Electron microscopy study of domain structure due to phase transitions in natural perovskite     

Yanbin Wang  Robert C. Liebermann 《Physics and Chemistry of Minerals》1993,20(3):147-158

Transmission electron microscopy on natural calcium metatitanate perovskite (dysanalyte) reveals the following twin laws in the orthorhombic (space group Pbnm) phase: reflection twins on the {110} and {112} planes, and 90° rotation twins about the [001] axis (referred to as [001]_90° twin). Single crystals that were heattreated and quenched from above 1585 K exhibit a dramatic change in domain structure compared with the starting material and specimens quenched from T < 1470=" k.=" mutually=" perpendicular=" {110}=" and=">_90° twins are observed throughout the crystal, forming a cross-hatched domain texture. 1/2[001] antiphase domains, which are very rarely observed in the starting material, also become dominant in the crystal. This change in domain structure is interpreted as due to a structural phase transition in perovskite at a temperature below 1585 K. From the point symmetry elements that describe the twin laws and the translational elements that relate the antiphase domains, the most likely phase near 1585 K is tetragonal with space group P4/mbm. These results are consistent with high-temperature powder X-ray diffraction study. On the other hand, density of the {112} twins is increased significantly in the crystal quenched from 1673 K. Twin domains are either bound by mutually perpendicular {110} and (001) walls, or by {112} walls with {110} twin domains within the polygonal {112} domains. Both twin density variation and domain morphology suggest that the crystal may be cubic at this temperature. Microstructure of a single crystal deformed at 1273 K and 3.5 GPa (within the orthorhombic stability field) is morphologically quite distinct from that of the heat-treated specimens. Dislocations dominate the microstructure and often interact with twin domain boundaries.A National Science Foundation Science and Technology Center  相似文献   

Cu 2p absorption spectroscopy as a probe for the site occupancy of (ZnxCu1−x)WO4 solid solution     

P. F. Schofield  C. M. B. Henderson  S. A. T. Redfern  G. van der Laan 《Physics and Chemistry of Minerals》1993,20(6):375-381

The solid solution sanmartinite (ZnWO₄)—cuproscheelite (CuWO₄) has been studied using Cu 2p X-ray absorption spectroscopy. While a single L₃ absorption peak is observed for CuWO₄, two distinct L₃ absorption peaks with a separation of ～0.8 eV are observed for the intermediate samples in the solid solution. The two peaks represent distinct Cu sites: one with all CuO₆ next nearest neighbours in the (Cu,Zn)O₆ chains, another having at least one ZnO₆ next nearest neighbour. Both sites show a linear increase in covalency as a function of increasing Cu-content. The relative intensities of the two absorption peaks is dependent upon the Cu-content and has been used to model the site occupancies. The results reveal that the local structural effects can be associated with a composition-dependent structural phase transition from P2/c (ZnWO₄) to P $\bar 1$ (CuWO₄). Deviations from a single-site model are explained in terms of the local environments, and evidence for site preferences and local clustering are explored.  相似文献   

The elastic properties of single-crystal fayalite as determined by dynamical measurement techniques     

Donald G. Isaak  Earl K. Graham  Jay D. Bass  Hong Wang 《Pure and Applied Geophysics》1993,141(2-4):393-414

We present new elasticity measurements on single-crystal fayalite and combine our results with other data from resonance, pulse superposition interferometry, and Brillouin scattering to provide a set of recommended values for the adiabatic elastic moduliC _ij and their temperature variations. We use a resonance method (RPR) with specimens that were previously investigated by pulse superposition experiments. The nineC _ij of fayalite are determined from three new sets of measurements. One set of our newC _ij data is over the range 300–500 K. We believe that the relatively large discrep ncies found in someC _ij are due in large part to specimen inhomogeneities (chemical and microstructural) coupled with differences in the way various techniques sample, rather than only systematic errors associated with experimental procedures or in the preparations of the specimens.Our recommendeaC _ij's (GPa) and (C _ij/T) _p (GPa/K) are: The resulting values for the isotropic bulk and shear moduli,K _s and , and their temperature derivatives are:K _s=134(4) GPa; =50.7(0.3) GPa; (K _s/T) _p =–0.024(0.005) GPa/K; and (/T) _p =–0.013(0.001) GPa/K. An important conclusion is thatK _s increases as the Fe/(Fe+Mg) ratio in olivine is increased.  相似文献   

Effects of onshore and offshore topography on sea breeze circulation: An observational study at eastern Attica,Greece     

M. Varvayanni  C. G. Helmis  G. T. Amanatidis  D. N. Asimakopoulos  J. G. Bartzis  A. Soilemes  K. H. Papadopoulos  H. D. Kambezidis 《Pure and Applied Geophysics》1993,140(4):681-720

