Antimony speciation in saline hydrothermal fluids: A combined X-ray absorption fine structure spectroscopy and solubility study   总被引：2，自引：0，他引：2  

Gleb S. Pokrovski  Anastassia Yu. Borisova  Jean-Louis Hazemann  Marie Tella 《Geochimica et cosmochimica acta》2006,70(16):4196-4214

Solubility of senarmontite (Sb₂O₃, cubic) in pure water and NaCl-HCl aqueous solutions, and local atomic structure around antimony in these fluids were characterized using in situ X-ray absorption fine structure (XAFS) spectroscopy at temperatures to 450 °C and pressures to 600 bars. These experiments were performed using a new X-ray cell which allows simultaneous measurement of the absolute concentration of the absorbing element in the fluid, and atomic environment around the absorber. Results show that aqueous Sb(III) speciation is dominated by the complex in pure water, mixed Sb-hydroxide-chloride complexes in acidic NaCl-HCl solutions (2 m NaCl-0.1 m HCl), and by Sb-chloride species in concentrated HCl solutions (3.5 m HCl). Interatomic Sb-O and Sb-Cl distances in these complexes range from 1.96 to 1.97 Å and from 2.37 to 2.47 Å, respectively. These structural data, together with senarmontite solubility determined from XAFS spectra, were complemented by batch-reactor measurements of senarmontite and stibnite (Sb₂S₃, rhombic) solubilities over a wide range of HCl and NaCl concentrations from 300 to 400 °C. Analysis of the whole dataset shows that Sb(III) speciation in high-temperature moderately acid (pH > 2-3) Cl-rich fluids is dominated by mixed hydroxy-chloride species like Sb(OH)₂Cl° and Sb(OH)₃Cl⁻, but other species containing two or three Cl atoms appear at higher acidities and moderate temperatures (?300 °C). Calculations using stability constants retrieved in this study indicate that mixed hydroxy-chloride complexes control antimony transport in saline high-temperature ore fluids at acidic conditions. Such species allow for a more effective Sb partitioning into the vapor phase during boiling and vapor-brine separation processes occurring in magmatic-hydrothermal systems. Antimony hydroxy-chloride complexes are however minor in the neutral low- to moderate-temperature solutions (?250-300 °C) typical of Sb deposits formation; the antimony speciation in these systems is dominated by Sb(OH)₃ and potentially Sb-sulfide species.  相似文献   

Doppler Lidar Measurements of Vertical Velocity Spectra in the Convective Planetary Boundary Layer   总被引：1，自引：1，他引：0  

Marie Lothon  Donald H. Lenschow  Shane D. Mayor 《Boundary-Layer Meteorology》2009,132(2):205-226

We utilized a Doppler lidar to measure spectra of vertical velocity w from 390m above the surface to the top of the daytime convective boundary layer (CBL). The high resolution 2μm wavelength Doppler lidar developed by the NOAA Environmental Technology Laboratory was used to detect the mean radial velocity of aerosol particles. It operated continuously during the daytime in the zenith-pointing mode for several days in summer 1996 during the Lidars-in-Flat-Terrain experiment over level farmland in central Illinois, U.S.A. The temporal resolution of the lidar was about 1 s, and the range-gate resolution was about 30m. The vertical cross-sections were used to calculate spectra as a function of height with unprecedented vertical resolution throughout much of the CBL, and, in general, we find continuity of the spectral peaks throughout the depth of the CBL. We compare the observed spectra with previous formulations based on both measurements and numerical simulations, and discuss the considerable differences, both on an averaged and a case-by-case basis. We fit the observed spectra to a model that takes into account the wavelength of the spectral peak and the curvature of the spectra across the transition from low wavenumbers to the inertial subrange. The curvature generally is as large or larger than the von Kármán spectra. There is large case-to-case variability, some of which can be linked to the mean structure of the CBL, especially the mean wind and the convective instability. We also find a large case-to-case variability in our estimates of normalized turbulent kinetic energy dissipation deduced from the spectra, likely due for the most part to a varying ratio of entrainment flux to surface flux. Finally, we find a relatively larger contribution to the low wavenumber region of the spectra in cases with smaller shear across the capping inversion, and suggest that this may be due partly to gravity waves in the inversion and overlying free atmosphere.  相似文献   

Upcoming international events     

Anne Marie de Grosbois 《Environmental Earth Sciences》2010,60(3):671-676

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Upcoming international events  相似文献   

