Experimental simulation of Titan's atmosphere: Detection of ammonia and ethylene oxide     

J. -M. Bernard  P. Coll  A. Coustenis  F. Raulin 《Planetary and Space Science》2003,51(14-15):1003

For several years now, an experimental simulation of Titan's atmosphere has been on going at LISA. A cold plasma is established in a gas mixture representative of the atmosphere of the satellite. In these experiments, more than 70 organic compounds have been identified, including the first identification in this type of experimental simulation of C₄N₂ already detected in its solid form on Titan, which suggests that the setup correctly mimics the chemistry of Titan's atmosphere.We have carried out the first experimental simulation including O-containing compounds in order to study the influence of the presence of CO on the chemical behavior of Titan's atmosphere. With the help of gas chromatography–mass spectrometry (GC–MS) and infrared spectroscopy (IRS) we can thus determine which minor species still undetected in Titan's atmosphere are likely to be present and understand the complex chemistry of the atmosphere of this satellite. Surprisingly we have identified unpredicted O-containing gaseous compounds, mainly ethylene oxide (also named oxirane, C₂H₄O). This molecule has been observed in the interstellar medium by observation in the millimeter region (Astrophys. J. 489 (1997) 553; Astron. Astrophys. 337 (1998) 275). On the contrary, the predicted O-compounds (formaldehyde and methanol) have not been identified in this experiment. Furthermore, we have identified NH₃ in the gaseous products with an initial mixture of N₂ (98%) and CH₄ (2%).The paper describes the experimental device used in this work, in particular the IRS and GC–MS techniques. We also comment the results related to the detection of the O-containing compounds and NH₃ and their implications on our knowledge of the chemistry of Titan's atmosphere and on the retrieval of the future Titan data expected from Cassini-Huygens.  相似文献   

Fracture energy release and size effect in borehole breakout     

Zdenk P. Baant  Feng-Bao Lin  Horst Lippmann 《国际地质力学数值与分析法杂志》1993,17(1):1-14

The paper presents a simple approximate analytical solution of the remote stresses that cause the collapse of a borehole or other circular cylindrical cavity in an infinite elastic space. Regions of parallel equidistant splitting cracks are assumed to form on the sides of the cavity. Their boundary is assumed to be an ellipse of a growing horizontal axis, the other axis remaining equal to the borehole diameter. The slabs of rock between the splitting cracks are assumed to buckle as slender columns, and their post-critical stress is considered as the residual stress in the cracked rock. The buckling of these slab columns is assumed to be resisted not only by their elastic bending stiffness but also shear stresses produced on rough crack faces by relative shear displacements. The energy release from the infinite medium caused by the growth of the elliptical cracking region is evaluated according to Eschelby's theorem. This release is set equal to the energy dissipated by the formation of all the splitting cracks, which is calculated under the assumption of constant fracture energy. This yields the collapse stress as a function of the elastic moduli, fracture energy, ratio of the remote principal stresses, crack shear resistance characteristic and borehole diameter. The collapse stress as a function of crack spacing is found to have a minimum, and the correct crack spacing is determined from this minimum. For small enough diameters, the crack spacing increases as the (4/5)-power of the borehole diameter, while for large enough diameters a constant spacing is approached. In contrast to plastic solutions, the breakout stress exhibits a size effect, such that for small enough diameters the breakout stress decreases as the (? 2/5)-power of the borehole diameter, while for large enough diameters a constant limiting value is approached. Finally, some numerical estimates are given and the validity of various simplifying assumptions made is discussed.  相似文献   

A 20 cm2 CCD mosaic camera for a dark matter search part I : Mechanics,optics and cryogeny     

