Long-term monitoring of bottom environments of the continental slope off Otsuchi Bay,northeastern Japan     

Kazumasa Oguri  Yasuo Furushima  Takashi Toyofuku  Takafumi Kasaya  Masahide Wakita  Shuichi Watanabe  Katsunori Fujikura  Hiroshi Kitazato 《Journal of Oceanography》2016,72(1):151-166

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Cathodoluminescence of high-pressure feldspar minerals as a shock barometer     

Masahiro Kayama  Toshimori Sekine  Naotaka Tomioka  Hirotsugu Nishido  Yukako Kato  Kiyotaka Ninagawa  Takamichi Kobayashi  Akira Yamaguchi 《Meteoritics & planetary science》2018,53(7):1476-1488

Cathodoluminescence (CL) analyses were carried out on maskelynite and lingunite in L6 chondrites of Tenham and Yamato-790729. Under CL microscopy, bright blue emission was observed in Na-lingunite in the shock veins. Dull blue-emitting maskelynite is adjacent to the shock veins, and aqua blue luminescent plagioclase lies farther away. CL spectroscopy of the Na-lingunite showed emission bands centered at ~330, 360–380, and ~590 nm. CL spectra of maskelynite consisted of emission bands at ~330 and ~380 nm. Only an emission band at 420 nm was recognized in crystalline plagioclase. Deconvolution of CL spectra from maskelynite successfully separated the UV–blue emission bands into Gaussian components at 3.88, 3.26, and 2.95 eV. For comparison, we prepared K-lingunite and experimentally shock-recovered feldspars at the known shock pressures of 11.1–41.2 GPa to measure CL spectra. Synthetic K-lingunite has similar UV–blue and characteristic yellow bands at ~550, ~660, ~720, ~750, and ~770 nm. The UV–blue emissions of shock-recovered feldspars and the diaplectic feldspar glasses show a good correlation between intensity and shock pressure after deconvolution. They may be assigned to pressure-induced defects in Si and Al octahedra and tetrahedra. The components at 3.88 and 3.26 eV were detectable in the lingunite, both of which may be caused by the defects in Si and Al octahedra, the same as maskelynite. CL of maskelynite and lingunite may be applicable to estimate shock pressure for feldspar-bearing meteorites, impactites, and samples returned by spacecraft mission, although we need to develop more as a reliable shock barometer.  相似文献   

Implications for behavior of volatile elements during impacts—Zinc and copper systematics in sediments from the Ries impact structure and central European tektites          下载免费PDF全文

Zuzana Rodovská  Tomáš Magna  Karel Žák  Chizu Kato  Paul S. Savage  Frédéric Moynier  Roman Skála  Josef Ježek 《Meteoritics & planetary science》2017,52(10):2178-2192

Moldavites are tektites genetically related to the Ries impact structure, located in Central Europe, but the source materials and the processes related to the chemical fractionation of moldavites are not fully constrained. To further understand moldavite genesis, the Cu and Zn abundances and isotope compositions were measured in a suite of tektites from four different substrewn fields (South Bohemia, Moravia, Cheb Basin, Lusatia) and chemically diverse sediments from the surroundings of the Ries impact structure. Moldavites are slightly depleted in Zn (~10–20%) and distinctly depleted in Cu (>90%) relative to supposed sedimentary precursors. Moreover, the moldavites show a wide range in δ⁶⁶Zn values between 1.7 and 3.7‰ (relative to JMC 3‐0749 Lyon) and δ⁶⁵Cu values between 1.6 and 12.5‰ (relative to NIST SRM 976) and are thus enriched in heavy isotopes relative to their possible parent sedimentary sources (δ⁶⁶Zn = ?0.07 to +0.64‰; δ⁶⁵Cu = ?0.4 to +0.7‰). In particular, the Cheb Basin moldavites show some of the highest δ⁶⁵Cu values (up to 12.5‰) ever observed in natural samples. The relative magnitude of isotope fractionation for Cu and Zn seen here is opposite to oxygen‐poor environments such as the Moon where Zn is significantly more isotopically fractionated than Cu. One possibility is that monovalent Cu diffuses faster than divalent Zn in the reduced melt and diffusion will not affect the extent of Zn isotope fractionation. These observations imply that the capability of forming a redox environment may aid in volatilizing some elements, accompanied by isotope fractionation, during the impact process. The greater extent of elemental depletion, coupled with isotope fractionation of more refractory Cu relative to Zn, may also hinge on the presence of carbonyl species of transition metals and electromagnetic charge, which could exist in the impact‐induced high‐velocity jet of vapor and melts.  相似文献   

