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31.
32.
Akira Imai    Yuki Nagai 《Resource Geology》2009,59(3):231-243
The Batu Hijau deposit is the only porphyry type deposit in production in the Sunda‐Banda arc, Indonesia. This study discusses the reason for the localization of copper grade at the deep part of the deposit based on the observation of opaque mineral assemblage. In addition, the formation condition of quartz veins and opaque minerals is discussed on the basis of the fluid inclusion microthermometry. Samples were selected from drill holes SBD100, SBD168, SBD194, SBD254, and SBD257 to cover the wide vertical range. At the Batu Hijau deposit, quartz veins have been classified mainly into four types called A, B, C and D veins, and the A veins contain mainly bornite, often associated with digenite and chalcocite. In addition, magnetite occurs in A veins. However, at the deep part of the deposit, there are quartz veins associated with magnetite, but few copper sulfides such as bornite and chalcopyrite in quartz veins, as observed in SBD257. Quartz veins at depth in SBD257 have abundant magnetite and pyrite. Pyrite in quartz veins at depth in SBD257 mainly occur at the rim of magnetite grains or interstices between them. In quartz veins in SBD254, there are abundant copper sulfides such as bornite and chalcopyrite in spite of the depth. Bornite and chalcopyrite occur as inclusions in magnetite grains in quartz veins in SBD254. Pyrite which often occurs in low grade zone in quartz veins in SBD254 is also recognized at the rims of copper sulfides. This indicates that pyrite in SBD257 and SBD254 formed later than magnetite. On the other hand, blebs of bornite and chalcopyrite inclusions in magnetite grains, which are recognized in quartz veins in SBD168 at shallow high grade part, suggest that the hydrothermal fluid, from which magnetite was deposited also brought the copper sulfides such as bornite and chalcopyrite to the deep part of the Batu Hijau deposit. Therefore, it is concluded that initially the high grade ore zone extended to depth without localization. However due to the later overprinting hydrothermal activity, copper sulfides and magnetite were replaced or dissolved and pyrite was formed, resulting the low grade zone at the deep part of the deposit. Dissolution temperatures (Td) of halite obtained by from fluid inclusion microthermometry show significant differences between SBD168 and other drill holes. The high Td obtained in SBD168 may indicate larger volume of NaCl crystals in hydrothermal fluid at the time of entrapment of the fluid inclusions and formation of other opaque minerals such as magnetite and copper‐iron sulfides. It suggests that the ratio of vapor to brine is also higher at the shallow part of the deposit. The higher vapor to brine ratio may suggest a higher degree of boiling. Removal of vapor phase separated from brine during boiling increases the concentration of substances dissolved in the brine, and this will result in saturation, as evidenced by the salinity and NaCl saturation. The higher degree of boiling suggested by the higher vapor to brine ratio at shallow part may have increased the copper concentration in the brine that may have lead the saturation, resulted in the deposition of copper‐bearing minerals.  相似文献   
33.
Carbon sources were estimated by measuring carbon isotope ratios (??13C and ??14C) with accelerator mass spectrometry (AMS) in forest soils of different lithology. Six locations were selected in temperate deciduous and coniferous stands in Slovenia (?irovski vrh, Idrija, Ko?evski Rog, Pohorje, Gori?nica, and Rakitna), where carbonate rocks consisting of limestone and dolomite are abundant as underlying bedrock. Carbon isotope fractionation would not have occurred in two carbonaceous soils, since the values of both ??13C and ??14C changed consistently in these soils after thermal (550°C, 2?h) or chemical (1?M HCl, 24?h) treatments. Organic components were found to be predominant carbon sources (70?C100%) in the uppermost portions (0?C2?cm in depth). In deeper portions at a depth of about 30?C35?cm, soil carbon may be derived completely from underlying carbonate minerals in Idria, western part of Slovenia. The Combination of heat and chemical treatments with AMS provides practical information on soil carbon sources in carbonaceous soils.  相似文献   
34.
