Biosorption of cadmium(II) from aqueous solution onto <Emphasis Type="Italic">Hydrilla verticillata</Emphasis>     

Ling-zhi Huang  Guang-ming Zeng  Dan-lian Huang  Li-feng Li  Chun-yan Du  Ling Zhang 《Environmental Earth Sciences》2010,60(8):1683-1691

Biosorption is an effective method to remove heavy metals from wastewater. In this work, the biosorption of Cd(II) onto Hydrilla verticillata was examined in aqueous solution with parameters of initial pH, adsorbent dosage, contact time, initial Cd(II) concentration, temperature, and co-existing ion. Linear Langmuir and Freundlich models were applied to describe the equilibrium isotherms, and both of the two models were fitted well. The monolayer adsorption capacity of Cd(II) was found to be 50 mg/g at pH 6 and 20°C. Dubinin–Radushkevich isotherm model was also applied to the equilibrium data. The mean free energy of adsorption (11.18 kJ/mol) indicated that the adsorption of Cd(II) onto H. verticillata might be carried out via chemical ion-exchange mechanism. Thermodynamic parameters, including free energy (∆G ⁰), enthalpy (∆H ⁰), and entropy (∆S ⁰) of adsorption, were also calculated. These results showed that the biosorption of Cd(II) onto H. verticillata was a feasible, spontaneous, and exothermic process in nature. Desorption experiments indicated that 0.01 mol/L EDTA and HNO₃ were efficient desorbents for the recovery of Cd(II) from biomass. IR spectrum analysis suggested that amido, hydroxyl, C=O and C–O could combine strongly with Cd(II). EDX spectrum analysis suggested that an ion exchange mechanism might be involved.  相似文献   

空心块体水沙动力及泥沙淤积特性研究     

侯仲荃  石进  王宪业  郭磊城  谢卫明  徐凡  黄明毅  何青 《海洋学报》2022,44(5):124-133

空心块体具有良好的阻水和促淤功能,近年来被广泛用于生态修复工程。本文结合水槽试验及Flow-3D数值模拟,分析了开敞型和半封闭型空心块体的阻水效应和泥沙淤积特性。结果表明:空心块体的开孔率对内部水流流速、紊动强度起主导作用,开孔率较小的半开敞型空心块体减速、制紊效果更强;开敞型和半封闭型空心块体近底层悬沙浓度分别增大56%和75%,两者均有利于促进泥沙在块体内部淤积,近底层水流紊动越强,泥沙淤积形态差异越大;空心块体所营造的低流速、泥沙微淤、内外连通的水沙环境是大型底栖生物的生境需求,半封闭型空心块体内部的低紊动水流结构更有利于大型底栖生物的栖息、繁衍。  相似文献   

HY-1C/D卫星中国海洋水色水温扫描仪几何定位方法     

刘建阳  毛志华  陶邦一  马力  朱乾坤  黄海清  刘建强  丁静 《海洋学报》2022,44(5):47-61

海洋一号C/D（HY-1C/D）卫星中国海洋水色水温扫描仪（Chinese Ocean Color and Temperature Scanner,COCTS）主要用于探测海洋水色、水温等要素,这些要素需要经过卫星资料处理才能获取,而几何定位是预处理的核心,直接影响这些要素的质量。COCTS具有114°视场角和四元逐点摆扫的特征,据此研究出一套完整的几何定位方法。从0级数据中提取卫星星历,利用插值法从中获取采样时间对应的卫星位置和速度,进而得到轨道（ORB）坐标系到地心旋转（ECR）坐标系的转换矩阵。基于四元逐点摆扫的特征,中心视矢量分别绕X轴、Y轴旋转相应角度,获得扫描行各采样点ORB视矢量,建立视矢量与地球交叉点关系模型,从而对根据波段数据绘制的遥感图像进行地理定位。本文使用插值法替代了传统需要6个轨道根数来计算卫星位置的复杂方法,同时直接计算ORB到ECR的转换矩阵,而不采用传统的两步转换方法。经过多组数据计算及定性定量验证,HY-1C/D COCTS几何定位结果一致;采样像元尺度效应导致从星下点到两侧边缘、从赤道到两极,误差逐渐增大,约在两个像元内。该方法满足一定的定位精度要求,可以用于COCTS的几何定位。  相似文献   

Hydrodynamic Response and Power Performance of A Heave and Pitch Buoy Wave Energy Converter Under Bimodal Ochi-Hubble Wave Spectrum     

