Binary Mixtures of Permanganate and Chlorinated Volatile Organic Compounds in Groundwater Samples: Sample Preservation and Analysis     

Karen T. Johnson  Margie Wickham‐St. Germain  Saebom Ko  Scott G. Huling 《Ground Water Monitoring & Remediation》2012,32(3):84-92

Groundwater samples collected at sites where in situ chemical oxidation (ISCO) has been deployed may contain binary mixtures of groundwater contaminants and permanganate (MnO₄^–), an oxidant injected into the subsurface to destroy the contaminant. Commingling of the oxidant and contaminant in aqueous samples may negatively impact the quality of the sample as well as the analytical instruments used to quantify contaminant concentrations. In this study, binary mixtures comprised of (1) a multicomponent standard with permanganate and (2) groundwater samples collected at two ISCO field sites were preserved with ascorbic acid. Ascorbic acid reacts rapidly with the MnO₄^– and limits the reaction between MnO₄^– and the organic compounds in the mixture. Consequently, most of the compounds in the multicomponent standard were within the control limit for quality assurance. However, despite timely efforts to preserve the samples, the rapid reaction between permanganate and contaminant caused the concentration of several sensitive compounds to fall significantly below the lower control limit. Concentrations of volatile organic compounds in the field‐preserved binary mixture groundwater samples were greater than in samples refrigerated in the field and preserved upon arrival at the laboratory, indicating the time‐dependency and benefit of field preservation. The molar ratio of ascorbic acid required to neutralize KMnO₄ was 1.64 (mol ascorbic acid/mol KMnO₄); this provided a baseline to estimate the volume of ascorbic acid stock solution and/or the weight of crystalline ascorbic acid required to neutralize MnO₄^–. Excess ascorbic acid did not negatively impact the quality of the aqueous samples, or analytical instruments, used in the analyses.  相似文献   

A statistical method for varve verification using seasonal pollen deposition     

Jeannine-Marie St. Jacques  Brian F. Cumming  John P. Smol 《Journal of Paleolimnology》2008,40(2):733-744

We developed a fast, inexpensive, statistically rigorous method of varve verification that uses prospective varve layer-splitting and seasonal pollen deposition. This method can be used on any sediment that contains seasonally deposited pollen, and avoids the need for radio-isotopic, optical, or thermoluminescence dating. The method uses a χ² test and non-parametric regression, together with recorded plant bloom times from pollen traps, to assess the differences in pollen abundances in light/dark (i.e. summer/winter-spring) sediment layers. A statistical test is required because such seasonally deposited data are inherently noisy, with a low signal-to-noise ratio. To illustrate this approach, visible laminations of Lake Mina, Minnesota, USA, were assessed in two separate regions of a core spanning 900 years. Results show that the laminations were deposited annually.  相似文献   

Identifying the probabilistic structure of drained areas as a function of hypsometry in river networks          下载免费PDF全文

Pierre‐Stéphane Gsell  Nicolas Le Moine  Roger Moussa  Pierre Ribstein 《水文研究》2015,29(7):1729-1745

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Thermodynamic controls on element partitioning between titanomagnetite and andesitic–dacitic silicate melts     

R.?H.?SievwrightEmail authorView author&#;s OrcID profile  J.?J.?Wilkinson  H.?St.?C.?O’Neill  A.?J.?Berry 《Contributions to Mineralogy and Petrology》2017,172(8):62

Titanomagnetite–melt partitioning of Mg, Mn, Al, Ti, Sc, V, Co, Ni, Cu, Zn, Ga, Zr, Nb, Mo, Hf and Ta was investigated experimentally as a function of oxygen fugacity (fO₂) and temperature (T) in an andesitic–dacitic bulk-chemical compositional range. In these bulk systems, at constant T, there are strong increases in the titanomagnetite–melt partitioning of the divalent cations (Mg²⁺, Mn²⁺, Co²⁺, Ni²⁺, Zn²⁺) and Cu²⁺/Cu⁺ with increasing fO₂ between 0.2 and 3.7 log units above the fayalite–magnetite–quartz buffer. This is attributed to a coupling between magnetite crystallisation and melt composition. Although melt structure has been invoked to explain the patterns of mineral–melt partitioning of divalent cations, a more rigorous justification of magnetite–melt partitioning can be derived from thermodynamic principles, which accounts for much of the supposed influence ascribed to melt structure. The presence of magnetite-rich spinel in equilibrium with melt over a range of fO₂ implies a reciprocal relationship between a(Fe²⁺O) and a(Fe³⁺O_1.5) in the melt. We show that this relationship accounts for the observed dependence of titanomagnetite–melt partitioning of divalent cations with fO₂ in magnetite-rich spinel. As a result of this, titanomagnetite–melt partitioning of divalent cations is indirectly sensitive to changes in fO₂ in silicic, but less so in mafic bulk systems.  相似文献   