New geochemical and Sr–Nd isotopic data for the Iratsu eclogite and surrounding metamorphic rocks of the Sanbagawa belt, Japan, show that, while the protoliths of the metamorphic rocks formed in a variety of tectonic settings, the Iratsu body represents a deeply subducted and accreted island arc. The igneous protoliths of eclogites and garnet amphibolites were probably generated from a mantle source that had components of both a depleted mantle modified by slab-released fluid (as seen in a negative Nb anomaly) and an enriched mantle, similar to that of ocean island basalts (OIB). Fractional crystallization modeling indicates that the protoliths of some garnet clinopyroxenites from the Iratsu body are cumulates from a basaltic magma that crystallized under high O2 and H2O fugacities in the middle to lower crust. The source characteristics and crystallization conditions suggest that the protoliths of the Iratsu rocks formed in an oceanic island arc. Quartz eclogites from the marginal zone of the Iratsu body have geochemical signatures similar to turbidites from the Izu–Bonin island arc (as seen in a negative Nb anomaly and a concave REE pattern). The protoliths might be volcaniclastic turbidites that formed in a setting proximal to the oceanic island arc. Geochemical and isotopic signatures of the surrounding mafic schists are similar to normal (N-) and enriched (E-) mid-ocean-ridge basalt (MORB), and distinct from the rocks from the Iratsu body. The protoliths of the mafic schists likely formed in a plume-influenced mid-ocean ridge or back-arc basin. Pelitic schists from the surrounding rocks and pelitic gneisses from the marginal zone of the Iratsu body have evolved, continental geochemical signatures (as seen in a negative εNd(t) value (~?5)), consistent with their origin as continent-derived trench-fill turbidites.  相似文献   
35.
The viscosity of a silicate melt of composition NaAlSi2O6 was measured at pressures from 1.6 to 5.5 GPa and at temperatures from 1,350 to 1,880°C. We employed in situ falling sphere viscometry using X-ray radiography. We found that the viscosity of the NaAlSi2O6 melt decreased with increasing pressure up to 2 GPa. The pressure dependence of viscosity is diminished above 2 GPa. By using the relationship between the logarithm of viscosity and the reciprocal temperature, the activation energies for viscous flow were calculated to be 3.7 ± 0.4 × 102 and 3.7 ± 0.5 × 102 kJ/mol at 2.2 and 2.9 GPa, respectively.  相似文献   
36.
This study presents a semi-empirical model for quantifying the reduction in the mechanical strength of bedrock beneath actively eroding soil-mantled hillslopes. The strength reduction of bedrock controls the rate of physical disintegration of saprolite, which supplies fresh minerals that are then exposed to intense chemical weathering in soil sections. To determine the values of parameters employed in the model requires knowledge of the denudation rate of the hillslope, the thickness of the soil and saprolite layers, the strength of fresh bedrock, and the threshold strength for physical erosion at the uppermost face of the saprolite. These parameters can be obtained from cosmogenic nuclide analyses for quartz samples from the soil–saprolite boundary and basic field- and laboratory-based investigations. Further testing of the model within a diverse range of climatic, tectonic, and lithologic environments is likely to provide clues to the mechanisms responsible for local and regional variations in the rates of soil production and chemical weathering upon hillslopes.  相似文献   
37.
A simple analytical model of the particle-dominated outflow with zero total electric current from central rotating objects is considered. 'Exact' solutions for both relativistic and non-relativistic cases demonstrate the decollimation of the magnetic field lines in the region of the current closure. Such a decollimation can explain the presence of an energetic equatorial wind observed in many compact objects.  相似文献   
38.
