Distribution of trace elements in filtered and non filtered aqueous fractions: Insights from rivers and streams of Sardinia (Italy)     

Rosa Cidu  Franco Frau 《Applied Geochemistry》2009

The distribution of several trace elements in different aqueous fractions has been studied in running waters from Sardinia (Italy). Trace elements and major components were determined in water samples collected at high- and low-discharge from rivers (90 samples) and streams (70 samples). At selected sites, total (non filtered samples) and dissolved (0.4 μm and 0.015 μm pore-size filtered samples) amounts of trace elements were determined, and the composition of the solid matter retained on the filters was investigated for estimating the eventual interrelationship. The elements B, Li, Rb, Sr, Ba, As, Sb, Mo, Tl and U in the studied waters showed small differences between total and dissolved amounts; dissolved concentrations were higher under low flow conditions, when the contribution of rainwater to the rivers was minimum; their concentrations were often correlated with total dissolved solids (TDS), and appeared to be related to the intensity of water-rock interaction processes. The elements Al, Fe, Mn, Pb, Zn, Cd, Cu, Co, Ni, Cs, Y, REE and Th were not related to TDS and/or major ions; they showed higher concentrations under high flow conditions; marked differences occurred between total and dissolved amounts; much lower concentrations were generally observed in the water filtered through 0.015 μm than in the water filtered through 0.4 μm, especially when sampling was carried out after heavy rain events that enhanced the load of solid matter in the water. These observations indicate an aqueous transport via sorption processes on very fine particles, such as Fe-oxide/hydroxide and clay mineral particles, which have been inferred by SEM-EDX analyses of the matter retained on the filters.  相似文献   

Low-pH waters discharging from submarine vents at Panarea Island (Aeolian Islands,southern Italy) after the 2002 gas blast: Origin of hydrothermal fluids and implications for volcanic surveillance     

Franco Tassi  Bruno Capaccioni  Giorgio Caramanna  Daniele Cinti  Giordano Montegrossi  Luca Pizzino  Fedora Quattrocchi  Orlando Vaselli 《Applied Geochemistry》2009

A geochemical survey of thermal waters collected from submarine vents at Panarea Island (Aeolian Islands, southern Italy) was carried out from December 2002 to March 2007, in order to investigate (i) the geochemical processes controlling the chemical composition of the hydrothermal fluids and (ii) the possible relations between the chemical features of the hydrothermal reservoir and the activity of the magmatic system. Compositional data of the thermal water samples were integrated in a hydrological conceptual model, which describes the formation of the vent fluid by mixing of seawater, seawater concentrated by boiling, and a deep, highly-saline end-member, whose composition is regulated by water-rock interactions at relatively high temperature and shows clear clues of magmatic-related inputs. The chemical composition of concentrated seawater was assumed to be represented by that of the water sample having the highest Mg content. The composition of the deep end-member was instead calculated by extrapolation assuming a zero-Mg end-member. The Na–K–Ca geothermometer, when applied to the thermal end-member composition, indicated an equilibrium temperature of approximately 300 °C, a temperature in agreement with the results obtained by gas-geothermometry.  相似文献   

Dynamics of continental collision: influence of the plate contact     

Roberta De Franco  Rob Govers  Rinus Wortel 《Geophysical Journal International》2008,174(3):1101-1120

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Sensitivity analysis of CDOM spectral slope in artificial and natural samples: an application in the central eastern Mediterranean Basin     

Luca Bracchini  Antonio Tognazzi  Arduino Massimo Dattilo  Franco Decembrini  Claudio Rossi  Steven Arthur Loiselle 《Aquatic Sciences - Research Across Boundaries》2010,72(4):485-498

In the past two decades, optical properties of chromophoric dissolved organic matter (CDOM) in marine environments have been extensively studied. Many of these studies report CDOM properties for the offshore environment where this complex mixture of optically active compounds is strongly diluted. Nevertheless, autochthonous and allochthonous sources have been identified and sinks related to photodegradation and bacterial activity have been demonstrated. The calculation of the spectral slope of the CDOM absorption curve has been proven to be useful and is often reported. However, a rigorous uncertainty analysis of the slope calculation is rarely reported. In this paper, we propose a method to evaluate the uncertainty of CDOM spectral slope calculated between 270 and 400 nm, using both naturally sampled and artificial solutions. We use these results to study the ultra-oligotrophic waters of the Mediterranean Sea (central eastern basin), where little is known about CDOM spatial distribution. We show that dilutions of both artificial and natural samples produce a Gaussian distribution of spectral slopes, indicating that consistent values may be determined, with a typical uncertainty of ±0.0004 nm⁻¹ when absorption at 300 nm was greater then 0.1 m⁻¹ (0.1 m pathlength). Comparing the distribution of spectral slopes from central eastern basin samples to a Gaussian distribution, we show differences between measurements that were significantly different. These values allow us to distinguish possible sources (algal derived CDOM), sinks (e.g. photo-bleaching) at different depths. We propose a subdivision of CDOM compounds into refractory and semilabile/refractory pools and evaluate the CDOM spectral slope of algal derived CDOM released at or near deep chlorophyll maximum.  相似文献   