Modeling coastal tsunami hazard from submarine mass failures: effect of slide rheology,experimental validation,and case studies off the US East Coast     

Grilli  Stéphan T.  Shelby  Mike  Kimmoun  Olivier  Dupont  Guillaume  Nicolsky  Dmitry  Ma  Gangfeng  Kirby  James T.  Shi  Fengyan 《Natural Hazards》2017,86(1):353-391

Natural Hazards - We perform numerical simulations to assess how coastal tsunami hazard from submarine mass failures (SMFs) is affected by slide kinematics and rheology. Two types of two-layer SMF...  相似文献   

Comparison of LiDAR waveform processing methods for very shallow water bathymetry using Raman,near‐infrared and green signals     

Tristan Allouis  Jean‐Stéphane Bailly  Yves Pastol  Catherine Le Roux 《地球表面变化过程与地形》2010,35(6):640-650

Airborne light detection and ranging (LiDAR) bathymetry appears to be a useful technology for bed topography mapping of non‐navigable areas, offering high data density and a high acquisition rate. However, few studies have focused on continental waters, in particular, on very shallow waters (<2 m) where it is difficult to extract the surface and bottom positions that are typically mixed in the green LiDAR signal. This paper proposes two new processing methods for depth extraction based on the use of different LiDAR signals [green, near‐infrared (NIR), Raman] of the SHOALS‐1000T sensor. They have been tested on a very shallow coastal area (Golfe du Morbihan, France) as an analogy to very shallow rivers. The first method is based on a combination of mathematical and heuristic methods using the green and the NIR LiDAR signals to cross validate the information delivered by each signal. The second method extracts water depths from the Raman signal using statistical methods such as principal components analysis (PCA) and classification and regression tree (CART) analysis. The obtained results are then compared to the reference depths, and the performances of the different methods, as well as their advantages/disadvantages are evaluated. The green/NIR method supplies 42% more points compared to the operator process, with an equivalent mean error (?4·2 cm verusu ?4·5 cm) and a smaller standard deviation (25·3 cm verusu 33·5 cm). The Raman processing method provides very scattered results (standard deviation of 40·3 cm) with the lowest mean error (?3·1 cm) and 40% more points. The minimum detectable depth is also improved by the two presented methods, being around 1 m for the green/NIR approach and 0·5 m for the statistical approach, compared to 1·5 m for the data processed by the operator. Despite its ability to measure other parameters like water temperature, the Raman method needed a large amount of reference data to provide reliable depth measurements, as opposed to the green/NIR method. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Hydrothermal calderas     

Olivier Merle  Stéphanie Barde-Cabusson  Benjamin van Wyk de Vries 《Bulletin of Volcanology》2010,72(2):131-147

The standard model of caldera formation is related to the emptying of a magma chamber and ensuing roof collapse during large eruptions or subsurface withdrawal. Although this model works well for numerous volcanoes, it is inappropriate for many basaltic volcanoes (with the notable exception of Hawaii), as these have eruptions that involve volumes of magma that are small compared to the collapse. Many arc volcanoes also have similar oversized depressions, such as Poas (Costa Rica) and Aoba (Vanuatu). In this article, we propose an alternative caldera model based on deep hydrothermal alteration of volcanic rocks in the central part of the edifice. Under certain conditions, the clay-rich altered and pressurized core may flow under its own weight, spread laterally, and trigger very large caldera-like collapse. Several specific mechanisms can generate the formation of such hydrothermal calderas. Among them, we identify two principal modes: mode 1: ripening with summit loading and flank spreading and mode II: unbuttressing with flank subsidence and flank sliding. Processes such as summit loading or flank subsidence may act simultaneously in hybrid mechanisms. Natural examples are shown to illustrate the different modes of formation. For ripening, we give Aoba (Vanuatu) as an example of probable summit loading, while Casita (Nicaragua) is the type example of flank spreading. For unbuttressing, Nuku Hiva Island (Marquesas) is our example for flank subsidence and Piton de la Fournaise (La Réunion) is our example of flank sliding. The whole process is slow and probably needs (a) at least a few tens of thousands of years to deeply alter the edifice and reach conditions suitable for ductile flow and (b) a few hundred years to achieve the caldera collapse. The size and the shape of the caldera strictly mimic that of the underlying weak core. Thus, the size of the caldera is not controlled by the dimensions of the underlying magma reservoir. A collapsing hydrothermal caldera could generate significant phreatic activity and trigger major eruptions from a coexisting magmatic complex. As the buildup to collapse is slow, such caldera-forming events could be detected long before their onset.  相似文献   

