Release of sulfur- and oxygen-bound components from a sulfur-rich kerogen during simulated maturation by hydrous pyrolysis     

Anke Putschew  Christine Schaeffer-Reiss  Philippe Schaeffer  Martin P Koopmans  Jan W de Leeuw  Michael D Lewan  Jaap S Sinninghe Damsté  James R Maxwell 《Organic Geochemistry》1998,29(8):1875-1890

An immature sulfur-rich marl from the Gessosso-solfifera Formation of the Vena del Gesso Basin (Messinian, Italy) has been subjected to hydrous pyrolysis (160 to 330°C) to simulate maturation under natural conditions. The kerogen of the unheated and heated samples was isolated and the hydrocarbons released by selective chemical degradation (Li/EtNH₂ and HI/LiAlH₄) were analysed to allow a study of the fate of sulfur- and oxygen-bound species with increasing temperature. The residues from the chemical treatments were also subjected to pyrolysis–GC to follow structural changes in the kerogens. In general, with increasing hydrous pyrolysis temperature, the amounts of sulfide- and ether-bound components in the kerogen decreased significantly. At the temperature at which the generation of expelled oil began (260°C), almost all of the bound components initially present in the unheated sample were released from the kerogen. Comparison with an earlier study of the extractable organic matter using a similar approach and the same samples provides molecular evidence that, with increasing maturation, solvent-soluble macromolecular material was initially released from the kerogen, notably as a result of thermal cleavage of weak carbon–heteroatom bonds (sulfide, ester, ether) even at temperatures as low as 220°C. This solvent-soluble macromolecular material then underwent thermal cleavage to generate hydrocarbons at higher temperatures. This early generation of bitumen may explain the presence of unusually high amounts of extractable organic matter of macromolecular nature in very immature S-rich sediments.  相似文献   

The end of moai quarrying and its effect on Lake Rano Raraku, Easter Island     

Henri J. Dumont  Christine Cocquyt  Michel Fontugne  Maurice Arnold  Jean-Louis Reyss  Jan Bloemendal  Frank Oldfield  Cees L.M. Steenbergen  Henk J. Korthals  Barbara A. Zeeb 《Journal of Paleolimnology》1998,20(4):409-422

We reconstruct aspects of the history of Easter Island over the last 4-5 centuries based on the study of a core from Rano Raraku Lake, situated in the crater that contains the quarry of the island's giant statues or moai. We use microfossils of plants and animals to identify five zones. The last three of these are separated by waves of immigration from South America and from the subantarctic. We argue that the first or South American wave, dated to the second half of the 14th century, may represent a visit by South American Indians. Magnetic information, pollen, diatoms, chrysophyte stomatocysts and fossil plant pigments reveal a synchronism between the South American contact and the cessation of moai quarrying. We therefore suggest that Amerindians contributed to the cultural collapse of the island. The second or subantarctic wave may reflect an early European visit to the island, possibly by Cpt. James Cook in 1774, or by Jacob Roggeveen in 1722.  相似文献   

Large earthquakes in the macquarie ridge complex: Transitional tectonics and subduction initiation   总被引：1，自引：0，他引：1  

Larry J. Ruff  Jeffrey W. Given  Chris O. Sanders  Christine M. Sperber 《Pure and Applied Geophysics》1989,129(1-2):71-129

While most aspects of subduction have been extensively studied, the process of subduction initiation lacks an observational foundation. The Macquarie Ridge complex (MRC) forms the Pacific-Australia plate boundary between New Zealand to the north and the Pacific-Australia-Antarctica triple junction to the south. The MRC consists of alternating troughs and rises and is characterized by a transitional tectonic environment in which subduction initiation presently occurs. There is a high seismicity level with 15 large earthquakes (M>7) in this century. Our seismological investigation is centered on the largest event since 1943: the 25 MAY 1981 earthquake. Love, Rayleigh, andP waves are inverted to find: a faulting geometry of right-lateral strike-slip along the local trend of the Macquarie Ridge (N30°E); a seismic moment of 5×10²⁷ dyn cm (M _w=7.7) a double event rupture process with a fault length of less than 100km to the southwest of the epicenter and a fault depth of less than 20km. Three smaller thrust earthquakes occurred previous to the 1981 event along the 1981 rupture zone; their shallow-dipping thrust planes are virtually adjacent to the 1981 vertical fault plane. Oblique convergence in this region is thus accommodated by a dual rupture mode of several small thrust events and a large strike-slip event. Our study of other large MRC earthquakes, plus those of other investigators, produces focal mechanisms for 15 earthquakes distributed along the entire MRC; thrust and right-lateral strike-slip events are scattered throughout the MRC. Thus, all of the MRC is characterized by oblique convergence and the dual rupture mode. The true best-fit rotation pole for the Pacific-Australia motion is close to the Minster & Jordan RM2 pole for the Pacific-India motion. Southward migration of the rotation pole has caused the recent transition to oblique convergence in the northern MRC. We propose a subduction initiation process that is akin to crack propagation; the 1981 earthquake rupture area is identified as the crack-tip region that separates a disconnected mosaic of small thrust faults to the south from a horizontally continuous thrust interface to the north along the Puysegur trench. A different mechanism of subduction initiation occurs in the southernmost Hjort trench region at the triple junction. newly created oceanic lithosphere has been subducted just to the north of the triple junction. The entire MRC is a soft plate boundary that must accommodate the plate motion mismatch between two major spreading centers (Antarctica-Australia and Pacific-Antarctica). The persistence of spreading motion at the two major spreading centers and the consequent evolution of the three-plate system cause the present-day oblique convergence and subduction initiation in the Macquarie Ridge complex.  相似文献   

