Kinetics of copper desorption from soils as affected by different organic ligands     

E. A. Elkhatib Ph.D.  A. M. Mahdy Ph.D.  M. E. Saleh Ph.D.  N. H. Barakat M.Sc. 《International Journal of Environmental Science and Technology》2007,4(3):331-338

Desorption of Cu and low molecular weight dissolved organics are the primary factors that impact fate and transport of Cu in soils. To improve predictions of the toxicity and threat from Cu contaminated soil, it is critical that time-dependent desorption behavior be understood. In this paper, the effect of organic ligands citrate, malate, and succinate on the kinetics of Cu desorption from contaminated soils varying widely in soil characteristics was investigated at 25° C and the soils used were referred to as clay, calcareous and sandy soils. The amount of Cu released by the used organic ligands varied greatly with physicochemical properties of the soils. The rate of Cu release by different extractants was in the order citric > malic > succinic, which was consistent with the stability constants of Cu complexes with these ligands. The modified Freundlich and the Elovich and Parabolic diffusion models were used to describe dsorption of Cu²⁺ from the three studied soils as affected by the organic ligands. All of the models fit the data well with correlation coefficients ranging from 0.83 to 1.00 (P < 0.01). Each Model has a set of assumptions for the different physical and chemical properties of the systems to which they are being applied. The uses of these equations yield different magnitudes for the calculated variable, but the relationships between the soil + organic ligands and their effect (i.e., increase or decrease) on these variables are the same. Such information is critical, since Cu is used in a variety of industrial and manufacturing processes and is one of the most common contaminants found at hazardous waste sites.  相似文献   

Geology and rare-earth element geochemistry of highly evolved, molybdenite-bearing granitic plutons, Southeastern Desert, Egypt     

Gehad M. Saleh 《中国地球化学学报》2007,26(4):333-344

The field relations, mineralogy, and major and trace elements (including REE analyses of whole-rock samples and minerals) of granites and their associated molybdenite uranium mineralized aplites in Southeastern Desert, Egypt, have been studied. The granites are leucocratic and mostly peraluminous in nature with muscovite increasing at the expense of biotite. The chemical and mineralogical characteristics of the granitic rocks indicate that their melts originated from the LILE-enriched mantle wedge by partial melting and are contaminated by crustal melts, followed by thermogravitational processes. Leucogranites with higher Na2O/K2O ratios from Um Dargag and Um Maiat crystallized under H2O-saturated equilibrium conditions in which the exsolved vapor continuously migrated away. The REE patterns of the granites studied are characterized by LREE enrichments and negative Eu anomalies. In comparison, the potassic aplites and the more sodic leucogranites are depleted in LREE, enriched in HREE and show more remarkable negative Eu anomalies. Allanite and monazite are the most important REE carriers in the granites. These minerals are strongly enriched in LREE, whereas fluorite and xenotime, which are more abundant in the aplites, are enriched in HREE. The average Lu/Ce ratio represents the fractionation trend with respect to HREE. It is 0.71 for radioactive fluorite, and it increases to 1.22 for non-radioactive fluorite. The high REE contents of molybdenite represent re-deposition of the mobilized Mo and REE. Due to the strong control of accessory minerals, the REEs are of limited use in petrogenetic modelling of highly evolved granitic systems.  相似文献   

Magnitude of industrialization in Jordan     

Hassan Abdel Kader Saleh 《GeoJournal》1995,37(1):125-132

In spite of Jordan's insignificant natural resources and geopolitical problems, industrial development is being emphasized in Jordan since 1972. Industries are now the second largest sector of economy. Industries contributed 10% of the GDP in 1972, 19.5% in 1989 and 17.4% in 1993. This is remarkable as the national investment in industries is declining. The investments for industrial development was 30% of the total national investment in five year development plans (1976–1980), 23% in the next plan (1981–1985), and 13% in the following plan (1986–1990).The number of; industries has increased from 2500 in 1959 to 4684 in 1974, to 8533 in 1984, and 18600 in 1992. The employment or labor force also increased from 10,000 in 1959 to 70,000 in 1988, and to 110,000 in 1992. It represents about 16.4% of the total labor force in Jordan, the index number of industrial production also increased from (100) in 1979 which was the same base year, to (151) in 1983 to (205) in 1987 and to (215) in 1993. The study was based on three hypotheses: (i) the magnitude varies from one industry to another at the national (Jordan) and local (governorate levels), (ii) temporal change in the magnitude of industries has taken place during the period 1979–1992, (iii) the temporal change in the magnitude of industries was positive in some industries and negative in others.  相似文献   

