The crystal structure of waylandite from Wheal Remfry, Cornwall, United Kingdom     

Stuart J. Mills  Anthony R. Kampf  Mati Raudsepp  William D. Birch 《Mineralogy and Petrology》2010,100(3-4):249-253

Sr- and Ca-rich waylandite, $ {\left( {{\hbox{B}}{{\hbox{i}}_{0.{54}}}{\hbox{S}}{{\hbox{r}}_{0.{31}}}{\hbox{C}}{{\hbox{a}}_{0.{25}}}{{\hbox{K}}_{0.0{1}}}{\hbox{B}}{{\hbox{a}}_{0.0{1}}}} \right)_{\Sigma 1.12}}{{\hbox{H}}_{0.{18}}}{\left( {{\hbox{A}}{{\hbox{l}}_{{2}.{96}}}{\hbox{C}}{{\hbox{u}}_{0.0{2}}}} \right)_{\Sigma 2.98}}{\left[ {{{\left( {{{\hbox{P}}_{0.{97}}}{{\hbox{S}}_{0.0{3}}}{\hbox{S}}{{\hbox{i}}_{0.0{1}}}} \right)}_{\Sigma 1.00}}{{\hbox{O}}_4}} \right]_2}{\left( {\hbox{OH}} \right)_6} $ , from Wheal Remfry, Cornwall, United Kingdom has been investigated by single-crystal X-ray diffraction and electron microprobe analyses. Waylandite crystallises in space group R $ \overline 3 $ ? m, with the cell parameters: a?=?7.0059(7) Å, c?=?16.3431(12) Å and V?=?694.69(11) ų. The crystal structure has been refined to R ₁?=?3.76%. Waylandite has an alunite-type structure comprised of a rhombohedral stacking of (001) composite layers of corner-shared AlO₆ octahedra and PO₄ tetrahedra, with (Bi,Sr,Ca) atoms occupying icosahedrally coordinated sites between the layers.  相似文献   

Thermochronometric constraints on the tectonic evolution of the Serifos detachment, Aegean Sea, Greece   总被引：1，自引：0，他引：1  

Stephanie Brichau  Stuart Thomson  Uwe Ring 《International Journal of Earth Sciences》2010,99(2):379-393

We constrain the timing and kinematics of the Serifos detachment in the southwestern Cyclades, Greece, using low-temperature thermochronometry. Fission-track dating shows that the Serifos detachment was active between ~13 and 6 Ma and that the Serifos granodiorite in its footwall intruded at or before ~12–11 Ma into the extensional shear zone and initially cooled very rapidly at rates >180°C per million year. The mylonite zone at the top of the granodiorite and mylonitic structures in its country rocks record a consistent top-SSW shear sense in the ductile crust. In the brittle regime top-NNE shear-sense indicators occur as well. Conjugate top-SSW and top-NNE high-angle normal faults are the youngest deformational features and cut across the detachment. Age–distance relationships for the fission-track data display a relatively flat pattern. We discuss a model advocating initial top-SSW movement on the Serifos detachment before and during emplacement of the granodiorite. Updoming of the detachment during exhumation and cooling caused subsequent bivergent extension in the brittle crust.  相似文献   

Electrodynamic Disaggregation: Does it Affect Apatite Fission-Track and (U-Th)/He Analyses?     

Jörg Giese  Diane Seward  Finlay M. Stuart  Eliane Wüthrich  Edwin Gnos  Daniel Kurz  Urs Eggenberger  Guido Schreurs 《Geostandards and Geoanalytical Research》2010,34(1):39-48

Apatite fission-track and (U-Th)/He analyses require the liberation of intact idiomorphic apatite grains from rock samples. While routinely being carried out by mechanical methods, electrodynamic disaggregation (ED) offers an alternative approach. The high-voltage discharges produced during the ED process create localised temperature peaks (10000 K) along a narrow plasma channel. In apatite, such high temperatures could potentially reduce the length of fission tracks, which start to anneal at temperatures > 60 °C, and could also enhance He diffusion, which becomes significant at 30–40 °C over geological time scales. A comparison of fission-track analyses and (U-Th)/He ages of apatites prepared both by mechanical (jaw crusher, disk mill) and ED processing provides a way of determining whether heating during the latter method has any significant effect. Apatites from three samples of different geological settings (an orthogneiss from Madagascar, the Fish Canyon Tuff, and a muscovite-gneiss from Greece) yielded statistically identical track length distributions compared to samples prepared mechanically. Additionally, (U-Th)/He ages of apatites from a leucogranite from Morocco prepared by both methods were indistinguishable. These first results indicated that during electrodynamic disaggregation apatite crystals were not heated enough to partially anneal the fission tracks or induce significant diffusive loss of He.  相似文献   