Oblique and near collision subduction, Sagami and Suruga Troughs —preliminary results of the French-Japanese 1984 Kaiko cruise, Leg 2     

Kazuaki Nakamura  Vincent Renard  Jacques Angelier  Jacques Azema  Jacques Bourgois  Christine Deplus  Kantaro Fujioka  Yozo Hamano  Philippe Huchon  Hajimu Kinoshita  Pierre Labaume  Yujiro Ogawa  Tetsuzo Seno  Akira Takeuchi  Manabu Tanahashi  Akinori Uchiyama  Jean-Louis Vigneresse 《Earth and Planetary Science Letters》1987,83(1-4)

Leg 2 of the French-Japanese 1984 Kaiko cruise has surveyed the Suruga and the Sagami Troughs, which lie on both sides of the northwestward moving and colliding Izu-Bonin Ridge, the northernmost part of the Philippine Sea plate. The transition from the Nankai Trough to the Suruga Trough is characterized by northward decrease in width of the accretionary prism, in good agreement with the increasing obliquity between the through axis and the direction of the convergence, as the strike of the convergent boundary changes from ENE-NNE to south-north. South of the area, the southern margin of the Zenisu Ridge shows contractional deformations. This supports the interpretation made by the team of Leg 1 who studied the western extension of the area we studied, that it is an intra-oceanic thrusting of the ridge over the Shikoku Basin. In the Sagami Trough, where the relative motion is highly oblique to the plate boundary, active subduction is mostly confined in the east-west trending portions of the trough located south of the Boso Peninsula and along the lower Boso Canyon, near the TTT triple junction. In between, the present motion is mainly right-lateral along the northwest trending Boso escarpment. However, an inactive but recent (Pliocene to lower Pleistocene) accretionary prism exists south of the Boso escarpment, which suggests that the relative motion was more northerly than at present before about 1 Ma ago.  相似文献   

Ecological classification of macrophytes and phytobenthos for rivers in Germany according to the water framework directive   总被引：9，自引：0，他引：9  

Jochen Schaumburg  Christine Schranz  Julia Foerster  Antje Gutowski  Gabriele Hofmann  Petra Meilinger  Susanne Schneider  Ursula Schmedtje 《Limnologica》2004,34(4):283-301

A new assessment system for macrophytes and phytobenthos in German rivers meeting the requirements of the Water Framework Directive (WFD) of the European Community is described. Biocoenotic types based on biological, chemical and hydromorphological data from over 200 river sites covering the main ecoregions, hydromorphological stream types and degradation forms have been defined. For developing a classification system the quality element macrophytes and phytobenthos was divided into three components: macrophytes, benthic diatoms and remaining phytobenthos. For macrophytes seven types including one subtype, for benthic diatoms 14 types including three subtypes and for the remaining phytobenthos five river types were identified. The benthic vegetation at reference condition was described for most of the river types. Degradation is characterised as deviation in benthic vegetation species composition and abundance from the reference biocoenosis. For classification in five ecological status classes, several metrics were developed and used in combination with existing indices. For some of the described river types additional investigations are necessary before a classification system can be developed.  相似文献   

L'ı̂le de la Dominique, à l'origine des avalanches de débris les plus volumineuses de l'arc des Petites AntillesThe Island of Dominica,site for the generation of the most voluminous debris avalanches in the Lesser Antilles Arc     

