Laboratory study of the rates and products of the phototransformations of naphthalene adsorbed on samples of titanium dioxide,ferric oxide,muscovite, and fly ash     

Chantal Guillard  Hervé Delprat  Can Hoang-van  Pierre Pichat 《Journal of Atmospheric Chemistry》1993,16(1):47-59

The photodegradation of naphthalene (NPH), chosen as a model of polynuclear aromatic pollutants, has been studied in the presence of a layer of four water-insoluble inorganic solids which can be found in the troposphere (TiO₂, Fe₂O₃, muscovite, and a fly ash sample). Direct photolysis of NPH is negligible at >340 nm. Dark adsorption of NPH on TiO₂ (mainly anatase, nonporous, 50 m² g^–1) at 293 K corresponds to a surface coverage ofca. 50% at equilibrium. Under these conditions (saturated surface), the stationary-state photocatalytic degradation reaches 0.4 molecule nm^–2 h^–1 (>340 nm, radiant fluxca. 22 mW cm^–2). Dioxygen is required and its partial pressure in air is such that the degradation is zero order in O₂. Water vapor markedly increases the rate. The other particulates have also an effect, less important than that of TiO₂, however quite noticeable with respect to surface area unit for the fly ash sample which contains 3.2% Fe₂O₃. Apart from 1,4-naphthoquinone, which is the main intermediate product in all cases, 2-naphthol, phthalide, phthaldialdehyde, phthalic acid, acetophenone, benzaldehyde, benzoic acid are also formed on dry TiO₂. Depending on their volatility, these compounds are transferred to the gas phase or remain principally adsorbed on the solid particles where they are further transformed. For instance, phthalic acid (or anhydride) and benzoic acid are generated from 1,4-naphthoquinone. Degradation mechanisms are briefly discussed.  相似文献   

A study of motions in the winter mesosphere using the partial reflection drift technique     

R.A. Vincent  T.J. Stubbs 《Planetary and Space Science》1977,25(5):441-455

Intensive partial reflection drift observations were made at Adelaide (35°S) for a seven day period in June 1973. The results have been analysed to isolate the prevailing motion and oscillations of various time scales: planetary, 24 hr, 12 hr and gravity waves. Each is discussed in turn with particular emphasis on the variability of energy from day to day and as a function of height. Evidence is presented for the local generation of planetary waves, the presence of the evanescent S_?2¹ mode in the 24 hr oscillation, the influence of the S₄² mode in the 12 hr oscillation and a definite polarization of gravity waves. The energies of all the forms of motion are shown to decay exponentially with increasing height and the deposition of energy and momentum in the upper mesosphere and lower thermosphere is discussed.  相似文献   

The hydrogen balmer lines and the structure of the quiet solar chromosphere     

Pierre Mein  Nicole Mein 《Solar physics》1975,40(2):317-328

Spectra of Hα, Hβ and Hδ have been taken under good seeing conditions with the vacuum tower telescope of Sacramento Peak Observatory. Intensity curves are given at various wavelengths in these lines to permit further comparison with a theoretical model. Moreover, considering in each case the range of height in which the lines are almost optically thin and using a few approximations, the following results are derived: between 2000 and 6000 km above the limb the average thermal + turbulent velocity of the atoms is found to increase from 20 km s^?1 to 30 km s^?1 and the mean number of hydrogen atoms per cm³ in level 2 is given by $$\log n_2 {\text{ = }}4.5{\text{ }} - {\text{ 0}}{\text{.00056(}}z - 2000)$$ z being the altitude above the limb in km. For line profile computations a new interpolation formula is presented; it gives good profiles with a small number of scans, saving microphotometer time.  相似文献   

Multi-stage mixing in subduction zones: Application to Merapi volcano (Java island, Sunda arc)     

Vinciane Debaille  Dominique Weis  Pierre Schiano 《Geochimica et cosmochimica acta》2006,70(3):723-741

Many studies have argued for the contribution of at least three components, namely the mantle wedge, the subducted oceanic crust, and its sediment cover, to describe the geochemistry of island arc volcanics. However, isotope correlations reflecting a simple binary mixing can be observed at the scale of a single arc island or volcano. Here we investigate the possibility that these trends reflect pseudo-binary mixing relationships in a three-component system. We present a simplified, two-stage model for the systematic isotope modelling of a cogenetic suite of arc lavas. This includes metasomatism of portions of the mantle wedge by hydrous phases released from the down-going oceanic crust, and sediments, followed by progressive mixing and melting. A consequence of this model is that it leads to a two end-member mixing process from the mantle wedge, oceanic crust, and sediment components. To solve the model we reduce it to a step-by-step procedure combined with a Monte-Carlo simulation. The procedure consists of: (i) producing a large number of random values on each variable of the model; (ii) using the computed values to calculate the isotopic compositions of lavas; and (iii) comparing the obtained isotopic compositions with measured data. Applied to a new set of Sr, Nd, and Pb isotope data for volcanics (basalts, basaltic andesites, trachybasalts, and basaltic trachyandesites) from Merapi volcano (Java island, Sunda arc), the model successfully reproduces the binary mixing relationships previously documented for the medium-K and high-K lava series from this volcano, thus giving further support to the hypothesis that this distinction is inherited from the primary magmas and primarily reflects a property of the mantle source. The results allow identification of a set of numerical values for bulk partition coefficients (solid/hydrous fluid, and solid/H₂O-rich melt) and variables (e.g., the mass ratio between the metasomatizing phase and the mantle wedge), which can be used for quantitative arc-lava petrogenetic calculations. They also require a direct relationship between dehydration of the slab and melting of the metasomatized mantle wedge. Finally, our evaluation shows that for isotope modelling of the Merapi lavas, the two-stage procedure is controlled more by the considered source components (mantle wedge, oceanic crust, sediments, and their derivatives) than by the various processes involved (dehydration, melting, and mixing).  相似文献   

