Experimental study on reduction of U (Ⅵ) by an anaerobic bacterium, Shewanella putrefaciens: Application to sandstone-hosted interlayer oxidation-zone type uranium deposits, China     

MIN Maozhong  XU Huifang  L.L.Barton  PENG Xinjian  Yin Lin  WANG Rucheng 《中国科学D辑(英文版)》2005,48(3)

An experimental study on reduction of U (Ⅵ) by anaerobic bacteria, Shewane//a putrefaciens, is first reported here in China. The experimental conditions were: 35℃ and pH =7.0-7.4, corresponding to a physicochemical environments in which the sandstone-hosted interlayer oxidation-zone type uranium deposit formed in Northwest China's Xinjiang. Bacteria adopted in the present experiment, Shewanella putrefaciens, occur extensively in natural environment. Our study shows that nano-crystal precipitates of uraninite quickly occurred on the surface of the cells within one week. It was found that the pitchblende was characterized by a random arrangement of uraninite nanocrystals (2-4 nm) in it, significantly different from natural pitchblende in which uraninite nanocrystals are arranged in order. Finally, a possible mechanism of uranium biomineralization by microorganisms in the deposits is discussed. Our investigation may supply a technical train of thoughts for bioremediation of nuclear-contaminated water environments and for underground dissolving extraction of the sandstone-hosted uranium ores.  相似文献   

Establishment of apparent quantum yield and maximum ecosystem assimilation on Tibetan Plateau alpine meadow ecosystem     

XU Lingling  ZHANG Xianzhou  SHI Peili  YU Guirui 《中国科学D辑(英文版)》2005,48(Z1)

The alpine meadow is widely distributed on the Tibetan Plateau with an area of about 1.2×106kn2. Damxung County, located in the hinterland of the Tibetan Plateau, is the place covered with this typical vegetation. An open-path eddy covariance system was set up in Damxung rangeland station to measure the carbon flux of alpine meadow from July to October,2003. The continuous carbon flux data were used to analyze the relationship between net ecosystem carbon dioxide exchange (NEE) and photosynthetically active radiation (PAR), as well as the seasonal patterns of apparent quantum yield (α) and maximum ecosystem assimilation (Pmax).Results showed that the daytime NEE fitted fairly well with the PAR in a rectangular hyperbola function, with α declining in the order of peak growth period (0.0244 μmolCO2 · μmol-1pAR) ＞early growth period ＞ seed maturing period ＞ withering period (0.0098 μmolCO2 · μmol-1pAR).The Pmax did not change greatly during the first three periods, with an average of 0.433mgCO2· m-2· s-1, i.e. 9.829 μmolCO2· m-2· s-1. However, during the withering period, Pmax was only 0.35 mgCO2 · m-2 · s-1, i.e. 7.945 μmolCO2 · m-2 · s-1. Compared with other grassland ecosystems, the α of the Tibetan Plateau alpine meadow ecosystem was much lower.  相似文献   

Vertical dynamic and thermodynamic characteristics of urban lower boundary layer and its relationship with aerosol concentration over Beijing   总被引：1，自引：0，他引：1  

ZHOU Mingyu  YAO Wenqing  XU Xiangde  YU Haiqing 《中国科学D辑(英文版)》2005,48(Z2)

By utilizing observational data from a 325 m tower of the Institute of Atmospheric Physics (IAP), Chinese Academy of Sciences (CAS) on March 19-29, 2001 and August 11-25, 2003, a comprehensive study was conducted on the vertical dynamical and thermodynamic characteristics of the urban lower boundary layer (ULBL) and its relationship with aerosol concentration over Beijing. Firstly, a comparative analysis was made on the gradient data (wind, temperature and humidity), ultrasonic data (atmospheric turbulences) and air-quality observations at different tower heights (47, 120 and 280 m). Secondly, a diagnosis was made to reveal the major features of normalized variances of velocity and temperature, turbulence kinetic energy as well as their relationship with aerosol concentrations. Furthermore, the characteristics of the ULBL vertical structure and the TSP concentration/distribution variations during a sand/dust weather process were also analyzed. The outcome of the study showed that under unstable stratification, the normalized variances of velocity (σu/u*, σv/u*, σw/u*) and temperature (σT/T*) at 47 and 120 m heights fit the Monin-Obukhov similarity (MOS) framework and the fitting formulas were given out accordingly. According to the stratification parameter (z′/L), the stable ULBL could be divided into 2 zones. With z′/L<0.1, it was a weakly stable zone and MOS framework was applicable. The other was a highly stable zone with z′/L>0.1 and the normalized velocity variances tended to increase along with higher stability, but it remained constant for normalized temperature variances. At daytime, the near-surface layer includes two heights of 47 and 120 m, while 280 m has been above it. The ULBL analysis in conjunction with a sand/dust weather process in Beijing in March 2001 indicated that the maximum concentration of Total Suspended Particulates (TSP) at 320 m reached 913.3 μg/m3 and the particles were transported from the upper to lower ULBL, which was apparently related to the development process of a low-level jet and its concomitant strong sinking motion.  相似文献   

