Diverse Range of Mineralization Induced by Phase Separation of Hydrothermal Fluid: Case Study of the Yonaguni Knoll IV Hydrothermal Field in the Okinawa Trough Back-Arc Basin     

Ryohei Suzuki    Jun-Ichiro Ishibashi    Miwako Nakaseama    Uta Konno    Urumu Tsunogai    Kaul Gena  Hitoshi Chiba 《Resource Geology》2008,58(3):267-288

The Yonaguni Knoll IV hydrothermal vent field (24°51′N, 122°42′E) is located at water depths of 1370–1385 m near the western edge of the southern Okinawa Trough. During the YK03–05 and YK04–05 expeditions using the submersible Shinkai 6500, both hydrothermal precipitates (sulfide/sulfate/carbonate) and high temperature fluids (Tmax = 328°C) presently venting from chimney‐mound structures were extensively sampled. The collected venting fluids had a wide range of chemistry (Cl concentration 376–635 mmol kg^?1), which is considered as evidence for sub‐seafloor phase separation. While the Cl‐enriched smoky black fluids were venting from two adjacent chimney‐mound structures in the hydrothermal center, the clear transparent fluids sometimes containing CO₂ droplet were found in the peripheral area of the field. This distribution pattern could be explained by migration of the vapor‐rich hydrothermal fluid within a porous sediment layer after the sub‐seafloor phase separation. The collected hydrothermal precipitates demonstrated a diverse range of mineralization, which can be classified into five groups: (i) anhydrite‐rich chimneys, immature precipitates including sulfide disseminations in anhydrite; (ii) massive Zn‐Pb‐Cu sulfides, consisting of sphalerite, wurtzite, galena, chalcopyrite, pyrite, and marcasite; (iii) Ba‐As chimneys, composed of barite with sulfide disseminations, sometimes associated with realgar and orpiment overgrowth; (iv) Mn‐rich chimneys, consisting of carbonates (calcite and magnesite) and sulfides (sphalerite, galena, chalcopyrite, alabandite, and minor amount of tennantite and enargite); and (v) pavement, silicified sediment including abundant native sulfur or barite. Sulfide/sulfate mineralization (groups i–iii) was found in the chimney–mound structure associated with vapor‐loss (Cl‐enriched) fluid venting. In contrast, the sulfide/carbonate mineralization (group iv) was specifically found in the chimneys where vapor‐rich (Cl‐depleted) fluid venting is expected, and the pavement (group v) was associated with diffusive venting from the seafloor sediment. This correspondence strongly suggests that the subseafloor phase separation plays an important role in the diverse range of mineralization in the Yonaguni IV field. The observed sulfide mineral assemblage was consistent with the sulfur fugacity calculated from the FeS content in sphalerite/wurtzite and the fluid temperature for each site, which suggests that the shift of the sulfur fugacity due to participation of volatile species during phase separation is an important factor to induce diverse mineralization. In contrast, carbonate mineralization is attributed to the significant mixing of vapor‐rich hydrothermal fluid and seawater. A submarine hydrothermal system within a back‐arc basin in the continental margin may be considered as developed in a geologic setting favorable to a diverse range of mineralization, where relatively shallow water depth induces sub‐seafloor phase separation of hydrothermal fluid, and sediment accumulation could enhance migration of the vapor‐rich hydrothermal fluid.  相似文献   

Response of a phytoplankton community to nutrient addition under different CO2 and pH conditions     

Takeo Hama  Tomoki Inoue  Risa Suzuki  Hiroto Kashiwazaki  Shigeki Wada  Daisuke Sasano  Naohiro Kosugi  Masao Ishii 《Journal of Oceanography》2016,72(2):207-223

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Box model analysis on phytoplankton production and grazing pressure in a eutrophic estuary   总被引：1，自引：0，他引：1  

Teruaki Suzuki  Katsuya Ishii  Kazumasa Imao  Yasuo Matsukawa 《Journal of Oceanography》1987,43(5):261-275