Corrigendum to “Climatological mean and decadal change in surface ocean pCO₂, and net sea–air CO₂ flux over the global oceans” [Deep Sea Res. II 56 (2009) 554–577]     

Taro Takahashi  Stewart C. Sutherland  Rik Wanninkhof  Colm Sweeney  Richard A. Feely  David W. Chipman  Burke Hales  Gernot Friederich  Francisco Chavez  Christopher Sabine  Andrew Watson  Dorothee C.E. Bakker  Ute Schuster  Nicolas Metzl  Hisayuki Yoshikawa-Inoue  Masao Ishii  Takashi Midorikawa  Yukihiro Nojiri  Arne Krtzinger  Tobias Steinhoff  Mario Hoppema  Jon Olafsson  Thorarinn S. Arnarson  Bronte Tilbrook  Truls Johannessen  Are Olsen  Richard Bellerby  C.S. Wong  Bruno Delille  N.R. Bates  Hein J.W. de Baar 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(11):2075-2076

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Pressure and temperature dependence of cation distribution in Mg-Mn olivine     

Tadashi Akamatsu  Kiyoshi Fujino  Mineo Kumazawa  Akio Fujimura  Manabu Kato  Hiroshi Sawamoto  Takamitsu Yamanaka 《Physics and Chemistry of Minerals》1988,16(2):105-113

Synthetic (Mg_0.51, Mn_0.49)₂SiO₄ olivine samples are heat-treated at three different pressures; 0, 8 and 12 GPa, all at the same temperature (～500° C). X-ray structure analyses on these single crystals are made in order to see the pressure effect on cation distribution. The intersite distribution coefficient of Mg and Mn in M1 and M2 sites, K _D = (Mn/Mg) _M1/(Mn/Mg) _M2, of these samples are 0.192 (0 GPa), 0.246 (8 GPa) and 0.281 (12 GPa), indicating cationic disordering with pressure. The small differences of cell dimensions between these samples are determined by powder X-ray diffraction. Cell dimensions b and c decrease, whereas a increases with pressure of equilibration. Cell volume decreases with pressure as a result of a large contraction of the b cell dimension. The effect of pressure on the free energy of the cation exchange reaction is evaluated by the observed relation between the cell volume and the site occupancy numbers. The magnitude of the pressure effect on cation distribution is only a fifth of that predicted from the observed change in volume combined with thermodynamic theory. This phenomenon is attributed to nonideality in this solid solution, and nonideal parameters are required to describe cation distribution determined in the present and previous experiments. We use a five-parameter equation to specify the cationic equilibrium on the basic of thermodynamic theory. It includes one energy parameter of ideal mixing, two parameters for nonideal effects, one volume parameter, and one thermal parameter originated from the lattice vibrational energy. The present data combined with some of the existing data are used to determine the five parameters, and the cation distribution in Mg-Mn olivine is described as a function of temperature, pressure, and composition. The basic framework of describing the cationic behavior in olivine-type mineral is worked out, although the result is preliminary: each of the determined parameters is not accurate enough to enable us to make a reliable prediction.  相似文献   

High time resolution monitoring of tropospheric temperature with a Radio Acoustic Sounding System (RASS)     