Response to the Comment by G. Druschel and M. Borda on “Pyrite dissolution in acidic media”     

Michael Descostes  Pierre Vitorge 《Geochimica et cosmochimica acta》2006,70(20):5251-5252

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Comment on “The Moroccan Hercynides” by Hoepffner et al. (Journal of African Earth Sciences, vol. 43, pp. 144–165)     

Martin Roddaz  Jean-Claude Soula  Mohamed Ben Abbou  Stphane Brusset  Pierre Debat  Ahmed Ntarmouchant  Youssef Driouch  Didier Bziat 《Journal of African Earth Sciences》2006,45(4-5):515-517

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Review: Microbial biocenoses in pristine aquifers and an assessment of investigative methods   总被引：2，自引：6，他引：2  

Nico Goldscheider  Daniel Hunkeler  Pierre Rossi 《Hydrogeology Journal》2006,14(6):926-941

The current knowledge of microbial biocenoses (communities) in pristine aquifers is presented in a review, which also discusses their relevance for questions of groundwater protection. Aquifers are heterogeneous on all scales and structured in a variety of habitats. The void spaces in many aquifers are small. The biocenoses are thus predominantly composed of microorganisms and, often, microinvertebrates. Larger voids and macroorganisms occur in karst cavities. Due to the absence of light, the biocenoses depend on chemical energy resources, which are, however, scarce in non-contaminated groundwater. The microorganisms thus show small cell sizes, low population densities and reduced activity; they developed specific strategies to survive oligotrophic conditions. The review also discusses the impact of contamination on the biocenoses, and the potential use of the biocenoses or specific organisms as indicators for groundwater quality, and the limits of this approach. Bacteria are either planktonic or attached to aquifer material, which requires both fluid and solid phase sampling. Most groundwater bacteria are viable but non-culturable. Consequently, cultivation techniques give an incomplete picture of the biocenoses, while methods from molecular microbiology provide genetic fingerprints of the entire community. Different analytical methods are available to count microorganisms, identify species, characterise microbial diversity, and measure activity.  相似文献   

Mathematical modelling is a necessary step in biology and in environmental sciences     

Pierre Auger  Jean-Christophe Poggiale 《Comptes Rendus Geoscience》2006,338(4):223-224

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Atténuation de l'intensité macrosismique pour la France métropolitaine : importance de l'intensité épicentrale     

Pierre Arroucau  Antoine Mocquet  Pierre Vacher 《Comptes Rendus Geoscience》2006,338(9):596-605

The main result of this work is to show that macroseismic intensity decay with distance strongly depends on the epicentral intensity. An attenuation law that takes this parameter into account is proposed for Metropolitan France, from the analysis of SISFRANCE macroseismic database. Such a model significantly reduces the difference between observed and theoretical intensities. A map of the attenuation variations is also set up for Metropolitan France. No major site effects are observed, but at a broad scale, young Alpine regions display a stronger attenuation than old Hercynian regions. To cite this article: P. Arroucau et al., C. R. Geoscience 338 (2006).  相似文献   

Optimization of nonconventional wells under uncertainty using statistical proxies     

Vincent Artus  Louis J. Durlofsky  Jérôme Onwunalu  Khalid Aziz 《Computational Geosciences》2006,10(4):389-404

The determination of the optimal type and placement of a nonconventional well in a heterogeneous reservoir represents a challenging optimization problem. This determination is significantly more complicated if uncertainty in the reservoir geology is included in the optimization. In this study, a genetic algorithm is applied to optimize the deployment of nonconventional wells. Geological uncertainty is accounted for by optimizing over multiple reservoir models (realizations) subject to a prescribed risk attitude. To reduce the excessive computational requirements of the base method, a new statistical proxy (which provides fast estimates of the objective function) based on cluster analysis is introduced into the optimization process. This proxy provides an estimate of the cumulative distribution function (CDF) of the scenario performance, which enables the quantification of proxy uncertainty. Knowledge of the proxy-based performance estimate in conjunction with the proxy CDF enables the systematic selection of the most appropriate scenarios for full simulation. Application of the overall method for the optimization of monobore and dual-lateral well placement demonstrates the performance of the hybrid optimization procedure. Specifically, it is shown that by simulating only 10% or 20% of the scenarios (as determined by application of the proxy), optimization results very close to those achieved by simulating all cases are obtained.  相似文献