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61.
This work is immediate continuation of Part I, using an identical method and evaluation for kinetic studies. The systems chalcocite-ethylene diamine tetra-acetic acid and chalcocite-ethylene diamine were studied. It was necessary to refine the geometrical model method for chalcocite in order to establish dissolution kinetics of polydispersions. This work confirms that chalcocite leaching proceeds through covellite even in the medium of complex-forming agents and kinetic equations for both leaching stages were evaluated with an attempt at physical interpretation. 相似文献
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On the relationship of thunderstorm ice hydrometeor characteristics and total lightning measurements 总被引:1,自引:0,他引:1
Wiebke Deierling John Latham Walter A. Petersen Scott M. Ellis Hugh J. Christian Jr. 《Atmospheric Research》2005,76(1-4):114
Satellite-borne and ground-based devices for the detection of lightning offer the opportunity to explore relationships–on all significant scales up to global–between lightning frequency, f, and other thundercloud parameters. Calculations predict that f is proportional to the product of the downflux p of solid precipitation and the upward mass flux, I, of ice crystals. This prediction has received support from limited computational studies. The physical reasons for such a relationship are explained in terms of the paramount role of ice in the electrification of thunderstorms. Herein, this prediction is subjected to further, preliminary examination through analysis of lightning and dual-polarimetric radar data collected during the STERAO experiment conducted in Northern Colorado during the summer of 1996. The analysis has yielded some highly provisional support for this flux hypothesis. Computed trends of radar derived hydrometeor fractions of solid precipitation and small ice show correlation to the total lightning frequency and raise the possibility of determining values of p and/or I from lightning measurements.It is shown that the extent to which the observed correlations between f and both solid precipitation and small ice trends are or are not strong can provide an indication as to whether the lightning activity is limited by the available concentrations of precipitating or non-precipitating ice in the upper regions of the charging zone of the thundercloud, where most of the charge transfer occurs. It is demonstrated that the most accurate determinations of precipitation rate p from measurements of lighting frequency f are likely to be for conditions where the field-growth is limited by the availability of graupel pellets. It is shown that the simultaneous time variations of f and solid precipitation trends of the type obtained in the STERAO experiment could enable us to determine the nature of the dominant glaciation process operative in the thunderclouds studied. 相似文献
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Embedding reach-scale fluvial dynamics within the CAESAR cellular automaton landscape evolution model 总被引:2,自引:2,他引:2
We introduce a new computational model designed to simulate and investigate reach-scale alluvial dynamics within a landscape evolution model. The model is based on the cellular automaton concept, whereby the continued iteration of a series of local process ‘rules’ governs the behaviour of the entire system. The model is a modified version of the CAESAR landscape evolution model, which applies a suite of physically based rules to simulate the entrainment, transport and deposition of sediments. The CAESAR model has been altered to improve the representation of hydraulic and geomorphic processes in an alluvial environment. In-channel and overbank flow, sediment entrainment and deposition, suspended load and bed load transport, lateral erosion and bank failure have all been represented as local cellular automaton rules. Although these rules are relatively simple and straightforward, their combined and repeatedly iterated effect is such that complex, non-linear geomorphological response can be simulated within the model. Examples of such larger-scale, emergent responses include channel incision and aggradation, terrace formation, channel migration and river meandering, formation of meander cutoffs, and transitions between braided and single-thread channel patterns. In the current study, the model is illustrated on a reach of the River Teifi, near Lampeter, Wales, UK. 相似文献
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Tom Koch Kenneth Denike 《Stochastic Environmental Research and Risk Assessment (SERRA)》2007,21(5):523-531
The problem is not uncertainty—proposed here as an inevitable condition—but the chimera of certainty asserted by most contemporary
researchers. Problems of data definition, collection, and their use are reviewed in terms of spatial epidemiology and health
data with examples drawn from several areas of contemporary health research. The argument is that preconceptions limit data
modeled in a manner assuming its completeness. The result, as the West Nile Virus example seeks to demonstrate, may obscure
other patterns and limit avenues of research. 相似文献
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A New Lichenometric Dating Curve For Southeast Iceland. 总被引:2,自引:0,他引:2
Tom Bradwell 《Geografiska Annaler: Series A, Physical Geography》2001,83(3):91-101
This paper presents a new lichenometric dating curve for southeast Iceland. The temporal framework for the curve is based on reliably dated surfaces covering the last 270 years, making it the best constrained study of this nature conducted in Iceland. The growth of lichen species within Rhizocarpon Section Rhizocarpon is non-linear over time, with larger (older) thalli apparently growing more slowly. The linear 'growth' curves derived previously by former authors working in Iceland represent only part of a curve which has an overall exponential form. Reasons for the non-linearity of the new dating curve are probably physiological, although climatic change over the last three centuries cannot be ruled out. Use of linear 'growth' curves in Iceland is problematic over time-spans of more than c . 80 years. Pre-20th century moraines dated using a constant, linear relationship between lichen size and age are probably older than previously believed. Those moraines lichenometrically 'dated' to the second half of the 19th century in Iceland may actually pre-date this time by several decades (30–100 years), thus throwing doubt on the exact timing of maximum glaciation during the 'Little Ice Age'. 相似文献