To determine the quantitative relationship between phytoplankton production and zooplankton grazing pressure in Atsumi Bay, a eutrophic and partially-mixed estuary, a series of investigations, including measurements of hydrographic conditions, dissolved oxygen, dissolved total nitrogen, particulate organic nitrogen, and phyto- and zooplankton biomass were conducted 13 times at intervals of 2–7 days in June and July 1984. Continuous measurements of water flow and salinity were also carried out to examine transverse flow and horizontal diffusivity. The supply of freshwater and nitrogen was estimated from given data. The changes of hydrographic condition, net photosynthetic rate and community primary production were calculated by a two-layered box model analysis. The grazing rate on phytoplankton obtained as the difference between net photosynthetic rate and community primary production was compared to the one estimated from zooplankton biomass and sardine,Sardinops melanosticta, biomass. The agreement between the data was remarkable in the upper layer, showing the grazing pressure on phytoplankton followed phytoplankton production, suggesting that a large part of produced phytoplankton was immediately grazed by zooplankton. Consequently, the community primary production was depressed to a fairly lower level. An important role of nutrient supply and water circulation, to limit phytoplankton production, was also confirmed. Dynamic response observed between the calculated grazing pressure and the biomass of phytoplankton and protozoa was also analyzed.  相似文献   

II-1 On the cross flow turbine for wave power plant (1st report, the characteristics of the turbine in steady air flow)     

Masahiko Akabane  Haruyuki Suzuki  Kunihiko Yamauchi 《Ocean Engineering》1985,12(6):562

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In situ measurement of incoming solar radiation by voluntary ships in the western Pacific     

Naoto Iwasaka  Susumu Kuwashima  Hirotaka Otobe  Kimio Hanawa  Hideki Hagiwara  Ruri Suzuki 《Journal of Oceanography》1994,50(6):713-723

We have been performingin situ measurement of downward short wave radiation (solar radiation) in the western Pacific Ocean in cooperation with voluntary ships since autumn 1990 in order to obtain much more precise knowledge of downward short wave radiation at the sea's surface than before. Preliminary result of the observation from autumn 1990 through spring 1992 is shown in this paper. The comparison of observed daily mean downward short wave radiation with that estimated from observed cloudiness by using Reed (1977) formula is also presented to show the necessity ofin situ measurement in the study of the downward short wave radiation at the sea's surface.  相似文献   

Chemical forms of minor metallic elements in the ocean     

Yukio Sugimura  Yoshimi Suzuki  Yasuo Miyake 《Journal of Oceanography》1978,34(3):93-96

In order to clarify the chemical forms of minor metallic elements occurring in the ocean, a new method of separation of organic compounds of metals in sea water by using XAD-2 resin was contrived. By applying the new method of determination, it is found that, (1) More than 80 % of V, Fe, Cd and Cu dissolved in sea water are present in organic forms regardless of the depth; (2) A most part of Co and Pb are present in organic forms near the surface, but they change into inorganic forms in the deep layer up to 50 to 60%; (3) Of the total amounts of dissolved Al, Ni, Zn, Ag, Mo, and U, less than 30 % are present in organic forms in sea water anywhere in the ocean; (4) Up to 45% of Se is in organic forms.  相似文献   

Criterion for stability of phytoplankton patchiness using a Liapunov method     

Michio J. Kishi  Hideaki Suzuki 《Journal of Oceanography》1978,34(6):276-287

A criterion for the stability of plankton patchiness is developed using a Liapunov function. Plankton growth, advection and diffusion in a closed area are considered. A critical length scale for the stability does not exist but a more common criterion which contains the growth rateα, diffusion coefficientA _l and arbitrary function of growthf can be introduced in an integral form.  相似文献   

Benthic Front and the Yamato Basin Bottom Water in the Japan Sea     

Tomoharu?SenjyuEmail author  Yutaka?Isoda  Takafumi?Aramaki  Shigeyoshi?Otosaka  Shinzo?Fujio  Daigo?Yanagimoto  Takashi?Suzuki  Kenshi?Kuma  Kosuke?Mori 《Journal of Oceanography》2005,61(6):1047-1058