Field measurements of wind, air temperature and humidity were taken at the eastern part of the Attika district in June 1991, to examine the topographic influences exerted on the local sea breezes. These influences are due either to the elongated Evia island, faced by the northern half of Attica coastline some tens of kilometers offshore, or to the coast-parallel range of Hymettos mountain, rising steeply 12 km onshore. The instrumentation consisted mainly of three tethered meteorological balloons released at characteristic sires (i.e., the coast, a location between shoreline and mountain foot and the mountain top) and three autographic ground-based anemometers operating at selected locations. Data from the ground-based and upper air stations of the Hellenic National Meteorological Service, as well as the diurnal weather maps were also obtained and analyzed. Observations were made under different synoptic wind and the latter was found to determine remarkably the significance of the topographic effects. A preliminary two-dimensional numerical approach was also made concerning the sea breeze capability to reach the Hymettos mountain top in the case of a weak opposing geostrophic flow.  相似文献   

Large-scale rheomorphic shear deformation in Miocene peralkaline ignimbrite E,Gran Canaria     

Philip T Leat  Hans-Ulrich Schmincke 《Bulletin of Volcanology》1993,55(3):155-165

the single ignimbrite cooling unit E (average thickness, 28 m; volume, ca. 30 km₃) forms the uppermost member of the Miocene Upper Mogán Formation on Gran Canaria. It is strongly chemically zoned from basal, first-erupted comendite (peralkaline rhyolite) to late-erupted trachyte, and, apart from an upper trachytic zone, it is densely welded. E was emplaced onto a surface inclined ca. 2–5° from the source caldera. Detailed mapping of key sections, up to 300 m long, exposed in barranco walls, ca. 10 km from the caldera margin, reveals structures that are interpreted to have been produced by rheomorphic deformation of the ignimbrite along shear zones. The shear zones formed within the lower-viscosity comenditic tuff. Extensional structures include mega-boudinage and decapitated sequences and compression resulted in sequence repitition by overthrusting. Mechanisms traditionally thought to be important during rheomorphic deformation of welded tuffs (compaction, lateral creep, folding, vertical density-driven diapirism) cannot account for these features, which reflect lateral (post-compactional) rheomorphic movement locally in excess of 800 m. We suggest the following sequence of events: emplacement of the several flow units; compaction, with little lateral movement; rheomorphic deformation. During and after compaction, layers of secondary porosity developed within the comenditic tuff, possibly where upward escape of gas was prevented by overlying, relatively impermeable layers of densely compacted ignimbrite. These structurally weak layers of high porosity subsequently acted as shear zones.  相似文献   

RADON DEPTH MIGRATION1     

S. T. HILDEBRAND  R. J. CARROLL 《Geophysical Prospecting》1993,41(2):229-240

A depth migration method is presented that uses Radon-transformed common-source seismograms as input. It is shown that the Radon depth migration method can be extended to spatially varying velocity depth models by using asymptotic ray theory (ART) to construct wavefield continuation operators. These operators downward continue an incident receiver-array plane wave and an assumed point-source wavefield into the subsurface. The migration velocity model is constrained to have longer characteristic wavelengths than the dominant source wavelength such that the ART approximations for the continuation operators are valid. This method is used successfully to migrate two synthetic data examples:

• 1 a point diffractor, and
• 2 a dipping layer and syncline interface model.

It is shown that the Radon migration method has a computational advantage over the standard Kirchhoff migration method in that fewer rays are computed in a main memory implementation.  相似文献   

用褶积滤波处理井水位对固体潮响应的滞后   总被引：2，自引：1，他引：1  

张昭栋  高玉斌 《地震》1993,(4):23-29

本文给出了一种用褶积滤波处理井水位对固体潮响应滞后的新方法。鲁07井水位观测资料用这种方法处理比一般回归方法的平均中误差少4.6mm。文中讨论了褶积滤波积分区间长度与水井含水层渗透系数的关系及褶积滤波比别尔采夫滤波的优越性。  相似文献   

新疆第四纪盐类矿产的形成和控制因素——兼论“高山深盆”成盐模式   总被引：1，自引：0，他引：1  

王得林 《新疆地质》1993,(1)

根据袁见齐教授“高山深盆”成盐模式,探讨新疆天山对第四纪盐类矿床的形成和控制作用,阐述了天山地貌、气候、水文特征与盐类矿产的分布规律和特征。认为“高山深盆”并非一定是四周环山的深盆,可以是某一高山与其间深盆或两侧盆地的有机组合。高山的屏障作用造成了垂直的气候分带,在潮湿多雨的山区利于成盐组份的析出并迁移到干旱少雨的闭流深盆中,形成盐类矿床。  相似文献   

