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The major elements, rare earth elements (REE) and trace elements of four basalt samples from central and western Pacific ferro- manganese crust provinces have been analyzed using chemical methods and ICP - MS, respectively. The results indicate that the samples have been extensively altered and that the contents of their major elements have changed significantly. However, the similarity of REE partition patterns and trace element contents of basalt samples to those of fresh oceanic island basalts (OIB) indicate that the basalt samples originated as OIB. Because of low-temperature alteration, the contents of A1203 , Fe203 , MnO, K20 and P205 increased, while MgO and FeO decreased. Active components, such as magnesium and iron, were leached from OIB resulting in the relative enrichment of SiO2. The leaching of active components can cause the relative enrichment of REE, while the precipitation of LREE-rich ferromanganese oxides in vesicles and fissures not only causes an increase of REE contents, but also induces "fractionation" of LREE and HREE. Based on the enrichment mechanism of REE contents, the theoretical quantities of precipitated ferromanganese oxides and the depleted quantities of active components are calculated : the depleted quantities of active components for the unit mass of fresh basalts vary in the range of 0.15 ~ 0. 657, and the precipitated quantities of ferromanganese oxides for the unit mass of fresh basahs vary in the range of 0. 006 ~ 0. 042. Of the major elements, the two most depleted are iron, and magnesium, with 18.28% ~ 70.95% of iron and 44.50% ~ 93.94% of magnesium in the fresh basalts was leached out. Theoretical calculation and geochemistry results both indicate that low-temperature alteration of basalts can supply abundant amount of metals to seawater, and may play an important role in ocean metal circulation. 相似文献
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稀土元素Ce对雨生红球藻生长及虾青素积累影响的研究 总被引:2,自引:0,他引:2
采用反相高效液相色谱分析法(RP-HPLC)研究了稀土元素铈(Ce^3+)对雨生红球藻(Haematococcus pluvialis)生长及虾青素积累的影响。结果表明,低质量浓度的Ce^3+对微藻生长和虾青素积累均具有明显的促进作用,当Ce^3+的质量浓度为0.1mgm时,对藻生长的促进效果最佳,细胞密度较对照组提高34%;当Ce^3+的质量浓度为1mg/L时,虾青素质量分数可达到细胞干质量的3.2%,较对照组提高167%。此外,高质量浓度Ce^3+的对雨生红球藻有抑制作用,当Ce^3+的质量浓度高于40mgm时,红球藻的生长完全被抑制,虾青素质量分数也明显降低。 相似文献
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By tracking and monitoring the profile configuration, topography, and hydrodynamic factors of an artificial cobble beach in Tianquan Bay, Xiamen, China over three consecutive years after its completion, we analyzed the evolution of its profile configuration and plane morphology, and its storm response characteristics. The evolution of the profile configuration of the artificial cobble beach in Tianquan Bay can be divided into four stages. The beach was unstable during the initial stage after the beach nourishment the profile configuration changed obviously, and an upper concave composite cobble beach formed gradually, which was characterized by a steep upper part and a gentle lower part. In the second stage, the cobble beach approached dynamic equilibrium with minor changes in the profile configuration. At the third stage the beach was in a high-energy state under the influence of Typhoon Meranti, and the response of the artificial cobble beach differed significantly from that of the low-tide terrace sandy beach. Within a short time, there was net onshore transport of cobbles in the cross-shore direction. The beach face was eroded, the beach berm was accumulated, and the slope of the beach was steepened considerably. In the alongshore direction, there was notable transport of cobbles on the beach from east to west along the shore, and the total volume of the beach decreased by 4.5×103 m~3, which accounted for 50% of the total amount of beach volume lost within three years. The fourth stage was the restoration stage after the typhoon, characterized by a little gentler profile slope and the increase in width and the decrease in height of beach berm. Because of the action of waves and the wave-driven longshore current caused by the specific terrain and landform conditions along the coast(e.g., coastal headlands, near-shore artificial structures, and reefs), the coastline of the artificial cobble beach gradually evolved from being essentially parallel to the artificial coast upon completion to a slightly curved parabolic shape, and three distinct erosion hotspots were formed on the west side of the cape and the artificial drainpipe, and the reefs. Generally, the adoption of cobbles for beach nourishment on this macro-tidal coast beach with severe erosion has yielded excellent stability and adaptability. 相似文献
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主体功能区规划已上升为国家制度和战略,对中国长期空间发展格局优化与再组织将发挥积极的引导和约束作用。从地域性角度出发,探寻主体功能区发生性(形成与演化)和反馈性(识别与规划)时空机理与规律是地理学具有时代意义的重要科学问题。以重庆市为例,通过国土空间开发条件综合评价,识别了主体功能区划分的适宜性空间格局。基于对西南山区发展约束条件的基本认识,提出了地域主体功能空间分异的主导性约束假设,设定地形和区位为原生性主导因素,验证了其与区划指标系统的定量关联性,以此为基础解析了主导因素约束机理并提出了地域主体功能区的空间稳定性机制。研究发现:①开发与保护适宜性识别结果的格局指向清晰。城市化适宜的区域主要集中于都市区和部分周边区县,区域副中心(万州和黔江)适宜性也相对较高。生态保护适宜的区域集中于渝东北秦巴山区及部分三峡库区区县,同时包括渝东南武陵山区所在区县。②地形和区位因子在本区域对主体功能区的识别与形成具有主导约束作用。回归分析显示,主体功能区划指标与地形因子相关性水平达到显著的超过70%,区位因子超过40%;两者综合后与区划标志变量(A、B指数)的相线性相关拟合度R2均超过0.8;地理探测器发现,地形和区位因子对区划指标的约束性分别有9个和7个达到0.05显著性水平,对A、B指数的解释度分别约为70%和60%,两者叠加后,约束水平全部达到显著,对A、B指数的解释度在90%左右。③空间稳定性机制表现为两个方面,其一是基于主导因素约束的稳定性传递机制,称为客观稳定性;其二是基于指标体系的局域相对性和算法的内部抵消机制,称为主观稳定性。两种机制的协同性验证了区划技术系统的地域适应性和科学性。 相似文献