T. Tsuda  Y. Masuda  H. Inuki  K. Takahashi  T. Takami  T. Sato  S. Fukao  S. Kato 《Pure and Applied Geophysics》1989,130(2-3):497-507

We have observed the time-height variation of the temperature field in the upper troposphere using a Radio Acoustic Sounding System (RASS) which consists of the MU radar and a high-power acoustic transmitter. The fast beam steerability of the MU radar has made it possible to measure temperature profiles in a fairly wide height range in the upper troposphere (5–11 km), even under intense wind conditions. Observations were continued for about 32 hr on 24–26 December, 1986 with a time-height resolution of 30 min and 150 m. During the observation period, the tropospheric jet was so intense that the acoustic wavefronts were severely distorted. Using wind velocity profiles observed by the MU radar we have numerically estimated the propagation of acoustic wavefronts, and further determined favorable pointing directions for the MU radar to receive significant backscattering from refractive index fluctuations produced by the acoustic waves. Conventional radiosonde soundings were carried out every 6 hr, which showed a temperature decrease of 4 K/day in the upper troposphere during the observation period. Temperature profiles taken by RASS agree well with the radiosonde results.  相似文献   

Melting relationships in the system Fe-Feo at high pressures: Implications for the composition and formation of the earth's core     

Takumi Kato  A. E. Ringwood 《Physics and Chemistry of Minerals》1989,16(6):524-538

A reconnaissance investigation has been carried out on melting relationships in the system Fe-FeO at pressures up to 25 GPa and temperatures up to 2200° C using an MA-8 apparatus. Limited studies were also made of the Co-CoO and Ni-NiO systems. In the system FeFeO, the rapid exsolution of FeO from liquids during quenching causes some difficulties in interpretation of textures and phase relationships. The Co-CoO and Ni-NiO systems are more tractable experimentally and provide useful analogues to the Fe-FeO system. It was found that the broad field of liquid immiscibility present at ambient pressure in the Co-CoO system had disappeared at 18 GPa, 2200° C and that the system displayed complete miscibility between molten Co and CoO, analogous to the behaviour of the Ni-NiO system at ambient pressure. The phase diagram of the system Fe-FeO at 16 GPa and from 1600–2200° C was constructed from interpretations based on the textures of quenched run products. The solubility of FeO in molten iron is considerably enhanced by high pressures. At 16 GPa, the Fe-FeO eutectic contains about 10–15 mol percent FeO and the eutectic temperature in this iron-rich region of the system occurs at 1700±25° C, some 350° C below the melting point of pure iron at the same pressure. The solubility of FeO in molten Fe increases rapidly as temperature increases from 1700 to 2200° C. A relatively small liquid immiscibility field is present above 1900° C but is believed to be eliminated above 2200° C. This inference is supported by thermodynamic calculations on the positions of key phase boundaries. A single run carried out on an Fe₅₀ FeO₅₀ composition at 25 GPa and 2200° C demonstrated extensive and probably complete miscibility between Fe and FeO liquids under these conditions. The melting point of iron is decreased considerably by solution of FeO at high pressures; moreover, the melting point gradient (dP/dT) of the Fe-FeO eutectic is much smaller than that of pure iron and is also smaller than that of mantle pyrolite under the P, T conditions studied. These characteristics make it possible for melting of metal phase and segregation of the core to proceed within the Earth under conditions where most of the mantle remains below solidus temperatures. Under these conditions, the core would inevitably contain a large proportion of dissolved FeO. It is concluded therefore, that oxygen is likely to be the principal light element in the core. The inner core may not be composed of pure iron, as often proposed. Instead, it may consist of a crystalline oxide solid solution (Ni, Fe)₂O.  相似文献   

Characteristics of ionic components in precipitation in Kitakyushu City,Japan     

Yasuhiro Yamato  Takashi Yamada  Kozo Kido 《Journal of Atmospheric Chemistry》1993,17(4):325-337