Hydrographic observations have revealed detailed structure of the Bottom Water in the Japan Sea. The Yamato Basin Bottom Water (YBBW) exhibits higher temperatures and lower dissolved oxygen concentrations than those found in the Japan Basin Bottom Water (JBBW). Both Bottom Waters meet around the boundary region between the Yamato and the Japan Basins, forming a clear benthic front. The structure of the benthic front suggests an estuary-like water exchange between both Basins, with the inflow from the Japan Basin passing under the outflow from the Yamato Basin. It is inferred from the property distributions that the JBBW flowing into the Yamato Basin is entrained by the cyclonic circulation in the basin, and modified to become the YBBW. Vertical diffusion and thermal balance in the YBBW are examined using a box model. The results show that the effect of geothermal heating has about 70% of the magnitude of the vertical thermal diffusion and both terms cancel the advection term of the cold JBBW from the Japan Basin. The box model also estimates the turnover time and vertical diffusivity for the YBBW as 9.1 years and 3.4 × 10⁻³ m²s^{− 1}, respectively.  相似文献   

Stable isotope and chemical composition of pearls: Biomineralization in cultured pearl oysters in ago bay, Japan     

Hodaka Kawahata  Mayuri Inoue  Masato Nohara  Atsushi Suzuki 《Journal of Oceanography》2006,62(4):405-412

The δ¹⁸O, δ¹³C and trace element composition of pearls collected from Ago Bay, Japan, were investigated in order to evaluate biomineralization in the cultured pearl oyster (Pinctada fucata martensii). The oxygen isotopic data suggest that the pearls were produced around 23–24°C, mainly in June to early July, which is consistent with their occurrence in the field. Therefore the pearls were produced under or close to isotopic equilibrium conditions, although they showed high calcification rates (higher than 0.2–1.0 g cm^{− 2}yr⁻¹) under which, for example, coral skeletons (calcification rate ∼0.28 g cm^{− 2}yr⁻¹) often show non-equilibrium isotope partitioning. The δ¹³C values were ∼− 2.9‰ lower than those calculated for offshore waters under equilibrium conditions. This may be due to low-δ¹³C bottom waters resulting from the degradation of organic matter (OM) or to a contribution of low-δ ¹³C food. In the latter case, a simple mass balance calculation gives a respiration component of 14%. Twelve trace elements of bulk pearl samples were classified into four groups on the basis of their enrichment/depletion patterns relative to seawater and inter-element relationships: group 1, Co, Cr, Pb; group 2, Ba, Cs, U; group 3, Cu, Sn, V, and group 4, Mn, Rb, Mo. Comparison with coral skeletons suggests that Ba and Mn (groups 2 and 4) were definitely much enriched in proteinaceous OM relative to aragonite crystals in pearls and that V (group 3) in pearls showed only slight enrichment in the organicrich layer. By contrast, the other elements showed small differences between both layers (enrichment factor of <3), suggesting that these elements occur largely in aragonite crystals.  相似文献   

A Box Model of Glacial-Interglacial Variability in the Japan Sea   总被引：2，自引：0，他引：2  

M. Ikeda  F. Suzuki  T. Oba 《Journal of Oceanography》1999,55(4):483-492

The Japan Sea has experienced drastic changes in the last 60 ka: the surface water was colder than the present value by five degrees and extremely freshened (24 ppt) in the last glacial maximum (15 ka), and then it contained Oyashio water for a few thousand years. It is an open question whether the inflow-outflow pattern was entirely reversed, opposite to the present exchange with an inflow through Tsushima Strait and an outflow through Tsugaru Strait. A box model is employed with two boxes representing the northern and the southern half domains in the upper (300-m-thick) layer. The model is driven by atmospheric forcing and inflow through Tsushima Strait and/or Tsugaru Strait. Here, the net transport through Tsushima to Tsugaru is given in the model. A baroclinic component is added to the net transport through each strait. It is the baroclinic components that allow the upper and the lower portions to flow to the opposite directions in the straits, and hence a reversal flow becomes possible against the net transport, under the condition of an extremely freshened Japan Sea. The fresh surface layer in 1814 ka is attributable to a near-shutoff of the inflow due to the low sea level. Shortly after the near-shutoff, the baroclinic transport through Tsugaru Strait yields intrusion of the Oyashio water into the Japan Sea. Thus, it is implied that Oyashio water existed in the Japan Sea a few thousand years after the reopening of Tsugaru Strait, even though the net transport was one-way, similar to the present state.  相似文献