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21.
Chantal Guillard Hervé Delprat Can Hoang-van Pierre Pichat 《Journal of Atmospheric Chemistry》1993,16(1):47-59
The photodegradation of naphthalene (NPH), chosen as a model of polynuclear aromatic pollutants, has been studied in the presence of a layer of four water-insoluble inorganic solids which can be found in the troposphere (TiO2, Fe2O3, muscovite, and a fly ash sample). Direct photolysis of NPH is negligible at >340 nm. Dark adsorption of NPH on TiO2 (mainly anatase, nonporous, 50 m2 g–1) at 293 K corresponds to a surface coverage ofca. 50% at equilibrium. Under these conditions (saturated surface), the stationary-state photocatalytic degradation reaches 0.4 molecule nm–2 h–1 (>340 nm, radiant fluxca. 22 mW cm–2). Dioxygen is required and its partial pressure in air is such that the degradation is zero order in O2. Water vapor markedly increases the rate. The other particulates have also an effect, less important than that of TiO2, however quite noticeable with respect to surface area unit for the fly ash sample which contains 3.2% Fe2O3. Apart from 1,4-naphthoquinone, which is the main intermediate product in all cases, 2-naphthol, phthalide, phthaldialdehyde, phthalic acid, acetophenone, benzaldehyde, benzoic acid are also formed on dry TiO2. Depending on their volatility, these compounds are transferred to the gas phase or remain principally adsorbed on the solid particles where they are further transformed. For instance, phthalic acid (or anhydride) and benzoic acid are generated from 1,4-naphthoquinone. Degradation mechanisms are briefly discussed. 相似文献
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A Strontium and Neodymium Isotopic Investigation of the Fongen--Hyllingen Layered Intrusion, Norway 总被引:1,自引:0,他引:1
The FongenHyllingen Intrusion, situated 60 km SE of Trondheim,Norway, is a synorogenic layered mafic intrusion of Caledonianage . The intrusion is divided into four evolutionary stages based on cryptic variations: StageIa basal reversal; Stage IIunchanged mineral chemistryor slight normal evolution; Stage IIIa gradual regression;Stage IV a strong normal fractionation trend Magma replenishmentdominated during most of the crystallization, i.e. during StagesI, II and III Replenishing magma was more dense than resident,evolved magma, and continuing influx eventually caused a compositionallystratified magma column to form. Cryptic lateral variation isan important feature in the southern part of the complex andformed by in situ crystallization from a stratified magma alongan inclined floor, where modal layering formed parallel to thecrystallization front. Initial Sr- and Nd-isotopic ratios inthe cumulates vary as a result of assimilation of country rockand subsequent mixing between uncontaminated, replenishing magmaand contaminated, resident magma. The parental magma had a moderatelydepleted isotope composition, relative to Bulk Earth, with Nd=584and Sri=070308, whereas the main contaminant was a partialmelt of metapelitic country rock with Nd=-874 and Sri=07195(Sri is the initial 87Sr/86Sr). Sri in the analysed cumulatewhole-rock samples ranges from 070308 to 070535 and initialNd ranges from. 158 to 584. There is a strong correlationbetween mineralogical composition and isotopic trends in mostof the cumulates: the most primitive samples are the least contaminated,as reflected by relatively high ed and low Sr,, and more evolvedsamples have progressively lower eNi and higher Sry A gradualregression of several hundred metres thickness characterizesStage III; stratigraphically upwards mineral compositions becomemore primitive and isotope compositions more depleted (higherNd and lower Sri), implying a process of. progressive mixing-inof replenishing, primitive and uncontaminated magma. Magma influxin Stage III took place by fountaining, whereas magma additionwas more tranquil in the earlier stages. The fountaining influxentrained resident, relatively evolved and contaminated magma,resulting in a hybrid magma which ponded at the floor. Duringprolonged magma addition with concomitant crystallization, thelowermost magma layer was replaced by progressively more primitivehybrid magma, creating a gradual regression in the crystallizingcumulate sequence. A detailed two-dimensional study revealslateral variations in mineral compositions both at the baseand top of Stage III, whereas lateral variations in Sr- andNd-isotopic compositions are present at the top, but not atthe base. This implies that the lowest crystallizing part ofthe magma column was essentially isotopically homogeneous, butcompositionally stratified, before influx in Stage III. Isotopicgradients in the magma were strong close to the roof, wheremost of the assimilation occurred, and decreased downwards,merging into isotopically homogeneous magma. This stratifiedsystem was destroyed by turbulent mixing between replenishingand resident magma during fountaining influx in Stage III, anda new stratification was established with both an isotopic anda compositional gradient. After the final influx, crystallizationcontinued in an essentially closed system, in which the remainingmagma column eventually became homogenized, as magma layersmixed when their densities converged owing to release of buoyant,residual liquid during fractional crystallization.