Spatial character of the gaseous and particulate state compound correlation of urban atmospheric pollution in winter and summer   总被引：1，自引：0，他引：1  

XU Xiangde  SHI Xiaohui  XIE Lian  DING Guoan  MIAO Qiuju  MA Jianzhong  ZHENG Xiangdong 《中国科学D辑(英文版)》2005,48(Z2)

The spatial/temporal variation information of atmospheric dynamic-chemical processes at observation site points of the "canopy" boundary of Beijing urban building ensemble and over urban area "surface", as well as the seasonal correlation structure of the gaseous and particulate states of urban atmospheric pollution (UAP) and its seasonal conversion feature at observation points are investigated, using the comprehensive observation data of the Beijing City Air Pollution Observation Experiment (BECAPEX) in winter and summer 2003 with a "point-surface" combined research approach. By using "one dimension spatial empirical orthogonal function (EOF)" principal component analysis (PCA) mode, the seasonal change of gaseous and particulate states of atmospheric aerosols and the association feature of pollutant species under the background of the complicated structure of urban boundary layer (UBL) are analyzed. The comprehensive analyses of the principal components of particle concentrations,gaseous pollutant species, and meteorological conditions reveal the seasonal changes of the complex constituent and structure features of the gaseous and particulate states of UAP to further trace the impact feature of urban aerosol pollution surface sources and the seasonal difference of the component structure of UAP. Research results suggest that in the temporal evolution of the gaseous and particulate states of winter/summer UAP, NOx, CO, and SO2 showed an "in-phase" evolution feature, however, O3 showed an "inverse-phase" relation with other species,all possessing distinctive dependent feature. On the whole, summer concentrations of gaseous pollutants CO, SO2, and NOx were obviously lower than winter ones, especially, the reduction in CO concentration was most distinctive, and ones in SO2 and NOx were next. However, the summer O3 concentration was more than twice winter one. Winter/summer differences in PM10and PM2.5 particle concentrations were relatively not obvious, which indicates that responses of PM10 and PM2.5 particle concentrations to the difference of winter/summer heating period emission sources are far less distinctive than those of NOx, SO2, and CO. The correlation feature of winter/summer gaseous and particulate states depicts that both PM10 and PM2.5 particles were significantly correlated with NOx, and their correlations with NOx are more significant than those with other pollutants. Through PCA, it is found that there was a distinctive difference in the principal component combination structure of winter/summer PM10 and PM2.5 particles: SO2 and NOx dominated in the principal component of winter PM10 and PM2.5 particles; while CO and NOx played the major role in the principal component of summer PM10 and PM2.5 particles. For winter/summer PM10 and PM2.5 particles, there might exist the gaseous and particulate states correlation structures of different "combinations" of such dependent pollutant species. Research results also uncover that the interaction processes of gaseous and particulate states were also related with the vertical structure of UBL, that is to say, the low value layer of UBL O3 concentration was associated with the collocation of atmospheric vertical structures of the low level inversion,inverse humidity, and small wind, which depicts summer boundary layer atmospheric character, i.e.the compound impact of the dependent factor "combination" of wind, temperature, and humidity elements and their collocation structure on the variations of different gaseous pollutant concentrations. Such a depth structure of the extremely low value of O3 concentration in the UBL accords with its "inverse-phase" relation with other gaseous pollutant species. The PCA of meteorological factors associated with PM10 and PM2.5 concentrations also reveals the sensitivity of PM10 and PM2.5 concentration to the combinatory feature of local meteorological conditions.  相似文献   

