Valorization of olive stone as adsorbent of chromium(VI): comparison between laboratory- and pilot-scale fixed-bed columns     

M. Ángeles Martín-Lara  Mª Carmen Trujillo Miranda  A. Ronda Gálvez  A. Pérez Muñoz  M. Calero de Hoces 《International Journal of Environmental Science and Technology》2017,14(12):2661-2674

The main aim of this work is to study the effect of scaling in the biosorption of chromium(VI) onto olive stone in two different fixed-bed columns. Firstly, the effect of flow rate, bed depth and inlet concentration of Cr(VI) in both columns was analyzed. The results revealed a better operation for lower flow rates, higher bed heights and lower inlet concentrations of metal. When decreasing flow rate, the operation time of the column increases. Therefore, as the solution flow rate increased the breakthrough and the exhaustion times decreased. An increase in bed depth increases the quantity of chromium eliminated and thus, the higher sorption capacity of the system. A decrease in the inlet concentration of chromium produces a delay in exhaustion time, and larger volumes of solution could be treated. The results were fitted to the BDST model, obtaining that the adsorptive capacity of the bed depth is similar in laboratory- and pilot-scale fixed-bed columns, considering the biosorption capacity as a biosorption-coupled reduction process. Results also could indicate that scaling affects more to the reduction process than properly biosorption process. The experimental data were also fitted to Adams–Bohart, Thomas, Yoon–Nelson and dose–response models. A good fit of the biosorption process of Cr(VI) was found for dose–response and Adams–Bohart models.  相似文献   

On the focal mechanism of the 26.05.1975 North Atlantic event contribution from tsunami modeling     

F. Kaabouben  A. I. Brahim  E. Toto  M. A. Baptista  J. M. Miranda  P. Soares  J. F. Luis 《Journal of Seismology》2008,12(4):575-583

The 1975 May 26 earthquake, of magnitude Ms = 7.9, occurred in the North Atlantic close to the Azores Archipelago. Its epicentre, as given by US Geological Survey, was 17.5° W, 35.9° N, 200 km south of the Gloria Fault. Several authors determined the focal mechanism as a dextral strike-slip event with no significant dip-slip component, compatible with the relative motion between Eurasia and Nubia plates but away from the presumed plate boundary. The 1975 earthquake generated a tsunami of small amplitude, recorded at the Portuguese tide-gauge network, in Spain and Northern Africa. The peculiar location of the earthquake and tsunami source and the generation of a noticeable tsunami were already discussed by several authors, but up to now, no direct modelling of the tsunami generation and propagation was made to judge the set of source solutions obtained by seismological analysis. In this paper, we present tsunami simulations, backward ray tracing and forward non-linear shallow water simulations using data from Iberia and Azores and Northern Africa. We show that a good fit between observed data and synthetic waveforms can be obtained with a focal mechanism with no significant dip-slip component, favouring its interpretation as almost pure dextral strike-slip event located in an old fracture zone south of Gloria Fault.  相似文献   

Assessment of mercury contamination and human exposure associated with coastal disposal of waste from a cinnabar mining operation, Palawan, Philippines   总被引：2，自引：0，他引：2  

T. M. Williams  J. M. Weeks  A.N. Apostol Jr.  C. R. Miranda 《Environmental Geology》1999,39(1):51-60

 An integrated geochemical and toxicological assessment of environmental mercury contamination and attendant human exposure in Honda Bay, Palawan was undertaken in 1995 following a nationally reported pollution scare centered on a coastal jetty, Sitio Honda Bay, constructed using approximately 1 million tons of tailings and beneficiation waste from a cinnabar mine. Mercury (Hg) data for marine and fluvial sediments, fish tissues and human hair indicate that the toxicological hazard is considerably lower than initially reported by state environment and health officials. Typical Hg concentrations in surficial Honda Bay sediments were found to lie within the global background range (<60 μg/kg). Downcore profiles provide no evidence of enhanced Hg fluxes coincident with the onset of mining and/or coastal tailings disposal. The mean and median Hg concentrations recorded in tissues of six species of Honda Bay fish are compliant with thresholds established by the US Environmental Protection Agency (US-EPA) for marketable stocks. Earlier reports of 'Minamata range' Hg concentrations in fish and shellfish from Honda Bay remain unsubstantiated. Geochemical analyses of samples of the Sitio Honda Bay substrate have confirmed the prevalence of solid-phase Hg concentrations to ca. 340 mg/kg. The speciation of Hg is, however, dominated by secondary oxides of low bioavailability. The mean Hg concentration in hair from Sitio Honda Bay residents (4.41 mg/kg) was found to be statistically analogous to that for a neighbouring coastal community unimpacted by the coastal disposal of mine waste. A negligible residential exposure factor is thus inferred for the former. Relatively high hair Hg burdens prevail throughout the coastal Honda Bay population, consistent with significant methyl Hg ingestion through daily fish consumption. The data presented provide no environmental or toxicological justification for immediate remedial action. Received: 14 May 1998/Accepted: 1 September 1998  相似文献   