Accuracy assessment of the Mexican National Forest Inventory map: A study in four ecogeographical areas     

Stéphane Couturier  Jean‐François Mas  Erna López‐Granados  Jorge Benítez  Valdemar Coria‐Tapia  Álvaro Vega‐Guzmán 《Singapore journal of tropical geography》2010,31(2):163-179

The accuracy of the Mexican National Forest Inventory (NFI) map is derived in four distinct ecogeographical areas, using an assessment design tailored for the project. A main achievement of the design was to integrate the high diversity of classes encompassed at the most detailed subcommunity level of the classification scheme within a cost‐controlled statistically sound assessment. A hybrid double sampling strategy was applied to the 2.5 million‐ha study area. A total of 5955 reference sites were verified against their NFI map label. The availability of detailed quasi‐synchronous reference data for the 2000 Landsat‐derived NFI and the high diversity of mapped classes allowed a careful thematic analysis on the selected regions, relevant for national extrapolation. Global accuracy estimates of 64–78 per cent were registered among the four ecogeographical areas (two with mainly temperate climate and the other two with mainly tropical climate), with the lower accuracy levels found in areas more densely covered with forests. According to the estimates, the NFI map tends to underestimate the presence of temperate forest (especially oak) and overestimate the presence of tropical forest in the areas investigated. The analysis of confusions reveals difficulties in unambiguously interpreting or labelling forests with secondary vegetation, herbaceous and/or shrub‐like vegetation as well as distinguishing between aquatic vegetation types. The design proved useful from the perspective of accuracy assessments of regional maps in biodiverse regions.  相似文献   

Fishing for diatoms: fish gut analysis reveals water quality changes over a 75-year period     

Isabelle Lavoie  Stéphane Campeau 《Journal of Paleolimnology》2010,43(1):121-130

Defining the reference state of some perturbed streams and rivers is challenging since their non-altered state is undocumented. Despite the near-absence of pristine sites in highly anthropogenic areas, information about aquatic communities that existed prior to human disturbance can be obtained from historic sources. Sediment coring is commonly used in paleolimnology to estimate past environmental conditions of lakes, but this technique is often not appropriate for studies of lotic systems. An alternative is to use diatom assemblages present in the guts of fish that were captured in the streams prior to significant human disturbance. The purpose of the present study was to evaluate the biological integrity of several streams in Ontario and Québec during the early twentieth century based on “paleo” diatom assemblages extracted from the guts of fish stored in museums. The Eastern Canadian diatom index (IDEC: Indice Diatomées de l’Est du Canada) was used to evaluate the biological status of “paleo” and “modern” diatom assemblages. The IDEC shows the position of diatom assemblages on a general pollution gradient. The comparison of IDEC values calculated for the 1925–1948 and the 2003–2007 periods showed that several streams were severely polluted in the early 1900s. In general, present water quality has declined compared to the early 1900s. The biological integrity of only three of the 22 sites has increased. IDEC values were not influenced by the species of fish studied.  相似文献   

Regional and interannual variability in sea level over 2002–2009 based on satellite altimetry, Argo float data and GRACE ocean mass     

William Llovel  Stéphanie Guinehut  Anny Cazenave 《Ocean Dynamics》2010,60(5):1193-1204

In this study, we have estimated the different sea level components (observed sea level from satellite altimetry, steric sea level from in situ hydrography—including Argo profiling floats, and ocean mass from Gravity Recovery and Climate Experiment; GRACE), in terms of regional and interannual variability, over 2002–2009. We compute the steric sea level using different temperature (and salinity) data sets processed by different groups (SCRIPPS, CLS, IPRC, and NOAA) and first focus on the regional variability in steric and altimetry-based sea level. In addition to El Nino–La Nina signatures, the observed and steric sea level data show clear impact of three successive Indian Ocean Dipoles in 2006, 2007, and 2008 in the Indian Ocean. We next study the spatial trend patterns in ocean mass signal by comparing GRACE observations over the oceans with observed minus steric sea level. While in some regions, reasonably good agreement is observed, discrepancy is noticed in some others due to still large regional trend errors in Argo and GRACE data, as well as to a possible (unknown) deep ocean contribution. In terms of global mean, interannual variability in altimetry-based minus steric sea level and GRACE-based ocean mass appear significantly correlated. However, large differences are reported when short-term trends are estimated (using both GRACE and Argo data). This prevents us to draw any clear conclusion on the sea level budget over the recent years from the comparison between altimetry-based, steric sea level, and GRACE-based ocean mass trends, nor does it not allow us to constrain the Glacial Isostatic Adjustment correction to apply to GRACE-based ocean mass term using this observational approach.  相似文献