生物制氢研究进展   总被引：1，自引：0，他引：1  

才金玲  王广策  杨素萍  周百成 《海洋科学集刊》2007,(48):176-190

目前, 世界上利用的能源90%以上都是“化石能源”(如石油、煤炭和天然气等)。随着人类不断利用这些不可再生的“化石能源”, 它将会逐渐枯竭, 且其燃烧形成的产物(如CO2和SO2等)造成的严重环境污染(如温室效应和酸雨), 也有害于人类健康。因此, 人类正面临着能源紧缺和环境污染的双重压力。为满足能源需求量日益增长和环境保护的需要, 我们必须寻找环保型的可再生能源来替代“化石能源” 以满足人类对能源的需求。 在各种可再生能源中氢能将有可能替代“化石能源”,成为未来能源利用的主要形式。氢能具有许多优点:①氢能燃烧时只生成水, 不产生任何污染物, 甚至连CO2也不会产生, 实现真正的“零污染” 和“零排放”;②氢能的能量密度高, 放热高达122 kJ/g, 是焦炭放热的4.5倍, 汽油的2.68倍;③氢能可经济有效的输送和储存, 可以利用已有的天然气管道输送, 输送成本低, 甚至优于输电, 因为输送氢能不会产生如电能输送过程中所产生的能量损耗;氢能的存储也比较简便, 其中储氢合金材料就是一种非常理想的储氢方法, 该方法储氢能力强、运输方便、操作容易, 且安全可靠。在利用储氢合金进行储氢时, 还可用以进行制冷或采暖(Kulkova et al., 2006), 因为储氢材料在吸氢时放热, 在放氢时吸热。正因为氢能具有如此多的优点, 许多大的跨国公司开始对制氢技术高度关注, 如主要汽车制造商(通用、福特、戴姆勒-克莱斯勒等)对开发以氢能作为燃料的汽车投入大量的人力和物力;宝马公司从20世纪70年代就开始研制以氢能为能源的汽车, 宝马公司现在已拥有了时速达240km的氢能汽车(Munro,2003)。同时, 一些发达国家的科研院所的科学家们对氢能的制备方法、制氢机制以及提高产氢量等进行了大量的研究。  相似文献   

Sediment–water interactions of natural oestrogens under estuarine conditions     

J. C. Bowman  J. L. Zhou  J. W. Readman 《Marine Chemistry》2002,77(4)

The natural human female hormones oestrone and 17β-oestradiol have been implicated in the disruption of endocrine systems in some wildlife adjacent to sewage effluents. The sorption behaviour of these two compounds under estuarine conditions was studied by spiking either 2.55 μg of oestrone or 2.65 μg of 17β-oestradiol in kinetic experiments. In equilibrium experiments, 3 ng of oestrone or 3.2 ng of 17β-oestradiol was added in each of the centrifuge tubes. Sorption onto sediment particles was relatively slow, with sorption equilibrium being reached in about 70 and 170 h for oestrone and 17β-oestradiol, respectively. The effects of a variety of environmental parameters on sorption were studied including salinity, sediment concentration (SC), the presence of a third phase, particle size and, also, surfactant concentrations. Results show that although salinity did not induce any statistically significant effect on the sorption of 17β-oestradiol, it did statistically enhance the sorption of oestrone, and a salting constant of 0.3 l mol⁻¹ was derived. The partition coefficient for both compounds decreased with increasing sediment concentration, a phenomenon that has been widely reported and attributed to the presence of colloids (which could enhance dissolved concentrations). In this paper, the true partition coefficients for sediment particles (K_p^true) and colloidal particles (K_c^true) have been calculated, and a K_p^true value of 141 and 102 ml g⁻¹ was obtained for oestrone and 17β-oestradiol, respectively. In addition, K_c^true values for oestrone (222×10² ml g⁻¹) and 17β-oestradiol (135×10² ml g⁻¹) were two orders of magnitude higher than their respective K_p^true values, suggesting that the colloidal particles are significantly stronger sorbents for natural oestrogens than sediment particles. Particles of different sizes were found to have different partition coefficients due to the strong relationships between partition coefficients for the two compounds and particulate organic carbon (POC) contents and specific surface areas (SSAs). The presence of a surfactant was shown to reduce the partition coefficients for the two compounds, although its concentrations being used were higher than those normally found in the natural environment.  相似文献   

南黄海及相邻陆区松散沉积层磁性地层的研究     

周墨清  葛宗诗 《海洋地质与第四纪地质》1990,(4)

本文通过研究区5个钻孔松散沉积岩心磁性地层的划分对比,获知布容与松山极性带的界线,南黄海和陆区北部位于80.0—99.5m。陆区的南部此界线于270.4m深处。松山和高斯极性带的界线,海区未揭露到,其沉积起始时间都小于1.7Ma。而陆区的南、北部分别位于117m和328.2m。高斯和吉尔伯特极性带的界线,陆区北部为140m,而南部区为460.15m。沉积起始时间为3.4Ma。吉尔伯特底界仅北部陆区所揭示,为190.5m。松散沉积层与下伏白垩纪(?)石灰岩接触面位于400.35m,沉积起始时间约17.0Ma。  相似文献   

常压法合成Methomyl的研究     

钱佐国  孙明昆  杨福顺  孙林枫  周曾昊 《中国海洋大学学报(自然科学版)》1990,(3)