Precipitation samples were collected by filtrating bulk sampler in Kitakyushu City, Japan, from January 1988 to December 1990. Volume weighted annual mean of pH was 4.93, but the pH distribution indicated that most probable value lay in the range pH 6.0–6.4. Volume weighted annual mean concentrations of major ionic components were as follows; SO ₄ ^2– : 84.2, NO ₃ ^– : 28.1, Cl^–: 86.3, NH ₄ ⁺ : 45.5, Ca²⁺: 63.3, Mg²⁺: 27.0, K⁺: 3.4, Na⁺: 69.0 µ eq l^–1. The highest concentrations of these ionic components were observed in winter and the lowest occurred in the rainy season. The ratio of ex-SO ₄ ^2– /NO ₃ ^– exhibited the lowest ratio in summer, and the highest ratio in winter. Good correlations were obtained between Cl^– and Na⁺, ex-SO ₄ ²⁺ and ex-Ca²⁺, NO ₃ ^– and ex-Ca²⁺, and NH ₄ ⁺ and ex-SO ₄ ^2– , respectively. However, no correlation between Cl^– and Na⁺ with Ca²⁺ was observed. The relationship of H⁺ with (ex-SO ₄ ^2– + NO ₃ ^– ) - (ex-Ca²⁺ + NH ₄ ⁺ ) indicated positive correlation.  相似文献   

Geomorphological study on a clastic accretionary prism: The Nankai Trough     

Kyoko  Okino Yukihiro  Kato 《Island Arc》1995,4(3):182-198

Abstract The Nankai Trough, off southwest Japan, is one of the best sites for the study of geomorphic characteristics of a clastic accretionary prism. A recent multibeam survey over the central and eastern parts of the Nankai accretionary prism has revealed a large variation of the topography along the trough axis. Analysis of the bathymetric data suggests the existence of prism deformational features of different scales, such as depressions, embayment structures and cusps. These structures are the results of slope instability caused by basement relief of subducted oceanic plate. Unstable slopes recover by new accretion and development of a low angle thrust. Small-scale deformation due to the subduction of a small isolated seamount is then adjusted to the regional trend. By contrast, a 30 km indentation of the wedge observed in the eastern part of the Nankai Trough, the Tenryu Cusp, has seemed to retain its geometry. The subducted Philippine Sea plate has deformed greatly near the eastern end of the Nankai Trough, because of the collision between the Izu-Ogasawara (Bonin) arc and central Japan. Therefore, the indentation may be the result of the continuous subduction of a basement high, such as the Zenisu Ridge, which has been formed under north-south compression due to the arc-arc collision.  相似文献   

Small scale turbulent diffusion determined with underwater flow visualization     

Takashi Ichiye  James McGrath  Michael Carnes 《Pure and Applied Geophysics》1982,120(4):758-771

Dye plumes were generated at three depths in the seasonal thermocline between 7 and 11 m, 22 km south of Key West on 21 August 1980 and photographed at about 10 second intervals with an underwater camera system. Eleven pairs of consecutive pictures are analyzed to determine the mean current vertical shear and the width of the plumes by positioning reference points relative to the rod attached to the camera system. The relative distances of reference points are calibrated with the stereophotogrammetric method for one pair. The eddy diffusivity is calculated by use of a model of turbulent diffusion developed byTaylor (1921). Its values range from 5 to 25 cm²s^–1 for the plume widths ranging from 33 to 132 cm. The Richardson number is calculated for each pair of pictures with the vertical density gradient estimated from temperature profiles. Its values are higher than the critical value of 0.25 except for one case. The diffusivity was higher by orders of magnitude than the molecular one and indicates the presence of turbulence together with billow like features of the plumes in spite of high Richardson numbers. This suggests that the billow turbulence might be caused by effects of surface gravity waves and not by the Kelvin-Helmholtz instability.  相似文献