Study of statistically correcting model CMAQ-MOS for forecasting regional air quality     

XU Jianming  XU Xiangde  LIU Yu  DING Guoan  CHEN Huailiang  HU Jiangkai  ZHANG Jianchun  WU Hao  LI Weiliang  HE Jinhai  YANG Yuanqin  WANG Jiahe 《中国科学D辑(英文版)》2005,48(Z2)

Based on analysis of the air pollution observational data at 8 observation sites in Beijing including outer suburbs during the period from September 2004 to March 2005, this paper reveals synchronal and in-phase characteristics in the spatial and temporal variation of air pollutants on a city-proper scale at deferent sites; describes seasonal differences of the pollutant emission influence between the heating and non-heating periods, also significantly local differences of the pollutant emission influence between the urban district and outer suburbs, i.e. the spatial and temporal distribution of air pollutant is closely related with that of the pollutant emission intensity. This study shows that due to complexity of the spatial and temporal distribution of pollution emission sources, the new generation Community Multi-scale Air Quality (CMAQ) model developed by the EPA of USA produced forecasts, as other models did, with a systematic error of significantly lower than observations, albeit the model has better capability than previous models had in predicting the spatial distribution and variation tendency of multi-sort pollutants. The reason might be that the CMAQ adopts average amount of pollutant emission inventory, so that the model is difficult to objectively and finely describe the distribution and variation of pollution emission sources intensity on different spatial and temporal scales in the areas, in which the pollution is to be forecast. In order to correct the systematic prediction error resulting from the average pollutant emission inventory in CMAQ, this study proposes a new way of combining dynamics and statistics and establishes a statistically correcting model CMAQ-MOS for forecasts of regional air quality by utilizing the relationship of CMAQ outputs with corresponding observations, and tests the forecast capability. The investigation of experiments presents that CMAQ-MOS reduces the systematic errors of CMAQ because of the uncertainty of pollution emission inventory and improves the forecast level of air quality. Also this work employed a way of combining point and area forecasting, i.e. taking the products of CMAQ for a center site to forecast air pollution for other sites in vicinity with the scheme of model products "reanalysis" and average over the "area".  相似文献   

Chemical forms of heavy metal contaminants in sediments of Miyun reservoir     

LIU Xiaoduan  XU Qing  GE Xiaoli  LIU Liu  WU Dianwei 《中国科学D辑(英文版)》2005,48(Z2)

The chemical forms, spatial distribution and sources of As, Hg, Cd, Pb and Zn in sediments of the Miyun reservoir were studied. The results of sequential extraction demonstrate that most of As, Pb and Zn were bound to the residual fraction, Hg was associated with the sulfide fraction while Cd was associated with the carbonate fraction and the residual fraction. On the vertical profiles the concentrations of the heavy metals in total and each fractions mostly decreased with increasing depths in sediments, suggesting that the heavy metals input from the upstream watershed increases yearly. Summation of the residual fraction, the sulfide fraction and the carbonate fraction accounts for 60.03%―85.60% of the total heavy metal contents in the sediments, which represent the geochemical background values of the elements and relate closely to soil erosion. Results of the main factor analysis show that most sediments of the reservoir come from the upstream soil erosion, the point source pollution and domestic waste. Moreover, the microbial activities taking place on the sediment-water interface are also one of the major factors to cause the increasing content of the organic matter fraction and the iron-manganese oxide fraction. Environmental change of the reservoir water could make the removability of the heavy metals increase, leading to the increase of their concentrations in pore water in sediments, and imperiling water quality of the reservoir.  相似文献   

Knowledge Representation Methods in Expert System for Earthquake Prediction ESEP 3.0     

Wang Wei 《中国地震研究》2005,19(1):43-53

INTRODUCTIONKnowledgerepresentationandknowledgeacquisitionarekeyissuesinbuildinganexpertsystem .Theyarecloselyrelatedtothedomainproblem solvinglevelandcompetenceoftheexpertsystem .Intheknowledgeacquisitionprocess,thedomainexpertwillfirstofferandorganizepr…  相似文献   