Reviews on books,internet and scientific media     

Anne Marie de Grosbois 《Environmental Earth Sciences》2010,61(2):441-442

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The role of climate variability and fire in early and mid Holocene forest dynamics of southern Sweden     

Annica Greisman  Marie‐José Gaillard 《第四纪科学杂志》2009,24(6):593-611

The objective of this study was to investigate the possible links between regional climate, fire and vegetation at the small spatial scale during the early and mid Holocene in southern Sweden using pollen, plant macrofossil and charcoal records from a small bog. The fire history was compared with climate reconstructions inferred from various proxy records in the study region. High fire activity is related to dry and warm climate around 8550, 7600, 5500–5100 and 4500 cal. a BC. Low fire activity ca. 6500–6000 and 4750 BC may correspond to the widespread ‘8.2 k event’ (ca. 6200 BC) recorded across the North Atlantic region, and a later, brief period of increased precipitation, respectively. The decrease in broadleaved trees culminating ca. 6500–6000 BC correlates with the ‘8.2 k event’. A long mid Holocene period with low fire activity (ca. 4350–1000 BC) agrees with the pattern emerging for Europe from the global charcoal database, and may correspond to generally wetter and cooler conditions. High fire activity ca. 8550 BC probably triggered the local establishment of Corylus. Warmer and drier conditions (and high fire activity) ca. 7600 BC might have favoured the establishment of Alnus, Quercus and Tilia. The fire‐adapted Pinus maintained important populations throughout the early and mid Holocene. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Reviews on books,internet and scientific media     

Anne Marie de Grosbois 《Environmental Earth Sciences》2010,61(4):881-882

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Experimental analysis of kaolinite particle orientation during triaxial path     

Mahdia Hattab  Jean‐Marie Fleureau 《国际地质力学数值与分析法杂志》2011,35(8):947-968

The goal of this study was to analyze the relation between the behaviour of a clayey material at the macroscopic scale and its microfabric evolution. This may lead to a better understanding of macroscopic strain mechanisms especially the contractancy and dilatancy phenomena. The approach proposed in this paper is based on the study of clay particles orientation by SEM picture analysis after different phases of triaxial loading. In the initial state of the samples (one‐dimensional compression), the SEM observations highlight a microstructural anisotropy with a preferential orientation of the particles normal to the loading direction. During isotropic loading, densification of the clayey matrix occurs related to a random orientation of particles indicated by the term ‘depolarization’. In the earlier stages of constant σ₃ drained triaxial path on slightly overconsolidated specimens, the microstructural depolarization seems to persist inside a macroscopic domain, in which only the volumetric strains due to the isotropic part of the stress tensor evolve. Then, a rotation mechanism of the particles towards preferred directions seems to be activated. The phenomenon appears directly linked to the evolution of the deviatoric part of the stress tensor. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Reviews on books, internet and scientific media     

Philip E. LaMoreaux  Anne Marie de Grosbois 《Environmental Geology》2008,56(3-4):809-810

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Long-Term Stability Of Geoidal Geopotential FromTopex/Poseidon Satellite Altimetry 1993–1999     

Burša  Milan  Kenyon  Steve  Kouba  Jan  Müller  Achim  Raděj  Karel  Vatrt  Viliam  Vojtíšková  Marie  Vítek  Vojtěch 《Earth, Moon, and Planets》1999,84(3):163-176

The TOPEX/POSEIDON (T/P) satellite altimeter data from January 1, 1993to October 24, 1999 (cycles 11–261) was used for investigating thelong-term variations in the geoidal geopotential W₀ and/orin the geopotential scale factor R₀ = GM/W₀ (GM is theadopted geocentric gravitational constant). The mean valuesdetermined for the whole period covered are: W₀ =(62 636 856.161 ± 0.002) m² s^-2, R₀ =(6 363 672.5448 ± 0.0002) m. The actual accuracy is limited bythe altimeter calibration error (2–3 cm) and it isestimated to be about ± 0.5 m² s^-2 (± 5 cm).The yearly variations of the above mean values are at the formalerror level. No long-term trend in W₀, representing the oceanvolume change, was found for the seven years period 1993–9 on thebasis of T/P altimeter (AVISO) data. No sea surface topography modelwas used in the solution. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Incipient shortening of a passive margin: the mechanical roles of continental and oceanic lithospheres   总被引：1，自引：0，他引：1  

Marie Leroy  Olivier Dauteuil  Peter R. Cobbold 《Geophysical Journal International》2004,159(1):400-411

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