提出一种合成Methomyl的改良法。该方法的特点是反应可在常压下进行。对常压反应的优宜条件作了系统研究,并讨论了反应机理。  相似文献   

东海XH凹陷烃资源预测──勘探层分析及石油资源专家系统分析     

肖国林  周才凡  李桂群 《中国海洋大学学报(自然科学版)》1995,(3)

应用勘探层分析及石油资源专家系统对ＸＨ凹陷下第三系勘探目的层的三个勘探层烃资源量作出了综合预测，结果表明，凹陷内各勘探层，尤其是渐新统勘探层，烃资源量相当可观。提出在渐新统内的地层圈闭中可进一步作详细的勘探工作。  相似文献   

六溴苯的合成研究     

钱佐国  孙明昆  苗世昌  刘新河  周曾昊 《中国海洋大学学报(自然科学版)》1991,(2)

对直接溴化法合成六溴苯作了系统的研究,并对文献方法进行了一系列的改进。包括选择适当的摧化剂及其用量,使反应基本上在室温下进行;利用水汽蒸馏法驱除残余溴,可直接得到无色或近乎无色的纯净产物,而勿需进行还原脱溴,且得率较高。提出一种以溴化物形式回收副产物的方法。  相似文献   

Embryonic and larval development of Babylonia formosae habei (Altena and Gittenberger, 1981) (Gastropoda:Buccinidae) on China''''s coast     

CHEN Yan  KE Caihuan  ZHOU Shiqiang  LI FuxueDepartment of Oceanography  Key Laboratory for Marine Environmental Science of the Ministry of Education  Xiamen University  Xiamen  China 《海洋学报(英文版)》2004,(3)

The development of embryos and larvae of Babylonia formosae habei living along the southeast coast of China is observed under laboratory conditions. The egg masses are laid by females on hard substrate at night and each capsule contains 100-500 eggs. Each egg is 250-280 mm in diameter. The first two cleavages of the embryo are meridional and equal, and a polar lobe is produced. Larval kidney, which only consists of a single cell, appears during the gastrula stage on each side of the embryo. The right tentacle develops prior to the left one. At 25-27℃, an intracapsulate veliger stage is reached about 4.5 d after deposition. The larvae hatch on the fifth day as swimming veligers with a shell length of 360 -500 mm. The newly hatched larva can ingest suspended algal cells from the water column and remains in the pelagic stage for 8-10 d. The newly settled juveniles are 900-1 200 mm in shell length.  相似文献   

Effect of shallow and narrow water on added mass of cylinders with various cross-sectional shapes     

Z.X. Zhou  Edmond Y.M. Lo  S.K. Tan 《Ocean Engineering》2005,32(10):1199-1215

The sway, heave and roll added masses of three uniform cylinders with semi-circular, rectangular and triangular cross-sectional shapes in shallow and narrow water are numerically analysed. The method is based on simulation of the potential flow induced by the cylinder's mode of motion. The effects of shallow and narrow water on added mass are analysed and presented. It is concluded that the shallow and narrow water effects on added mass depend on the different cross-section shapes of the cylinders. In particular, the water depth effect on sway added mass is stronger than that on heave added mass while the narrow water effect on sway is weaker than that on heave. The shallow water effect on added mass tends to weaken the narrow water effect. Lastly the effect of shallow and narrow water on added mass on a rectangular cylinder is the strongest while that on a triangular cylinder is the weakest.  相似文献   

Embryonic and larval development of Babylonia formosae habei(Altena and Gittenberger, 1981)(Gastropoda: Buccinidae) on China''s coast     

CHEN Yan  KE Caihuan  ZHOU Shiqiang  LI Fuxue 《海洋学报(英文版)》2004,23(3):521-531

The development of embryos and larvae of Babyloniaformosae habei living along the southeast coast of China is observed under laboratory conditions. The egg masses are laid by females on hard substrate at night and each capsule contains 100-500 eggs. Each egg is 250-280 mm in diameter. The fast two cleavages of the embryo are meridional and equal, and a polar lobe is produced. Larval kidney, which only consists of a single cell, appears during the gastrula stage on each side of the embryo. The right tentacle develops prior to the left one. At 25-27 ℃, an intracapsulate veliger stage is reached about 4.5 d after deposition. The larvae hatch on the fifth day as swimming veligers with a shell length of 360 -500 mm. The newly hatched larva can ingest suspended algal cells from the water column and remains in the pelagic stage for 8-10 d. The newly settled juveniles are 900-1 200 mm in shell length.  相似文献   

自由生活海洋线虫的系统分类学   总被引：1，自引：0，他引：1  

张志南  周红 《中国海洋大学学报(自然科学版)》2003,33(6):891-900

自由生活海洋线虫是海洋中最丰富的后生动物 ,它属于小型底栖动物的永久性成员 ,即分选时 ,可通过 0 .5 mm或 1 mm网筛但被 0 .0 31 mm或 0 .0 4 2 mm孔径网筛蓄留的动物 ,本文讨论线虫在动物界的分类地位 ,与相近动物类群的亲缘关系 ,泄腺纲与泄管纲分类系统的由来和演变。海洋线虫属于泄腺纲 ,由 Bremerhaven种名录和 L orenzen确立的分类系统已得到广泛的应用。海洋线虫的分类系统仍处在发展和完善中 ,需要发现更多更有价值的共近裔性状用于物种水平和较高分类阶元的分析和鉴定  相似文献