南半球对流层气候年代际变化及其与太阳活动的联系   总被引：7，自引：0，他引：7  

曲维政  陈璐  黄菲  张微  朱小洁  邓声贵  杜凌 《地球科学进展》2005,20(7):794-803

通过南半球对流层温度场谱分析和逐次滤波分析发现，南半球对流层大气温度场半个多世纪以来呈现明显的持续升温趋势，升温幅度由低层到高层逐步增加，其中地面层1 000 hPa年升温率为0.013℃/a，对流层中部500 hPa年升温率为0.019℃/ a，对流层上部300 hPa年升温率为0.036℃/ a；滤除南半球大气温度场的趋势变化，发现南半球大气温度场从地面层直至对流层顶广泛盛行着十分显著的与太阳磁场磁性22年周期变化相一致的变化周期。太阳磁场磁性周期变化趋势略有超前，分析认为，这是南半球对流层大气气候系统对太阳磁场周期性变化的响应。进一步分析还发现，南半球从地面层1 000 hPa到对流层顶，再到平流层中部10 hPa各层次大气温度变化22年周期分量振荡位相基本一致，周期振幅由低层到高层迅速增大，说明太阳磁场变化对对流层高层比低层影响大，对平流层影响更大。其中地面层1 000 hPa温度场的22年变化周期是在滤除趋势变化和11年周期之后才显现出来的，所以太阳磁场磁性周期变化对地面层气候的影响较小并且经常处于被掩盖状态；南半球地面层1 000 hPa温度场滤除趋势变化之后显示出十分显著的与太阳活动11年周期相一致的变化周期，分析认为，这是南半球对流层大气气候系统对太阳活动11周期性变化的响应。对流层上层300 hPa温度场滤除趋势变化和22年周期之后也显示出11年变化周期，而对流层中部500 hPa则无此周期反应，说明太阳活动11年周期对地面层1 000 hPa大气气候影响最明显，对流层中上层影响较弱。  相似文献   

湖南千里山-大义山-九嶷山成矿金三角的控矿意义     

陈庆  徐惠长  何周虎  黄革非 《华南地质与矿产》2005,(1):31-36,46

在综合前人资料的基础上，结合千里山-大义山-九嶷山地区典型矿区的实际调查，以矿床成矿系列理论为指导，根据壳源改造型和壳幔混熔型两类不同性质花岗岩(包括过渡产物)分异演化活动的成岩成矿规律以及矿源层与成矿的关系，揭示了本区成矿物质在区域地质构造不断演化过程中的行为，即成矿物质组合的变化、分散或富集规律，指出该地区今后地质找矿的六个重点区域。  相似文献   

Biomineralization of Uranium: A Simulated Experiment and Its Significance   总被引：5，自引：0，他引：5  

L. L. BARTON  H. WIATROWSKI 《《地质学报》英文版》2005,79(1):134-138

A simulated experimental reduction of U^v1 and the synthesis of uraninite by a sulfate-reducing bacteria,Desulfovibrio desulfuricans DSM 642, are first reported. The simulated physicochemical experimental conditions were:35℃, pH=7.0-7.4, corresponding to the environments of formation of the sandstone-hosted interlayer oxidation-zone type uranium deposits in Xinjiang, NW China. Uraninite was formed on the surface of the host bacteria after a one-week‘s incubation. Therefore, sulfate-reducing bacteria, which existed extensively in Jurassic sandstone-producing environments,might have participated in the biomineralization of this uranium deposit. There is an important difference in the orderdisorder of the crystalline structure between the uraninite produced by Desulfovibrio desulfuricans and naturally occurring uraninite. Long time and slow precipitation and growth of uraninite in the geological environment might have resulted in larger uraninite crystals, with uraninite nanocrystals arranged in order, whereas the experimentally produced uraninite is composed of unordered uraninite nanocrystals which, in contrast, result from the short time span of formation and rapid precipitation and growth of uraninite. The discovery has important implications for understanding genetic significance in mineralogy, and also indicates that in-situ bioremediation of U-contaminated environments and use of biotechnology in the treatment of radioactive liquid waste is being contemplated.  相似文献