Molecular and isotopic characteristics of gas hydrate-bound hydrocarbons in southern and central Lake Baikal   总被引：4，自引：4，他引：0  

Akihiro Hachikubo  Oleg Khlystov  Alexey Krylov  Hirotoshi Sakagami  Hirotsugu Minami  Yutaka Nunokawa  Satoshi Yamashita  Nobuo Takahashi  Hitoshi Shoji  Shin’ya Nishio  Masato Kida  Takao Ebinuma  Gennadiy Kalmychkov  Jeffrey Poort 《Geo-Marine Letters》2010,30(3-4):321-329

We investigated the molecular composition (methane, ethane, and propane) and stable isotope composition (methane and ethane) of hydrate-bound gas in sediments of Lake Baikal. Hydrate-bearing sediment cores were retrieved from eight gas seep sites, located in the southern and central Baikal basins. Empirical classification of the methane stable isotopes (δ¹³C and δD) for all the seep sites indicated the dominant microbial origin of methane via methyl-type fermentation; however, a mixture of thermogenic and microbial gases resulted in relatively high methane δ¹³C signatures at two sites where ethane δ¹³C indicated a typical thermogenic origin. At one of the sites in the southern Baikal basin, we found gas hydrates of enclathrated microbial ethane in which ¹³C and deuterium were both highly depleted (mean δ¹³C and δD of –61.6‰ V-PDB and –285.4‰ V-SMOW, respectively). To the best of our knowledge, this is the first report of C₂ δ¹³C–δD classification for hydrate-bound gas in either freshwater or marine environments.  相似文献   

Phytoplankton dynamics associated with the monsoon in the Sulu Sea as revealed by pigment signature   总被引：2，自引：0，他引：2  

Meguru Miki  Neelam Ramaiah  Shigenobu Takeda  Ken Furuya 《Journal of Oceanography》2008,64(5):663-673

Phytoplankton dynamics during the northeast monsoon was investigated in the Sulu Sea from algal pigment analysis. We visited the Sulu Sea in February 2000, a mid period of the northeast monsoon, and in November and December 2002, the beginning of the northeast monsoon. SeaWiFS images showed generally low concentrations of surface chlorophyll a (Chl a) during the southwest monsoon and higher concentrations with several peaks during the northeast monsoon. In the beginning of the northeast monsoon, subsurface chlorophyll maxima (SCM) occurred, where vertical variation in class-specific composition as estimated from pigment signatures was prominent. Prochlorococcus, cyanobacteria, prymnesiophytes and crysophytes were important groups above the SCM, and the contribution of cyanobacteria to Chl a became much lower at and below the SCM. Contributions of chlorophytes and prasinophytes to Chl a generally showed maxima near the SCM. This distribution was accompanied by vertical changes in the concentration of photoprotective pigments relative to photosynthetic accessory pigments. During the mid northeast monsoon, the upward supply of nutrients was probably enhanced at some stations due to vertical mixing, and as a consequence diatoms dominated in the upper 100 m water column of these stations, and other eukaryotic flagellates including prymnesiophytes, chrysophytes and cryptophytes were secondary major components of the community. The elevation of Chl a concentration and changes in phytoplankton community during the northeast monsoon likely influence the variation in biological production at higher trophic levels in the Sulu Sea.  相似文献   

SAR-imaged spiral eddies in Mutsu Bay and their dynamic and kinematic models     

Satoshi Yamaguchi  Hiroshi Kawamura 《Journal of Oceanography》2009,65(4):525-539

A pattern of slick streaks winding into a spiral, known as a spiral eddy, was identified in 5 images taken by the ERS-1/2 synthetic aperture radar (SAR) in Mutsu Bay (Japan); dynamic and kinematic models of these spiral eddies have been proposed. Common characteristics of the five spiral eddies are: 1) an eddy diameter of about 15 km; 2) their location in the western part of the bay; and 3) their cyclonic direction of rotation. Moreover, the wind conditions over the bay were common: prior to acquiring the images, a strong easterly wind continued blowing for more than one day. The wind field on the bay is known to be orographically steered and has strong windstress vorticity, which generates cyclonic circulation. The diameter and location of the circulation simulated with a numerical ocean model corresponded well to those of the identified spiral eddies. Based on these facts, we propose a dynamic model for the movement of a slick streak, and a kinematic model for the formation of a spiral eddy. We have assumed calm air, a microlayer and seawater with a cyclonic circulation in the dynamic model. The balance of forces is established in the microlayer among the frictional force from the seawater, the frictional force from the calm air, the gravitational force, and the Coriolis force. As a result, the velocity vector of the microlayer deflects slightly towards the center of the cyclonic circulation. We have assumed a point source of the microlayer in the kinematic model. The shapes of a slick streak simulated with the models agree well with the identified patterns in the SAR images.  相似文献   