Anne Le Friant  Georges Boudon  Jean-Christophe Komorowski  Christine Deplus 《Comptes Rendus Geoscience》2002,334(4):235-243

Results from recent fieldwork and the Aguadomar marine survey in the Lesser Antilles clearly indicate that the volcanic field of southern Dominica has experienced three major edifice collapse events. This led to formation of the most voluminous debris avalanches known in the Caribbean Arc. Submarine hummocky morphology with plurikilometric megablocks is characteristic of debris avalanche deposits. We propose that steep slopes on the western Caribbean side of the island and intense hydrothermal alteration lead to recurrent large-scale edifice collapses. Therefore islands in the Lesser Antilles face a non-negligible risk from generation of tsunamis associated with potential future edifice collapse. To cite this article: A. Le Friant et al., C. R. Geoscience 334 (2002) 235–243.  相似文献   

Temporal aspects of the abrasion of microphytic crusts under grain impact   总被引：1，自引：0，他引：1  

Cheryl McKenna Neuman  Christine Maxwell 《地球表面变化过程与地形》2002,27(8):891-908

Wind‐tunnel simulations of the response of two moss crusts to grain impact indicate that, given sufficient time, these surfaces will deteriorate under very low wind velocities only slightly above u_*t for the loose, saltating grains. In parallel with these experiments, the frequency distributions of ultimate strength and penetration energy were determined for each of the two crust types via penetrometry. Pohlia was found to be stronger than Tortula; but, even so, both of these crusts had ultimate strengths 20–350 times higher than the force delivered by a single grain impacting each surface at a velocity of 1 ms^?1. In comparison, the modulus of deformation and penetration energy data were very similar for the two surface types, especially for the weakest areas of crust development. This observation is in accord with the wind‐tunnel simulations that also found no consistent difference in the response of these two crust types to impact. In comparison with crusts formed by clay and salt, fibrous microphytic crusts are morphologically complex and typically weak. The notable elasticity of these surfaces does reduce the force of grain impact, and thereby provides some protection against rupture. One of the central conclusions of this study suggests that not only is the particle kinetic energy at impact important in crust breakdown, but also tiny fractures at points of localized stress concentration contribute to a progressive reduction in the integrity of the filament net. In some of the experiments conducted as part of this study, up to 50 or more minutes of constant bombardment was required to produce small abrasion marks on selected areas of the microphytic crust. This study prepares a foundation for future experiments needed to examine the breakdown of complex crusts formed in nature. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

Contrasting the geochemistry of oxic sediments across ecosystems: a synthesis   总被引：1，自引：0，他引：1  

Leah I. Bendell-Young  Christine A. Thomas  J. R. Pierre Stecko 《Applied Geochemistry》2002,17(12):128

The geochemistry of oxic sediments was contrasted across a range of Canadian aquatic ecosystems; 7 freshwater lakes, (3 circumneutral and 4 acidic), 15 peatlands (5 mineral-rich, 5 moderately-poor and 5 mineral-poor), 9 wetlands (3 oligosaline, 3 mesosaline and 3 euryhaline), an estuary (deposited and suspended sediments) and an intertidal region. Sediments were characterized by a simultaneous extraction that separated sediments into easily reducible (ER) metal (oxyhydroxides of Mn and easily reducible amorphous oxyhydroxides of Fe) and reducible (R) metal (more crystalline forms of oxyhydroxides of Fe), organic matter, and, the concentrations and partitioning of Zn, Cu and Cd associated with these 3 sediment components. Ecosystems were distinct with respect to ER Fe and organic matter [canonical variate analysis (CVA)] with 53% of among system variation in geochemistry attributed to these 2 components. Sediments of peatlands and wetlands contained greater amounts of organic matter whereas sediments of lakes, intertidal and estuarine deposited and suspended sediments were characterized by greater amounts of ER Fe. A further 21% of among system variation could be ascribed to organically bound Fe that was greater in acidic lakes and mineral-rich peatlands as compared to other systems. Concentration and partitioning of Cd within sediments was regionally dependent with 41% of among system variation (CVA) attributed to differences in ER Cd and R Cd. Cadmium from peatlands and lakes located in Ontario was recovered from all 3 sediment components whereas sediment from wetlands, the estuary and the intertidal regions of British Columbia (BC) contained no organically bound Cd with amounts recovered occurring mostly as ER Cd. Lakes and peatlands located in Ontario contained 3–5-fold total Cd as compared to ecosystems located in BC. A further 21% of among ecosystem variation was attributed to Zn partitioning. Zinc in peatland and wetland sediments occurred as R Zn as compared to lake and estuarine deposited sediments where Zn was recovered both as ER and R Zn. Total Zn was also 3–5-fold greater in sediments of systems in Ontario as compared to those sampled in BC. Concentration and partitioning of Cu was similar across all systems with Cu recovered from the organic component of sediment. The geochemistry of surficial oxic sediments with respect to ER Mn, R Fe and organic matter and the geochemical associations among these sediment components is ecosystem and region dependent. For assessing impacts of metals on sediment dwelling biota the geochemical characteristics of the system under study should first be defined.  相似文献   

