Identification of Pb sources in Yellow Sea sediments using stable Pb isotope ratios   总被引：1，自引：0，他引：1  

Man-Sik Choi  Hi-Il Yi  Shou Ye Yang  Chang-Bok Lee  Hyun-Ju Cha 《Marine Chemistry》2007

Rapid economic developments in East Asian countries have inevitably resulted in environmental degradation in the surrounding seas, and concern for both the environment and protection from pollutants is increasing. Identification of sources of contaminants is essential to environmental pollution management. In this study, the provenance of anthropogenic lead (Pb), a major pollutant of Yellow Sea sediments, was determined for river mouth sediments, including those of the Changjiang, Huanghe, Han, and Geum Rivers, and for age-determined shelf core sediments through the measurement of Pb isotope ratios in the HCl-leached fraction using multi-collector inductively coupled plasma-mass spectrometry (MC ICP/MS). Anthropogenic Pb has accumulated in shelf core sediments since 1910, and its isotope ratios were estimated as 0.863–0.866 and 2.119–2.125 for ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb, respectively, from the mixing relationships of the two endmembers. River mouth sediments exhibited enough distinction in anthropogenic Pb isotope ratios to be discriminated: 0.874 (2.144) in the Huanghe, 0.856 (2.129) in the Han, 0.857 (2.122) in the Geum, and 0.854 (2.101) in the Changjiang for ²⁰⁷Pb/²⁰⁶Pb (²⁰⁸Pb/²⁰⁶Pb), respectively. Although isotope ratios of geogenic Pb in sediments dating before 1910 showed narrow ranges (0.842–0.845 and 2.088–2.100 for ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb, respectively), distinct isotope ratios in each core permitted source identification of sediments in the Yellow Sea based on geographic locations and the geogenic Pb of each river. By comparing the isotope ratios of the estimated anthropogenic Pb to source-related materials, the provenances of anthropogenic Pb in Chinese river sediments were presumed to be Chinese coal or ore, which is also a major source of atmospheric particulate Pb. The anthropogenic Pb in the shelf core sediments in the northern Yellow Sea originated from northern Chinese cities such as Beijing and Tianjin through atmospheric pathways. Pb isotope ratios indicated that Pb in Korean river sediments was characteristic of local Korean ores.  相似文献   

三角褐指藻Phaeodactylum tricornutum的亚硝酸盐释放及其生态学意义   总被引：2，自引：0，他引：2  

朱明远  杨小龙 《中国海洋大学学报(自然科学版)》1991,(2)

本文在藻类不同生长时期、光照、黑暗和光照+DCMU以及不同硝酸盐浓度、温度和pH条件下,研究了环境因子对三角褐指藻亚硝酸盐释放的影响。研究结果表明:三角褐指藻在光照、硝酸盐浓度大于10μmol/L、温度范围18～22℃和pH为8左右条件下,亚硝酸盐释放速率最大。亚硝酸盐在特定条件下的释放对于我们了解海洋中由浮游植物产生的亚硝酸盐第一最大层的形成机制有着十分重要的意义。  相似文献   

Determination of palladium and platinum in seaweed     

Jae Sam Yang 《Journal of Oceanography》1989,45(6):369-374

Palladium and platinum concentrations were determined for twenty two species of seaweed from the California coast, U.S.A.. A new sensitive analytical technique using atomic absorption spectrometry was developed for palladium in seaweed. For the first time, palladium contents in seaweed were obtained. The contents of palladium and platinum varied from 0.09 to 0.61 ng g^–1 and 0.25 to 1.75 ng g^–1 in dried material, respectively.The average ratio of Pt/Pd found in seaweed was 3.5, while the ratio of Pt/Pd was 4.5 in seawater. Therefore, it is postulated that there is no discrimination for seaweed to accumulate palladium and platinum from the ambient seawater due to the chemical similarity of the metals.  相似文献   

东亚温带气旋及其长期预报（一）—气候特征及其影响因素     

战淑芸  杨淑瑞 《海洋预报》1993,10(4):17-22

本文分析了影响我国近海的温带气旋气候特征及其影响因素。分析得出：３－７月是温带气旋的盛季，４月份是全年中温带气旋最多的月份。赤道东太平洋海温异常增暖的年份，温带气旋增多。  相似文献   