Morpho-tectonic analysis of the Azores Volcanic Plateau from a new bathymetric compilation of the area   总被引：13，自引：0，他引：13  

Lourenço  N.  Miranda  J.M.  Luis  J.F.  Ribeiro  A.  Victor  L.A. Mendes  Madeira  J.  Needham  H.D. 《Marine Geophysical Researches》1998,20(3):141-156

The existing studies of the Azores triple junction, although based on specific geological or geophysical data, largely rely upon morphological considerations. However, there is no systematic bathymetric coverage of this area, and the quality of the available bathymetric charts does not allow consistent morpho-structural analysis.In this work we present a new bathymetric grid elaborated with all the available data sources in an area comprised between 24° W to 32° W and 36° N to 41° N. The basic data set corresponds to the merge of NGDC data with new swath profiles. This new map, included as an Appendix, combined with other results from seismology and neotectonics, is the basis for the study of the morpho-structural pattern of the Azores area, the present day stress field and its implications on the current view of the Azores geodynamics.As a major result, we conclude that the Azores region is controlled by two sets of conjugated faults with 120° and 150° strikes that establish the framework for the onset of volcanism, expressing as linear volcanic ridges or as point source volcanism. This interaction develops what can be considered as the morphological signature of the Azores Spreading axis segmentation. We argue that the Azores domain, presently in a broad transtensional regime, is acting simultaneously as a ultra slow spreading centre and as a transfer zone between the MAR and the dextral Gloria Fault, as it accommodates the differential shear movement between the Eurasian and African plates.  相似文献   

Evaluation of seismic displacement demands from the September 19, 2017 Puebla‐Morelos (Mw = 7.1) earthquake in Mexico City          下载免费PDF全文

Jorge Ruiz‐García  Eduardo Miranda 《地震工程与结构动力学》2018,47(13):2726-2732

This short communication presents the assessment of seismic inelastic and elastic displacement demands computed from earthquake ground motions (EQGMs) recorded in Mexico City during the intermediate‐depth intraslab Puebla‐Morelos earthquake on 19 September 2017 (Mw = 7.1). Evaluation is conducted by means of peak elastic and inelastic displacement demand spectra, inelastic displacement ratio, C_R, spectra, and generalized interstory drift spectra computed for selected recording stations located in different soil sites of Mexico City, including those located in areas of reported collapsed buildings. Results of this study confirm previous observations made from interplate (subduction) EQGMs that peak inelastic displacement demands are greater than corresponding elastic counterparts for short‐to‐medium period structures, while the opposite is true for medium‐to‐long period structures. Possible basin site effects were identified from generalized interstory drift spectra. It is also shown that an equation introduced in the literature to obtain estimates of C_R developed from interplate EQGMs provides also a good estimate for mean C_R computed from the intermediate‐depth intraslab EQGMs.  相似文献   

Evaluation of bias on the probability of collapse from amplitude scaling using spectral-shape-matched records     

Héctor Dávalos  Eduardo Miranda 《地震工程与结构动力学》2019,48(8):970-986

Although for many years it was thought that amplitude scaling of acceleration time series to reach a target intensity did not introduce any bias in the results of nonlinear response history analyses, recent studies have showed that scaling can lead to an overestimation of deformation demands with increasing scale factors. Some studies have suggested that the bias can be explained by differences in spectral shape between the response spectra of unscaled and scaled records. On the basis of these studies, some record selection procedures assume that if records are selected using spectral-shape-matching procedures, amplitude scaling does not induce any bias on the structural response. This study evaluates if bias is introduced on lateral displacement demands and seismic collapse risk estimates even when spectral shape is carefully taken into consideration when selecting ground motions. Several single-degree-of-freedom and multiple-degree-of-freedom systems are analyzed when subjected to unscaled and scaled ground motions selected to approximately match the mean and the variance of the conditional spectrum at the target level of intensity. Results show that an explicit consideration of spectral shape is not enough to avoid a systematic overestimation of lateral displacement demands and collapse probabilities as the scale factor increases. Moreover, the bias is observed in practically all cases for systems with strength degradation and it increases with decreasing period and decreasing lateral strength relative to the strength required to remain elastic. Key reasons behind the bias are presented by evaluating input energy, causal parameters, and damaging pulse distributions in unscaled and scaled ground motion sets.  相似文献   

Strength-reduction factors for the design of light nonstructural elements in buildings     

Athanasia K. Kazantzi  Eduardo Miranda  Dimitrios Vamvatsikos 《地震工程与结构动力学》2020,49(13):1329-1343