Spatial Variability Mapping of Some Soil Properties in Jadwal Al_Amir Project/Babylon/Iraq     

Amal Muhammad Saleh 《Journal of the Indian Society of Remote Sensing》2018,46(9):1481-1495

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Multi-factor impact analysis of agricultural production in Bangladesh with climate change   总被引：1，自引：0，他引：1  

Alex C. Ruane  David C. Major  Winston H. Yu  Mozaharul Alam  Sk. Ghulam Hussain  Abu Saleh Khan  Ahmadul Hassan  Bhuiya Md. Tamim Al Hossain  Richard Goldberg  Radley M. Horton  Cynthia Rosenzweig 《Global Environmental Change》2013,23(1):338-350

Diverse vulnerabilities of Bangladesh's agricultural sector in 16 sub-regions are assessed using experiments designed to investigate climate impact factors in isolation and in combination. Climate information from a suite of global climate models (GCMs) is used to drive models assessing the agricultural impact of changes in temperature, precipitation, carbon dioxide concentrations, river floods, and sea level rise for the 2040–2069 period in comparison to a historical baseline. Using the multi-factor impacts analysis framework developed in Yu et al. (2010), this study provides new sub-regional vulnerability analyses and quantifies key uncertainties in climate and production. Rice (aman, boro, and aus seasons) and wheat production are simulated in each sub-region using the biophysical Crop Environment REsource Synthesis (CERES) models. These simulations are then combined with the MIKE BASIN hydrologic model for river floods in the Ganges-Brahmaputra-Meghna (GBM) Basins, and the MIKE21 Two-Dimensional Estuary Model to determine coastal inundation under conditions of higher mean sea level. The impacts of each factor depend on GCM configurations, emissions pathways, sub-regions, and particular seasons and crops. Temperature increases generally reduce production across all scenarios. Precipitation changes can have either a positive or a negative impact, with a high degree of uncertainty across GCMs. Carbon dioxide impacts on crop production are positive and depend on the emissions pathway. Increasing river flood areas reduce production in affected sub-regions. Precipitation uncertainties from different GCMs and emissions scenarios are reduced when integrated across the large GBM Basins’ hydrology. Agriculture in Southern Bangladesh is severely affected by sea level rise even when cyclonic surges are not fully considered, with impacts increasing under the higher emissions scenario.  相似文献   

Galaxy evolution, cosmology and dark energy with the Square Kilometer Array     

S. Rawlings  F.B. Abdalla  S.L. Bridle  C.A. Blake  C.M. Baugh  L.J. Greenhill  J.M. van der Hulst 《New Astronomy Reviews》2004,48(11-12):1013

The present-day Universe is seemingly dominated by dark energy and dark matter, but mapping the normal (baryonic) content remains vital for both astrophysics – understanding how galaxies form – and astro-particle physics – inferring properties of the dark components.The Square Kilometer Array (SKA) will provide the only means of studying the cosmic evolution of neutral hydrogen (HI) which, alongside information on star formation from the radio continuum, is needed to understand how stars formed from gas within dark-matter over-densities and the rôles of gas accretion and galaxy merging.‘All hemisphere’ HI redshift surveys to z 1.5 are feasible with wide-field-of-view realizations of the SKA and, by measuring the galaxy power spectrum in exquisite detail, will allow the first precise studies of the equation-of-state of dark energy. The SKA will be capable of other uniquely powerful cosmological studies including the measurement of the dark-matter power spectrum using weak gravitational lensing, and the precise measurement of H₀ using extragalactic water masers.The SKA is likely to become the premier dark-energy-measuring machine, bringing breakthroughs in cosmology beyond those likely to be made possible by combining CMB (e.g. Planck), optical (e.g. LSST, SNAP) and other early-21st-century datasets.  相似文献   

Cosmological systematics beyond nuisance parameters: form-filling functions     

T. D. Kitching  A. Amara  F. B. Abdalla  B. Joachimi  A. Refregier 《Monthly notices of the Royal Astronomical Society》2009,399(4):2107-2128