黄、东海近海面空气湿度分析及估算     

陈永利  杨连素  赵永平  张必成 《海洋科学》1992,16(4):41-44

利用1974～1982年黄、东海海洋水文气象标准断面实测资料对近海面空气湿度的分布、变化进行了分析。讨论了冬、夏季海、气温与湿度的关系,并对冬、夏季近海面空气湿度进行了估算。结果表明,夏季,空气湿度为气温的函数;冬季,除了考虑空气本身平流的水汽外,还必须考虑海洋向大气的水汽输送。  相似文献   

闽江口第四纪地层中的孢粉、有孔虫、硅藻组合及其古地理意义   总被引：7，自引：1，他引：7  

杨蕉文  华棣  吴立成 《海洋地质与第四纪地质》1991,11(3):75-82

本文通过对闽江口琅岐岛钻孔的孢粉,有孔虫及硅藻的综合分析,发现第四纪地层中有五个孢粉组合带,五个硅藻组合带与一个微体化石层。结合~(14)C测年资料与沉积物特征认为该地区第四纪地层可以划分为晚更新世晚期与全新世(早期、中期、晚期)。气候演化依次为:冷干→温暖略干→温暖湿润→炎热潮湿→温暖略干。沉积相发展顺序为:冲积相、冲洪积相→河流相、湖沼相→湖沼相、河口相→海湾相→河口相。  相似文献   

黄、东海毗邻海域悬浮体与水团的对应关系及影响因素   总被引：2，自引：0，他引：2  

杨作升  郭志刚  王兆祥  徐景平  高文兵 《中国海洋大学学报(自然科学版)》1991,(3)

对黄、东海毗邻海域由陆架到深海的悬浮体进行了大量加密取样,获得了较准确的结果。给出了悬浮体含量及其三维分布,确定它们与水团及其边界有良好的对应关系。并从物源、动力和成因等解释了这种对应,提出了水团对悬浮体研究的重要意义。研究表明黑潮次—中层混合爬升水及其混合水形成悬浮体含量最低值区,横亘在陆架与深海之间,形成阻隔含有大部分悬浮体的陆架中、下层水体向深海输送的洁净“水障”,台湾暖流北上的顶托也起类似作用,并分析了影响悬浮体含量的各种因素及有关机制。  相似文献   

长江口南港水道潮流特征分析   总被引：6，自引：0，他引：6  

杨许侯  金成法  马道华 《海洋通报》1999,18(1):1-11

根据１９９６年长江口南港水道枯、丰水期（１月、７月）大、中、小潮两次各２６ｈ以上的全潮水文实测资料,统计分析了实测流的特征和潮流类型、运动形式、潮流垂直变化、余流、Ｍ２分潮流及分潮流对涨、落潮流不等的影响。  相似文献   

粘土矿物对海水中主要营养盐的吸附研究   总被引：20，自引：1，他引：20  

俞志明  马锡年  谢阳 《海洋与湖沼》1995,26(2):208-214

对海水中磷盐和硝酸盐在粘土矿物上的吸附行为的研究发现，海水体系中高岭土对磷酸盐的吸附能力大于蒙脱土，其原因为，粘土颗粒的表层铝／硅结构比是控制磷酸盐吸附的主要因素，其中铝含量越高，肿附能力越大。考察ＰＨ、粘土酸改性处理等因素对吸附作用的影响，结果表明，ＰＨ＜８．５的磷酸盐吸附ＰＨ曲线呈峰形，其吸附作用以阴离子交换为主；ＰＨ＞８．５时磷酸盐的吸附作用以沉淀吸附为主。酸改性蒙脱土可提高吸附磷酸盐的能力  相似文献   

养殖对虾与海捕对虾鉴别方法初探   总被引：1，自引：1，他引：1  

薛长湖  曹杨  陈修白  李爱杰 《中国海洋大学学报(自然科学版)》1993,(1)

通过对养殖中国对虾(Penaeus orientalis)和海捕中国对虾肌肉煮熟后的失水率,提取物中的甜菜碱和氧化三甲胺含量,以及虾肉脂质中所含脂肪酸组成和含量进行了分析比较,得到下列结果:(1)两类对虾鲜样煮熟后失水率相差6％以上;(2)海捕对虾肌肉中的甜菜碱和氧化三甲胺含量比养殖对虾的高,两者有显著差别;(3)养殖对虾肌肉所含C18:2ω6为17.3±1.5％,海捕对虾为2.0±0.8％。从以上结果本文推荐以脂肪酸C18:2ω6含量来鉴别养殖对虾与海捕对虾。  相似文献