Mantle heat drives hydrothermal fluids responsible for carbonate-hosted base metal deposits: evidence from 3He/4He of ore fluids in the Irish Pb-Zn ore district     

B. Davidheiser-Kroll  F. M. Stuart  A. J. Boyce 《Mineralium Deposita》2014,49(5):547-553

There is little consensus on whether carbonate-hosted base metal deposits, such as the world-class Irish Zn + Pb ore field, formed in collisional or extensional tectonic settings. Helium isotopes have been analysed in ore fluids trapped in sulphides samples from the major base metal deposits of the Irish Zn-Pb ore field in order to quantify the involvement of mantle-derived volatiles that require melting to be realised, as well as test prevailing models for the genesis of the ore fields. ³He/⁴He ratios range up to 0.2 R _a, indicating that a small but clear mantle helium contribution is present in the mineralising fluids trapped in galena and marcasite. Sulphides from ore deposits with the highest fluid inclusion temperatures (~200 °C) also have the highest ³He/⁴He (>0.15 R _a). Similar ³He/⁴He are recorded in fluids from modern continental regions that are undergoing active extension. By analogy, we consider that the hydrothermal fluids responsible for the carbonate-hosted Irish base metal mineralization circulated in thinned continental crust undergoing extension and demonstrate that enhanced mantle heat flow is ultimately responsible for driving fluid convection.  相似文献   

Scales and causes of heterogeneity in bars in a large multi‐channel river: Río Paraná, Argentina     

Arnold J. H. Reesink  Philip J. Ashworth  Gregory H. Sambrook Smith  James L. Best  Daniel R. Parsons  Mario L. Amsler  Richard J. Hardy  Stuart N. Lane  Andrew P. Nicholas  Oscar Orfeo  Steven D. Sandbach  Christopher J. Simpson  Ricardo N. Szupiany 《Sedimentology》2014,61(4):1055-1085

To date, published studies of alluvial bar architecture in large rivers have been restricted mostly to case studies of individual bars and single locations. Relatively little is known about how the depositional processes and sedimentary architecture of kilometre‐scale bars vary within a multi‐kilometre reach or over several hundreds of kilometres downstream. This study presents Ground Penetrating Radar and core data from 11, kilometre‐scale bars from the Río Paraná, Argentina. The investigated bars are located between 30 km upstream and 540 km downstream of the Río Paraná – Río Paraguay confluence, where a significant volume of fine‐grained suspended sediment is introduced into the network. Bar‐scale cross‐stratified sets, with lengths and widths up to 600 m and thicknesses up to 12 m, enable the distinction of large river deposits from stacked deposits of smaller rivers, but are only present in half the surface area of the bars. Up to 90% of bar‐scale sets are found on top of finer‐grained ripple‐laminated bar‐trough deposits. Bar‐scale sets make up as much as 58% of the volume of the deposits in small, incipient mid‐channel bars, but this proportion decreases significantly with increasing age and size of the bars. Contrary to what might be expected, a significant proportion of the sedimentary structures found in the Río Paraná is similar in scale to those found in much smaller rivers. In other words, large river deposits are not always characterized by big structures that allow a simple interpretation of river scale. However, the large scale of the depositional units in big rivers causes small‐scale structures, such as ripple sets, to be grouped into thicker cosets, which indicate river scale even when no obvious large‐scale sets are present. The results also show that the composition of bars differs between the studied reaches upstream and downstream of the confluence with the Río Paraguay. Relative to other controls on downstream fining, the tributary input of fine‐grained suspended material from the Río Paraguay causes a marked change in the composition of the bar deposits. Compared to the upstream reaches, the sedimentary architecture of the downstream reaches in the top ca 5 m of mid‐channel bars shows: (i) an increase in the abundance and thickness (up to metre‐scale) of laterally extensive (hundreds of metres) fine‐grained layers; (ii) an increase in the percentage of deposits comprised of ripple sets (to >40% in the upper bar deposits); and (iii) an increase in bar‐trough deposits and a corresponding decrease in bar‐scale cross‐strata (<10%). The thalweg deposits of the Río Paraná are composed of dune sets, even directly downstream from the Río Paraguay where the upper channel deposits are dominantly fine‐grained. Thus, the change in sedimentary facies due to a tributary point‐source of fine‐grained sediment is primarily expressed in the composition of the upper bar deposits.  相似文献   