New Ar–Ar age constraints on the deformation along the Machaoying fault zone: Implications for Early Cambrian tectonism in the North China Craton     

Yigui  Shihong  Franco  Yu  Yuanhou   《Gondwana Research》2009,16(2):255

The Machaoying fault zone extends along the southern margin of the North China Craton (NCC) and controlled the regional structures and hydrothermal mineral systems in this area. The fault underwent at least two major deformational phases, as revealed by macro- and micro-structural observations from a well-developed segment of the fault in the Hongzhuang–Baitu area, located south of the Xiong'er Mountains. Early ductile deformation is characterized by thrusting from north to south, which was subsequently overprinted by late brittle faulting. Syntectonic strain shadows of biotite are preserved around rotated porphyroclasts of quartz amygdales in mylonite. The biotite yields a ⁴⁰Ar–³⁹Ar plateau age of 524.9 ± 1.9 Ma, which is interpreted as the time of regional thrusting along the Machaoying fault zone. The thrusting may be temporally correlated with an Early Cambrian discontinuity in sedimentation observed in the rocks sequences of the NCC, suggesting a compressional regime in this area and a craton-wide tectonic event. Many 540–500 Ma tectonic events have been previously identified in the Qinling–Qilian–Kunlun Orogenic Belt of central China and in massifs in northeastern China, both of which surround the NCC, and some of these were interpreted to be associated with assembly of Gondwana. However, paleomagnetic data indicate that the NCC was unlikely to have been connected with Gondwana in the Early Cambrian and thus our new biotite date cannot record deformation along the Gondwanan margin. Dating of K-feldspar from a quartz–K-feldspar vein formed along one of the brittle faults of the Machaoying fault zone yields a much younger ⁴⁰Ar–³⁹Ar plateau age of 119.5 ± 0.7 Ma. This is a minimum age for the brittle deformation along the southern margin of the NCC, which also overlaps the age of widespread gold and molybdenum mineralization in the region.  相似文献   

Phytoplankton composition indicators for the assessment of eutrophication in marine waters: Present state and challenges within the European directives     

Maialen Garmendia  Ángel Borja  Javier Franco  Marta Revilla 《Marine pollution bulletin》2013,66(1-2):7-16

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Upper Ocean Temperatures Hit Record High in 2020     

Lijing CHENG  John ABRAHAM  Kevin ETRENBERTH  John FASULLO  Tim BOYER  Ricardo LOCARNINI  Bin ZHANG  Fujiang YU  Liying WAN  Xingrong CHEN  Xiangzhou SONG  Yulong LIU  Michael EMANN  Franco RESEGHETTI  Simona SIMONCELLI  Viktor GOURETSKI  Gengxin CHEN  Alexey MISHONOV  Jim REAGAN  Jiang ZHU 《大气科学进展》2021,38(4):523-530

The long-term warming of the ocean is a critical indicator of both the past and present state of the climate system. It also provides insights about the changes to come, owing to the persistence of both decadal variations and secular trends,which the ocean records extremely well(Hansen et al., 2011;IPCC, 2013;Rhein et al., 2013;Trenberth et al., 2016;Abram et al., 2019).  相似文献   

Refractor velocity analysis: a signal processing procedure     

Roberto de Franco 《Geophysical Prospecting》2011,59(3):432-454

This paper presents a signal processing procedure to perform refractor velocity analysis. The procedure enables one to obtain the seismic velocity from the refracted wavefield without the picking of refracted arrival times. Two processing procedures are derived, one starting from a seismic interferometric approach and another, from the conventional reciprocal method and generalized reciprocal method approaches. The theoretical equivalence of the two approaches is also demonstrated. The proposed processing procedure is applied to synthetic data in order to test the influence of some procedural parameters and its capability to reconstruct a known velocity model starting from refracted signals, without and with perturbations, in arrival times and noise; finally, it is applied to a field data set.  相似文献   