HUANG Shu-ting  LIU Yan-jun  XUE Gang  XUE Yi-fan 《中国海洋工程》2022,36(1):28-37

In coastal sea areas with the bimodal Ochi-Hubble wave spectrum, such as parts of the China Sea and Indian Ocean,wave energy is the superposition of wind wave and swell. Traditional heaving buoy wave energy converters developed with narrowband wave spectrums suffer from big energy loss in these areas, leading to lower power absorption efficiency and higher generating costs. In contrast, multi-freedom buoy has different resonant frequencies and maximal power capture wave frequencies in different ...  相似文献   

Restoration of Ultimate Strength of Dented Hemispheres Under External Hydrostatic Pressure     

Huang  Chen  Zhang  Jian  Wang  Fang  Di  Chen-yang 《中国海洋工程》2022,36(3):500-507

China Ocean Engineering - This study aimed to restore the ultimate strength of dented stainless-steel hemispheres with a radius of 90 mm and a thickness of 0.86 mm. All of the hemispheres were...  相似文献   

空间视角下城乡物流网络的内涵、构成要素与研究框架     

王钊  李涛  黄文杰 《地理科学》2023,43(1):82-91

地理学视角的物流网络研究已成为物流科学领域的热点方向。从地理学的空间视角出发,在明确城乡物流网络理论来源和相关概念的基础上,对城乡物流网络的内涵、构成及研究框架进行梳理。基于研究,首先给出了城乡物流网络的定义,认为城乡物流网络的本质是旧的城市物流网络和乡村物流网络在空间上的延伸、衔接和提效。其次,从空间视角将城乡物流网络分解为节点、连线和域面3要素,指出网络各要素均出现了功能强化和更新,如节点的管理、衔接和经济社会功能强化;连线的联结功能和平衡功能出现,域面的协同组织、动态调整功能突出。最后,遵循地理学“格局-过程-机理-决策”的科学逻辑,提出“数据采集与融合、要素映射与解析、时空比较与分析、机理探究与优化”4个模块的城乡物流网络分析框架,为深刻揭示城乡物流网络结构及其演化机理提供基础。进一步指出未来应探讨城乡物流节点、连线、域面及网络的地区类型、区域适宜性及要素间相互作用机制,提炼适应不同区域、能有效提升要素流通效应的多尺度空间组织模式,加强对城乡要素流通系统的科学认知,科学支撑城乡地域融合发展实践。  相似文献   

UPLC-MS metabolomics provides insights into the differences between black- and white-shelled Pacific oysters Crassostrea gigas     

Chen  Xi  Jiang  Qiuyun  Song  Hongce  Li  Lingling  Xie  Chaoyi  Huang  Baoyu  Liu  Yaqiong  Zhang  Meiwei  Wei  Lei  Wang  Xiaotong 《中国海洋湖沼学报》2021,39(1):340-349

Journal of Oceanology and Limnology - A variety of shell colors are one of the most fundamental characteristics of molluscs, which have importantly ecological and economic significance. The Pacific...  相似文献   

Retrieving multi-scale climatic variations from high dimensional time-series MODIS green vegetation cover in a tropical/subtropical mountainous island     