The 2dF galaxy redshift survey: clustering properties of radio galaxies     

Manuela Magliocchetti  Steve J. Maddox  Ed Hawkins  John A. Peacock  Joss Bland-Hawthorn  Terry Bridges  Russell Cannon  Shaun Cole  Matthew Colless  Chris Collins  Warrick Couch  Gavin Dalton  Roberto de Propris  Simon P. Driver  George Efstathiou  Richard S. Ellis  Carlos S. Frenk  Karl Glazebrook  Carole A. Jackson  Bryn Jones  Ofer Lahav  Ian Lewis  Stuart Lumsden  Peder Norberg  Bruce A. Peterson  Will Sutherland  Keith Taylor 《Monthly notices of the Royal Astronomical Society》2004,350(4):1485-1494

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Charles Lyell and the extraordinary publishing history of his works     

Stuart A. Baldwin 《Geology Today》1998,14(3):113-115

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Agricultural Chemical News     

Stuart Cohen 《Ground Water Monitoring & Remediation》1998,18(3):68-69

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Sampling the vertical particle flux in the upper water column using a large diameter free-drifting NetTrap adapted to an Indented Rotating Sphere sediment trap     

Michael L. Peterson  Joan Fabres  Stuart G. Wakeham  Cindy Lee  Ivn J. Alonso  Juan Carlos Miquel 《Deep Sea Research Part II: Topical Studies in Oceanography》2009,56(18):1547-1557

Further development of the large, surface-tethered sediment trap (NetTrap) employed as part of the MedFlux program is described whereby the large collection capacity of the NetTrap is combined with an Indented Rotating Sphere/Sample Carousel (IRSC) sediment trap (IRSC–NT). This trap is capable of collecting particle flux either in a time series or settling velocity mode; settling velocity mode allows the collection of particles that fall within discrete settling velocity intervals. During short field deployments in the Mediterranean Sea the IRSC–NT configured in the settling velocity mode successfully collected unpoisoned samples for chemical and microbiological experiments. In addition to the development of the IRSC–NT, particle-settling behavior above and below the swimmer-excluding IRS valve was tested during on-deck experiments using a specially constructed water-tight trap. Chemical analyses of settling materials (published elsewhere) suggested that separation of particles by settling velocity was achieved. However, due to the motion of the ship, it was not possible to directly measure particle-settling velocities within the trap. Particle release from the IRS did not bias the apparent settling velocity spectrum. Rotation of the IRS did not engender turbulence at the surface of the sphere or within the skewed funnel below. Tests of different ball designs over the course of the MedFlux program showed that a “ridge and saddle” pattern was optimal for efficiently transferring particles under the IRS seal while still reducing swimmer entrance to the collection funnel. The large size of the IRSC–NT did not prevent it from drifting effectively with the current. Several modifications of the present design are proposed that should improve the accuracy of the settling velocity measurements.  相似文献   

MedFlux: Investigations of particle flux in the Twilight Zone     

Cindy Lee  Robert A. Armstrong  J. Kirk Cochran  Anja Engel  Scott W. Fowler  Madeleine Goutx  Pere Masqu  Juan Carlos Miquel  Michael Peterson  Christian Tamburini  Stuart Wakeham 《Deep Sea Research Part II: Topical Studies in Oceanography》2009,56(18):1363-1368

The MedFlux project was devised to determine and model relationships between organic matter and mineral ballasts of sinking particulate matter in the ocean. Specifically we investigated the ballast ratio hypothesis, tested various commonly used sampling and modeling techniques, and developed new technologies that would allow better characterization of particle biogeochemistry. Here we describe the rationale for the project, the biogeochemical provenance of the DYFAMED site, the international support structure, and highlights from the papers published here. Additional MedFlux papers can be accessed at the MedFlux web site (http://msrc.sunysb.edu/MedFlux/).  相似文献