Soil bulk density (ρb) is commonly treated as static in studies of land surface dynamics. Magnitudes of errors associated with this assumption are largely unknown. Our objectives were to (a) quantify ρb effects on soil hydrologic and thermal properties and (b) evaluate effects of ρb on surface energy balance and heat and water transfer. We evaluated 6 soil properties, volumetric heat capacity, thermal conductivity, soil thermal diffusivity, water retention characteristics, hydraulic conductivity, and vapour diffusivity, over a range of ρb, using a combination of 6 models. Thermal conductivity, water retention, hydraulic conductivity, and vapour diffusivity were most sensitive to ρb, each changing by fractions greater than the associated fractional changes in ρb. A 10% change in ρb led to 10–11% change in thermal conductivity, 6–11% change in saturated and residual water content, 49–54% change in saturated hydraulic conductivity, and 80% change in vapour diffusivity. Subsequently, 3 field seasons were simulated with a numerical model (HYDRUS‐1D) for a range of ρb values. When ρb increased 25% (from 1.2 to 1.5 Mg m?3), soil temperature variation decreased by 2.1 °C in shallow layers and increased by 1 °C in subsurface layers. Surface water content differed by 0.02 m3 m?3 for various ρb values during drying events but differences mostly disappeared in the subsurface. Matric potential varied by >100 m of water. Surface energy balance showed clear trends with ρb. Latent heat flux decreased 6%, sensible heat flux increased 9%, and magnitude of ground heat flux varied by 18% (with a 25% ρb increase). Transient ρb impacted surface conditions and fluxes, and clearly, it warrants consideration in field and modelling investigations.  相似文献   
39.
Takashikozo is a phenomenon of Quaternary sediments in Japan. They are cylindrical Fe-oxyhydroxide nodules that form as plaques round plant roots, where Fe is preferentially concentrated to develop a solid wall. Structural features suggest that after the roots have decayed, the central space where the roots were situated acts as a flow path for oxidized water. Analysis of microbial 16S rDNA extracted from the nodules identified iron-oxidizing bacteria encrusted round the roots where they are the likely initiators of nodule formation. Direct microscopic observation revealed an accumulation of Fe-oxyhydroxides that fill the pore spaces and is also likely to be linked with the encrusting microbial colonies. Geological history and nanofossil evidence suggest that these Fe-nodules may have been buried at a depth of up to several tens of meters for at least 105 years in reducing Quaternary sediments. Thus Fe-oxyhydroxide nodules that have formed in a geological environment at the interfaces between water and rock by microbial mediation can persist under reducing conditions. If this is the case, the phenomenon is significant as an analogue of post-closure conditions in radioactive waste repositories, since it could influence nuclide migration.  相似文献   
40.
The sound velocity (V P) of liquid Fe–10 wt% Ni and Fe–10 wt% Ni–4 wt% C up to 6.6 GPa was studied using the ultrasonic pulse-echo method combined with synchrotron X-ray techniques. The obtained V P of liquid Fe–Ni is insensitive to temperature, whereas that of liquid Fe–Ni–C tends to decrease with increasing temperature. The V P values of both liquid Fe–Ni and Fe–Ni–C increase with pressure. Alloying with 10 wt% of Ni slightly reduces the V P of liquid Fe, whereas alloying with C is likely to increase the V P. However, a difference in V P between liquid Fe–Ni and Fe–Ni–C becomes to be smaller at higher temperature. By fitting the measured V P data with the Murnaghan equation of state, the adiabatic bulk modulus (K S0) and its pressure derivative (K S ) were obtained to be K S0 = 103 GPa and K S  = 5.7 for liquid Fe–Ni and K S0 = 110 GPa and K S  = 7.6 for liquid Fe–Ni–C. The calculated density of liquid Fe–Ni–C using the obtained elastic parameters was consistent with the density values measured directly using the X-ray computed tomography technique. In the relation between the density (ρ) and sound velocity (V P) at 5 GPa (the lunar core condition), it was found that the effect of alloying Fe with Ni was that ρ increased mildly and V P decreased, whereas the effect of C dissolution was to decrease ρ but increase V P. In contrast, alloying with S significantly reduces both ρ and V P. Therefore, the effects of light elements (C and S) and Ni on the ρ and V P of liquid Fe are quite different under the lunar core conditions, providing a clue to constrain the light element in the lunar core by comparing with lunar seismic data.  相似文献   
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