Arnaud  M.  Aubourg  E.  Bareyre  P.  Br';ehin  S.  Caridroit  R.  de Kat  J.  Dispau  G.  Djidi  K.  Gros  M.  Lachièze-Rey  M.  Laigneau  Y.  Laurent  B.  Lesquoy  E.  Lavocat  Ph.  Magneville  C.  Mazeau  B.  Milsztajn  A.  Moscoso  L.  Pasquaud  J.  Paul  B.  Perrin  P.  Petibon  J.  Piret  Y.  Queinnec  F.  Rich  J.  Spiro  M.  de Trogoff  J.  Vigroux  L.  Zylberajch  S.  Ansari  R.  Cavalier  F.  Moniez  M.  Beaulieu  J. P.  Ferlet  R.  Grison  Ph.  Vidal-Madjar  A.  Adrianzyk  G.  Berger  J. P.  Burnage  R.  Delclite  J. C.  Kohler  D.  Magnan  R.  Richaud  A.  Guibert  J.  Moreau  O.  Tajahmady  F.  Baranne  A.  Maurice  E.  Prévôt  L.  Gry  C. 《Experimental Astronomy》1994,4(3-4):265-278

A 20cm ² CCD mosaic camera has been especially built to search for dark galactic halo objects by the gravitational microlensing effect. The sensitive area is made of 16 edge-buttable CCDs developped by Thomson-CTS, with 23×23 µm ² pixels. The 35 kg camera housing and mechanical equipment is presented. The associated electronics and data acquisition system are described in a separate paper. The camera resides at the focal plane of a 40 cm, f/10, Ferson reflector. The instrument has been in operation since December 1991 at the La Silla Observatory (ESO).  相似文献   

The estimation of the shape of an array using a hidden Markov model     

Quinn  B.G. Barrett  R.F. Kootsookos  P.J. Searle  S.J. 《Oceanic Engineering, IEEE Journal of》1993,18(4):557-564

A hidden Markov model (HMM) technique for the estimation of the shape of a towed array is presented. It is assumed that there is a far-field source radiating sound containing possibly weak spectral lines. The technique uses either the Fourier coefficients at a given frequency computed from a single time block or the maximal eigenvector of a sample spectral covariance matrix. The technique is illustrated using several simulations. The results of these simulations indicate that the HMM technique yields shape and bearing estimates more accurate than those provided by a maximum-likelihood array shape estimation technique  相似文献   

Late Oligocene-Miocene syn-/-late-orogenic successions in Western and Central Mediterranean Chains from the Betic Cordillera to the Southern Apennines*     

F. Guerrera  A. Martin-Algarra  V. Perrone 《地学学报》1993,5(6):525-544

The identification of syn- and late-orogenic flysch deposits, extending from the Betic Cordillera to the Southern Apennines, assists in the reconstruction of the tectonic-sedimentary evolution of the perimediterranean chains. A microplate was located between the European and African Plates during the Late Jurassic–Early Cretaceous, bordered northwards by the Piemontese Ocean and southwards by another (North Africa ‘Flysch’ Basin or Maghrebian) Ocean. The Piemontese Ocean and the northern margin of the microplate were structured from the Late Cretaceous to the Eocene to create an Eo-alpine Chain. The southern margin of the microplate was deformed in the Aquitanian, when the internal areas of the Maghrebian Ocean were characterized by syn-orogenic flysch deposits. This episode culminated with metamorphism (25–22 Ma) and nappe emplacement, which destroyed the former palaeogeography and created an orogenic belt (AlKaPeCa). Afterwards, a lower Burdigalian late-orogenic cycle started in the deformed area, which as a result of the opening of the Algero-Provençal Basin, caused the fragmentation of the AlKaPeCa, its thrusting on the ‘Flysch’ Basin and the collision with the North Africa and South Iberia Margins. These latter were folded and thrusted, the ‘Flysch’ Units pushed over the External Domain and also back-thrusted. Langhian late-orogenic deposits suture the new tectonic features. Finally, the whole orogen was thrust onto the foredeep during the Middle–Late Miocene.  相似文献   

Shakedown in layered pavements under moving surface loads     

I. F. Collins  A. P. Wang  L. R. Saunders 《国际地质力学数值与分析法杂志》1993,17(3):165-174

Elastic–plastic deformations in pavements consisting of layers of different frictional materials are investigated. The upper bound, kinematic shakedown theorem is used to obtain estimates of the critical shakedown loads. Fully general three-dimensional deformations are considered. The influence of the loading distribution, interactions between loads, and the effect of varying the thickness, stiffness and strength of the layers are explored. Consequences of this investigation for particular existing designs of flexible pavements are investigated. In particular, it is found that the strength of the subgrade has no effect on the magnitude of the critical shakedown load.  相似文献   

