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101.
Thermodynamic characterization of the partitioning of iron between soluble and colloidal species in the Atlantic Ocean 总被引:2,自引:1,他引:2
Recent electrochemical measurements have shown that iron (Fe) speciation in seawater is dominated by complexation with strong organic ligands throughout the water column and have provided important thermodynamic information about these compounds. Independent work has shown that iron exists in both soluble and colloidal fractions in the Atlantic Ocean. Here we have combined these approaches in samples collected from a variety of regimes within the Atlantic Ocean. We measured the partitioning of Fe between soluble (< 0.02 μm) and colloidal (0.02 to 0.4 μm) size classes and characterized the concentrations and conditional stability constants of Fe ligands within these size classes. Results suggest that equilibrium partitioning of Fe between soluble and colloidal ligands is partially responsible for the distribution of Fe between soluble and colloidal size classes. However, a significant fraction of the colloidal Fe was inert to ligand exchange as soluble Fe concentrations were generally lower than values predicted by a simple equilibrium partitioning model.In surface waters, strong ligands with conditional stability constants of 1013 relative to total inorganic Fe appeared to dominate speciation in both the soluble and colloidal fractions. In deep waters these ligands were absent, and instead we found ligands with stability constants 12–15 fold smaller that were predominantly in the soluble pool. Nevertheless, significant levels of colloidal Fe were found in these samples, which we inferred must be inert to coordination exchange. 相似文献
102.
浙江近海夜光藻的分布及其生态学特点 总被引:4,自引:1,他引:4
本文利用历次夜光藻调查资料,阐述了其在浙江近岸海域的分布特点,丰度高峰主要出现在春秋季,夏季亦存在暴发性增殖的可能性,冬季则基本见不到夜光藻的踪迹。杭州湾口等水体浑浊区是夜光藻的低丰度区,仅在春夏季有零星出现,这与水体透明度低、悬浮泥沙含量高及强烈的水动力因子等密切相关。在时间尺度上,夜光藻丰度呈上升趋势,根本原因是海域富营养化加剧的结果。 相似文献
103.
A moving particle image velocimetry (PIV) system was successfully developed and used in a large towing tank for ship model tests to observe velocity fields near ship models. The experimental method involved adjustable optical devices for various test conditions and a special particle-seeding device. The streamwise and cross-streamwise flow fields of a yacht model and a tanker model were measured. Ship type, bottom shape, and towing speed were found to be the causes of problems affecting optical access and image quality. Possible solutions, deeper optical ducts, dark painting color, and pre-processed analysis method, were proposed and discussed. 相似文献
104.
The effects of Prorocentrum donghaiense,Karenia mikimotoi,Alexandrium catenella,the causative species of Harmful Algal Blooms in the East China Sea,on the survival and growth of Neomysis awatschensis and Artemia salina were investigated.And the toxicity of eleven strains of Alexandrium----A.lusitanicum(AL-1)、A.minutum(AM-1)、A.spp.(A-K)、A.tamarense(ATHK,ATCI02,ATCI03,AT5-1,AT5-3,AT-6)、A.affine(AS-1,AC-1) to the two above organisms were compared. The results showed that P.donghaiense and K.mikimotoi had no adverse effect on the survival and growth of N.awatschensis and A.salina at 96h.However,the survival rate of N.awatschensis and A.salina declined linearly with the increasing density of A.catenella,and the 96h LC50 for N.awatschensis and A.salina was 4500 and 460 cells/mL,respectively, Five strains of Alexandrium----A.spp,A.lusitanicum (AL-1),A.tamarense(AT5-3,AT-6) and A.affine (AS-1)at the density of 4000cells/mL and 96h had no adverse impacts on N.awatschensis. But other six strains of Alexandrium a.Tamarense(AT5-1,ATHK,ATCI02,ATCI03),A.affine(AC-1) and A.minutum(AM-1)decreased the survival fate of N.awatschensis significantly. Two strains of Alexandrium----A.lusitanicum(AL-1) and A.tamarense(AT-6),at the density of 500cells/mL. had no adverse effects on A.salina in 96h;while the other Alexandrium strains all had adverse effeets on the survival of a.salina, A.salina could increase its length with the increasing density of P.donghaiense,K.mikimotoi and A.luxitanicum. The results indicate that P.donghaiense and K.mikimotoi have nio significant effect on the survival of crustaeean zoop lankton in a short period. But several Alexandrium specised/strains could influence the survival of crustacean zooplankton likely by non-PSP substances. A.salina is shown to be more sensitive than N.awatschensis as test organisms to harmful species. 相似文献
105.
106.
In this study, the dynamic stresses within the seabed induced by non-linear progressive waves were explored through a series of hydraulic model tests on a movable bed within a wave flume. By comparing Stokes’ 2nd-order wave theory with the theory of wave-induced dynamic stresses within the seabed as proposed by Yamamoto et al. [1978. On the response of a poro-elastic bed to water waves. Journal of Fluid Mechanics 87 (1), 193–206.] and Hsu and Jeng [1994. Wane-induced soil response in an unsaturated anisotropic seabed of finite thickness. International Journal for Numerical and Analytical Methods in Geomechanics 18, 785–807], the experimental results show that the pressure on the seabed surface, the pore water pressure within the seabed as well as the vertical and the horizontal stresses are all smaller than their theoretical values. If we were to obtain the characteristics of seabed soil, the analytical solution of Hsu and Jeng [1994. Wane-induced soil response in an unsaturated anisotropic seabed of finite thickness. International Journal for Numerical and Analytical Methods in Geomechanics 18, 785–807] might agree to the simulation of the wave-induced effective stresses and shear stress in the sandy seabed. A different phase shift exists among all the three soil stresses. Their influences on the three dynamic stresses within seabed soil are important for seabed stability, and can be used in the verification of numerical models. In the whole, the non-linear progressive waves and the naturally deposited seabed are found to have a strong interaction, and the behavior of the induced dynamic stresses within the seabed is very complicated, and should be investigated integrally. 相似文献
107.
为了探讨西太平洋暧地区热带波动的天气效应,利用1980年2-9月140°E日本静止卫星纬度时间剖面卫星云图,分析了5d和14d左右周期热带波动云的演变特征,井综合分析了14d周期的云系演变型式与流场的关系,为预报热带中期天气变化规律提供了依据;热带波动中30-60d大气低频振荡的云量变化最显著,北半球夏半年热带波动的天气压主要在10°N-0°,各半年在10°N-10°S,超过这个区域热带云量的港分布型式就有明显的变化。 相似文献
108.
109.
本文是根据南极“八五”国家攻关课题中的“南极海冰监测和预报”的考核目标,实现为南极考察船在 冰区中航行提供精确和清晰的冰图和预报。 相似文献
110.
Ping Chang 《Journal of Oceanography》1993,49(5):477-489
The effects of short waves on the propagration of velocity discontinuity along the interface of two uniform potential vorticity, zones on anf-plane is examined. It is shown, using a multiple scale analysis, that the dispersion introduced by the short waves can balance the nonlinear steepening effects predicted by the semigeostrophic theory. The time evolution of a shear disturbance along the front is governed by a Korteweg-de Vries equation. Numerical solutions of the solitary waves along the front are presented. 相似文献