The role of lithology,catchment size and the alluvial zone on the hydrogeochemistry of two intermittent Mediterranean streams     

Susana Bernal  Francesc Sabater 《水文研究》2008,22(10):1407-1418

Hydrology and solute concentrations of two intermittent Mediterranean streams draining two nested catchments were compared. The two catchments were mainly underlain by granitic rocks and different types of sericitic schists. Only the lowland catchment had an alluvial zone and a well‐developed riparian forest. The rainfall–runoff relationship and the correlation between daily flow concentrations showed that hydrological behaviour was similar at both sites during most of the year. However, reverse fluxes were detected during the wetting and drying up periods only in the stream with an alluvial zone. The intermittence in stream flow also had effects on absolute solute concentrations, temporal solute dynamics and streamwater stoichiometry. Streamwater chemistry was not affected by drainage area, except for cations produced mainly by bedrock dissolution (i.e. calcium and magnesium) that increased with increasing catchment size. Differences in the relationship among cations and anions were detected between the two streams, which could be attributed to biogeochemical processes occurring in the alluvial zone. The multivariate model used in this study showed that stoichiometry was more useful than absolute concentrations when analyzing the influence of different lithologies on streamwater chemistry. Such differences were amplified in autumn, likely due to a low hydrological connectivity between the two nested catchments. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Raman spectroscopic analysis of cyanobacterial colonization of hydromagnesite, a putative martian extremophile     

Howell G.M. Edwards  Caroline D. Moody  Susana E. Jorge Villar  Michael J. Russell 《Icarus》2005,175(2):372-381

Raman spectra of an extremophile cyanobacterial colony in hydromagnesite from Lake Salda in Turkey have revealed a biogeological modification which is manifest as aragonite in the stratum associated with the colony. The presence of key spectral biomarkers of organic protectant molecules such as β-carotene and scytonemin indicate that the survival strategy of the cyanobacteria is significantly one of UV-radiation protection. The terrestrial location of this extremophile is worthy of consideration further because of its possible putative link with the “White Rock” formations in Sabaea Terra and Juventae Chasma on Mars.  相似文献   

Groundwater behaviour in Madeira, volcanic island (Portugal)     

Susana Nascimento Prada  Manuel Oliveira da Silva  José Virgílio Cruz 《Hydrogeology Journal》2005,13(5-6):800-812

Madeira Island is a hot-spot originating from a mantle plume. K-Ar age determinations indicate that the emerged part of the island was generated during Post-Miocene times 6000–7000 years B.P. Groundwater occurs in perched-water bodies, spring discharge from them is high, about 3,650 l/s; in dike-impounded water and basal groundwater. Basal groundwater is exploited by tunnels (1,100 l/s) and wells (1,100 l/s). Hydraulic gradients range from 10^–4 to 10^–2 and transmissivity ranges from 1.16×10^–2 to 2.89×10^–1 m²/s, indicating the heterogeneity of the volcanic aquifers. Water mineralisation is variable, and electrical conductivity ranges from 50 to 3,300 S/cm. There is a difference between groundwater discharging from perched-water bodies (43–201 S/cm) and from basal groundwater (109–3,300 S/cm). Groundwater average pH is 7.37, with waters acid to slightly alkaline (6.13–8.4), and generally cold. Nevertheless, a few samples associated with fault zones can be classified as thermal waters.

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Resumen La Isla de Madeira tuvo origen en un punto caliente proveniente de una pluma del manto. Las dataciones K – Ar, indican que la parte emergida de la isla se formó durante en Post—Mioceno, hace unos 6000–7000 años. El agua subterránea se encuentra en acuíferos colgados, cuya descarga a través de manantiales es alta, alrededor de 3650 l/s; también como agua retenida en diques o bien como agua subterránea propiamente dicha. Esta última es explotada por túneles (1100 l/s) y pozos (1100 l/s). Los gradientes hidráulicos varían desde 10–4 hasta 10–2 y la transmisividad varía desde 1.16×10^–2 hasta 2.89×10^–1 m²/s, indicando la heterogeneidad de los acuíferos volcánicos. La mineralización de agua es variable y la conductividad eléctrica varía desde 50 mS/cm hasta 3300 mS/cm. Hay una diferencia entre el agua subterránea proveniente de acuíferos colgados (43–201 mS/cm) y aquella del acuífero principal (109–3300 mS/cm). El pH promedio para el agua subterránea es 7.37; con variación desde ácida hasta ligeramente alcalina (6.13–8.4), y es generalmente fría. Sin embargo unos pocos ejemplos asociados con zonas de falla, pueden ser clasificados como agua termal.