大别杂岩中混合岩的矿物空间分布研究   总被引：2，自引：0，他引：2  

王江海 《岩石矿物学杂志》1993,12(3):243-250

介绍了矿物空间分布研究的基本原理及两种统计方法(接触频数法和线切法)。作者对混合岩矿物空间分布的研究表明:(1)前人提出的统计方法存在方法上的缺陷和应用上的局限性,作者推导出矿物接触类型的概率公式;(2)部分浅色体中矿物显示聚集分布的特征,而绝大部分的浅色体中矿物具有分散分布的特点。结合质量平衡和地球化学研究认为:大别杂岩中主体混合岩成因机制是重熔和交代作用。  相似文献   

Cesstibtantite—a geologic introduction to the inverse pyrochlores     

T. S. Ercit  P. Černý  F. C. Hawthorne 《Mineralogy and Petrology》1993,48(2-4):235-255

Summary The crystal structure of cesstibtantite has been solved from diffractometer data collected on samples from Leshaia, Russia and the Tanco pegmatite, Manitoba. Cesstibtantite from the Leshaia pegmatite (type locality) hasa 10.515(2) Å, space groupFd3m, composition Cs_0.31(Sb_0.57Na_0.31Pb_0.02Bi_0.01)_O.91(Ta_1.88Nb_0.12)₂(O_5.69[OH, F]_0.31)₆(OH, F)_0.69, Z 8; its structure was refined toR 3.8,wR 4.3% using 96 observed (F > 3[F]) reflections (MoK). Cesstibtantite from the Tanco pegmatite hasa 10.496(1) Å, space groupFd3m, composition (Cs_0.22K_0.01)_0.23(Na_0.45Sb_0.39Pb_0.14· Ca_0.06Bi_0.02)_1.06(Ta_1.95Nb_0.05)₂(O_5.78[OH,F]_0.22)₆(OH,F)_0.55,Z 8; its structure was refined toR 3.9w R 3.7% using 104 observed reflections. Cesstibtantite differs from the normal pyrochlores in that it contains significant amounts of very large cations such as Cs. As these cations are too large (^VIII[r] > 1.60 Å) for the conventional [8]-coordinated A site, they occupy the [18]-coordinated site, which normally contains monovalent anions. Natural cesstibtantite samples are non-ideal in that both Cs and monovalent anions occur at the site; thus cesstibtantite is intermediate to thenormal pyrochlores (with only monovalent anions at the site) and theinverse pyrochlores (with only large cations at the site).

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Cesstibtantit—eine geologische Einfiihrung in die inversen Pyrochlore

Zusammenfassung Die Kristallstruktur von Cesstibtantit wurde auf der Basis von Diffraktometerdaten von Proben von Leshaia, Russland and dem Tanco Pegmatit, Manitoba, gelöst. Cesstibtantit aus dem Leshaia Pegmatit (Typlokalität) hat a 10.515(2) Å, RaumgruppeFd3m, die Zusammensetzung CS_0.31(Sb_0.57Na_0.31Pb_0.02Bi_0.01)_0.91(Ta_1.88Nb_0.12)₂· (O_5.69OH, F_0.31)₆(OH, F)_0.69 Z 8; die Struktur wurde aufR 3.8,wR 4.3% verfeinert unter Benützung von 96 beobachteten Reflexen. Cesstibtantit vom Tanco Pegmatit hat a 10.496(1) Å, RaumgruppeFd3m, die Zusammensetzung (Cs_0.22K_0.01)_0.23(Na_0.45· Sb_0.39Pb_0.14Ca_0.06Bi_0.02)_1.06(Ta_1.95Nb_0.05)₂(O_5.78OH,F_0.22)₆(OH,F)_0.55,Z 8; seine Struktur wurde aufR 3.9wR 3.7% auf der Basis von 104 beobachteten Rettexen verfeinert. Cesstibtantit unterscheidet sich von normalen Pyrochloren insofern, als er signifikante Mengen von sehr großen Kationen, wie z.B. Cs enthält. Da these Kationen zu groß sind (^VIII r 1.60 Å) für eine konventionelle [8]-koordinierteA Stelle, nehmen she die [18]-koordinierten Positionen ein, welche normalerweise monovalente Anionen enthalten. Natürliche Cesstibtantitproben sind nicht ideal insofern als sowohl Cs als auch monovalente Anionen in der Position vorkommen. Somit ist Cesstibtantit intermediär zu den normalen Pyrochloren (mit nur monovalenten Anionen auf der Position) and den inversen Pyrochloren (mit ausschließlichen großen Kationen an der Position).

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