Strength-reduction factors that reduce ordinates of floor spectra acceleration due to nonlinearity in the secondary system are investigated. In exchange for permitting some inelastic deformation to occur in the secondary system or its supports, these strength reduction factors allow to design the nonstructural elements or their supports for lateral forces that are smaller than those that would be required to maintain them elastically during earthquakes. This paper presents the results of a statistical analysis on component strength-reduction factors that were computed considering floor motions recorded on instrumented buildings in California during various earthquakes. The effect of yielding in the component or its anchorage/bracing in offering protection against excessive component acceleration demands is investigated. It is shown that strength-reduction factors computed from floor motions are significantly different from those computed from ground motions recorded on rock or on firm soils. In particular, they exhibit much larger reductions for periods tuned or nearly tuned to the dominant modal periods of the building response. This is due to the large differences in frequency content of ground motions and floor motions, with the former typically characterized by wide-band spectra whereas the latter are characterized by narrow-band spectra near periods of dominant modes in the response of the building. Finally, the study provides approximate equations to estimate component strength-reduction factors computed through nonlinear regression analyses.  相似文献   

Partitioning of rainfall in a cocoa (Theobroma cacao lour.) plantation     

Ricardo Augusto  Calheiros De Miranda 《水文研究》1994,8(4):351-358

To consolidate knowledge of some aspects of the partitioning of incident rainfall into throughfall, stemflow and interception loss, a study was made in a typical cocoa (Theobroma cacao Lour.) plantation in south-east Bahia, Brazil. The samples were collected, on a per shower basis, from locations at different levels in the canopy over a period of two and a half years. During the period studied, of the amount of incident rainfall reaching the cocoa plantation, on average 16% was retained by shelter trees, 19% by cocoa trees and 9% by the ground litter. Losses due to interception caused some variations and were mainly regulated by temporal variations and by the amount and intensity of rainfall in the plantation. The amount of rainfall intercepted, as determined in this study, is comparable with other tropical stands, but important differences do exist and are believed to be influenced by the previous level of moisture availability within the cocoa plantation.  相似文献   

Seed magnetic Fields Generated by Primordial Supernova Explosions     

Oswaldo D. Miranda  Merav Opher  & Reuven Opher 《Monthly notices of the Royal Astronomical Society》1998,301(2):547-550

The origin of the magnetic field in galaxies is an open question in astrophysics. Several mechanisms have been proposed related, in general, to the generation of small seed fields amplified by a dynamo mechanism. In general, these mechanisms have difficulty in satisfying both the requirements of a sufficiently high strength for the magnetic field and the necessary large coherent scales. We show that the formation of dense and turbulent shells of matter, in the multiple explosion scenario of Miranda &38; Opher for the formation of the large-scale structures of the Universe, can naturally act as a seed for the generation of a magnetic field. During the collapse and explosion of Population III objects, a temperature gradient not parallel to a density gradient can naturally be established, producing a seed magnetic field through the Biermann battery mechanism. We show that seed magnetic fields ∼ 10⁻¹²–10⁻¹⁴ G can be produced in this multiple explosion scenario on scales of the order of clusters of galaxies (with coherence length L  ∼ 1.8 Mpc) and up to ∼ 4.5 × 10⁻¹⁰ G on scales of galaxies ( L  ∼ 100 kpc).  相似文献   

Evaluation of the crustal deformations in the northern region of Lake Nasser (Egypt) derived from 8 years of GPS campaign observations     

A. Rayan  R.M.S. Fernandes  H.A. Khalil  S. Mahmoud  J.M. Miranda  A. Tealab 《Journal of Geodynamics》2010,49(3-4):210-215

The proper evaluation of crustal deformations in the Aswan (Egypt) region is crucial due to the existence of one major artificial structure: the Aswan High Dam. This construction induced the creation of one of the major artificial lakes: Lake Nasser, which has a surface area of about 5200 km² with a maximum capacity of 165 km³. The lake is nearly 550 km long (more than 350 km within Egypt and the remainder in Sudan) and 35 km across at its widest point. Great attention has focused on this area after the November 14, 1981 earthquake (M_L = 5.7), with its epicenter southwest of the High Dam.In order to evaluate the present-day kinematics of the region, its relationship with increasing seismicity, and the possible influence of the Aswan High Dam operation, a network of 11 GPS sites was deployed in the area. This network has been reobserved every year since 2000 in campaign style. We present here the results of the analysis of the GPS campaign time-series. These time-series are already long enough to derive robust solutions for the motions of these stations. The computed trends are analyzed within the framework of the geophysical and geological settings of this region. We show that the observed displacements are significant, pointing to a coherent intraplate extensional deformation pattern, where some of the major faults (e.g., dextral strike-slip Kalabsha fault and normal Dabud fault) correspond to gradients of the surface deformation field. We also discuss the possible influence of the water load on the long-term deformation pattern.  相似文献