Corresponding author 相似文献
23.
Spectra of Hα, Hβ and Hδ have been taken under good seeing conditions with the vacuum tower telescope of Sacramento Peak Observatory. Intensity curves are given at various wavelengths in these lines to permit further comparison with a theoretical model. Moreover, considering in each case the range of height in which the lines are almost optically thin and using a few approximations, the following results are derived: between 2000 and 6000 km above the limb the average thermal + turbulent velocity of the atoms is found to increase from 20 km s?1 to 30 km s?1 and the mean number of hydrogen atoms per cm3 in level 2 is given by $$\log n_2 {\text{ = }}4.5{\text{ }} - {\text{ 0}}{\text{.00056(}}z - 2000)$$ z being the altitude above the limb in km. For line profile computations a new interpolation formula is presented; it gives good profiles with a small number of scans, saving microphotometer time. 相似文献
24.
Many studies have argued for the contribution of at least three components, namely the mantle wedge, the subducted oceanic crust, and its sediment cover, to describe the geochemistry of island arc volcanics. However, isotope correlations reflecting a simple binary mixing can be observed at the scale of a single arc island or volcano. Here we investigate the possibility that these trends reflect pseudo-binary mixing relationships in a three-component system. We present a simplified, two-stage model for the systematic isotope modelling of a cogenetic suite of arc lavas. This includes metasomatism of portions of the mantle wedge by hydrous phases released from the down-going oceanic crust, and sediments, followed by progressive mixing and melting. A consequence of this model is that it leads to a two end-member mixing process from the mantle wedge, oceanic crust, and sediment components. To solve the model we reduce it to a step-by-step procedure combined with a Monte-Carlo simulation. The procedure consists of: (i) producing a large number of random values on each variable of the model; (ii) using the computed values to calculate the isotopic compositions of lavas; and (iii) comparing the obtained isotopic compositions with measured data. Applied to a new set of Sr, Nd, and Pb isotope data for volcanics (basalts, basaltic andesites, trachybasalts, and basaltic trachyandesites) from Merapi volcano (Java island, Sunda arc), the model successfully reproduces the binary mixing relationships previously documented for the medium-K and high-K lava series from this volcano, thus giving further support to the hypothesis that this distinction is inherited from the primary magmas and primarily reflects a property of the mantle source. The results allow identification of a set of numerical values for bulk partition coefficients (solid/hydrous fluid, and solid/H2O-rich melt) and variables (e.g., the mass ratio between the metasomatizing phase and the mantle wedge), which can be used for quantitative arc-lava petrogenetic calculations. They also require a direct relationship between dehydration of the slab and melting of the metasomatized mantle wedge. Finally, our evaluation shows that for isotope modelling of the Merapi lavas, the two-stage procedure is controlled more by the considered source components (mantle wedge, oceanic crust, sediments, and their derivatives) than by the various processes involved (dehydration, melting, and mixing). 相似文献
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Review: Microbial biocenoses in pristine aquifers and an assessment of investigative methods 总被引:2,自引:6,他引:2
The current knowledge of microbial biocenoses (communities) in pristine aquifers is presented in a review, which also discusses their relevance for questions of groundwater protection. Aquifers are heterogeneous on all scales and structured in a variety of habitats. The void spaces in many aquifers are small. The biocenoses are thus predominantly composed of microorganisms and, often, microinvertebrates. Larger voids and macroorganisms occur in karst cavities. Due to the absence of light, the biocenoses depend on chemical energy resources, which are, however, scarce in non-contaminated groundwater. The microorganisms thus show small cell sizes, low population densities and reduced activity; they developed specific strategies to survive oligotrophic conditions. The review also discusses the impact of contamination on the biocenoses, and the potential use of the biocenoses or specific organisms as indicators for groundwater quality, and the limits of this approach. Bacteria are either planktonic or attached to aquifer material, which requires both fluid and solid phase sampling. Most groundwater bacteria are viable but non-culturable. Consequently, cultivation techniques give an incomplete picture of the biocenoses, while methods from molecular microbiology provide genetic fingerprints of the entire community. Different analytical methods are available to count microorganisms, identify species, characterise microbial diversity, and measure activity. 相似文献
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The main result of this work is to show that macroseismic intensity decay with distance strongly depends on the epicentral intensity. An attenuation law that takes this parameter into account is proposed for Metropolitan France, from the analysis of SISFRANCE macroseismic database. Such a model significantly reduces the difference between observed and theoretical intensities. A map of the attenuation variations is also set up for Metropolitan France. No major site effects are observed, but at a broad scale, young Alpine regions display a stronger attenuation than old Hercynian regions. To cite this article: P. Arroucau et al., C. R. Geoscience 338 (2006). 相似文献
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