Ionospheric currents and fields during the solar eclipse     

Masahiko Takeda  Tohru Araki 《Planetary and Space Science》1984,32(8):1013-1019

We calculate electric fields and currents in the ionosphere during the solar eclipse. Three dimensional anisotropic and inhomogeneous conductivity distribution is taken into consideration. Electrical conductivity is assumed to be decreased by the solar eclipse, but winds are not altered. It is shown that the additional currents and fields due to the eclipse are essentially understood as those generated by the obstruction to Sq currents. However, the currents flow preferably in the region nearer to the noon meridian and at the Equator and partly escape through the field-aligned currents to the opposite hemisphere, and therefore the effect of the solar eclipse is also seen in the opposite hemisphere in the deformed shape.  相似文献   

Ar‐Ar and I‐Xe ages and the thermal history of IAB meteorites     

Donald D. Bogard  Daniel H. Garrison  Hiroshi Takeda 《Meteoritics & planetary science》2005,40(2):207-224

Abstract— Studies of several samples of the large Caddo County IAB iron meteorite reveal andesitic material enriched in Si, Na, Al, and Ca, which is essentially unique among meteorites. This material is believed to have formed from a chondritic source by partial melting and to have further segregated by grain coarsening. Such an origin implies extended metamorphism of the IAB parent body. New ³⁹Ar‐⁴⁰Ar ages for silicate from three different Caddo samples are consistent with a common age of 4.50‐4.51 Gyr. Less well‐defined Ar‐Ar degassing ages for inclusions from two other IABs, EET (Elephant Moraine) 83333 and Udei Station, are ?4.32 Gyr, whereas the age for Campo del Cielo varies considerably over about 3.23‐4.56 Gyr. New ¹²⁹I‐¹²⁹Xe ages for Caddo County and EET 83333 are 4557.9 ± 0.1 Myr and 4557–4560 Myr, respectively, relative to an age of 4562.3 Myr for Shallowater. Considering all reported Ar‐Ar degassing ages for IABs and related winonaites, the range is ?4.32‐4.53 Gyr, but several IABs give similar Ar ages of 4.50‐4.52 Gyr. We interpret these older Ar ages to represent cooling after the time of last significant metamorphism on the parent body and the younger ages to represent later ⁴⁰Ar diffusion loss. The older Ar‐Ar ages for IABs are similar to Sm‐Nd and Rb‐Sr isochron ages reported in the literature for Caddo County. Considering the possibility that IAB parent body formation was followed by impact disruption, reassembly, and metamorphism (e.g., Benedix et al. 2000), the Ar‐Ar ages and IAB cooling rates deduced from Ni concentration profiles in IAB metal (Herpfer et al. 1994) are consistent if the time of the postassembly metamorphism was as late as about 4.53 Gyr ago. However, I‐Xe ages reported for some IABs define much older ages of about 4558–4566 Myr, which cannot easily be reconciled with the much younger Ar‐Ar and Sm‐Nd ages. An explanation for the difference in radiometric ages of IABs may reside in combinations of the following: a) I‐Xe ages have very high closure temperatures and were not reset during metamorphism about 4.53 Gyr ago; b) a bias exists in the ⁴⁰K decay constants which makes these Ar‐Ar ages approximately 30 Myr too young; c) the reported Sm‐Nd and Rb‐Sr ages for Caddo are in error by amounts equal to or exceeding their reported 2‐sigma uncertainties; and d) about 30 Myr after the initial heating that produced differentiation of Caddo silicate and mixing of silicate and metal, a mild metamorphism of the IAB parent body reset the Ar‐Ar ages.  相似文献   

Mineralogy of interstitial rim materials of the Y74123 and Y790981 ureilites and their origin     

Hiromi Ogata    Hiroshi Takeda 《Meteoritics & planetary science》1991,26(3):195-201

Abstract— Y74123 is an olivine-rich, relatively unshocked ureilite and contains more interstitial pigeonitic materials than do ureilites which have been reported previously. Thus, Y74123 is especially suited for detailed study of the interstitial materials. We have studied these materials by optical microscope, electron microprobe, scanning electron microscope, high resolution transmission electron microscope (TEM) and analytical TEM to gain a better understanding of their nature and origin. Y790981, with shock partial melts, has also been examined by the same techniques. Bulk chemical compositions of the interstitial materials in Y74123 are pyroxene-like and have higher CaO and Al₂O₃ contents than the large pigeonite and olivine core. Interstitial materials at olivine-pigeonite grain boundaries are richer in CaO and Al₂O₃ than those at olivine-olivine grain boundaries. TEM observations of the interstitial material of Y74123 show that it consists of alternating pigeonite-augite lamellae more than 3.5 μm thick on (001). This texture suggests that the rim material had already crystallized before the parent body breakup. The shock-produced glassy veins in Y790981 cut through the rim materials. These observations are consistent with the idea that the interstitial materials in this ureilite are a mixture of residual liquids of high Ca melts and shock-produced partial melts of olivine and pigeonite. This mixture accumulated along the grain boundaries and some of it is trapped within grains.  相似文献   

Does the gas flow through a porous dust aggregate help its growth in a protoplanetary disk?     