Geological, geochemical characteristics and isotope systematics of the Longqiao iron deposit in the Lu-Zong volcano-sedimentary basin, Middle-Lower Yangtze (Changjiang) River Valley, Eastern China   总被引：8，自引：0，他引：8  

Zhou Taofa  Wu Mingan  Fan Yu  Duan Chao  Yuan Feng  Zhang Lejun  Liu Jun  Qian Bing  Franco Pirajno  David R. Cooke 《Ore Geology Reviews》2011,43(1):154-169

The Middle-Lower Yangtze (Changjiang) River Valley metallogenic belt is located on the northern margin of the Yangtze Craton of eastern China. Most polymetallic deposits in the Changjiang metallogenic belt are clustered in seven districts where magmatism of Mesozoic age (Yanshanian tectono-thermal event) is particularly extensive. From west to east these districts are: E-dong, Jiu-Rui, Anqing-Guichi, Lu-Zong, Tong-Ling, Ning-Wu and Ning-Zhen. World-class iron ore deposits occur in the Lu-Zong and Ning-Wu ore clusters, which are mainly located in continental fault-bound volcanic-sedimentary basins. One of these deposits is the Longqiao iron deposit, discovered in the northern part of the Lu-Zong Basin in 1985. This deposit consists of a single stratabound and stratiform orebody, hosted in sedimentary carbonate rocks of the Triassic Dongma'anshan Formation. A syenite pluton (Longqiao intrusion) is situated below the deposit. The iron ore is massive and disseminated and the ore minerals are mainly magnetite and minor pyrite. Wall rock alteration mostly consists of skarn minerals, such as diopside, garnet, potassic feldspar, quartz, chlorite, phlogopite and anhydrite. Thin sedimentary siderite beds of Triassic age occur as relict laminated ore at the top and the margin of the magnetite orebody. These sideritic laminae are part of Triassic evaporite-bearing carbonate deposits (Dongma'anshan Formation).Sulfur isotopic compositions show that the sulfur in the deposit was derived from a mixture of magmatic hydrothermal fluids and carbonate–evaporite host rocks. Similarly, the C and O isotopic compositions of limestones from the Dongma'anshan Formation indicate that these rocks interacted with magmatic hydrothermal fluids. The O isotopic compositions of the syenitic rocks and minerals from the deposit show that the hydrothermal magnetite and skarn minerals were formed from magmatic fluids. The Pb isotopic compositions of sulfides are similar to those of the Longqiao syenite. Phlogopite coexisting with magnetite in the magnetite ores yielded a plateau age of 130.5 ± 1.1 Ma (2σ), whereas the LA-ICP MS age of the syenite intrusion is 131.1 ± 1.5 Ma, which is slightly older than the age of phlogopite.The Longqiao syenite intrusion may have crystallized from a parental alkaline magma, generated by partial melting of lithospheric mantle, during extensional tectonics. The ore fluids were probably first derived from magma at depth, later emplaced in the sedimentary rocks of the Dongma'anshan Formation, where it interacted with siderite and evaporite-bearing carbonate strata, resulting in the formation of magnetite and skarn minerals. The Longqiao iron deposit is a skarn-type stratabound and stratiform mineral system, genetically and temporally related to the Longqiao syenite intrusion. The Longqiao syenite is part of the widespread Mesozoic intracontinental magmatism (Yanshanian event) in eastern China, which has been linked to lithospheric delamination and asthenospheric upwelling.  相似文献   

Diatom quantification and their distribution with salinity brines in coastal sediments of Terra Nova Bay (Antarctica)     

Baldi F  Facca C  Marchetto D  Nguyen TN  Spurio R 《Marine environmental research》2011,71(4):304-311

Benthic diatoms represent an important element of global nutritional productivity; to raise attention on their role, which is often neglected due to analytical difficulties, surface (1 cm top layer) coastal sediments from Gerlache inlet to Penguin Bay at Terra Nova Bay were collected and stored at -20 °C. DNA amplification by real-time PCR, based on diatom-specific oligonucleotide primers designed on small-subunit rRNA (SSU rRNA), was performed in addition to diatom conventional cell counting and spectrophotometric determination of photo-pigments. Moreover, cations and anions were determined in sediments with the aim to identify factors involved in the control of diatom abundance. Diatom distribution was found quite heterogeneous displaying significant differences from site to site. The salinity in sediments ranged from 45.1 at Gerlache inlet to 76.2 at Penguin Bay and it was correlated with cell abundance, biodiversity, amount of pigments and amplified DNA. The dominant species, Fragilariopsis curta, was associated to sediment salinity brines.  相似文献