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The assessment of copper and chromium concentrations in plants requires the quantification of a large number of soil factors that affect their potential availability and subsequent toxicity and a mathematical model that predicts their relative concentrations in plants. While many soil characteristics have been implicated as altering copper and chromium availability to plants in soil, accurate, rapid and simple predictive models of metal concentrations are still lacking for soil and plant analysis. In the current study, an artificial neural network model was developed and applied to predict the exposure of bean leaves (BL) to high concentrations of copper and chromium versus some selected soil properties (pH, soil electrical conductivity and dissolved organic carbon). A series of measurements was performed on soil samples to assess the variation of copper and chromium concentrations in BL versus the soil inputs. The performance of the artificial neural network model was then evaluated using a test data set and applied to predict the exposure of the BL to the metal concentration versus the soil inputs. Correlation coefficients of 0.99981 and 0.9979 for Cu and 0.99979 and 0.9975 for Cr between the measured and artificial neural networks predicted values were found, respectively, during the testing and validation procedures. Results showed that the artificial neural network model can be successfully applied to the rapid and accurate prediction of copper and chromium concentrations in BL.  相似文献   
2.
The goal of this study was to analyze the relation between the behaviour of a clayey material at the macroscopic scale and its microfabric evolution. This may lead to a better understanding of macroscopic strain mechanisms especially the contractancy and dilatancy phenomena. The approach proposed in this paper is based on the study of clay particles orientation by SEM picture analysis after different phases of triaxial loading. In the initial state of the samples (one‐dimensional compression), the SEM observations highlight a microstructural anisotropy with a preferential orientation of the particles normal to the loading direction. During isotropic loading, densification of the clayey matrix occurs related to a random orientation of particles indicated by the term ‘depolarization’. In the earlier stages of constant σ3 drained triaxial path on slightly overconsolidated specimens, the microstructural depolarization seems to persist inside a macroscopic domain, in which only the volumetric strains due to the isotropic part of the stress tensor evolve. Then, a rotation mechanism of the particles towards preferred directions seems to be activated. The phenomenon appears directly linked to the evolution of the deviatoric part of the stress tensor. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
3.
This study aims at investigating the cementation of marine sediments from the Gulf of Guinea by using physicochemical analysis. In order to highlight the presence of cementation in the sediments, three conventional consolidation tests were conducted on intact and remoulded samples. Mercury intrusion porosimetry analyses were then carried out on the specimens taken from samples after consolidation tests. Several physicochemical experimental techniques were used to analyze these cementations, such as cation exchange capacity analysis, batch test, scanning electron microscope imaging coupled with EDS chemical analysis, and thermal analysis. The results seem to indicate that the cementation of these sediments is predominated by the presence of smectite gel between clay aggregates (clusters). Finally, a conceptual sediment microstructural model is proposed to describe the cementation.  相似文献   
4.
Soil losses and siltation of the hydrological system (watershed–dam) of K’sob were obtained using direct and indirect methods. The Wadi K’sob watershed of 1,484 km2, average slope of 0.14, and average elevation of 1,060 m is located in a semiarid climate. The average annual rainfall is 341 mm and the mean annual water discharge is 0.89 m3/s. Data from the Medjez gauging station located 6 km upstream of the dam, are the daily liquid flow and instantaneous concentrations of suspended sediments. Over a time period from 1973 to 2010, the relationship between water and sediment discharges is quantified by the equation: Q s?=?5.6 Q 1.31. Thus, in view of the availability data on a daily scale, the assessment of soil erodibility of the K’sob watershed was used to estimate specific soil losses of 203 t?km?2?year?1or 301,000 t eroded annually from the K’sob basin. The bathymetric measurements of the sediment volumes deposited in the K’sob dam, has quantified the annual siltation of 0.8 hm3, corresponding to an average erodibility of the K’sob watershed of 809 t?km?2?year?1. However, when adding the volume of sediment removed by the dredging operation and de-silting by the valves during heavy floods, the value of soil losses is 2,780 t?km?2?year?1. The indirect assessment of soil erodibility of the basin was obtained by applying two models: the quantitative geomorphological analysis (QGA) and PISA model (prediction of silting in the artificial reservoirs, in Italian: Previsioni dell’Interimento nei Serbatoi Artificiali) using physical and climatic factors in the watershed. The obtained results by QGA method underestimate specific soil losses of 524 t?km?2?year?1. The PISA model gives a value of 2,915 t?km?2?year?1, which is close to the value obtained by bathymetric measurements. This study concludes that PISA model is most suitable to estimate soil loss and siltation of the K’sob hydrological system.  相似文献   
5.
Zhao  Dan  Hattab  Mahdia  Yin  Zhen-Yu  Hicher  Pierre-Yves 《Acta Geotechnica》2019,14(4):1003-1019
Acta Geotechnica - This paper studies the dilative behavior of clay during drained creep along triaxial tests under constant mean effective stress, where the volumetric strain is caused by the sole...  相似文献   
6.
This study strives to analyze the compressibility of deep water marine sediments originating from the Gulf of Guinea. Our approach is multi-scaled and, on the macroscopic level, based on two equations which link the overburden effective stress with the liquidity index, the Biarez & Favre equation on the one hand, and the Burland equation on the other hand (after calculation of the ICL expression as a function of the IL parameter). On the local level, the evolution of the microstructures is analysed and compared with GoG remoulded clay. Two additional observation techniques have been used, the scanning electron microscope and the mercury intrusion porosimetry.  相似文献   
7.
The goal in this research was to analyze the effects of decompression and suction on the formation of cracks in a clay rock from the Andra (French National Radioactive Waste Management Agency) site at Bure (Meuse–Haute-Marne, France). The article investigates the relationship between the changes in the hydromechanical properties and the changes in microstructure and porosity. Concerning the effect of decompression, at the macroscopic scale, the study highlighted an important effect on the elastic modulus and permeability, but little effect at the microscopic scale except an evolution of mineralogy related to the oxidation of pyrite often present in layers where cracks develop. Concerning the effect of suction, at the macroscopic level, the results showed that, on drying path, the change in the properties of the material was very small, whereas, on wetting path, a large decrease in tensile strength and gas permeability was observed. At the microscopic level, observations with SEM and ESEM, and measurements with MIP, highlighted the evolution of microstructural organization as a function of suction, and the propagation and enlargement of cracks on wetting path, rather than on drying path.  相似文献   
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