Minoru Sekiya  Hidenori Takeda 《Icarus》2005,176(1):220-223

Sekiya and Takeda [2003, Earth Planets Space 55, 263-269] showed that the hydrodynamic gas flow around a dust aggregate larger than the mean free path of gas molecules prevents the growth of the body. In contrast to Wurm et al. [2004, Astrophys. J. 606, 983-987], we argue that this conclusion is not altered even if we take account of the effect of the flow through a porous dust aggregate.  相似文献   

Local time variation of geomagnetic transfer functions   总被引：1，自引：0，他引：1  

Masahiko Takeda 《Geophysical Journal International》1997,130(3):765-770

The local time (LT) variation of the geomagnetic transfer function at the 32-min period was examined for observatories distributed worldwide. Two distinct variation types (types 1 and 2) were found in the real part of A. Type 1 is conspicuous at lower latitudes and its seasonal variation is small, whereas type 2 is found at higher latitudes and has its maximum in summer. These two types of LT variation are seen globally and are conspicuous when solar activity is high. The amplitudes of both types of variation vary from 0.018 to 0.078, and are independent of the mean values at each observatory. These values are relatively small, but the amplitude of Chambon la Foret is larger than the mean value, which shows that Au changes its sign in local time. The amplitudes of type 1 and 2 variations decrease and increase with geomagnetic latitude, respectively. These features suggest that they are generated by some global external fields. The most probable cause is the Sq field, although the Dp field may contribute to type 1 variation. On the other hand, for the islands of the Pacific Ocean at low latitudes, such as Honolulu and Chichijima, the type 1 variation appears not in the real but in the imaginary part of A, which suggests that currents induced in the ocean also contribute to the local time variation.  相似文献   

Influences of channelization on discharge of suspended sediment and wetland vegetation in Kushiro Marsh, northern Japan     

Futoshi Nakamura  Tadashi Sudo  Satoshi Kameyama  Mieko Jitsu 《Geomorphology》1997,18(3-4)

The effects of wetlands on hydrology, water quality, and wildlife habitat are internationally recognized. Protecting the remaining wetlands is one of the most important environmental issues in many countries. However wetlands in Japan have been gradually shrinking due to agricultural development and urbanization, which generally lowers the groundwater level and introduces suspended sediment and sediment-associated nutrients into wetlands. We examined the influences of channelization on discharge of suspended sediment and wetland vegetation in Hokkaido, northern Japan. The impact of river channelization was confirmed not only by the sediment budgets but also by river aggradation or degradation after the channelization and by the resultant vegetational changes. The budgets of suspended sediment demonstrated that wash load was the predominant component accounting for 95% of the total suspended load delivered into the wetland. This suspended sediment was primarily transported into the wetland by flooding associated with heavy rainfall. Twenty-three percent of the wash load and 63% of the suspended bed material load were deposited in the channelized reach, which produced aggradation of about 2 m at the end of the reach. A shorting of the length of the channel, due to channelization of a meandering river, steepened the slope and enhanced the stream power to transport sediment. This steepening shifted the depositional zones of fine sediment 5 km downstream and aggraded the riverbed. Development of the watershed may increase not only the water discharge but also the amount of suspended sediments. The aggradation reduced the carrying capacity of the channel and caused sediment ladened water to flood over the wetlands. The fine sediment accumulated on the wetlands gradually altered the edaphic conditions and wetland vegetation. A low percentage (10 to 15%) of organic contents of wetlands' soil is more evidence indicating that the present condition is far different from normal. Original vegetation such as sedges and Alnus japonica were disappearing from the adjacent areas of the river channel and were being replaced by willow trees (Salix spp.).  相似文献   

Crystal-field theory calculations for Fe2+ Ions in bronzite,augite, and olivine     

Takahiro Hiroi  Hiroshi Takeda 《Physics and Chemistry of Minerals》1992,19(4):229-235

Crystal-field theory was applied to Fe²⁺ ions in three types of silicates in an attempt to assign all the major absorption bands with only one parameter to adjust. Coulomb potential energy field were calculated by Fourier method based on all the actual atomic coordinates refined by X-ray diffraction studies. Perturbed d-electron splitting energies of the central Fe²⁺ ion were calculated by introducing Configuration Interaction (CI) method for the lowest energy spectral states. All the major absorption bands observed in powdered bronzite, augite, and olivine, were assigned to the transitions between those calculated energy levels by optimizing only one parameter that expresses expansion or contraction of d-electron cloud. The result of the calculations gives almost the same assignments as the other previous works for bronzites, different assignments for augites, and a possibility of the existence of the fourth band hidden in the composite 1-μm band of olivines.  相似文献