The origin of the polycyclic aromatic hydrocarbon (PAH) perylene in sediments and petroleum has been a matter of continued debate. Reported to occur in Phanerozoic organic matter (OM), fossil crinoids and tropical termite mounds, its mechanism of formation remains unclear. While a combustion source can be excluded, structural similarities to perylene quinone-like components present in e.g. fungi, plants, crinoids and insects, potentially suggest a product-precursor relationship. Here, we report perylene concentrations, 13C/12C, and D/H ratios from a Holocene sediment profile from the Qingpu trench, Yangtze Delta region, China. Perylene concentrations differ from those of pyrogenic PAHs, and rise to prominence in a stratigraphic interval that was dominated by woody vegetation as determined by palynology including fungal spores. In this zone, perylene concentrations exhibit an inverse relationship to the lignin marker guaiacol, D/H ratios between −284‰ and −317‰, similar to the methoxy groups in lignin, as well as co-variation with spores from wood-degrading fungi. 13C/12C of perylene differs from that of land plant wax alkanes and falls in the fractionation range expected for saprophytic fungi that utilise lignin, which is isotopically lighter than cellulose and whole wood. During progressive lignin degradation, the relative carbon isotopic ratio of the perylene decreases. We therefore hypothesise a relationship of perylene to the activity of wood-degrading fungi. To support our hypothesis, we analysed a wide range of Phanerozoic sediments and oils, and found perylene to generally be present in subordinate amounts before the evolutionary rise of vascular plants, and to be generally absent from marine-sourced oils, few exceptions being attributed perhaps to a contribution of marine and/or terrestrial-derived fungi, anoxia (especially under marine conditions) and/or contamination of core material by fungi. A series of low-molecular-weight aromatic quinones bearing the perylene-backbone were detected in Devonian and Cretaceous sediments, potentially representing precursor components to perylene. 相似文献
Natural Hazards - Karachi is Pakistan’s largest city with population exceeding 18 million and is amongst the top five most congested cities in the world. Karachi has experienced no earthquake... 相似文献
Natural Hazards - An environmental variation has caused Pakistan an alarming portrait of vulnerability in flood disasters. The government has focused on a number of realistic actions, heartening... 相似文献
Ocean Science Journal - Blooms of the moon jellyfish (Aurelia coerulea) have been responsible for huge economic losses and environmental disruptions in oceans around the world. The mass occurrence... 相似文献
Incised valleys form excellent stratigraphic pinch-out traps. Traditional seismic data analysis techniques fail to predict quantitatively the porous and low-velocity sand-fills for incised valleys. The 3D quantitative seismic inverted porosity–velocity (3DQSIPV) analysis was applied in the Indus Basin, SW Pakistan. The reflection strength attribute better portrayed the reservoir sandstone and faults compared to seismic amplitude attribute. The sweetness-based continuous wavelet transform authenticated the development of the stratigraphic play. The 17 Hz amplitude delineated the non-porous seal and porous reservoirs of sand-filled incised valley and strand plain, and faults. The integrated model of seismic attributes categorizes the reservoir and seal constituents. The petrophysical modeling corroborated the gas-bearing “sweet-spots” within the stratigraphic-based dynamical system. The facies modeling predicted the for coarse-grained sandstone and fine-grained shales, depositional environments, fluctuations of sea level and their impacts on the overall development of stratigraphic plays. The predicted density and P-wave velocity for the sandstone-filled incised valley of the lowstand system tract were?~?1.4–1.75 g/cc and?~?3217–3802 m/s, respectively. The predicted density and P-wave velocity for the sealing shales facies of strand plain of transgressive system tract were?~?1.9–2.1 g/cc and 2.55–2.7 g/cc and 3900–4700 m/s, respectively. The 3DQSIPV predicted?>?25% porosity and?~?3300 m/s velocity of reservoirs in the west. The eastern zones shows?<?12% porosity and high velocity of?~?4580 m/s. Cross-plots of porosity, velocity, and thickness showed correlation coefficients of R2?>?0.90 for inverted velocity. This workflow may serve as an analogue for the remaining oil and gas fields of the Indus Basins of Pakistan and similar geological settings of divergent plate margins.
The present study aims at the assessment of six satellite rainfall estimates (SREs) in Pakistan. For each assessed products, both real-time (RT) and post adjusted (Adj) versions are considered to highlight their potential benefits in the rainfall estimation at annual, monthly, and daily temporal scales. Three geomorphological climatic zones, i.e., plain, mountainous, and glacial are taken under considerations for the determination of relative potentials of these SREs over Pakistan at global and regional scales. All SREs, in general, have well captured the annual north-south rainfall decreasing patterns and rainfall amounts over the typical arid regions of the country. Regarding the zonal approach, the performance of all SREs has remained good over mountainous region comparative to arid regions. This poor performance in accurate rainfall estimation of all the six SREs over arid regions has made their use questionable in these regions. Over glacier region, all SREs have highly overestimated the rainfall. One possible cause of this overestimation may be due to the low surface temperature and radiation absorption over snow and ice cover, resulting in their misidentification with rainy clouds as daily false alarm ratio has increased from mountainous to glacial regions. Among RT products, CMORPH-RT is the most biased product. The Bias was almost removed on CMORPH-Adj thanks to the gauge adjustment. On a general way, all Adj versions outperformed their respective RT versions at all considered temporal scales and have confirmed the positive effects of gauge adjustment. CMORPH-Adj and TMPA-Adj have shown the best agreement with in situ data in terms of Bias, RMSE, and CC over the entire study area. 相似文献
The initial collision between Indian and Asian continents marked the starting point for transformation of land-sea thermal contrast, uplift of the Tibet-Himalaya orogen, and climate change in Asia. In this paper, we review the published literatures from the past 30 years in order to draw consensus on the processes of initial collision and suturing that took place between the Indian and Asian plates. Following a comparison of the different methods that have been used to constrain the initial timing of collision, we propose that the tectono-sedimentary response in the peripheral foreland basin provides the most sensitive index of this event, and that paleomagnetism presents independent evidence as an alternative, reliable, and quantitative research method. In contrast to previous studies that have suggested collision between India and Asia started in Pakistan between ca. 55 Ma and 50 Ma and progressively closed eastwards, more recent researches have indicated that this major event first occurred in the center of the Yarlung Tsangpo suture zone (YTSZ) between ca. 65 Ma and 63 Ma and then spreading both eastwards and westwards. While continental collision is a complicated process, including the processes of deformation, sedimentation, metamorphism, and magmatism, different researchers have tended to define the nature of this event based on their own understanding, an intuitive bias that has meant that its initial timing has remained controversial for decades. Here, we recommend the use of reconstructions of each geological event within the orogenic evolution sequence as this will allow interpretation of collision timing on the basis of multidisciplinary methods. 相似文献