CHANG Chung-te  WANG Hsueh-ching  HUANG Cho-ying 《山地科学学报》2014,11(2):407-420

【Title】
There are knowledge gaps in our understanding of vegetation responses to multi-scale climate-related variables in tropical/subtropical mountainous islands in the Asia-Pacific region. Therefore, this study investigated inter-annual vegetation dynamics and regular/irregular climate patterns in Taiwan. We applied principal component analysis （PCA） on 11 years （2001~2011） of high-dimensional monthly photosynthetically active vegetation cover （PV） derived from the Moderate Resolution Imaging Spectroradiometer （MODIS） and investigated the relationships between spatiotemporal patterns of the eigenvectors and loadings of each component through time and multi-scale climate-related variations. Results showed that the first five components contributed to 96.4% of the total variance. The first component （PC1, explaining 94.5% of variance） loadings, as expected, were significantly correlated with the temporal dynamics of the PV （r = 0.94）, which was mainly governed by regional climate. The temporal loadings of PC2 and PC3 （0.8% and 0.6% of variance, respectively） were significantly correlated with the temporal dynamics of the PV of forests （r = 0.72） and the farmlands （r = 0.80）, respectively. The low-order components （PC4 and PC5, 0.3% and 0.2% of variance, respectively） were closely related to the occurrence of drought （r = 0.49） and to irregular ENSO associated climate anomalies （r = -0.54）, respectively. Pronounced correlations were also observed between PC5 and the Southern Oscillation Index （SOI） with one to three months of time lags （r = -0.35 ~ -0.43, respectively）, revealing biophysical memory effects on the time-series pattern of the vegetation through ENSO-related rainfall patterns. Our findings reveal that the sensitivity of the ecosystems in this tropical/subtropical mountainous island may not only be regulated by regional climate and human activities but also be susceptible to large-scale climate anomalies which are crucial and comparable to previous large scale analyses. This study demonstrates that PCA can be an effective tool for analyzing seasonal and inter-annual variability of vegetation dynamics across this tropical/subtropical mountainous islandin the Pacific Ocean, which provides an opportunity to forecast the responses and feedbacks of terrestrial environments to future climate scenarios.  相似文献   

Linking Tarim Basin sea retreat (west China) and Asian aridification in the late Eocene   总被引：1，自引：0，他引：1  

R. Bosboom  G. Dupont‐Nivet  A. Grothe  H. Brinkhuis  G. Villa  O. Mandic  M. Stoica  W. Huang  W. Yang  Z. Guo  W. Krijgsman 《Basin Research》2014,26(5):621-640

The Tarim Basin in western China formed the easternmost margin of a shallow epicontinental sea that extended across Eurasia and was well connected to the western Tethys during the Paleogene. Climate modelling studies suggest that the westward retreat of this sea from Central Asia may have been as important as the Tibetan Plateau uplift in forcing aridification and monsoon intensification in the Asian continental interior due to the redistribution of the land‐sea thermal contrast. However, testing of this hypothesis is hindered by poor constraints on the timing and precise palaeogeographic dynamics of the retreat. Here, we present an improved integrated bio‐ and magnetostratigraphic chronological framework of the previously studied marine to continental transition in the southwest Tarim Basin along the Pamir and West Kunlun Shan, allowing us to better constrain its timing, cause and palaeoenvironmental impact. The sea retreat is assigned a latest Lutetian–earliest Bartonian age (ca. 41 Ma; correlation of the last marine sediments to calcareous nannofossil Zone CP14 and correlation of the first continental red beds to the base of magnetochron C18r). Higher up in the continental deposits, a major hiatus includes the Eocene–Oligocene transition (ca. 34 Ma). This suggests the Tarim Basin was hydrologically connected to the Tethyan marine Realm until at least the earliest Oligocene and had not yet been closed by uplift of the Pamir–Kunlun orogenic system. The westward sea retreat at ca. 41 Ma and the disconformity at the Eocene–Oligocene transition are both time‐equivalent with reported Asian aridification steps, suggesting that, consistent with climate modelling results, the sea acted as an important moisture source for the Asian continental interior.  相似文献   

汉江上游3200-2800aBP特大古洪水重建研究(英文)     

查小春  黄春长  庞奖励  周亚利 《地理学报(英文版)》2014,24(3):446-456

Palaeoflood hydrology study is a leading subject in global change study. Through field investigation in the upper reaches of Hanjiang River, palaeoflood slackwater deposits(SWD) were found in the bedrock gorges of the Yunxi reach. The results of field observation, laboratory analysis including particle-size distribution and magnetic susceptibility, and comparison with modern flood deposits, the SWD were identified as the most typical Holocene palaeoflood deposits of the Hanjiang River. By using stratigraphic correlation and OSL dating method, the palaeoflood event was dated to be 3200–2800 a BP at the turn from the middle to late Holocene. According to the palaeoflood peak stage and hydraulic parameters, the peak discharges of the palaeoflood were reconstructed as 48,830–51,710 m3/s by using the slope-area method. At same time, the flood peak discharges of 1983, 2005 and 2010 severe floods were reconstructed with the same method and hydraulic parameters in the same cross section. The error between the reconstructed and gauged discharges was 1.99%–4.21%. This showed that the reconstructed palaeoflood peak discharges were reliable. The flood peak discharge-frequency relationship at 10,000-year time scale was established by a combination of the gauged flood, historical flood and palaeoflood hydrological data. These results are very important for hydraulic engineering and flood mitigation on the Hanjiang River.  相似文献