In the absence of any compelling physical model, cosmological systematics are often misrepresented as statistical effects and the approach of marginalizing over extra nuisance systematic parameters is used to gauge the effect of the systematic. In this article, we argue that such an approach is risky at best since the key choice of function can have a large effect on the resultant cosmological errors.
As an alternative we present a functional form-filling technique in which an unknown, residual, systematic is treated as such. Since the underlying function is unknown, we evaluate the effect of every functional form allowed by the information available (either a hard boundary or some data). Using a simple toy model, we introduce the formalism of functional form filling. We show that parameter errors can be dramatically affected by the choice of function in the case of marginalizing over a systematic, but that in contrast the functional form-filling approach is independent of the choice of basis set.
We then apply the technique to cosmic shear shape measurement systematics and show that a shear calibration bias of  | m ( z )| ≲ 10⁻³ (1 + z )^0.7  is required for a future all-sky photometric survey to yield unbiased cosmological parameter constraints to per cent accuracy.
A module associated with the work in this paper is available through the open source icosmo code available at http://www.icosmo.org .  相似文献   

Very Low Frequency Remote Sensing Measurements of the Lower Ionosphere at Site of the United Arab Emirates     

Hamid M. K. Al-Naimiy  Ala A. J. Al-Douri  Abdalla A. Alnajjar  Umran Inan 《Earth, Moon, and Planets》2009,104(1-4):189-193

The proposed research project is aiming for providing basic data for quantitative comparison of lightning-induced disturbances of the ionosphere and the radiation belts in the American, European and Asia sectors. Most of the current data on such phenomena has so far been obtained in the western hemisphere, and the weight of scientific information indicates that lightning-induced effects at high altitudes and in the radiation belts may dominate other processes on a global scale. The proposed research project will facilitate the establishment and conduct of Very Low Frequency observations in the United Arab Emirates as a part of the Asia sector, thus providing a basis for comparison to facilitate global extrapolations and conclusions. Under the proposed project, Stanford University partners with Sharjah University, deploying one of their Very Low Frequency receivers at Sharjah University campus. Sharjah University provides the data digitization and recording equipment to facilitate continuous acquisition of the data. All data from the proposed project will be available for analysis over the Internet, and a series of annual visits are planned to maximize interactions and information exchange between the two universities.  相似文献   

CFD-Based Model for Estimating the River Bed Morphological Characteristics near Cylindrical Bridge Piers Due to Debris Accumulation     

Al-Awadi  Aysar Tuama  Al-Khafaji  Mahmoud Saleh 《Water Resources》2021,48(5):763-773

Water Resources - The scour and flow field patterns with accumulation of debris around bridge piers are completely different due to the reduction of flow area and the increase in depth average...  相似文献   

Morphological and Phylogenetic Studies of a Copepod Species,Irodes parupenei Ho and Lin (2007), Infecting Parupeneus rubescens in Saudi Arabia     

DKHIL Mohamed A  ALHAFIDH Wejdan  AL-QURAISHY Saleh  ALOTAIBI Mashael  BANAEEM Manal  ALSALEH Thekra  ABDEL-GABER Rewaida 《中国海洋大学学报(英文版)》2022,21(2):457-464

Dammam City is one of the gorgeous coastal areas in the Arabian Gulf of Saudi Arabia.The present study aimed to ex-amine one of the copepod species infecting the rosy goatfish that represents a highly consumed fish species by the local population in the Arabian Gulf.The copepod species isolated from the infected fish specimens belong to the family Taeniacanthidae and was iden-tified as Irodes parupenei Ho and Lin(2007),primarily based on its morphological,morphometric,and ultrastructural characteris-tics,especially the structures of the dorsal cephalic area,segmentation of the first antenna,the absence of the maxilliped claw in the fe-male specimens,and the setation and spinulation of the legs 2-4 for the adult females are of great significance in the taxonomic iden-tification.The 18S rRNA gene sequence was analyzed to ensure the precise identity and exact taxonomic status of the copepod species.The result showed that this copepod species belong to Taenicanthidae and closely related to Irodes sauridi(gb|JF781550.1)in the same taxon.More details on the specificity of the goatfish for Irodes species and identifying these parasitic taxa using molecular analysis are given in the present study.  相似文献