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Résumé Lîle de Madeira est un point chaud, provenant dun panache mantélique. Les datations par la méthode de K-Ar indiquent que la part émergée de lîle a été générée pendant le Post Miocène, il y a 6000–7000 ans. Les eaux souterraines sont cantonnées dans des aquifères perchées qui se déchargent par des sources à grands débits, avec des valeurs dapproximativement de 3500 l/s, ainsi que dans les dikes. Une importante quantité des eaux souterraine se trouve sur la forme deau de fonds, formant une nappe basale, qui est exploitée par des tunnels (1100 l/s) et par des puits (1100 l/s). Les gradients hydrauliques ont des valeurs dans lintervalle de 10^–2 à 10^–4, tandis que les transmissivités se rangent entre 1.16×10^–2 m²/s et 2.81×10^–1 m²/s, ce quindique la hétérogénéité de laquifère volcanique. La minéralisation des eaux est aussi variable avec des conductivités électriques qui se rangent ente 50 mS/cm et 3300 mS/cm. Il y a une différence entre la conductivité des eaux provenant des aquifères perchées (30–201 mS/cm) par rapport à la conductivité les eaux de la nappe basale (109–3300 mS/cm). Le pH moyen est de 7.37 avec des valeurs de 6.13 pour les eaux acides et de 8.4 pour les eaux à faible alcalinité. En général il sagit des eaux froides, mais quelques échantillons provenant des zones faillées peuvent être classifiés comme des eaux thermales.

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Sediment disturbance off the Tagus Estuary, Western Portugal: chronic contamination, sewage outfall operation and runoff events     

Silva S  Ré A  Pestana P  Rodrigues A  Quintino V 《Marine pollution bulletin》2004,49(3):154-162

Sediment disturbance patterns in the coastal area off the Tagus Estuary (Portugal) have been assessed using a set of combined techniques. The potential sources of disturbance in the area include chronic contamination of the fine sediments originating from the estuary, a local input from a long-sea sewage outfall and occasional high runoff episodes following torrential rain. The Sediment Quality Triad approach, combining environmental chemistry (namely organic contaminants), macrofaunal benthic communities and laboratory sediment toxicity assays, was performed on sediment samples from 20 sites. The samples were collected before the outfall commenced operation and four years after commissioning, in order to evaluate the relative magnitudes of the three potential sources of disturbance. The sediment contamination created by the estuary was identified as the most important cause of reduced sediment quality, as disturbance in all three components of the Sediment Quality Triad were only found in a site located near the estuary.  相似文献   

The use of the marine biotic index AMBI in the assessment of the ecological status of the Obidos lagoon (Portugal)     

Carvalho S  Gaspar MB  Moura A  Vale C  Antunes P  Gil O  da Fonseca LC  Falcão M 《Marine pollution bulletin》2006,52(11):1414-1424

This study reports the longitudinal distribution of sediment properties, including inorganic and organic contaminants, and the structure of the benthic community in Obidos lagoon, a coastal system permanently connected to the sea and with negligible freshwater sources. Sediments from the upper to central lagoon consist of fine particles (91%) and from the lower lagoon of sands (94%). Chemical composition is strongly correlated to the percentage of fine particles. Contamination is relatively low in those sediments suggesting the effect of diffuse sources. The increase in organic matter content from down- to upstream areas was associated with the dominance of opportunistic species, while sensitive and indifferent species to organic enrichment were mainly associated to the clean sandy downstream area. The marine biotic index (AMBI) was suitable for the discrimination of the biological and environmental gradients in the Obidos lagoon and was highly related with the gradient of organic matter content in this system.  相似文献   

Coastal ridge constructive processes at a multi-decadal scale in Barreta Island (southern Portugal)     

Xabier Herrero  Susana Costas  Katerina Kombiadou 《地球表面变化过程与地形》2020,45(2):411-423

Multiple ridges across prograding coasts may display variable geometries, commonly expressed through varying elevations. Changes in ridge elevation have been traditionally related to the occurrence of fluctuating progradation rates, which might, in turn, be driven by shifting environmental conditions. Here, we explore the geometry and growth mechanisms of multiple ridges, generated at Barreta Island (Ria Formosa, southern Portugal), as a consequence of the rapid progradation of the island over the last 70 years, following the artificial fixation of the downdrift Faro-Olhão inlet with jetties in 1955. The variability in the morphology of these features was analysed in combination with available wind and wave data, in order to better distinguish growth mechanisms and understand the main parameters determining the final geometry of the observed ridges. The results suggest that (1) most of the identified ridges fall in the beach ridge classification, as they have been mostly built by marine processes, and (2) the parameters derived from, or closely related to wave climate variability (e.g. progradation rates, storm occurrence) can jointly explain most of the observed morphological changes, while aeolian processes played a secondary role. Indeed, ridge geometry appears mainly controlled by progradation rates, with higher ridges associated with lower progradation rates. Progradation rate, in turn, is mostly related to longshore wave power, storminess, and the occurrence storm groups. Yet, the final configuration of ridges can also be affected by runup levels and onshore winds. Therefore, establishing the relation between ridge geometry and wave climate is not a straightforward task, because of the complex processes and interactions that control coastal morphodynamics. © 2019 John Wiley & Sons, Ltd.  相似文献   