Spectroscopic binaries near the North Galactic Pole paper 18: HD 118670     

R. F. Griffin 《Journal of Astrophysics and Astronomy》1990,11(4):533-540

Photoelectric radial-velocity measurements show that HD 118670 is a double-lined spectroscopic binary in an orbit which is not quite circular and whose period is about 48 days. Spectral types of K0 V and K7 V would satisfy the photometry and the mass ratio; the mass function would then suggest the possibility of eclipses. However, actual spectral classification indicates a luminosity somewhat above the main sequence  相似文献   

Upscaling of elastic properties for large scale geomechanical simulations     

F. Chalon  M. Mainguy  P. Longuemare  P. Lemonnier 《国际地质力学数值与分析法杂志》2004,28(11):1105-1119

Large scale geomechanical simulations are being increasingly used to model the compaction of stress dependent reservoirs, predict the long term integrity of under‐ground radioactive waste disposals, and analyse the viability of hot‐dry rock geothermal sites. These large scale simulations require the definition of homogenous mechanical properties for each geomechanical cell whereas the rock properties are expected to vary at a smaller scale. Therefore, this paper proposes a new methodology that makes possible to define the equivalent mechanical properties of the geomechanical cells using the fine scale information given in the geological model. This methodology is implemented on a synthetic reservoir case and two upscaling procedures providing the effective elastic properties of the Hooke's law are tested. The first upscaling procedure is an analytical method for perfectly stratified rock mass, whereas the second procedure computes lower and upper bounds of the equivalent properties with no assumption on the small scale heterogeneity distribution. Both procedures are applied to one geomechanical cell extracted from the reservoir structure. The results show that the analytical and numerical upscaling procedures provide accurate estimations of the effective parameters. Furthermore, a large scale simulation using the homogenized properties of each geomechanical cell calculated with the analytical method demonstrates that the overall behaviour of the reservoir structure is well reproduced for two different loading cases. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

Geometry and kinematics of recent deformation in the Mondy–Tunka area (south-westernmost Baikal rift zone, Mongolia–Siberia)     

A. Arjannikova  C. Larroque  J. -F. Ritz  J. Déverchère  J. F. Stéphan  S. Arjannikov  V. San'kov 《地学学报》2004,16(5):265-272

We used satellite imagery and field data to investigate the south‐westernmost Baikal rift zone. We focus our study in the Mondy and Ikhe Ukhgun valleys, site of an Mw = 6.9 seismic event in 1950. Surface deformations are observed along the E–W‐trending Mondy strike‐slip fault and along the Ikhe Ukhgun thrust. The Mondy fault system is 80 km long and is composed of four segments 10–15 km long. These segments are characterized by subvertical planes with left‐lateral movements. The Ikhe Ukhgun thrust is 20 km long, dips 40° to the south and shows reverse movement with a left‐lateral component. These observations are consistent with the present‐day regional NNE–SSW compression and with the focal mechanism of the 1950 Mondy earthquake that was recently re‐evaluated. These features, like those observed in the Tunka basin, demonstrate a recent change of regional strain regime from transtension to transpression that we place before the Late Pleistocene.  相似文献   

Preliminary organic petrography of Palaeozoic rocks from the Grand Banks,Newfoundland     

F. Goodarzi  L.R. Snowdon  P.R. Gunther  W.A.M. Jenkins 《Marine and Petroleum Geology》1985,2(3):254-259

Samples of lower Palaeozoic bedrock from the Grand Banks of Newfoundland were examined using reflected light microscopy and Rock-Eval pyrolysis. These samples contained organic material which included bitumen (structureless organic material), acritarchs, chitinozoa, scolecodonts and graptolites. The reflectance of the organic material increased from acritarchs towards graptolites with bitumen showing a wide range of reflectance. Multiple phases of oil migration through one sample were inferred by examination of the bitumens: the lowest reflecting being more recent than the highest reflecting bitumen. Combined reflectance and Rock-Eval analysis indicate that these samples are mature to overmature. The two oldest samples (Arenig-Llanvirn, Ordovician) are assessed as mature and as having potential for generation of liquid hydrocarbons, but must be considered as mainly gas prone.  相似文献