Rare earth element variations resulting from inversion of pigeonite and subsolidus reequilibration in lunar ferroan anorthosites   总被引：1，自引：0，他引：1  

Odette B. James  Christine FlossJames J. McGee 《Geochimica et cosmochimica acta》2002,66(7):1269-1284

We present results of a secondary ion mass spectrometry study of the rare earth elements (REEs) in the minerals of two samples of lunar ferroan anorthosite, and the results are applicable to studies of REEs in all igneous rocks, no matter what their planet of origin. Our pyroxene analyses are used to determine solid-solid REE distribution coefficients (D = C_REE in low-Ca pyroxene/C_REE in augite) in orthopyroxene-augite pairs derived by inversion of pigeonite. Our data and predictions from crystal-chemical considerations indicate that as primary pigeonite inverts to orthopyroxene plus augite and subsolidus reequilibration proceeds, the solid-solid Ds for orthopyroxene-augite pairs progressively decrease for all REEs; the decrease is greatest for the LREEs. The REE pattern of solid-solid Ds for inversion-derived pyroxene pairs is close to a straight line for Sm-Lu and turns upward for REEs lighter than Sm; the shape of this pattern is predicted by the shapes of the REE patterns for the individual minerals.Equilibrium liquids calculated for one sample from the compositions of primary phases, using measured or experimentally determined solid-liquid Ds, have chondrite-normalized REE patterns that are very slightly enriched in LREEs. The plagioclase equilibrium liquid is overall less rich in REEs than pyroxene equilibrium liquids, and the discrepancy probably arises because the calculated plagioclase equilibrium liquid represents a liquid earlier in the fractionation sequence than the pyroxene equilibrium liquids. “Equilibrium” liquids calculated from the compositions of inversion-derived pyroxenes or orthopyroxene derived by reaction of olivine are LREE depleted (in some cases substantially) in comparison with equilibrium liquids calculated from the compositions of primary phases. These discrepancies arise because the inversion-derived and reaction-derived pyroxenes did not crystallize directly from liquid, and the use of solid-liquid Ds is inappropriate. The LREE depletion of the calculated liquids is a relic of formation of these phases from primary LREE-depleted minerals. Thus, if one attempts to calculate the compositions of equilibrium liquids from pyroxene compositions, it is important to establish that the pyroxenes are primary. In addition, our data suggest that experimental studies have underestimated solid-liquid Ds for REEs in pigeonite and that REE contents of liquids calculated using these Ds are overestimates.Our results have implications for Sm-Nd age studies. Our work shows that if pigeonite inversion and/or subsolidus reequilibration between augite and orthopyroxene occurred significantly after crystallization, and if pyroxene separates isolated for Sm-Nd studies do not have the bulk composition of the primary pyroxenes, then the Sm-Nd isochron age and ε_Nd will be in error.  相似文献   

Comparison of the performance of flow‐routing algorithms used in GIS‐based hydrologic analysis     

John P. Wilson  Christine S. Lam  Yongxin Deng 《水文研究》2007,21(8):1026-1044

Flow direction and specific catchment area were calculated for different flow‐routing algorithms using TAPES‐G and TauDEM. A fuzzy classification was used along with eight topo–climatic attributes to delineate six landscape classes from a 10‐m USGS DEM. A series of maps and tabular outputs were produced to compare flow‐routing predictions in different parts of the study area in the Santa Monica Mountains of southern California. The matched pair t‐test was used to compare the performance of pairs of specific catchment area grids across six user‐defined fuzzy landscape classes. The results show that (1) the ‘source’ cells predicted with the D∞, DEMON, and FD8 algorithms were confined to hilltops; (2) two single flow‐routing algorithms (Rho8, D8) produced poor results; and (3) the choice of flow‐routing algorithm has potentially important consequences for the calculation of upslope contributing areas, sediment transport capacity, topographic wetness, and several other topographic indices. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献