Experimental modelling of flocculation processes-the case of Paraiba do Sul Estuary     

Alfredo TRENTO  Susana VINZN 《国际泥沙研究》2014,29(3):378-390

The aggregation dynamics of fine sediments was analysed through laboratory tests using Couette and disk flocculators.It was shown that floc sizes tend to increase as concentrations grow both in fresh and salt water,in agreement with the aggregation theory,and that equilibrium diameters are slightly greater in salt environments for flocs developed either under shear stress or by differential sedimentation.Their transport and the aggregation processes were preliminarily studied in the estuary of the Paraiba do Sul River using a particle tracking model and field data.The floc breakup process by shear stress was included in the model.Yield stresses,which were determined by fractal dimensions and differential density,were accounted for.After the calibration of the collision efficiency coefficients,the numerical model was able to predict floc sizes comparable with those measured at the Paraiba do Sul estuary,which,in turn,were similar to those obtained during the laboratory experiments in the Couette flocculator.  相似文献   

Deep-sea Fe-Mn Crusts from the Northeast Atlantic Ocean: Composition and Resource Considerations     

Susana Bolhão Muiños  James R. Hein  Martin Frank  José Hipólito Monteiro  Luís Gaspar  Tracey Conrad 《Marine Georesources & Geotechnology》2013,31(1):40-70

Eighteen deep-sea ferromanganese crusts (Fe-Mn crusts) from 10 seamounts in the northeast Atlantic were studied. Samples were recovered from water depths of ～1,200 to ～4,600 m from seamounts near Madeira, the Canary and Azores islands, and one sample from the western Mediterranean Sea.

The mineralogical and chemical compositions of the samples indicate that the crusts are typical continental margin, hydrogenetic Fe-Mn crusts. The Fe-Mn crusts exhibit a Co + Cu + Ni maximum of 0.96 wt%. Platinum-group element contents analyzed for five samples showed Pt contents from 153 to 512 ppb.

The resource potential of Fe-Mn crusts within and adjacent to the Portuguese Exclusive Economic Zone (EEZ) is evaluated to be comparable to that of crusts in the central Pacific, indicating that these Atlantic deposits may be an important future resource.  相似文献   

Degradation and Detoxification of Chlorophenols in Continuous‐Flow Fixed‐Bed Aerobic Reactors     

Alfredo Gallego  Virginia L. Gemini  Susana L. Rossi  Carlos E. Gómez  Gustavo D. Bulus Rossini  Sonia E. Korol 《洁净——土壤、空气、水》2011,39(8):774-780

An indigenous bacterial strain of Delftia sp. capable of degrading 2,4‐dicholorophenol and an indigenous bacterial community that degrades 2,4,6‐trichlorophenol (TCP) were employed to inoculate continuous down‐flow fixed‐bed reactors. Continuous‐reactors were constructed from PVC employing hollow PVC cylinders as support material. Synthetic wastewater was prepared by dissolving the corresponding chlorophenol in non‐sterile groundwater. Biodegradation was evaluated by spectrophotometry, chloride release, GC, and microbial growth. Detoxification was evaluated by using Daphnia magna as test organism. Delftia sp. was able to remove an average of 95.6% of DCP. Efficiency in terms of chemical oxygen demand (COD) was of 88.9%. The indigenous bacterial community that degrades TCP reached an average efficiency of 96.5 and 91.6% in terms of compound and COD removal, respectively. In both cases stoichiometric removal of chloride and detoxification was achieved. When synthetic wastewater feed was cut off for 7 days, both reactors showed a fast recovery after inflow restarting, reaching average outlet concentration values within 36 h. The promising behavior of the microorganisms and the low cost of the reactors tested allow us to suggest their possible application to remediation processes.  相似文献   

Accumulation of paralytic shellfish toxins in digestive gland of Octopus vulgaris during bloom events including the dinoflagellate Gymnodinium catenatum     

Pedro Reis Costa  Maria Joo Botelho  Susana Margarida Rodrigues 《Marine pollution bulletin》2009,58(11):1747-1750

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