along the range divide between 5600 and 5700 m above sea level (asl), bedrock tors in the periglacial domain are eroding at 5.0 ± 0.5 to 13.1 ± 1.2 meters per million years (m/m.y.)., principally by frost shattering. At lower elevation in the unglaciated domain, erosion rates for tributary catchments vary between 0.8 ± 0.1 and 2.0 ± 0.3 m/m.y. Bedrock along interfluvial ridge crests between 3900 and 5100 m asl that separate these tributary catchments yield erosion rates <0.7 ± 0.1 m/m.y. and the dominant form of bedrock erosion is chemical weathering and grusification. Erosion rates are fastest where glaciers conditioned hillslopes above 5100 m asl by over‐steepening slopes and glacial debris is being evacuated by the fluvial network. For range divide tors, the long‐term duration of the erosion rate is considered to be 40–120 ky. By evaluating measured ¹⁰Be concentrations in tors along a model ¹⁰Be production curve, an average of ~24 cm is lost instantaneously every ~40 ky. Small (<4 km²) unglaciated tributary catchments and their interfluve bedrock have received very little precipitation since ~300 ka and the long‐term duration of their erosion rates is 300–750 ky and >850 ky, respectively. These results highlight the persistence of very slow erosion in different geomorphic domains across the southwestern slope of the Ladakh Range, which on the scale of the orogen records spatial changes in the locus of deformation and the development of an orogenic rain shadow north of the Greater Himalaya. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Using meteorological observer data to compare wind erosion during two great droughts in eastern Australia; the World War II Drought (1937–1946) and the Millennium Drought (2001–2010)          下载免费PDF全文

Tadhg O'Loingsigh  Grant H. McTainsh  Katherine Parsons  Craig L. Strong  Phil Shinkfield  Nigel J. Tapper 《地球表面变化过程与地形》2015,40(1):123-130

Australian meteorological observers started using the World Meteorological Organization (WMO) weather coding system in the 1950s. This system is still in use around the world today. However, observing and recording the weather in an organized and systematic manner had been ongoing for over 100 years prior to the adoption of this coding system, and much like Australia, most countries will have historical meteorological records. In this paper we compare the wind erosion of two of the greatest droughts in Australian recorded history; the World War II (WWII) Drought (1937–1945) and the Millennium Drought (2001–2009). To do this we analysed previously unavailable meteorological observer records from the Australian Bureau of Meteorology (ABM). Wind erosion records, mostly in long‐hand written form, were translated to the modern WMO coding system for the WWII Drought and compared with the wind erosion of Australia's recently‐ended Millennium Drought, one of the longest and harshest on record. We quantify wind erosion using Dust Event Days (DED) and a modified version of a published Dust Storm Index (DSI) to show that wind erosion during the WWII Drought was up to 4.6 times higher than during the Millennium Drought. This study has international significance because it demonstrates a methodology for tracking changes in wind erosion over the past 75 years based on observer records available in every country with a history of organized weather observation. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Selenium and mercury concentrations in harbor seals (Phoca vitulina) from central California: Health implications in an urbanized estuary     

Elizabeth A. McHuron  James T. Harvey  J. Margaret Castellini  Craig A. Stricker  Todd M. O’Hara 《Marine pollution bulletin》2014

We measured total selenium and total mercury concentrations ([TSe] and [THg]) in hair (n = 138) and blood (n = 73) of harbor seals (Phoca vitulina) from California to assess variation by geography and sex, and inferred feeding relationships based on carbon, nitrogen, and sulfur stable isotopes. Harbor seals from Hg-contaminated sites had significantly greater [THg], and lesser [TSe] and TSe:THg molar ratios than seals from a relatively uncontaminated site. Males had significantly greater [THg] than females at all locations. Sulfur stable isotope values explained approximately 25% of the variability in [THg], indicating increased Hg exposure for seals with a greater use of estuarine prey species. Decreased [TSe] in harbor seals from Hg-contaminated regions may indicate a relative Se deficiency to mitigate the toxic effects of Hg. Further investigation into the Se status and the potential negative impact of Hg on harbor seals from Hg-contaminated sites is warranted.  相似文献